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Molecules 2018, 23(4), 946; https://doi.org/10.3390/molecules23040946

Zeta Potential of Beta Zeolites: Influence of Structure, Acidity, pH, Temperature and Concentration

1
Laboratory of Industrial Chemistry and Reaction Engineering, Faculty of Science and Engineering, Johan Gadolin Process Chemistry Centre, Åbo Akademi University, FI-20500 Turku/Åbo, Finland
2
Chuiko Institute of Surface Chemistry, National Academy of Sciences of Ukraine, 03164 Kiev, Ukraine
3
National Institute of Chemical Physics and Biophysics, Akadeemia tee 23, 12618 Tallinn, Estonia
*
Author to whom correspondence should be addressed.
Received: 11 March 2018 / Revised: 11 April 2018 / Accepted: 13 April 2018 / Published: 18 April 2018
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Abstract

Measurements of the zeta potential of solid heterogeneous supports are important for preparation of metal supported catalysts and for shaping zeolites into extrudates. In the current work, different types of heterogeneous support materials such as SiO2, Al2O3, and a range of beta zeolites of different silica- to-alumina ratio were analysed. It was observed that parameters such as temperature, pH and acidity significantly affect the zeta potential. In several instances, depending on the materials’ acidity and microstructure, maxima in zeta potential were observed. The solid materials were thoroughly characterized using XRD, SEM, EDX, TEM, nitrogen physisorption, Al-NMR and FTIR with pyridine before zeta potential measurements. View Full-Text
Keywords: zeolites; beta; zeta potential zeolites; beta; zeta potential
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This is an open access article distributed under the Creative Commons Attribution License which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited (CC BY 4.0).
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Liu, X.; Mäki-Arvela, P.; Aho, A.; Vajglova, Z.; Gun’ko, V.M.; Heinmaa, I.; Kumar, N.; Eränen, K.; Salmi, T.; Murzin, D.Y. Zeta Potential of Beta Zeolites: Influence of Structure, Acidity, pH, Temperature and Concentration. Molecules 2018, 23, 946.

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