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Keywords = titanium aluminides based on γ-TiAl

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23 pages, 4649 KB  
Article
Laser Powder Bed Fusion of Intermetallic Titanium Aluminide Alloys Using a Novel Process Chamber Heating System: A Study on Feasibility and Microstructural Optimization for Creep Performance
by Reinhold Wartbichler, Tobias Maiwald-Immer, Fabian Pürstl and Helmut Clemens
Metals 2022, 12(12), 2087; https://doi.org/10.3390/met12122087 - 5 Dec 2022
Cited by 5 | Viewed by 4690
Abstract
A laser powder bed fusion process operating at elevated temperatures is introduced capable of fabricating crack-free and dense intermetallic titanium aluminide alloy specimens as well as demonstrator components using a base plate heating up to 900 °C and a unique heating system of [...] Read more.
A laser powder bed fusion process operating at elevated temperatures is introduced capable of fabricating crack-free and dense intermetallic titanium aluminide alloy specimens as well as demonstrator components using a base plate heating up to 900 °C and a unique heating system of the uppermost powder bed layer up to 1200 °C. Two so-called 4th generation alloys, TNM and TNM+, were used for this study. The microstructure and its evolution during subsequent heat treatments were investigated and explained by employing scanning electron microscopy, hardness testing, X-ray diffraction, differential scanning calorimetry and thermodynamic equilibrium calculation. Selected specimens were subjected to creep tests at 750 °C. The microstructures after processing consist of extraordinarily fine lamellar γ-TiAl/α2-Ti3Al-colonies with globular γ and βo-TiAl grains for both the TNM and TNM+ alloy, exhibiting a microstructure gradient from the last consolidated powder layer down to the starting layer due to cellular reaction, which increases the amount of globular γ and βo at the boundaries of the γ/α2-colonies. During annealing in proximity to the γ-solvus temperature, banded microstructures might form, as the α-grain size is only partially controlled by heterogeneously distributed γ/β-phase, which stems from the process-related Al loss. Additionally, the occurrence of thermally-induced porosity is investigated. Optimizing the microstructure to a homogenized, almost fully lamellar microstructure, involved annealing in the β-single phase field region and led to improved creep properties. Finally, TNM demonstrator components with complex geometries, such as aero engine blades and turbocharger turbine wheels, are fabricated by employing the novel laser powder bed fusion process. Full article
(This article belongs to the Special Issue Intermetallics for Structural Applications)
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18 pages, 7500 KB  
Article
A Novel Approach for Real-Time Quality Monitoring in Machining of Aerospace Alloy through Acoustic Emission Signal Transformation for DNN
by David Adeniji, Kyle Oligee and Julius Schoop
J. Manuf. Mater. Process. 2022, 6(1), 18; https://doi.org/10.3390/jmmp6010018 - 25 Jan 2022
Cited by 23 | Viewed by 5434
Abstract
Gamma titanium aluminide (γ-TiAl) is considered a high-performance, low-density replacement for nickel-based superalloys in the aerospace industry due to its high specific strength, which is retained at temperatures above 800 °C. However, low damage tolerance, i.e., brittle material behavior with a propensity to [...] Read more.
Gamma titanium aluminide (γ-TiAl) is considered a high-performance, low-density replacement for nickel-based superalloys in the aerospace industry due to its high specific strength, which is retained at temperatures above 800 °C. However, low damage tolerance, i.e., brittle material behavior with a propensity to rapid crack propagation, has limited the application of γ-TiAl. Any cracks introduced during manufacturing would dramatically lower the useful (fatigue) life of γ-TiAl components, making the workpiece surface’s quality from finish machining a critical component to product quality and performance. To address this issue and enable more widespread use of γ-TiAl, this research aims to develop a real-time non-destructive evaluation (NDE) quality monitoring technique based on acoustic emission (AE) signals, wavelet transform, and deep neural networks (DNN). Previous efforts have opted for traditional approaches to AE signal analysis, using statistical feature extraction and classification, which face challenges such as the extraction of good/relevant features and low classification accuracy. Hence, this work proposes a novel AI-enabled method that uses a convolutional neural network (CNN) to extract rich and relevant features from a two-dimensional image representation of 1D time-domain AE signals (known as scalograms), subsequently classifying the AE signature based on pedigreed experimental data and finally predicting the process-induced surface quality. The results of the present work show good classification accuracy of 80.83% using scalogram images, in-situ experimental data, and a VGG-19 pre-trained neural network, establishing the significant potential for real-time quality monitoring in manufacturing processes. Full article
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13 pages, 2161 KB  
Article
Drilling Process in γ-TiAl Intermetallic Alloys
by Aitor Beranoagirre, Gorka Urbikain, Amaia Calleja and Luis Norberto López de Lacalle
Materials 2018, 11(12), 2379; https://doi.org/10.3390/ma11122379 - 26 Nov 2018
Cited by 17 | Viewed by 4582
Abstract
Gamma titanium aluminides (γ-TiAl) present an excellent behavior under high temperature conditions, being a feasible alternative to nickel-based superalloy components in the aeroengine sector. However, considered as a difficult to cut material, process cutting parameters require special study to guarantee component quality. In [...] Read more.
Gamma titanium aluminides (γ-TiAl) present an excellent behavior under high temperature conditions, being a feasible alternative to nickel-based superalloy components in the aeroengine sector. However, considered as a difficult to cut material, process cutting parameters require special study to guarantee component quality. In this work, a developed drilling mechanistic model is a useful tool in order to predict drilling force (Fz) and torque (Tc) for optimal drilling conditions. The model is a helping tool to select operational parameters for the material to cut by providing the programmer predicted drilling forces (Fz) and torque (Tc) values. This will allow the avoidance of operational parameters that will cause excessively high force and torque values that could damage quality. The model is validated for three types of Gamma-TiAl alloys. Integral hard metal end-drilling tools and different cutting parameters (feeds and cutting speeds) are tested for three different sized holes for each alloy. Full article
(This article belongs to the Special Issue Machining—Recent Advances, Applications and Challenges)
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19 pages, 9606 KB  
Review
Advancement of Compositional and Microstructural Design of Intermetallic γ-TiAl Based Alloys Determined by Atom Probe Tomography
by Thomas Klein, Helmut Clemens and Svea Mayer
Materials 2016, 9(9), 755; https://doi.org/10.3390/ma9090755 - 6 Sep 2016
Cited by 55 | Viewed by 8482
Abstract
Advanced intermetallic alloys based on the γ-TiAl phase have become widely regarded as most promising candidates to replace heavier Ni-base superalloys as materials for high-temperature structural components, due to their facilitating properties of high creep and oxidation resistance in combination with a low [...] Read more.
Advanced intermetallic alloys based on the γ-TiAl phase have become widely regarded as most promising candidates to replace heavier Ni-base superalloys as materials for high-temperature structural components, due to their facilitating properties of high creep and oxidation resistance in combination with a low density. Particularly, recently developed alloying concepts based on a β-solidification pathway, such as the so-called TNM alloy, which are already incorporated in aircraft engines, have emerged offering the advantage of being processible using near-conventional methods and the option to attain balanced mechanical properties via subsequent heat-treatment. Development trends for the improvement of alloying concepts, especially dealing with issues regarding alloying element distribution, nano-scale phase characterization, phase stability, and phase formation mechanisms demand the utilization of high-resolution techniques, mainly due to the multi-phase nature of advanced TiAl alloys. Atom probe tomography (APT) offers unique possibilities of characterizing chemical compositions with a high spatial resolution and has, therefore, been widely used in recent years with the aim of understanding the materials constitution and appearing basic phenomena on the atomic scale and applying these findings to alloy development. This review, thus, aims at summarizing scientific works regarding the application of atom probe tomography towards the understanding and further development of intermetallic TiAl alloys. Full article
(This article belongs to the Special Issue Physical Metallurgy of High Performance Alloys)
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27 pages, 2724 KB  
Review
In Situ Characterization Techniques Based on Synchrotron Radiation and Neutrons Applied for the Development of an Engineering Intermetallic Titanium Aluminide Alloy
by Petra Erdely, Thomas Schmoelzer, Emanuel Schwaighofer, Helmut Clemens, Peter Staron, Andreas Stark, Klaus-Dieter Liss and Svea Mayer
Metals 2016, 6(1), 10; https://doi.org/10.3390/met6010010 - 4 Jan 2016
Cited by 36 | Viewed by 12117
Abstract
Challenging issues concerning energy efficiency and environmental politics require novel approaches to materials design. A recent example with regard to structural materials is the emergence of lightweight intermetallic TiAl alloys. Their excellent high-temperature mechanical properties, low density and high stiffness constitute a profile [...] Read more.
Challenging issues concerning energy efficiency and environmental politics require novel approaches to materials design. A recent example with regard to structural materials is the emergence of lightweight intermetallic TiAl alloys. Their excellent high-temperature mechanical properties, low density and high stiffness constitute a profile perfectly suitable for their application as advanced aero-engine turbine blades or as turbocharger turbine wheels in next-generation automotive engines. As the properties of TiAl alloys during processing as well as during service are dependent on the phases occurring, detailed knowledge of their volume fractions and distribution within the microstructure is of paramount importance. Furthermore, the behavior of the individual phases during hot deformation and subsequent heat treatments is of interest to define reliable and cost-effective industrial production processes. In situ high-energy X-ray diffraction methods allow tracing the evolution of phase fractions over a large temperature range. Neutron diffraction unveils information on order-disorder transformations in TiAl alloys. Small-angle scattering experiments offer insights into the materials’ precipitation behavior. This review attempts to shine a light on selected in situ diffraction and scattering techniques and the ways in which they promoted the development of an advanced engineering TiAl alloy. Full article
(This article belongs to the Special Issue Metals Challenged by Neutron and Synchrotron Radiation)
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14 pages, 1160 KB  
Article
In Situ High-Energy X-ray Diffraction during Hot-Forming of a Multiphase TiAl Alloy
by Andreas Stark, Marcus Rackel, Aristide Tchouaha Tankoua, Michael Oehring, Norbert Schell, Lars Lottermoser, Andreas Schreyer and Florian Pyczak
Metals 2015, 5(4), 2252-2265; https://doi.org/10.3390/met5042252 - 30 Nov 2015
Cited by 23 | Viewed by 8341
Abstract
Intermetallic γ-TiAl based alloys exhibit excellent high-temperature strength combined with low density. This makes them ideal candidates for replacing the twice as dense Ni base super-alloys, currently used in the medium temperature range (~700 °C) of industrial and aviation gas turbines. An important [...] Read more.
Intermetallic γ-TiAl based alloys exhibit excellent high-temperature strength combined with low density. This makes them ideal candidates for replacing the twice as dense Ni base super-alloys, currently used in the medium temperature range (~700 °C) of industrial and aviation gas turbines. An important step towards the serial production of TiAl parts is the development of suitable hot-forming processes. Thermo-mechanical treatments often result in mechanical anisotropy due to the formation of crystallographic textures. However, with conventional texture analysis techniques, their formation can only be studied after processing. In this study, in situ high-energy X-ray diffraction measurements with synchrotron radiation were performed during hot-forming. Thus, it was possible to record the evolution of the phase constitution as well as the formation of crystallographic texture of different phases directly during processing. Several process temperatures (1100 °C to 1300 °C) and deformation rates were investigated. Based on these experiments, a process window can be recommended which results in the formation of an optimal reduced texture. Full article
(This article belongs to the Special Issue Metals Challenged by Neutron and Synchrotron Radiation)
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16 pages, 1107 KB  
Article
A Model for Creep and Creep Damage in the γ-Titanium Aluminide Ti-45Al-2Mn-2Nb
by William Harrison, Zakaria Abdallah and Mark Whittaker
Materials 2014, 7(3), 2194-2209; https://doi.org/10.3390/ma7032194 - 14 Mar 2014
Cited by 26 | Viewed by 12324
Abstract
Gamma titanium aluminides (γ-TiAl) display significantly improved high temperature mechanical properties over conventional titanium alloys. Due to their low densities, these alloys are increasingly becoming strong candidates to replace nickel-base superalloys in future gas turbine aeroengine components. To determine the safe operating life [...] Read more.
Gamma titanium aluminides (γ-TiAl) display significantly improved high temperature mechanical properties over conventional titanium alloys. Due to their low densities, these alloys are increasingly becoming strong candidates to replace nickel-base superalloys in future gas turbine aeroengine components. To determine the safe operating life of such components, a good understanding of their creep properties is essential. Of particular importance to gas turbine component design is the ability to accurately predict the rate of accumulation of creep strain to ensure that excessive deformation does not occur during the component’s service life and to quantify the effects of creep on fatigue life. The theta (θ) projection technique is an illustrative example of a creep curve method which has, in this paper, been utilised to accurately represent the creep behaviour of the γ-TiAl alloy Ti -45Al-2Mn-2Nb. Furthermore, a continuum damage approach based on the θ-projection method has also been used to represent tertiary creep damage and accurately predict creep rupture. Full article
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