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Technical Note

Synthesis and Structural Identification of a Biaryl Ether-Linked Zearalenone Dimer

1
Department Analytical Chemistry, Reference Materials, Bundesanstalt für Materialforschung und -prüfung (BAM), Richard-Willstätter-Straße 11, 12489 Berlin, Germany
2
Department of Food Chemistry and Toxicology, Technische Universität Berlin, Gustav-Meyer-Allee 25, 13355 Berlin, Germany
*
Author to whom correspondence should be addressed.
Molecules 2018, 23(10), 2624; https://doi.org/10.3390/molecules23102624
Submission received: 14 September 2018 / Revised: 8 October 2018 / Accepted: 11 October 2018 / Published: 12 October 2018
(This article belongs to the Collection Advances in Food Analysis)

Abstract

A new dimer of the food-relevant mycotoxin zearalenone was isolated after electrochemical and chemical oxidation. The structure was determined as a 16-O-15′-biaryl ether-linked dimer based on spectroscopic analyses (1H- and 13C-NMR, COSY, HMBC, and HSQCAD) and high-resolution mass spectrometry analysis (Q-TOF).
Keywords: mycotoxin; dimerization; HRMS; NMR mycotoxin; dimerization; HRMS; NMR

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MDPI and ACS Style

Keller, J.; Hantschke, L.; Haase, H.; Koch, M. Synthesis and Structural Identification of a Biaryl Ether-Linked Zearalenone Dimer. Molecules 2018, 23, 2624. https://doi.org/10.3390/molecules23102624

AMA Style

Keller J, Hantschke L, Haase H, Koch M. Synthesis and Structural Identification of a Biaryl Ether-Linked Zearalenone Dimer. Molecules. 2018; 23(10):2624. https://doi.org/10.3390/molecules23102624

Chicago/Turabian Style

Keller, Julia, Luisa Hantschke, Hajo Haase, and Matthias Koch. 2018. "Synthesis and Structural Identification of a Biaryl Ether-Linked Zearalenone Dimer" Molecules 23, no. 10: 2624. https://doi.org/10.3390/molecules23102624

APA Style

Keller, J., Hantschke, L., Haase, H., & Koch, M. (2018). Synthesis and Structural Identification of a Biaryl Ether-Linked Zearalenone Dimer. Molecules, 23(10), 2624. https://doi.org/10.3390/molecules23102624

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