Preparation of Magnetic Polymers for the Elimination of 3-Isobutyl-2-methoxypyrazine from Wine
ARC Training Centre for Innovative Wine Production and School of Agriculture, Food and Wine, The University of Adelaide, Waite Campus, PMB 1, Glen Osmond SA 5064, Australia
*
Author to whom correspondence should be addressed.
Molecules 2018, 23(5), 1140; https://doi.org/10.3390/molecules23051140
Received: 27 April 2018
/
Revised: 4 May 2018
/
Accepted: 8 May 2018
/
Published: 10 May 2018
(This article belongs to the Collection Wine Chemistry)
3-Isobutyl-2-methoxypyrazine (IBMP), the most prevalent grape-derived methoxypyrazine, can contribute green bell pepper, vegetative and herbaceous aromas and flavours to wines. At elevated concentrations, this potent odorant may mask desirable fruity and floral aromas in wine and may be considered as a fault. A new remediation method for wines with elevated IBMP levels has been trialled using magnetic polymers, prepared in the same way as ordinary polymers but with the incorporation of iron oxide nanoparticles as magnetic substrates. Characterisation by Fourier transform-infrared (FTIR) spectroscopy and scanning electron microscopy (SEM) showed no difference between thermally synthesised and microwave synthesised polymers. Magnetic polymers were found to have removed over 40% of the IBMP present in spiked model wine and white wine within ten minutes. The addition of magnetic nanoparticles and microwave-induced polymerisation did not affect the adsorption properties of the polymer in model wine and the polymer could be regenerated at least five times. Both Langmuir and Freundlich isotherms were found to fit the data for both types of polymer. However, attempts to produce imprinted polymers were not achieved, as they were found not to be differentiated from non-imprinted counterparts via adsorption tests.
View Full-Text
▼
Show Figures
Figure 1
This is an open access article distributed under the Creative Commons Attribution License which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited
- Supplementary File 1:
PDF-Document (PDF, 413 KiB)
MDPI and ACS Style
Liang, C.; Jeffery, D.W.; Taylor, D.K. Preparation of Magnetic Polymers for the Elimination of 3-Isobutyl-2-methoxypyrazine from Wine. Molecules 2018, 23, 1140. https://doi.org/10.3390/molecules23051140
AMA Style
Liang C, Jeffery DW, Taylor DK. Preparation of Magnetic Polymers for the Elimination of 3-Isobutyl-2-methoxypyrazine from Wine. Molecules. 2018; 23(5):1140. https://doi.org/10.3390/molecules23051140
Chicago/Turabian StyleLiang, Chen, David W. Jeffery, and Dennis K. Taylor. 2018. "Preparation of Magnetic Polymers for the Elimination of 3-Isobutyl-2-methoxypyrazine from Wine" Molecules 23, no. 5: 1140. https://doi.org/10.3390/molecules23051140
Find Other Styles
Note that from the first issue of 2016, MDPI journals use article numbers instead of page numbers. See further details here.
