Open and Periodic Boundary Conditions in Statistical Mechanics: A Case Study of the Antiferromagnetic Ising Chain

The transfer-matrix method is employed to investigate a spin-1/2 Ising chain under open and periodic boundary conditions. It is demonstrated that finite-size Ising chains with antiferromagnetic coupling may exhibit significantly distinct magnetic behavior under open and periodic boundary conditions. While the open Ising chains display intriguing magnetic features regardless of the system size, mainly due to a specific contribution of boundary spins, the magnetic behavior of closed Ising chains depends basically on the number of spins. The closed Ising chains with an odd number of spins are subject to a geometric spin frustration leading to an additional plateau in the magnetization curve, which is naturally absent in the closed Ising chains with an even number of spins. Despite different microscopic origins, the magnetization curves of open and closed Ising chains with an odd number of spins exhibit an identical intermediate plateau, with only small quantitative differences appearing at moderate temperatures, which means that a geometric spin frustration of odd-membered rings is somewhat similar to the effect of open boundaries. The magnetization curves of the open Ising chains with an even number of spins differ drastically from those of the closed Ising chains due to the presence of an additional intermediate magnetization plateau. Furthermore, the initial susceptibility, inverse initial susceptibility, and susceptibility–temperature product are examined in detail as functions of temperature. These magnetic response functions demonstrate that the Curie constant and Weiss temperature represent fundamental characteristics of the magnetic system that are independent of the choice of boundary conditions.