Search Results (22)

The Jinqingding gold deposit, characterized as an extra-large quartz-vein-type deposit, is located in the middle of the Mouping–Rushan metallogenic belt in the Jiaodong Peninsula, and there is still controversy over its sources of ore-forming materials and fluids. This paper divides the mineralization of Jinqinding gold deposits into four stages, based on a field geological investigation and indoor petrographic observations: (1) coarse-grained pyrite–quartz stage, (2) quartz–fine-grained pyrite stage, (3) quartz–polymetallic sulfide stage, and (4) quartz–carbonate stage. The quartz fluid inclusions showed δD values of −96.0 to −81.8‰ and δO_V-SMOW values of 0.70 to 6.32‰, indicating that the ore-forming fluids were mainly magmatic water, with some metamorphic water and atmospheric precipitation. The in situ δ³⁴S values in different subzones of the pyrites of the Jinqingding gold deposit range from 6.69 to 10.86‰. The δ³⁴S value range of the Jinqingding gold deposit is basically consistent with the contemporaneous intermediate–basic dikes in the region, suggesting a shared material source. In situ LA-ICP-MS geochemical analyses of the pyrites show large variations of Co/Ni ratios (0.21 to 99.5), which suggest a hydrothermal origin for the gold deposit. We infer that the ore-forming fluid of the Jinqingding gold deposit originated from the magma from the upper mantle and the mantle–crust transition zone. Full article

The mineralization and geochemical features of the Tolparovo ore occurrence are studied to reveal the contribution of diagenetic and epigenetic processes in the formation of copper mineralization in redbed deposits. The methods of electron microscopy, ICP MS, X-ray fluorescence, X-ray phase, atomic absorption, thermogravimetric analyses, and C and O isotopic composition were used. The ore is confined to the fault zone and feathering dolomite–calcite veins, having formed at temperatures of ~330–200 °C and pressures of 0.8–0.2 kbar. Similar to other copper redbed occurrences of the Bashkirian uplift, the Tolparovo copper ore occurrence is confined to basal Neoproterozoic deposits. Siliciclastic and carbonate deposits of this level were accumulated at low paleoequator latitudes in arid climates of continental and coastal–marine environments close to evaporite ones. Rocks of this stratigraphic interval demonstrate increased background concentrations of copper (~2–5 times exceeding the clark), which explains the stratification of redbed copper ore occurrences, indicating a predominantly sedimentary copper source. However, most of the redbed copper ore occurrences of the Bashkirian uplift are located in tectonic zones and are associated with the dikes of the Inzer gabbrodolerite complex. This connects the generation of ore occurrences with the formation of the Southern Urals Arsha Large Igneous Province (707–732 Ma) and the activity of postmagmatic fluids. Magmatic processes were presumably activated due to the collapse of the Rodinia supercontinent. It is shown that copper mineralization in stratiform deposits may result from a joint manifestation of dia- and epigenesis processes. Full article

Geological, mineralogical, and petrological observations are reported for hornfels-like fine-grained granular mafic rocks in the Early Paleozoic Olkhon collisional orogen (West Baikal area, Russia). The rocks are composed of orthopyroxene, clinopyroxene, amphibole, plagioclase, and ilmenite; some samples also contain olivine, phlogopite, spinel, and titanomagnetite (Opx+Cpx+Amp+Pl+Ilm±Ol±Bt±Spl±Ti-Mag). There are three occurrences of these rocks in the area: a 500 m × 1000 m field in the Shirokaya Valley, another occurrence within the Tazheran Massif (a complex of igneous and metamorphic rocks), and dismembered dikes on the southern margin of the Birkhin gabbro intrusion. The Shirokaya field is located between two 500 Ma intrusions of the Birkhin gabbro; the Tazheran occurrence coexists with syenite, including nepheline syenite, subalkaline gabbro, and marble protrusions; and the dismembered dikes coexist with carbonates and display progressive alteration of dolerite through typical granular varieties. The dikes associated with granite and marble veins mark a part of a large arc-shaped shear zone that traverses the whole intrusive body produced by rotation of a rigid gabbro block during the peak of tectonic deformation at 470–460 Ma. All three occurrences of the hornfels-like rocks lack any evident source of heat that would be responsible for the thermal alteration of the igneous protolith. We hypothesize that the precursor, subvolcanic dolerite, may have undergone autometamorphism maintained by self-generated heat. Mafic magma intruded during high-rate strike–slip faulting, which caused rapid recrystallization of magmatic minerals and produced the observed metamorphic structures. Proceeding from the controversy in the formation mechanisms, with a heat source required for hornfels but lacking from the sampled occurrences of hornfels-like rocks, we suggest identifying the latter as beerbachite, though the term has mostly fallen into disuse. The reason is that the Olkhon rocks we study have a mineralogy, structure, and texture that are perfectly identical to those of beerbachites described in publications from the first half of the 20th century. Full article

Metal migration and precipitation in hydrothermal fluids are important topics in economic geology. The Hongling polymetallic deposit comprises one of the most important parts of the Huanggangliang–Ganzhuermiao polymetallic metallogenic belt, which is in eastern Inner Mongolia. Except for lead–zinc skarn, minor cassiterite in the skarn and disseminated W–Sn mineralization in granitic rocks have also been found. The dominant Sn–W mineralization is in the northern part of the deposit, occurring as disseminated wolframite and cassiterite in aplite hosted in Mesozoic granite porphyry. The aplite together with pegmatite K-feldspar–quartz comprises vein dikes hosted in the granite porphyry, providing evidence for the transition from melt to fluid. The veins, dikes, and Sn–W mineralization in the aplite provide an opportunity to investigate fluid exsolution and the mechanics of metal precipitation. Based on field observations, the micrographic and scanning electron microscopy/energy dispersive spectroscopy (SEM/EDS) results of the vein dikes, chronology, and the whole-rock geochemistry of the host rock, together with the fluid inclusion results, this paper discusses the characteristics of the causative magma, the mechanics of fluid exsolution and W–Sn precipitation. Our results show that the causative magma is of highly fractionated A-type granite affinity and has an intrusive age of late Mesozoic (133.3 ± 0.86 Ma). The magmatic evolution during shallow emplacement led to immiscibility between highly volatile, high-silica, and W- and Sn-enriched melts from the parent magma, followed by fluid exsolution from the water-rich melt. The alkaline-rich fluid exsolution led to a change in the redox state of the magma and the chilling of the melt. Fluid boiling occurred soon after the fluid exsolution and was accompanied by the degassing of CO₂. The boiling and escape of CO₂ from the fluid led to changes in fluid redox and W and Sn precipitation; thus, the W and Sn mineralization are mostly hosted in causative intrusions or peripheral wall rocks, which can be used as indicators for Sn–W exploration in the area. Full article

The NE-trending multiphase Late Devonian Eagle Lake granite (ELG) in southwestern New Brunswick is mineralized, consisting of hypabyssal porphyritic stocks and dikes that intruded Silurian metabasic volcanic rocks; however, its various phases, ages, and associations with notable stockwork Cu–Mo–Au mineralization and alteration have yet to have been studied. The ELG suite is predominantly composed of phenocrysts and a microcrystalline groundmass of quartz, K-feldspar, and plagioclase, with minor biotite and accessory minerals. In situ LA ICP-MS U–Pb zircon dating of this pluton yielded 360 ± 5 Ma (Late Devonian), so this pluton is considered part of the Late Devonian granitic series in southwestern New Brunswick. The isotopic analysis of two granitic samples yielded an initial ¹⁴³Nd/¹⁴⁴Nd of 0.512164 and 0.512184, initial ⁸⁷Sr/⁸⁶Sr of 0.70168 and 0. 70675, and initial ¹⁷⁶Hf/¹⁷⁷Hf of 0.282619 and 0.282631. The εNd (360 Ma) is −0.37 to +0.03, whereas the εHf (360 Ma) values are +2.1 and +2.5. Pb isotopic analysis yielded a ²⁰⁶Pb/²⁰⁴Pb of 18.49 and 18.72, ²⁰⁷Pb/²⁰⁴Pb of 15.62 and 15.63, and ²⁰⁸Pb/²⁰⁴Pb of 38.26 and 38.37, indicative of a relatively radiogenic source contaminating a primitive mantle melt. Potassic alteration and pyrite-quartz stockwork Cu–Mo–Au veining is evident in some parts of these porphyries. Petrographic and geochemical evidence indicates that this composite pluton is a low-T, I-type granite with zircon saturation temperatures between 720° and 825 °C, with emplacement depths of 10.3 to 4.4 km. ELG was emplaced along a major structural trend manifested by contemporaneous faults and shear zones, i.e., the Belleisle Fault Zone in southern New Brunswick. Full article

Porphyry and epithermal deposits are important sources of base and precious metals. Most actively mined deposits have been exhumed such that ore bodies are relatively close to the surface and are therefore locatable and economic to extract. Identifying and characterizing concealed deposits, particularly more deeply buried porphyry deposits, represents a far greater challenge for mineral exploration, and will become progressively more important as near-surface resources are gradually exhausted over time. We report high-precision ⁴⁰Ar/³⁹Ar dates for coarsely crystalline alunite that precipitated from magmatic steam in open fractures in Oligocene dacitic volcanic rocks, and a SHRIMP ²⁰⁶Pb/²³⁸U zircon date for one of several rhyolite dikes present at Alunite Ridge and Deer Trail Mountain, Utah. Both the magmatic-steam alunite and rhyolite dikes are related to concealed intrusions. The rhyolite dike yielded an age of 30.72 ± 0.36 Ma, which is older than a commonly cited 27.1 Ma age estimate for the Three Creeks Tuff Member of the Bullion Canyon Volcanics that is cut by the dike. ⁴⁰Ar/³⁹Ar data for samples of magmatic-steam alunite and sericite from six mines and prospects provide evidence for at least two periods of episodic hydrothermal activity at ca. 15.7–15.1 Ma and ca. 14.7–13.8 Ma, with the older and younger pulses of activity recorded at the more eastern and western sites, respectively. These two periods of hydrothermal activity are consistent with previous interpretations that Alunite Ridge and Deer Trail Mountain are underlain by two concealed porphyry stocks. ⁴⁰Ar/³⁹Ar analyses of individual bands in a sample of massive, centimeter-scale banded vein alunite yield indistinguishable ages with a weighted mean of 13.98 ± 0.12 Ma, consistent with a short-lived (≲250 ka) magmatic event with episodic vapor discharge recurring on short timescales (≲36 ka). ⁴⁰Ar/³⁹Ar geochronology of magmatic-steam alunite is a valuable tool to constrain the timing and duration of magmatic hydrothermal activity associated with unexposed intrusions and potentially porphyry deposits, and therefore may be useful in exploration. Full article

Field observations of active and fossil natural geothermal fields indicate that geothermal fluids are primarily transported along dikes and fault zones. Fluid transport along dikes (commonly through fractures at their margins) is controlled by the cubic law where the volumetric flow rate depends on the aperture of the fracture in the 3rd power. Dikes (and inclined sheets) also act as heat sources for geothermal fields. In high-temperature fields in volcanoes in Iceland dikes and inclined sheets constitute 80–100% of the rock at crustal depths of 1.5–2 km. Holocene feeder-dikes are known to have increased the activity of associated geothermal fields. Fault zones transport geothermal fluids along their two main hydromechanical units, the core and the damage zone. The core is comparatively thin and primarily composed of breccia, gouge, and clay and related low-permeability porous materials. By contrast, the fault damage zone is characterised by fractures whose frequency is normally highest at the contact between the core and the damage zone. Fluid transport in the damage zone, and in the core following fault slip, is controlled by the cubic law. During non-slip periods fluid transport in the core is primarily controlled by Darcy’s law. Secondary mineralisation (forming mineral veins and amygdales) tends to reduce the fault-zone permeability. Repeated earthquake activity is thus needed to maintain the permeability of fault zones in active natural geothermal fields. Full article

Different rock types (syenogranite, alkali feldspar granite and quartz syenite intruded by microgranite dikes and quartz veins) were investigated in the Nikeiba region in Egypt. The main components of the studied intrusive rocks, comprised of granites and quartz syenite, are plagioclase, amphibole, biotite, quartz and K-feldspar in different proportions. Ground gamma ray measurements show that syenogranite, quartz syenite and microgranite dikes have the highest radioactivity (K, eU, eTh and their ratios) in comparison with alkali feldspar granite. Geochemically, syenogranite, alkali feldspar granite and quartz syenite are enriched with large-ion lithophile elements (LILE; Ba, Rb, Sr) and high field-strength elements (HFSE; Y, Zr and Nb), but have decreased Ce, reflecting their alkaline affinity. These rocks reveal calc–alkaline affinity, metaluminous characteristics, A-type granites and post-collision geochemical signatures, which indicates emplacement in within-plate environments under an extensional regime. U and Th are increased in syenogranite and quartz syenite, whereas alkali feldspar granite shows a marked decrease in U and Th. The highest average values of A_U (131 ± 49 Bq·kg⁻¹), A_Th (164 ± 35) and A_K (1402 ± 239) in the syenogranite samples are higher than the recommended worldwide average. The radioactivity levels found in the samples are the result of the alteration of radioactive carrying minerals found inside granite faults. The public’s radioactive risk from the radionuclides found in the investigated granitoid samples is estimated by calculating radiological risks. The excess lifetime cancer (ELCR) values exceed the permissible limit. Therefore, the granitoids are unsuitable for use as infrastructure materials. Full article

This review paper aims to integrate geological, tectonic and metallogenetic data, including new data, and propose a regional model for the gold (and base metal) mineralization in the south Amazonian Craton to support the mineral exploration concerning magmatic–hydrothermal deposits. The Proterozoic evolution of the Amazonian Craton comprises the accretion of terrains to the Archean Carajás Mineral Province. In the Tapajós and Juruena mineral provinces, located at the south part of the Amazonian craton, a long-lived ocean–continent subduction event produced ca. 2.0 to 1.77 Ga continental magmatic arcs. Extensive lava flows, volcaniclastic, sedimentary, and plutonic rocks were originated during at least four major orogenic magmatic events (ca. 2.1, 1.9, 1.88, and 1.80 Ga) and two post- to anorogenic events (ca. 1.87 and 1.77 Ga). Gold mineralization occurs in: (i) alluvial/colluvial occurrences, (ii) orogenic carbonate–sulfide-rich quartz veins in shear zones, (iii) stockworks, veins, and dissemination in granites, (iv) contact of basic dikes, (v) well-preserved high-, intermediate- and low-sulfidation epithermal mineralization, and (vi) porphyry-like and intrusion-related gold systems associated with late- to post-orogenic epizonal granites. The estimated historical gold production, mainly in secondary deposits, is over 27 Moz at the Tapajós and 6 Moz at the Juruena provinces. A total resource of over 5 Moz Au is currently defined in several small to large primary gold deposits. Andesite to rhyolite, volcaniclastic, and clastic sedimentary rocks (1.96–1.88 Ga) host epithermal (high-, intermediate-, and low-sulfidation) Au–(Ag–Pb–Zn) mineralization, whereas Au–Cu and Cu–Mo–Au mineralization is hosted in sub-volcanic tonalitic to granitic plutons. Advanced argillic alteration (alunite, pyrophyllite, enargite) associated with high-sulfidation mineralization occurs in ring volcanoes around nested volcanic calderas. This zone grades outward to propylitic or chlorite alteration, often covered by silica caps with vuggy silica. Lava flows and volcaniclastic rocks within faults or associated with volcanic edifices and rhyolitic domes host low- and intermediate-sulfidation mineralization. Low-sulfidation alteration zones typically have adularia and illite or sericite. Chalcopyrite, sphalerite, galena, pyrite, digenite, and manganiferous calcite are related to intermediate-sulfidation gold mineralization. Late- to post-orogenic evolved oxidized I-type granitoids host alkalic-type epithermal and porphyry-like gold mineralization. Porphyry-style hydrothermal alteration is analogous to those of modern systems, with inner sodic and potassic (potassic feldspar ± biotite or biotite) alterations grading to propylitic, muscovite-sericite, chlorite–sericite, and chlorite alterations. Potassic alteration zones are the locus of Cu–Mo mineralization, and gold-rich zones occur in muscovite/sericite–quartz–pyrite alteration. The Paleoproterozoic epithermal and porphyry-like mineralization in these large provinces defines a new frontier for the exploration of world-class gold deposits in the worldwide Proterozoic arc-related magmatic terrains. Full article

In this research, drone-based photogrammetry was utilized for mapping geology with the objective of mineral exploration in the Shahzadeh Abbas Cu deposit, Kerman province, Iran. Cu mineralization is of vein-type and follows geological structures. A low-cost drone was used to collect geological data. A spatial resolution of 3.26 cm was achieved by considering a flight altitude of 70 m. To reach the accuracy of less than 5 cm, 70% lateral and 80% front image overlaps were applied and 220 temporary ground control points (TGCPs) were used in an area of 2.02 km². TGCPs were accurately positioned using DGPS-RTK measurements. Agisoft PhotoScan software was used for photogrammetric processing. The orthophoto product was performed for outlining geological units through visual interpretation. The digital elevation model (DEM) was converted to a hill-shade model in ArcGIS software to extract the geological structures such as faults and dikes. A draft geology map was prepared using orthophoto and hill-shade images to minimize the time and cost of the subsequent field work. Rock sampling was carried out and Cu-bearing veins were specified through field investigations. The geology map was finalized based on field work data and petrology studies. The geological survey indicated that diabase dikes with a northwest–southeast strike often host Cu mineralization in the study area. The position of Cu-bearing dikes was delineated for the next stage of the exploration program. This research demonstrated the time- and cost-effectiveness of using drone-based photogrammetry for preparing base geology maps for the exploration of vein-type mineralization in far districts with rough topography. Full article

Space-borne multispectral and radar data were used to comprehensively map geological contacts, lithologies and structural elements controlling gold-bearing quartz veins in the Wadi Hodein area in Egypt. In this study, enhancement algorithms, band combinations, band math (BM), Principal Component Analysis (PCA), decorrelation stretch and mineralogical indices were applied to Landsat-8 OLI, ASTER and ALOS PALSAR following a pre-designed flow chart. Together with the field observations, the results of the image processing techniques were exported to the GIS environment and subsequently fused to generate a potentiality map. The Wadi Hodein shear belt is a ductile shear corridor developed in response to non-coaxial convergence and northward escape tectonics that accompanied the final stages of terrane accretion and cratonization (~680–600 Ma) in the northern part of the Arabian–Nubian Shield. The evolution of this shear belt encompassed a protracted ~E–W shortening and recurrent sinistral transpression as manifested by east-dipping thrusts and high-angle reverse shear zones. Gold-mineralized shear zones cut heterogeneously deformed ophiolites and metavolcaniclastic rocks and attenuate in and around granodioritic intrusions. The gold mineralization event was evidently epigenetic in the metamorphic rocks and was likely attributed to rejuvenated tectonism and circulation of hot fluids during transpressional deformation. The superposition of the NW–SE folds by NNW-trending, kilometer scale tight and reclined folds shaped the overall framework of the Wadi Hodein belt. Shallow NNW- or SSE-plunging mineral and stretching lineations on steeply dipping shear planes depict a considerable simple shear component. The results of image processing complying with field observations and structural analysis suggest that the coincidence of shear zones, hydrothermal alteration and crosscutting dikes in the study area could be considered as a model criterion in exploration for new gold targets. Full article

The main mass of the Sevathur carbonatite complex (Tamil Nadu, India) consists of dolomite carbonatite with a small number of ankerite carbonatite dikes. Calcite carbonatite occurs in a very minor amount as thin veins within the dolomite carbonatite. The age (²⁰⁷Pb/²⁰⁴Pb) of the Sevathur carbonatites is 801 ± 11 Ma, they are emplaced within the Precambrian granulite terrains along NE–SW trending fault systems. Minor minerals in dolomite carbonatite are fluorapatite, phlogopite (with a kinoshitalite component), amphibole and magnetite. Pyrochlore (rich in UO₂), monazite-Ce, and barite are accessory minerals. Dolomite carbonatite at the Sevathur complex contains norsethite, calcioburbankite, and benstonite as inclusions in primary calcite and are interpreted as primary minerals. They are indicative of Na, Sr, Mg, Ba, and LREE enrichment in their parental carbonatitic magma. Norsethite, calcioburbankite, and benstonite have not been previously known at Sevathur. The hydrothermal processes at the Sevathur carbonatites lead to alteration of pyrochlore into hydropyrochlore, and Ba-enrichment. Also, it leads to formation of monazite-(Ce) and barite-II. Full article

The Dulong Sn-Zn-In polymetallic deposit in the Yunnan province, SW China, hosts a reserve of 5.0 Mt Zn, 0.4 Mt Sn, and 7 Kt In. It is one of the most important polymetallic tin ore districts in China. Granites at Dulong mining area include mainly the Laojunshan granite (third phase), which occurs as quartz porphyry or granite porphyry dikes in the Southern edge of the Laojunshan intrusive complex. Granites of phases one and two are intersected at drill holes at depth. There are three types of cassiterite mineralization developed in the deposit: cassiterite-magnetite ± sulfide ore (Cst I), cassiterite-sulfide ore (Cst II) within the proximal skarn in contact with the concealed granite (granites of phases one to two and three), and cassiterite-quartz vein ore (Cst III) near porphyritic granite. Field geology and petrographic studies indicate that acid neutralising muscovitization and pyroxene reactions were part of mechanisms for Sn precipitation resulting from fluid-rock interaction. In situ U–Pb dating of cassiterite samples from the ore stages of cassiterite-sulfide (Cst II) and Cassiterite-quartz vein (Cst III) yielded Tera-Wasserburg U–Pb lower intercept ages of 88.5 ± 2.1 Ma and 82.1 ± 6.3 Ma, respectively. The two mineralization ages are consistent with the emplacement age of the Laojunshan granite (75.9–92.9 Ma) within error, suggesting a close temporal link between Sn-Zn(-In) mineralization and granitic magmatism. LA-ICPMS trace element study of cassiterite indicates that tetravalent elements (such as Zr, Hf, Ti, U, W) are incorporated in cassiterite by direct substitution, and the trivalent element (Fe) is replaced by coupled substitution. CL image shows that the fluorescence signal of Cst I–II is greater than that of Cst III, which is caused by differences in contents of activating luminescence elements (Al, Ti, W, etc.) and quenching luminescence element (Fe). Elevated W and Fe but lowered Zr, Hf, Nb, and Ta concentrations of the three type cassiterites from the Dulong Sn-Zn-In polymetallic deposit are distinctly different from those of cassiterites in VMS/SEDEX tin deposits, but similar to those from granite-related tin deposits. From cassiterite-magnetite ± sulfide (Cst I), cassiterite-sulfide ore (Cst II), to cassiterite-quartz vein ore-stage (Cst III), high field strength elements (HFSEs: Zr, Nb, Ta, Hf) decrease. This fact combined with cassiterite crystallization ages, indicates that Cst I–II mainly related to concealed granite (Laojunshan granites of phases one and two) while Cst III is mainly related to porphyritic granite (Laojunshan granites of phase three). Full article

Ian Carmichael wrote of an “andesite aqueduct” that conveys vast amounts of water from the magma source region of a subduction zone to the Earth’s surface. Diverse observations indicate that subduction zone magmas contain 5 wt % or more H₂O. Most of the water is released from crystallizing intrusions to play a central role in contact metamorphism and the genesis of ore deposits, but it also has important effects on the plutonic rocks themselves. Many plutons were constructed incrementally from the top down over million-year time scales. Early-formed increments are wall rocks to later increments; heat and water released as each increment crystallizes pass through older increments before exiting the pluton. The water ascends via multiple pathways. Hydrothermal veins record ascent via fracture conduits. Pipe-like conduits in Yosemite National Park, California, are located in or near aplite–pegmatite dikes, which themselves are products of hydrous late-stage magmatic liquids. Pervasive grain-boundary infiltration is recorded by fluid-mediated subsolidus modification of mineral compositions and textures. The flood of magmatic water carries a large fraction of the total thermal energy of the magma and transmits that energy much more rapidly than conduction, thus enhancing the fluctuating postemplacement thermal histories that result from incremental pluton growth. The effects of water released by subduction zone magmas are central not only to metamorphism and mineralization of surrounding rocks, but also to the petrology and the thermal history of the plutons themselves. Full article

The purpose of this work is to evaluate the long-term effects of radiation on the structure of naturally occurring apatite in the hope of assessing its potential for use as a solid nuclear waste form for actinide sequestration over geologically relevant timescales. When a crystal is exposed to radioactivity from unstable constituent atoms undergoing decay, the crystal’s structure may become damaged. Crystalline materials rendered partially or wholly amorphous in this way are deemed “partially metamict” or “metamict” respectively. Intimate proximity of a non-radioactive mineral to a radioactive one may also cause damage in the former, evident, for example, in pleochroic haloes surrounding zircon inclusions in micas. Radiation damage may be repaired through the process of annealing. Experimental evidence suggests that apatite may anneal during alpha particle bombardment (termed “self-annealing”), which, combined with a low solubility in aqueous fluids and propensity to incorporate actinide elements, makes this mineral a promising phase for nuclear waste storage. Apatite evaluated in this study occurs in a Grenville-aged crustal carbonatite at the Silver Crater Mine in direct contact with U-bearing pyrochlore (var. betafite)—a highly radioactive mineral. Stable isotope analyses of calcite from the carbonatite yield δ¹⁸O and δ¹³C consistent with other similar deposits in the Grenville Province. Although apatite and betafite imaged using cathodoluminescence (CL) show textures indicative of fracture-controlled alteration, Pb isotope analyses of betafite from the Silver Crater Mine reported in previous work are consistent with a model of long term Pb loss from diffusion, suggesting the alteration was not recent. Thus, it is interpreted that these minerals remained juxtaposed with no further metamorphic overprint for ≈1.0 Ga, and therefore provide an ideal opportunity to study the effects of natural, actinide-sourced radiation on the apatite structure over long timescales. Through broad and focused X-ray beam analyses and electron backscatter diffraction (EBSD) mapping, the pyrochlore is shown to be completely metamict—exhibiting no discernible diffraction associated with crystallinity. Meanwhile, apatite evaluated with these methods is confirmed to be highly crystalline with no detectable radiation damage. However, the depth of α-decay damage is not well-understood, with reported depths ranging from tens of microns to just a few nanometers. EBSD, a surface sensitive technique, was therefore used to evaluate the crystallinity of apatite surfaces which had been in direct contact with radioactive pyrochlore, and the entire volume of small apatite crystals whose cores may have received significant radiation doses. The EBSD results demonstrate that apatite remains crystalline, as derived from sharp and correctly-indexed Kikuchi patterns, even on surfaces in direct contact with a highly radioactive source for prolonged periods in natural systems. Full article