Search Results (131)

Chromium slag sites pose severe environmental risks due to hexavalent chromium (Cr(VI)) contamination, characterized by high mobility and toxicity. This study focused on chromium-contaminated soil from a historical chromium slag site in North China, where long-term accumulation of chromate production residues has led to serious Cr(VI) pollution, with Cr(VI) accounting for 13–22% of total chromium and far exceeding national soil risk control standards. To elucidate Cr(VI) transformation mechanisms and elemental linkages, a combined approach of macro-scale condition experiments and micro-scale analysis was employed. Results showed that acidic conditions (pH < 7) significantly enhanced Cr(VI) reduction efficiency by promoting the conversion of CrO₄²⁻ to HCrO₄⁻/Cr₂O₇²⁻. Among reducing agents, FeSO₄ exhibited the strongest effect (reduction efficiency >30%), followed by citric acid and fulvic acid. Temperature variations (−20 °C to 30 °C) had minimal impact on Cr(VI) transformation in the 45-day experiment, while soil moisture (20–25%) indirectly facilitated Cr(VI) reduction by enhancing the reduction of agent diffusion and microbial activity, though its effect was weaker than chemical interventions. Soil grain-size composition influenced Cr(VI) distribution unevenly: larger particles (>0.2 mm) in BC-35 and BC-36-4 acted as main Cr(VI) reservoirs due to accumulated Fe-Mn oxides, whereas BC-36-3 showed increased Cr(VI) in smaller particles (<0.074 mm). μ-XRF and correlation analysis revealed strong positive correlations between Cr and Ca, Fe, Mn, Ni (Pearson coefficient > 0.7, p < 0.01), attributed to adsorption–reduction coupling on iron-manganese oxide surfaces. In contrast, Cr showed weak correlations with Mg, Al, Si, and K. This study clarifies the complex factors governing Cr(VI) behavior in chromium slag soils, providing a scientific basis for remediation strategies such as pH adjustment (4–6) combined with FeSO₄ addition to enhance Cr(VI) reduction efficiency. Full article

The feed industry is characterized by high energy consumption during the grinding stage, where hammer mills can account for up to 50% of total electricity usage; furthermore, efficiency analyses are based only on the classical equations reported in the literature. In this context, the present theoretical-applied research aimed to improve the efficiency of a plant operating below its nominal capacity. To achieve this, a comprehensive mathematical model was developed, integrating power and grain disintegration equations while overcoming the limitations of classical comminution theories. The model incorporates key factors such as feed rate, moisture content, absorbed power and hammer wear. Additionally, specific correction factors for temperature ($K_t$) and mechanical degradation ($K_d$) were introduced to accurately represent real operating conditions. The study was based on extensive measurements of electrical current, power factor, energy consumption, particle size distribution and thermal variations under different load conditions. The statistical analysis, which included ANOVA, ANCOVA and multiple regressions, demonstrated a predictive accuracy of 98% (R²) and a pseudo-R² of 89%. This high correlation allowed for an 18% reduction in energy consumption equivalent to 4 kWh/t and up to a 30% improvement in particle size uniformity, surpassing typical factory performance. The findings highlight that integrating operational, thermodynamic and wear-related factors enhances the robustness of the model, promoting more reliable energy-management practices in hammer mills. Consequently, the results confirm that the developed model serves as a scientifically robust, efficient and applicable tool for improving energy efficiency and reducing environmental impacts in the agri-food industry. Full article

As emerging contaminants, rare earth elements (REEs) have undergone significant anthropogenic enrichment in aquatic systems. This study investigates the REE concentrations, major metal elements, and grain size in surface sediments from the East Tiaoxi (ETX) River in eastern China, a small urban river subjected to substantial anthropogenic influences. Total REE concentrations of surface sediments ranged from 133.62 to 222.92 mg/kg with MREE enrichment and HREE depletion. REE concentration and fractionation were strongly correlated with Ca, Fe, Mg, and Mn, which may reflect the control of clay minerals, Fe-Mn oxides, and specific heavy minerals, and differences in REE behavior between riparian sediments and riverbed sediments highlighted the impact of hydrodynamic sorting and chemical weathering on REE distribution. Anthropogenic activities, particularly urbanization, were found to increase REE concentrations, especially at urban-adjacent sites (e.g., RBS2 and RS2), while natural processes such as soil transport and chemical weathering primarily contributed to REE variation at other sites. The enrichment factor and ecological risk assessment revealed that the enrichment and moderate risks associated with REEs occurred in river sediments adjacent to urbanized areas, though agricultural impacts were less pronounced. The findings emphasize the combined influence of urbanization and natural processes on REE distribution and ecological risks in the ETX River basin and underscore the need to prioritize urban-derived REE contamination in environmental management strategies. Full article

It is imperative to understand the shear mechanical properties and pore evolution of granite under thermal shock to assess the fracturing of hot dry rock reservoirs. In this study, variable-angle shear tests were performed on coarse- and fine-grained granite samples following liquid nitrogen (LN₂) cooling under different high-temperature conditions. The effect of thermal treatment temperature, particle type, and cooling method on the shear strength, cohesion, and angle of internal friction of granite was then analyzed. To this end, low field nuclear magnetic resonance (NMR) and scanning electron microscopy (SEM) were used to investigate the pore size distribution and microstructural evolution of granite. The experimental results indicate that both the shear strength and cohesion of granite initially increase and then decrease with the rise in thermal treatment temperature. The maximum increases in shear strength and cohesion are 38.0% and 36.7%, respectively, while the maximum decreases reach 43.7% and 42.4%. Notably, the most pronounced thermal hardening effect is observed at 200 °C. In contrast, the internal friction angle exhibits a decreasing-then-increasing trend as the temperature rises, with a maximum reduction of 5.4% and a maximum increase of 14.5%. In addition, fine-grained granite exhibits superior shear strength and a more pronounced thermal hardening effect compared to coarse-grained granite. Furthermore, the damage effect caused by thermal shock increases with increasing heat treatment temperature, with the damage effect induced by liquid nitrogen cooling being particularly significant compared to water cooling. Furthermore, for both types of granite at the same shear angle, an increase in the heat treatment temperature results in a corresponding increase in the total fracture area, with the fracture area after liquid nitrogen cooling being more significant. The macroscopic failure mode changes from a mixed compression–shear failure mode to a direct shear failure mode with increasing shear angle. NMR testing shows that liquid nitrogen cooling can effectively increase the proportion of medium pores and large pores in the granite and increase the connectivity of internal pores; specifically, in coarse-grained granite, medium pores and large pores collectively increased by 10.5%, while in fine-grained granite, the total increase in medium pores reached 51%. As the heat treatment temperature increases, the type of crack that develops in granite changes from intragranular to transgranular. In addition, the fracture surface of granite is more prone to form micropores and small pores when cooled with liquid nitrogen, increasing the connectivity of the crack network. The results of this research will be useful for fracturing hot dry rock reservoirs. Full article

The patterns of meiofaunal distribution in a submarine canyon and adjacent open-slope habitats at Campos Basin, southwest Atlantic, were investigated. A total of eight stations was sampled, four inside the Canyon Almirante Câmara and four on the adjacent open slope. These stations represented four isobaths (400, 700, 1000, 1300 m) and were sampled during two distinct periods (2008, 2009). At each station, three replicates were obtained and sectioned into layers of 0–2, 2–5 and 5–10 cm. Nematoda was the most abundant group in both habitats, comprising more than 85% of the total meiofauna in both sampling periods. The density and assemblage structure of the meiofauna showed high variability between the 400 m isobath and the other three isobaths in the canyon habitat. These results reinforce the roles of habitat heterogeneity and the availability of food sources as key factors strongly influencing the deep-sea meiofauna in the southwest Atlantic Ocean. Phytopigments were significantly correlated with the two major meiofaunal groups (Nematoda and Copepoda), as well as with total meiofaunal density, only in the canyon habitat. On the adjacent open slope, only copepods showed a significant correlation with sediment characteristics (mean grain size and carbonates), suggesting that distinct environmental factors influence the distribution of meiofauna in the two habitats. Full article

The microstructural, mechanical and corrosion properties of low-alloyed Mg-Zn-Ca alloys with different Zn/Ca atomic ratios were investigated. The results show that the microstructure of the extruded Mg-1Zn-0.3Ca (ZX1.0) alloy mainly consists of α-Mg and Ca₂Mg₆Zn₃ phases and a small amount of Mg₂Ca phase. In contrast, the Mg₂Ca phase disappears in the alloys Mg-1.4Zn-0.3Ca (ZX1.4), Mg-1.8Zn-0.3Ca (ZX1.8) and Mg-2.3Zn-0.5Ca (ZX2.3). The Ca₂Mg₆Zn₃ phases are mainly distributed along the extrusion direction, showing irregular particle shapes and banded particles. Meanwhile, the grain size of the extruded Mg-Zn-Ca alloy is reduced gradually with the increase of the Zn and Ca contents, decreasing from 1.87 μm in ZX1.0 to 1.28 μm in ZX2.3 alloy. Fine grain strengthening and second-phase strengthening increase the yield strength and ultimate tensile strength of the alloy. In addition, when the Zn/Ca ratio is the same, the total elemental content dominates the effect on alloy properties. When increasing the Zn/Ca ratio, the potential difference between Ca₂Mg₆Zn₃ and the Mg matrix increased, resulting in an increase in galvanic corrosion. The negative effect of the volume fraction of the second phase and the positive effect of the fine grain size determine the corrosion performance together. Therefore, ZX1.8 exhibits the best corrosion resistance, of 0.14 mm/y. Full article

In the Southeastern Ordos Basin, the Chang 2 low-permeability sandstone reservoir of the Triassic Yanchang Formation is a typical heterogeneous reservoir. Quantitatively characterizing and analyzing its complex pore throat structure has become crucial for enhancing storage and production in the study area. The pore throat structure is a key factor influencing reservoir properties. To achieve this, a comprehensive suite of analytical techniques was employed, including cast thin section (CTS), scanning electron microscopy (SEM), cathodoluminescence (CL), X-ray diffraction (XRD), and mercury intrusion capillary pressure (MICP). This study quantitatively characterizes the pore size distribution of reservoirs in the Southeast Ordos Basin. Based on fractal theory, it clarifies the complexity of the pore throat structure and the degree of microscopic heterogeneity at different scales. Finally, this study reveals the correlation between fractal dimensions and storage and permeability capacities and analyzes the controlling factors. The findings indicate that the predominant lithotype in the study area is fine-grained feldspar sandstone, which develops pore types such as intergranular pores, dissolution pores, and microfractures. Based on the shapes of mercury injection curves and pore throat structural parameters, and in conjunction with SEM images, the samples are categorized into three types. Type I samples exhibit good pore throat connectivity and are characterized by a lattice model. Type II samples are characterized by a tubular pore throat model. Type III samples have poor pore throat connectivity and are characterized by an isolated model. The pore throat network of low-permeability sandstone is primarily composed of micropores (pore throat radius r < 0.1 μm), mesopores (0.1 < r < 1.0 μm), and macropores (r > 1.0 μm). The complexity of the reservoir pore throat structure was quantitatively characterized by fractal theory. The total fractal dimension (D) of all the samples is between 2 and 3, which indicates that the reservoir has capillary fractal characteristics. The average fractal dimension of micropores (D1) is 2.57, while that for mesopores (D2) and macropores (D3) is slightly higher, at an average of 2.68. This suggests that micropores have higher self-similarity and homogeneity. The fractal dimensions D1, D2, and D3 of the three types of reservoirs all exhibit a negative correlation with porosity and permeability. This shows that the more complex the pore throat structure is, the worse the storage and seepage capacity of the reservoir. For type I samples, the correlation of D3 with pore throat structural parameters such as entry pressure, skewness, and maximum mercury saturation is better than that of D2 and D1. For type II and type III samples, D2 shows a significant correlation with pore throat structural parameters. This indicates that the heterogeneity and complexity of mesopores are key factors influencing the pore throat structure of poor-quality reservoirs. Different mineral compositions have varying effects on the fractal characteristics of pore structures. Quartz, feldspar, and clay exert both negative and positive dual impacts on reservoir quality by altering the pore throat structure and the diagenetic processes. The mineral content exhibits a complex quadratic relationship with the fractal dimension. Moreover, micropores are more significantly influenced by the mineral content. The study of the relationship between the fractal dimension and physical properties, pore throat structural parameters, and mineral composition can improve the understanding of the reservoir quality of low-permeability reservoirs. This provides a theoretical basis for exploration and improving the recovery rate in the study area. Full article

In this study, samples were collected from different types of artificial fish reefs and prevention and control areas in the sea areas of the northern part of Da Changshan Island and the northeastern part of Xiao Changshan Island in the North Yellow Sea. The purpose is to compare the differences in the bacterial communities among different regions, determine the impacts of environmental factors on the bacterial communities, and evaluate the ecological effects of artificial fish reefs on the marine bacterial communities. We obtained a total of 2,128,186 effective sequences and 4321 bacterial operational taxonomic units (OTUs), which were classified into 14 phyla and 76 genera. Proteobacteria were the most abundant phylum across the 32 samples, followed by Bacteroidetes. We found that all samples from the deep-sea control area exhibited the highest bacterial richness. In addition, all samples from the shallow-water concrete reef exhibited high community richness. The distribution of bacterial communities showed differences among different regions. In two specific sea areas, the bacteria in the sediment samples exhibited particularly remarkable characteristics of high diversity. Importantly, environmental factors significantly influence bacterial communities. In seawater samples, salinity (Sal) and dissolved oxygen (DO) were the primary factors affecting bacterial communities. Furthermore, grain size (GS) emerged as the most critical physicochemical factor influencing bacterial communities in sediment. This study compared the characteristics of bacterial communities in different types of artificial reefs and control areas in two marine ranches and revealed the main environmental factors affecting the bacterial communities. This is of great significance for protecting biodiversity and evaluating the ecological effects of artificial reef placement. Full article

The construction of artificial reefs is the primary ecological project of marine ranching and one of the most important methods of creating habitats for marine organisms. To date, studies on artificial reefs have taken a macroscopic perspective, with few studies having investigated the fungal communities in artificial reefs in the North Yellow Sea. Therefore, the aim of this study was to determine the distribution patterns of seawater quality, sediment properties, and fungal communities following the placement of artificial reefs of different materials in the North Yellow Sea. A sampling survey of marine ranching in the northern Yellow Sea was conducted in August 2023. Sediment and seawater samples were collected from the stone and concrete artificial reef areas as well as from the areas without constructed reefs as a control. Research shows that the total phosphorus (TP), total nitrogen (TN), and total organic carbon (TOC) concentrations were higher in the concrete reef than that in the other two regions. We obtained 735 fungal operational taxonomic units (OTUs) which were assigned to 11 phyla and 374 genera. Significant differences in the beta-diversity of the fungal communities were found among the three sampling regions, and the dominant species varied in seawater and sediment samples from different reef areas. Ascomycota was the most abundant phylum in the seawater and sediment samples, followed by Basidiomycota. pH and dissolved oxygen (DO) emerged as the most important factors affecting fungal communities in the seawater samples, whereas mean grain size, TN, and TOC had a significant effect on the communities in the sediments, with TP and TOC playing the most critical roles. Our study compared the characteristics of fungal communities in seawater and sediments in distinct types of artificial reefs and control areas, revealing the main environmental factors affecting fungal communities, which is of great significance for protecting biodiversity and evaluating the ecological effects of artificial reef placement. Full article

The Ayla Oasis in Aqaba, Jordan, is a major tourism and residential development project in Aqaba, Jordan, containing three artificial lagoons. This study explores the ecological sustainable development of Ayla Lagoons, focusing on the seawater and bottom sediment quality, and the bottom habitat, in addition to coral conservation and restoration initiatives. The flushing time, averaging 3.7 days for the Upper Lagoon and 2.4 days for the Middle Lagoon, plays a crucial role in maintaining water quality. These measures secure the well-being of all visitors and residents, while also preserving the marine biodiversity. The Upper, Middle, and Tidal Lagoons exhibit physiochemical properties in alignment with seawater characteristics of the Gulf of Aqaba. Sediment quality analysis shows organic carbon levels and grain size distribution vary among lagoons, indicating expected different energy conditions and a healthy environment. The lagoons support a diverse range of species, with a total of 2343 fish individuals belonging to 22 species across 17 families recorded. The comprehensive analysis of the Ayla Oasis lagoons’ seawater and sediment quality revealed a dynamic and resilient ecosystem. Ayla’s coral conservation and restoration initiative within its lagoons feature 166 reef balls, 5 coral nurseries, and 2 metal structures, all designed to foster marine biodiversity. The project demonstrates the effectiveness of Ayla Oasis’ environmental resilience and monitoring strategies, showcasing a commitment to sustainable management and environmental stewardship. These efforts reflect Ayla’s ongoing dedication to protecting and preserving the marine ecosystem, ensuring the long-term health of its coral reefs and surrounding marine life. Full article

This study examines sediment distribution patterns in the Aegean Sea, focusing on the western coast of Evia Island and the southern Evoikos and Petalioi Gulfs. A total of 200 granulometric data points were analyzed to evaluate textural characteristics, including mean grain size, sorting, and skewness. The findings reveal significant variation in mean grain size: finer sediments (ϕ = 5–8) dominate the northern Aegean near Skyros, while coarser sands (ϕ = 2–4) are prevalent in the South Evoikos and Petalioi gulfs. The coarsest materials (ϕ = 0–2) are found around Chalkis, with sorting generally poor except in those two areas. Negative skewness values in the northern part of the study area indicate a predominance of finer particles, while southern regions exhibit slightly positive skewness, suggesting a greater proportion of coarser grains. Complex net transport patterns between Evia and Skyros are influenced by north-northeast trending water currents from the northern Aegean, with fluvial influx observed in the southern Evia coastal area. Around Skyros, the interplay of water currents and prevailing north-northwest winds dictates the orientation of net transport vectors. In the Evoikos gulfs, sediment movement aligns with a general northward flow, featuring coarse sediments in the Petalioi Gulf and muddy deposits in the narrower northern segment, where minimal transport indicates stagnant conditions. Coarse-grained materials in North Evoikos are primarily influenced by strong tidal activity. Full article

This paper investigates the effects of particle morphology (PM) and particle size distribution (PSD) on the micro-macro mechanical behaviours of granular soils through a novel X-ray micro-computed tomography (μCT)-based discrete element method (DEM) technique. This technique contains the grain-scale property extraction by the X-ray μCT, DEM parameter calibration by the one-to-one mapping technique, and the massive derivative DEM simulations. In total, 25 DEM samples were generated with a consideration of six PSDs and four PMs. The effects of PSD and PM on the micro-macro mechanical behaviours were carefully investigated, and the coupled effects were highlighted. It is found that (a) PM plays a significant role in the micro-macro mechanical responses of granular soils under triaxial shear; (b) the PSD uniformity can enhance the particle morphology effect in dictating the peak deviatoric stress, maximum volumetric strain, contact-based coordination number, fabric evolution, and shear band formation, while showing limited influences in the maximum dilation angle and particle-based coordination number; (c) with the same PSD uniformity and PM degree, the mean particle volume shows minimal effects on the macro-micro mechanical behaviours of granular soils as well as the particle morphology effects. Full article

In recent years, the excellent mechanical properties and lightweight characteristics of multi-layer hollow components have led to a surge in research focused on their forming processes. This growing interest has greatly advanced technological progress in aerospace and other related fields. In this paper, the metal flow behavior of TA15 titanium alloy at different temperatures from 840 °C to 940 °C and different strain rates from 0.001 s⁻¹ to 0.1 s⁻¹ was studied. Utilizing the finite element method, this study examined the local stress concentration, total strain distribution, thickness thinning characteristics, and pressure loading control during the superplastic forming process of the component. The integrated solid/hollow four-layer grid lightweight structural parts were successfully fabricated using the superplastic forming/diffusion bonding (SPF/DB) process. The quality of the components was evaluated using X-ray and ultrasonic C-scan detection methods. The results show that the maximum elongation of the alloy is 1340% at 900 °C/0.001 s⁻¹. When the temperature is too high, the grain size increases remarkably, and the elongation decreases. Based on the finite element simulation results, 900 °C is the best superplastic forming temperature. Under this temperature parameter, the maximum thinning rate of the core sheet is 39.7%, the SPF time is 10,000 s, the maximum thinning rate of the face sheet is 9.8%, and the SPF time is 2400 s. In addition, the solid block has a minimal effect on the thinning of the core sheet. The grid exhibits obvious stress concentration and thinning at its rounded corners, while the thickness distribution in other areas remains relatively uniform. The nondestructive testing results confirmed that the ribs of the component are fully formed, with no missing or broken ribs. The grid exhibits good geometry and high-quality diffusion bonding. The average thickness at key positions of the component is 1.84 mm, with the minimum thickness being 1.7 mm. As the size of the grid cavity decreases, the thickness of the component tends to increase gradually. The maximum error between the simulated and measured values is 4.47%, indicating good accuracy in the simulation. Additionally, the thickness distribution of the component is relatively uniform. Full article

The spatial heterogeneity of soil nutrients is crucial for the water bird and whole floodplain wetland ecosystem in large lakes, and it is influenced by the dramatic water level changes and sedimentation progress in West Dongting Lake (WDL). Soil samples were collected at various soil depths along the Yuan River and Li River that feed into WDL. The concentrations of soil total organic carbon (TOC), total nitrogen (TN), total phosphorus (TP), and soil grain size were tested. The stoichiometric ratios of C, N, P, and the mean value of soil grain size (Mz) were calculated. The differences of soil TOC, TN, TP and the stoichiometric ratio at different sites and soil depths were compared. Linear regression was used to explore the relationships of Mz and nutrient concentrations, and relationships between TOC, TN, and TP. Redundancy analysis was used to explore the relationship between soil nutrients, heavy metal concentrations, and plant community diversity. The results showed that the distributions of soil TOC, TN, and TP concentrations differed across regions in west Dongting Lake along the Yuan and Li Rivers. Total organic carbon concentration differed at different sedimentation depths. Soil grain size showed negative effect with soil TOC, TN, and TP concentrations in this region. Plant community diversity correlated positively with soil TOC and negatively with Hg. West Dongting Lake was N limited despite the high wet deposition of N. It could potentially be attributed to the insufficient presence of aerobic environments for microbes during intermittent flooding of the floodplain, coupled with feeble mineralization. This study can provide valuable insights for the conservation of water bird habitats and wetland ecosystems. Full article

This article researches the effect of ultrafine (submicron) tungsten carbide powder addition on the microstructure and mechanical properties of WC-10Co cemented carbide produced by the extrusion of a highly filled polymer. This addition aims to develop a material with a good combination of toughness, hardness, and yield strength. The results demonstrate that increasing the ratio between ultrafine and micron WC particles from 0/100 to 45/55 in the initial powder results in successive decreases in average grain size from 2.61 µm to 1.75 µm. When 45% of ultrafine powder is introduced into the mixture, a high number of fine tungsten carbide grains is produced. This promotes inter-grain contact and reduces the free path of the binder phase, which results in a more rigid structure and in the material becoming more brittle. The best mechanical characteristics are achieved in WC-10Co cemented carbide with 15% content of ultrafine powder in the total weight of WC. Here, a microstructure with a bimodal distribution of tungsten carbide grains in a virtually non-intermittent cobalt phase was formed. This allowed us to achieve a compressive strength of 2449 MPa at the deformation of 6.69%, while the modulus of elasticity was 38.8 GPa. The results indicate a good combination of strength and ductility properties in the developed cemented carbide. Full article