Search Results (11)

Rapid urbanisation and industrialisation have intensified the Urban Heat Island (UHI) effect, significantly increasing energy demand for thermal comfort. Urban buildings consume considerable energy throughout the year, which can be reduced by incorporating Phase Change Materials (PCMs) into building materials. PCMs effectively regulate temperature by storing and releasing heat as latent heat during phase transitions. However, to prevent leakage, PCMs can be encapsulated in co-axial polymeric Phase Change Fibres (PCFs), representing an innovative approach in scientific research. This study optimised the coagulation bath and produced PCFs using commercial cellulose acetate as the sheath and polyethylene glycol (PEG 600 and 1000) as the core via the wet-spinning method. The first part of this work investigated the coagulation bath using Attenuated Total Reflectance-Fourier Transform Infrared Spectroscopy (ATR-FTIR) analyses of the characteristic peak areas. In contrast, the second part examined the PCFs’ morphological, chemical and thermal properties using Bright-field microscopy, ATR-FTIR, Differential Scanning Calorimetry (DSC) and Thermogravimetric Analysis (TGA) techniques. The results demonstrated the successful production of PCFs with an optimised coagulation bath. Bright-field microscopy and ATR-FTIR confirmed the well-defined morphology and the presence of PEG in the fibre core. TGA analysis showed high thermal stability in the PCFs, with mass loss observed at high degradation temperatures, ranging from ~264 °C to 397 °C for the PCFs with PEG 600 and from ~273 °C to 413 °C for the PCFs with PEG 1000. Meanwhile, DSC analysis revealed melting points of ~12.64 °C and 11.04 °C, with endothermic enthalpy of ~39.24 °C and 30.59 °C and exothermic enthalpy of ~50.17 °C and 40.93 °C, respectively, for PCFs with PEG 600, and melting points of ~40.32 °C and 41.13 °C, with endothermic enthalpy of ~83.47 °C and 98.88 °C and exothermic enthalpy of ~84.66 °C and 88.79 °C, respectively, for PCFs with PEG 1000. These results validate the potential of PCFs for applications in building materials for civil engineering, promoting thermal efficiency and structural stability. Full article

One of the main icons of the Roman civilisation are thermal baths, built as public places for personal hygiene, body and mind relaxation, recreation, social encounters, and sport. In Sicily, there is evidence of several thermal buildings dating back to the time of the Roman Empire. Notably, the “Terme della Rotonda”, in the city of Catania, have always attracted strong interest due to their intricate and fascinating architecture. However, at present the dating of the building remains within the complex is still uncertain, and diverse assumptions have been advanced on their original use. In this framework, this study presents the findings of a multidisciplinary research initiative aimed at advancing knowledge of this thermal complex. To this end, a 3D integrated survey of the complex was carried out, and architectural, typological, and construction analyses were conducted to examine the primary building elements. These investigations enabled us to provide detailed insights into the materials and construction techniques used, leading to a new hypothesis on the original layout of the thermal rooms. Additionally, a virtual platform of the archaeological site was developed to serve as a spatial information database, facilitating both scientific research and the dissemination of knowledge about the complex. Full article

Urban heat islands (UHI) are a growing issue due to urbanization, causing citizens to suffer from the inadequate thermal properties of building materials. Therefore, the need for climate-resistant infrastructure is crucial for quality of life. Phase change materials (PCMs) offer a solution by being incorporated into construction materials for thermoregulation. PCMs store and release heat as latent heat, adjusting temperatures through phase changes. Polymeric phase change fibers (PCFs) are an innovative technology for encapsulating PCMs and preventing leaks. This study produced PCFs via wet-spinning, using commercial cellulose acetate (CA, Mn 50,000) as the sheath and polyethylene glycol (PEG 2000) as the core. The PCFs were cut using a hot-cutting method at three different temperatures and washed with distilled water. Morphological analysis was conducted with a bright-field microscope, and chemical analysis was performed using Fourier transform infrared spectroscopy (FTIR) before and after controlled washing. Additionally, the washing baths were analyzed by UV-visible spectroscopy to detect PEG. The PCFs displayed a well-defined core-shell structure. Although some PEG 2000 leakage occurred in unsuccessful cuts, cuts at 50 °C showed sealed ends and less material in the baths, making it viable for civil engineering materials. Full article

A multidisciplinary study, involving hydrogeological, geochemical, and mineralogical analyses, was conducted to define the evolution of thermal mineral springs in the Sabatini Volcanic District (SVD) (Central Italy) in a historic period. The outcomes were integrated with the archeological findings to improve the knowledge of the evolution of Veii, a settlement established since the Iron Age and later expanded by Etruscans and Romans. During the archeological excavations, water-related buildings were identified, especially at the Campetti Southwest site in the Veii settlement. Votive inscriptions also suggest the presence of buildings linked to sacred waters, even if a clear definition of the source and type of water is missing. In the SVD, some low-flow thermal mineral springs are present as a result of the mixing of thermal and CO₂-rich groundwater from the deep carbonate aquifer and the cold, shallow volcanic aquifer. Mineralogical and chemical analyses characterized the travertine and Fe-hydroxide deposits on Roman tanks and walls in Campetti Southwest and in a nearby ancient Roman bath along the Valchetta River. These deposits showed different relative concentrations of sedimentary and volcanic-related elements, testifying a geochemical evolution of the groundwater mixing and the presence of a paleothermal mineral spring in Campetti Southwest. Full article

The Arab baths of Hernando de Zafra, popularly known as Casa de las Tumbas, are found at the intersection of calle Elvira and calle San Andrés in the historic centre of Granada (Spain). This article presents a thermodynamic study of the environmental operation of this complex of Arab baths, which has a furnace and hot, warm, and cold rooms, as well as auxiliary adjoining spaces and annexes. Computer models are used for the finite element analysis of the fluid dynamics for the process of lighting the furnace and subsequently diffusing the temperature, and smoke is expelled through the chimneys. The FDS software used—verified and validated by the NIST—processes the conditions for lighting the furnace and the thermal transmission of the generated heat to the different rooms in the building. This is the first case of this software being used for an analysis of the ancient Arab baths. The results show the global thermal behaviour, and the conclusions establish the temperatures reached inside the rooms and the thermal energy contributions needed to reach these temperatures. Full article

As the urgency to mitigate climate change intensifies, the achievement of zero carbon targets in the built environment has become a critical objective. Building retrofitting plays a vital role in reducing energy consumption and carbon emissions in existing buildings. This paper presents an approach that combines Building Information Modeling (BIM) with multiple domains to strive for zero carbon targets in building retrofit projects. The proposed approach is based on a dynamic multi-parameter analysis that integrates indoor comfort, energy savings, CO_2eq reduction, and the social cost of carbon while considering investment costs. Renewable energy technologies, such as photovoltaic panels and solar thermal systems, are emphasized to achieve the desired zero-carbon outcomes. Real-time monitoring mechanisms enable continuous performance evaluation and adaptive retrofit strategies for further energy savings. This approach is validated through a case study of an existing thermal bath building, known as “Terme Lucane”, located in southern Italy. The results of the study demonstrate significant reductions in energy consumption and carbon emissions, highlighting the potential of the proposed approach to achieve zero carbon targets through the integration of multi-data BIM implementation. These findings offer a promising pathway for building retrofit projects aiming for zero carbon targets through multi-data BIM modeling. Full article

We investigate the time-dependent behaviour of the energy current between a quantum spin chain and its surrounding non-Markovian and finite temperature baths, together with its relationship to the coherence dynamics of the system. To be specific, both the system and the baths are assumed to be initially in thermal equilibrium at temperature $T_s$ and $T_b$, respectively. This model plays a fundamental role in study of quantum system evolution towards thermal equilibrium in an open system. The non-Markovian quantum state diffusion (NMQSD) equation approach is used to calculate the dynamics of the spin chain. The effects of non-Markovianity, temperature difference and system-bath interaction strength on the energy current and the corresponding coherence in cold and warm baths are analyzed, respectively. We show that the strong non-Markovianity, weak system-bath interaction and low temperature difference will help to maintain the system coherence and correspond to a weaker energy current. Interestingly, the warm baths destroy the coherence while the cold baths help to build coherence. Furthermore, the effects of the Dzyaloshinskii–Moriya ($DM$) interaction and the external magnetic field on the energy current and coherence are analyzed. Both energy current and coherence will change due to the increase of the system energy induced by the $DM$ interaction and magnetic field. Significantly, the minimal coherence corresponds to the critical magnetic field which causes the first order phase transition. Full article

One of the most crucial factors for energy transition and the incorporation of renewable energy sources into the existing energy map is citizen engagement. Local energy communities (LECs), which are cooperative-based coalitions aimed at reducing the carbon footprint of the residential building sector, have received increasing attention in the past decade. This is because residential buildings account for almost half of the total energy consumed worldwide. A resounding 75% of it is used for thermal energy consumption, heating and cooling, cooking and bathing. However, the main focus of the literature worldwide is explicitly on electrical LECs, despite the fact that the significant increase in natural gas and oil prices, creates instability in the heating and cooling prices. The scope of this study is to provide an overview of the research field regarding Thermal LECs, using both a thorough literature review as well as bibliometric analysis (VOSviewer software), in order to validate the findings of the review. The results indicate a collective scarcity of literature in the field of thermal/cooling energy communities, despite their proven value to the energy transition. A significant lack of directives, research background and state initiatives in the context of LECs incorporating thermal/cooling energy production, storage and distribution systems, was also observed. Case studies and the applications of such systems are scarce in the available literature, while published studies need further feasibility assessments. Full article

Hydronic systems installed in buildings utilize water to transport thermal energy within the building for heating and cooling purposes. These systems can be closed loop, where the water is chemically treated and circulated indefinitely, or they can be open loop, where the water is not treated and is effluxed as a result of occupant activities, such as bathing or cooking. Water in an open loop system may circulate within the system for a limited time before it is extracted from the system by occupant activities and replaced with new water from the local water supply. The implementation of open loop hydronic systems is becoming more common in multi-unit residential buildings, even though a number of questions regarding the use of such systems remain unanswered. One concern regarding the use of circulated potable water for heating purposes is the potential effects on the occupant perceptions of the palatability of the service water being delivered to their suites. In an open-loop HVAC system (Heating Ventilating, Air Conditioning System), heating water is subject to repeated thermal cycles and continuous recirculation, which creates the potential for chemical alterations of the materials present in the water or leaching of materials from the equipment and piping. Through the use of Flavor Profile Analysis (FPA) established by the American Water Works Association, and a multi-unit HVAC system constructed in a controlled environment, the palatability effects of the operational system were evaluated for a number of scenarios. The collected feedback from the study participants was then tabulated to quantify the impacts of using potable water as a recirculating heating medium on the perceptions of the occupants. The resulting observations led us to conclude that utilizing potable water as a heating medium has a negligible effect on the palatability of water in the system for average retention times under one day, and a non-objectionable, but noticeable, effect for higher average retention times. Full article

We present in this work simulations using the finite difference approximation in 2D for the melting of an encapsulated phase-change material suitable for heat storage applications; in particular, we study CaCl₂·6H₂O in a cylindrical encapsulation of internal radius 8 mm. We choose this particular salt hydrate due to its availability and economic feasibility in high thermal mass building walls or storage. Considering only heat conduction, a thermostat is placed far from the capsule, providing heat for the melting of the phase-change material (PCM), which is initially frozen in a water bath. The difference in density between the solid and liquid phases is taken into account by considering a void in the solid PCM. A simple theoretical model is also presented, based on solving the heat equation in the steady state. The kinetics of melting is monitored by the total solid fraction and temperatures in the inner and outer surfaces of the capsule. The effect of different parameters is presented (thermostat temperature, capsule thickness, capsule conductivity and natural convection in the bath), showing the potential application of the method to select materials or geometries of the capsule. Full article

Adequate ventilation is necessary for thermal comfort and reducing risks from infectious bio-aerosols in hospital wards, but achieving this with mechanical ventilation has carbon and energy implications. Natural ventilation is often limited to window-based designs whose dilution/mixing effectiveness are subject to constraints of wind speed, cross ventilation, and in the case of hospital wards, proximity of patients to external walls. A buoyancy-driven natural ventilation system capable of achieving dilution/mixing was shown to be feasible in a preceding study of novel system called natural personalised ventilation (NPV). This system combined both architecture and airflow engineering principles of space design and buoyancy and was tested and validated (salt-bath experiment) for a single bed ward. This research extends the previous work and is proof-of-concept on the feasibility of NPV system for multi-bed wards. Two different four-bed ward types were investigated of using computational fluid dynamics (CFD) simulations under wind-neutral conditions. Results predict that NPV system could deliver fresh air to multiple patients, including those located 10 m away from external wall, with absolute flow rates of between 32 L·s⁻¹ and 54 L·s⁻¹ for each patient/bed. Compared to same wards simulated using window design, ingress of airborne contaminants into patients’ breathing zone and summer overheating potential were minimised, while overall ward dilution was maximised. Findings suggest the NPV has potentials for enabling architects and building service engineers to decouple airflow delivery from the visualisation and illumination responsibilities placed upon windows. Full article