Next Article in Journal
Purification and Characterization of Chitinases from Ridgetail White Prawn Exopalaemon carinicauda
Next Article in Special Issue
Preparation of a Titania/X-Zeolite/Porous Glass Composite Photocatalyst Using Hydrothermal and Drop Coating Processes
Previous Article in Journal
Characterization of Four Popular Sweet Cherry Cultivars Grown in Greece by Volatile Compound and Physicochemical Data Analysis and Sensory Evaluation
Previous Article in Special Issue
Energy and Molecules from Photochemical/Photocatalytic Reactions. An Overview
Open AccessArticle

Visible Light Induced Green Transformation of Primary Amines to Imines Using a Silicate Supported Anatase Photocatalyst

School of Chemistry, Physics and Mechanical Engineering, Science and Engineering Faculty, Queensland University of Technology, Brisbane QLD 4001, Australia
*
Author to whom correspondence should be addressed.
Academic Editor: Pierre Pichat
Molecules 2015, 20(2), 1941-1954; https://doi.org/10.3390/molecules20021941
Received: 30 October 2014 / Accepted: 22 January 2015 / Published: 26 January 2015
(This article belongs to the Special Issue Photocatalysis)
Catalytic oxidation of amine to imine is of intense present interest since imines are important intermediates for the synthesis of fine chemicals, pharmaceuticals, and agricultural chemicals. However, considerable efforts have been made to develop efficient methods for the oxidation of secondary amines to imines, while little attention has until recently been given to the oxidation of primary amines, presumably owing to the high reactivity of generated imines of primary amines that are easily dehydrogenated to nitriles. Herein, we report the oxidative coupling of a series of primary benzylic amines into corresponding imines with dioxygen as the benign oxidant over composite catalysts of TiO2 (anatase)-silicate under visible light irradiation of λ > 460 nm. Visible light response of this system is believed to be as a result of high population of defects and contacts between silicate and anatase crystals in the composite and the strong interaction between benzylic amine and the catalyst. It is found that tuning the intensity and wavelength of the light irradiation and the reaction temperature can remarkably enhance the reaction activity. Water can also act as a green medium for the reaction with an excellent selectivity. This report contributes to the use of readily synthesized, environmentally benign, TiO2 based composite photocatalyst and solar energy to realize the transformation of primary amines to imine compounds. View Full-Text
Keywords: benzylamine; imine; visible light; anatase; silicate benzylamine; imine; visible light; anatase; silicate
Show Figures

Graphical abstract

MDPI and ACS Style

Zavahir, S.; Zhu, H. Visible Light Induced Green Transformation of Primary Amines to Imines Using a Silicate Supported Anatase Photocatalyst. Molecules 2015, 20, 1941-1954.

Show more citation formats Show less citations formats

Article Access Map by Country/Region

1
Only visits after 24 November 2015 are recorded.
Back to TopTop