Evaluation of Transition Metal Catalysts in Electrochemically Induced Aromatic Phosphonation
Abstract
:1. Introduction
2. Results and Discussion
2.1. Oxidative Conditions
2.2. Electroreduction Conditions
3. Materials and Methods
3.1. Cyclic Voltammetry
3.2. Synthesis of the Metal Complexes
3.3. Data Processing of Voltammetric Measurements of Complexes
4. Conclusions
Supplementary Materials
Author Contributions
Funding
Acknowledgments
Conflicts of Interest
References
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Sample Availability: Samples of the all compounds are available from the authors. |
Catalytic System | Ratio [Complex:DEP] | ic/ip (v = 0.1V/s) | TOF, s−1 |
---|---|---|---|
CoCl2bpy: HP(O)(OEt)2 | 1:144 | - | - |
Ni(BF4)2bpy: HP(O)(OEt)2 | 1:72 | 1.3 | 160 |
MnCl2bpy: HP(O)(OEt)2 | 1:196 | 3.6 | 355 |
MnCl2bpy/Ni(BF4)2bpy: HP(O)(OEt)2 | 1:180 | 6.1 | 690 |
MnCl2bpy/CoCl2bpy: HP(O)(OEt)2 | 1:180 | - | - |
CoCl2bpy/Ni(BF4)2bpy: HP(O)(OEt)2 | 1:24 | 2.7 | 721 |
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Strekalova, S.; Khrizanforov, M.; Budnikova, Y. Evaluation of Transition Metal Catalysts in Electrochemically Induced Aromatic Phosphonation. Molecules 2019, 24, 1823. https://doi.org/10.3390/molecules24091823
Strekalova S, Khrizanforov M, Budnikova Y. Evaluation of Transition Metal Catalysts in Electrochemically Induced Aromatic Phosphonation. Molecules. 2019; 24(9):1823. https://doi.org/10.3390/molecules24091823
Chicago/Turabian StyleStrekalova, Sofia, Mikhail Khrizanforov, and Yulia Budnikova. 2019. "Evaluation of Transition Metal Catalysts in Electrochemically Induced Aromatic Phosphonation" Molecules 24, no. 9: 1823. https://doi.org/10.3390/molecules24091823