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Keywords = vacuum-induced transparency

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15 pages, 7516 KiB  
Article
Luminescence and Electron–Hole-Trapping Centers in α-Ca2P2O7Mn
by Turlybek N. Nurakhmetov, Temirulan T. Alibay, Keleshek B. Zhangylyssov, Aibek S. Nurpeissov, Sapargali Pazylbek, Diana Griesiute, Aleksej Zarkov and Aivaras Kareiva
Crystals 2024, 14(5), 406; https://doi.org/10.3390/cryst14050406 - 26 Apr 2024
Cited by 2 | Viewed by 1218
Abstract
The mechanisms of formation of induced intrinsic and impurity radiative states, which consist of intrinsic and impurity electron–hole-trapping center states in irradiated Ca2P2O7Mn and Ca2P2O7  phosphates, were [...] Read more.
The mechanisms of formation of induced intrinsic and impurity radiative states, which consist of intrinsic and impurity electron–hole-trapping center states in irradiated Ca2P2O7Mn and Ca2P2O7  phosphates, were investigated using thermoactivation and vacuum-ultraviolet spectroscopy methods. These centers are excited at photon energies of 4.0 eV and 4.5 eV, which are within the matrix’s transparency region. New radiative-induced states at 3.06 eV and 2.92 eV are demonstrated to be generated upon the excitation of anions by photons with energies of 5.0 and 5.64 eV. This process is due to charge transfer from the ion to the impurities, specifically Mn2+(O2Mn2+) and the neighboring ion O 2(P2O7)4. Furthermore, upon the excitation of matrix anions with photon energies exceeding the band gap (8.0–8.25 eV), electron-trapping by impurities such as Mn2+ and (P2O7)4 ions results. Full article
(This article belongs to the Section Inorganic Crystalline Materials)
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23 pages, 549 KiB  
Article
Quark Clusters, QCD Vacuum and the Cosmological 7Li, Dark Matter and Dark Energy Problems
by Rachid Ouyed, Denis Leahy, Nico Koning and Prashanth Jaikumar
Universe 2024, 10(3), 115; https://doi.org/10.3390/universe10030115 - 1 Mar 2024
Cited by 4 | Viewed by 1632
Abstract
We propose a non-exotic electromagnetic solution (within the standard model of particle physics) to the cosmological 7Li problem based upon a narrow 2 MeV photo-emission line from the decay of light glueballs (LGBs). These LGBs form within color superconducting quark clusters (SQCs), [...] Read more.
We propose a non-exotic electromagnetic solution (within the standard model of particle physics) to the cosmological 7Li problem based upon a narrow 2 MeV photo-emission line from the decay of light glueballs (LGBs). These LGBs form within color superconducting quark clusters (SQCs), which are tens of Fermi in size, in the radiation-dominated post-BBN epoch. The mono-chromatic line from the LGBγ+γ decay reduces Big Bang nucleosynthesis (BBN) 7Be by 2/3 without affecting other abundances or the cosmic microwave background (CMB) physics, provided the combined mass of the SQCs is greater than the total baryonic mass in the universe. Following the LGB emission, the in-SQC Quantum ChromoDynamics (QCD) vacuum becomes unstable and “leaks” (via quantum tunneling) into the external space-time (trivial) vacuum, inducing a decoupling of SQCs from hadrons. In seeking a solution to the 7Li problem, we uncovered a solution that also addresses the Dark Energy (DE) and dark matter (DM) problem, making these critical problems intertwined in our model. Being colorless, charge-neutral, optically thin, and transparent to hadrons, SQCs interact only gravitationally, making them a viable cold DM (CDM) candidate. The leakage (i.e., quantum tunneling) of the in-SQC QCD vacuum to the trivial vacuum offers an explanation of DE in our model and allows for a cosmology that evolves into a ΛCDM universe at a low redshift with a possible resolution of the Hubble tension. Our model distinguishes itself by proposing that the QCD vacuum within SQCs possesses the ability to tunnel into the exterior trivial vacuum, resulting in the generation of DE. This implies the possibility that DM and hadrons might represent distinct phases of quark matter within the framework of QCD, characterized by different vacuum properties. We discuss SQC formation in heavy-ion collision experiments at moderate temperatures and the possibility of detection of MeV photons from the LGBγ+γ decay. Full article
(This article belongs to the Section Cosmology)
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17 pages, 9913 KiB  
Article
Hollow Microcavity Electrode for Enhancing Light Extraction
by Seonghyeon Park, Byeongwoo Kang, Seungwon Lee, Jian Cheng Bi, Jaewon Park, Young Hyun Hwang, Jun-Young Park, Ha Hwang, Young Wook Park and Byeong-Kwon Ju
Micromachines 2024, 15(3), 328; https://doi.org/10.3390/mi15030328 - 27 Feb 2024
Cited by 1 | Viewed by 2682
Abstract
Luminous efficiency is a pivotal factor for assessing the performance of optoelectronic devices, wherein light loss caused by diverse factors is harvested and converted into the radiative mode. In this study, we demonstrate a nanoscale vacuum photonic crystal layer (nVPCL) for light extraction [...] Read more.
Luminous efficiency is a pivotal factor for assessing the performance of optoelectronic devices, wherein light loss caused by diverse factors is harvested and converted into the radiative mode. In this study, we demonstrate a nanoscale vacuum photonic crystal layer (nVPCL) for light extraction enhancement. A corrugated semi-transparent electrode incorporating a periodic hollow-structure array was designed through a simulation that utilizes finite-difference time-domain computational analysis. The corrugated profile, stemming from the periodic hollow structure, was fabricated using laser interference lithography, which allows the precise engineering of various geometrical parameters by controlling the process conditions. The semi-transparent electrode consisted of a 15 nm thick Ag film, which acted as the exit mirror and induced microcavity resonance. When applied to a conventional green organic light-emitting diode (OLED) structure, the optimized nVPCL-integrated device demonstrated a 21.5% enhancement in external quantum efficiency compared to the reference device. Further, the full width at half maximum exhibited a 27.5% reduction compared to that of the reference device, demonstrating improved color purity. This study presents a novel approach by applying a hybrid thin film electrode design to optoelectronic devices to enhance optical efficiency and color purity. Full article
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14 pages, 2743 KiB  
Article
The Effect of C60 and Pentacene Adsorbates on the Electrical Properties of CVD Graphene on SiO2
by Jacopo Oswald, Davide Beretta, Michael Stiefel, Roman Furrer, Dominique Vuillaume and Michel Calame
Nanomaterials 2023, 13(6), 1134; https://doi.org/10.3390/nano13061134 - 22 Mar 2023
Cited by 2 | Viewed by 2926
Abstract
Graphene is an excellent 2D material for vertical organic transistors electrodes due to its weak electrostatic screening and field-tunable work function, in addition to its high conductivity, flexibility and optical transparency. Nevertheless, the interaction between graphene and other carbon-based materials, including small organic [...] Read more.
Graphene is an excellent 2D material for vertical organic transistors electrodes due to its weak electrostatic screening and field-tunable work function, in addition to its high conductivity, flexibility and optical transparency. Nevertheless, the interaction between graphene and other carbon-based materials, including small organic molecules, can affect the graphene electrical properties and therefore, the device performances. This work investigates the effects of thermally evaporated C60 (n-type) and Pentacene (p-type) thin films on the in-plane charge transport properties of large area CVD graphene under vacuum. This study was performed on a population of 300 graphene field effect transistors. The output characteristic of the transistors revealed that a C60 thin film adsorbate increased the graphene hole density by (1.65 ± 0.36) × 1012 cm−2, whereas a Pentacene thin film increased the graphene electron density by (0.55 ± 0.54) × 1012 cm−2. Hence, C60 induced a graphene Fermi energy downshift of about 100 meV, while Pentacene induced a Fermi energy upshift of about 120 meV. In both cases, the increase in charge carriers was accompanied by a reduced charge mobility, which resulted in a larger graphene sheet resistance of about 3 kΩ at the Dirac point. Interestingly, the contact resistance, which varied in the range 200 Ω–1 kΩ, was not significantly affected by the deposition of the organic molecules. Full article
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5 pages, 354 KiB  
Proceeding Paper
Optical Transparency near a MoS2 Nanodisk
by Nikos Iliopoulos, Ioannis Thanopulos, Vasilios Karanikolas and Emmanuel Paspalakis
Mater. Proc. 2022, 9(1), 18; https://doi.org/10.3390/materproc2022009018 - 24 Apr 2022
Viewed by 1141
Abstract
It has recently been shown that the molybdenum disulfide (MoS2) nanodisk leads to sharp and high peaks in the Purcell enhancement factor of a quantum emitter nearby the nanodisk, leading to strong light–matter coupling with nearby quantum systems. In this work, [...] Read more.
It has recently been shown that the molybdenum disulfide (MoS2) nanodisk leads to sharp and high peaks in the Purcell enhancement factor of a quantum emitter nearby the nanodisk, leading to strong light–matter coupling with nearby quantum systems. In this work, we show that the strong coupling at the nanoscale can lead to vacuum-induced transparency. For example, we study the case where a three-level quantum system is placed near an MoS2 nanodisk. We find that we may obtain either single or multiple vacuum-induced transparency effects, depending on the distance between the quantum system and the MoS2 nanodisk and the resonance energy of the quantum system. Full article
(This article belongs to the Proceedings of The 3rd International Online-Conference on Nanomaterials)
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13 pages, 5088 KiB  
Article
Fabrication of Stretchable Transparent Electrode by Utilizing Self-Induced Vacuum Force
by Chunghwan Lee, Jaesool Shim, Chulho Bae and Kisoo Yoo
Appl. Sci. 2019, 9(23), 4986; https://doi.org/10.3390/app9234986 - 20 Nov 2019
Cited by 1 | Viewed by 3119
Abstract
The key challenge in fabricating a stretchable transparent electrode is the effective transfer of an electric conductor to a stretchable substrate. To this end, we used vacuum force to fully permeate the elastomer substrate into the electric conductor. The vacuum force was self-induced [...] Read more.
The key challenge in fabricating a stretchable transparent electrode is the effective transfer of an electric conductor to a stretchable substrate. To this end, we used vacuum force to fully permeate the elastomer substrate into the electric conductor. The vacuum force was self-induced from the evaporation of the solvent in the electric conductor. Hence, a solvent, having a high evaporation rate, is postulated to exhibit superior fabrication quality. To demonstrate this, three different solvents were tested for preparation of the conductor slurry. In the test, the high-vapor-pressure solvents resulted in the superior quality of the fabricated stretchable electrode. Furthermore, the heating direction was changed during thermal curing to maximize the self-induced vacuum force. The plate-heating curing exhibited better transferring efficiency of the electric conductor because the evaporation of the solvent in the conductor slurry was accelerated faster than that of the thermal curing of the elastomer substrate. Besides the achieved high quality of the electrode, the fabrication cost can be drastically reduced because the extra process required to dry the electric conductor is omitted by simultaneous curing of the electric conductor and the stretchable elastomer substrate. Full article
(This article belongs to the Special Issue Selected Papers from the ICMR 2019)
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