Search Results (136)

This study investigates the processing of shea nut shells (SNSs), an abundant agricultural waste, into porous activated carbon for supercapacitor electrodes through a two-stage thermal treatment involving pyrolysis and physical activation with CO₂ and steam. The aim was to develop sustainable, high-performance electrode materials while addressing waste management. Carbonization followed by activation yielded 16.5% (CO₂) and 11.3% (steam) activation yields, with total yields of 4.3% and 2.9%, respectively. CO₂ activation produced carbon (AC_CO₂) with a specific surface area (S_BET) of 1528 m² g⁻¹ and a total pore volume of 0.72 cm³ g⁻¹, a graphitization degree (I_D/I_G = 1.0), and low charge transfer resistance (9.05 Ω), delivering a specific capacitance of 47.5 F g⁻¹ at 0.5 A g⁻¹, an energy density of 9.5 Wh kg⁻¹ at 299 W kg⁻¹, and a fast discharge time of 2.10 s, ideal for power-intensive applications. Steam activation yielded carbon (AC_H₂O) with a higher specific surface area (1842 m² g⁻¹) and pore volume (1.57 cm³ g⁻¹), achieving a superior specific capacitance of 102.2 F g⁻¹ at 0.5 A g⁻¹ and a power density of 204 W kg⁻¹ at 9.2 Wh kg⁻¹, suited for energy storage. AC_CO₂ also exhibited exceptional cyclic stability (90% retention after 10,000 cycles). These findings demonstrate SNS-derived activated carbon as a versatile, eco-friendly material, with CO₂ activation optimizing power delivery and steam activation enhancing energy capacity, offering tailored solutions for supercapacitor applications and sustainable waste utilization. Full article

With the increasing deployment of DC power systems, particularly in DC distribution systems, there is a growing demand for rapid and effective fault current limiting solutions. Conventional fault current limiters (FCLs) often suffer from limitations in terms of response time, size, and operational complexity. As a solution to these challenges, this paper proposes a hybrid FCL based on a pyro conductor switch (PCS), which combines passive limiting elements with an active switching mechanism. The proposed PCS FCL consists of a pyro fuse, an IGBT switch, a limiting inductor, and a damping resistor. Upon fault detection, the IGBT switch is first turned off to initiate current transfer into the limiting branch. Subsequently, the pyro fuse operates by explosively severing the embedded conductor using a pyrotechnic charge, thereby providing galvanic isolation and reinforcing current commutation into a high-impedance path. This operational characteristic enables effective fault current suppression without requiring complex control or real-time sensing. A detailed analysis using PSCAD/EMTDC simulations was conducted to evaluate the current limiting characteristics under fault conditions, and a prototype was subsequently developed to validate its performance. The simulation results were verified through experimental testing, indicating the limiter’s ability to reduce peak fault current. Furthermore, the results demonstrated that the degree of current limitation can be effectively designed through the selection of appropriate current limiting parameters. This demonstrates that the proposed PCS-based FCL provides a practical and scalable solution for improving protection in DC power distribution systems. Full article

Internal Dry Reforming of Methane (IDRM) in biogas fed Solid Oxide Fuel Cells (SOFCs) was investigated on Fe-Au modified Ni/GDC electrolyte-supported cells at 900 and 850 °C. The aim was to clarify the synergistic interaction between Fe and Au, focusing on the effect of X wt.% of Au loading (where X = 1 or 3 wt.%) in binary Au-Ni/GDC and ternary 0.5 wt.% Fe-Au-Ni/GDC fuel electrodes. The investigation combined i-V, Impedance Spectroscopy and Gas Chromatography electrocatalytic measurements. It was found that modification with 0.5Fe-Au enhanced significantly the electrocatalytic activity of Ni/GDC for the IDRM reaction, whereas the low wt.% Au content had the most promoting effect. The positive interaction of 0.5 wt.% Fe with 1 wt.% Au increased the conductivity of Ni/GDC and enhanced the corresponding IDRM charge transfer electrochemical processes, especially those in the intermediate frequency region. Comparative long-term measurements, between cells comprising Ni/GDC and 0.5Fe-1Au-Ni/GDC, highlighted the significantly higher IDRM electrocatalytic activity of the modified electrode. The latter operated for almost twice the time (280 h instead of 160 h for Ni/GDC) with a lower degradation rate (0.44 mV/h instead of 0.51 mV/h). Ni/GDC degradation was ascribed to inhibited charge transfer processes in the intermediate frequencies region and to deteriorated ohmic resistance. Stoichiometric analysis on the (post-mortem) surface state of each fuel electrode showed that the wt.% content of reduced nickel on Ni/GDC was lower, compared to 0.5Fe-1Au-Ni/GDC, verifying the lower re-oxidation degree of the latter. This was further correlated to the hindered H₂O production during IDRM operation, due to the lower selectivity of the modified electrode for the non-desired RWGS reaction. Full article

This study focuses on the numerical analysis of the impact of geometric modifications of sheet-gyroid structures on heat transfer in thermal energy storage systems utilizing sodium acetate trihydrate as a phase change material. The aim was to enhance the thermal conductivity of SAT, which is inherently low in the solid phase, by embedding a thermally conductive metallic structure made of aluminum alloy 6061. The simulations compared four gyroid configurations with different degrees of torsional deformation (0°, 90°, 180°, and 360°) alongside a reference model without any structure. Using numerical analysis, the study evaluated the time required to heat the entire volume of SAT above its phase transition temperature (58 °C) as well as the spatial distribution of the temperature field. The results demonstrate that all gyroid configurations significantly reduced the charging time compared with the reference case, with the highest efficiency achieved by the 360° twisted structure. Temperature maps revealed a more uniform thermal distribution within the phase change material and a higher heat flux into the volume. These findings highlight the strong potential of TPMS-based structures for improving the performance of latent heat thermal energy storage systems. Full article

Understanding electron density migration along excited-state pathways in photochemical systems is critical for optimizing solar energy conversion processes. In this study, we investigate photoinduced electron transfer (PET) in a covalently linked donor–bridge–acceptor (D-B-A) system, where [Cu(I)-bis(1,10-phenanthroline)]⁺ acts as an electron donor, and anthraquinone, tethered to one of the phenanthroline ligands via a vibrationally active ethyne bridge, behaves as an electron acceptor. Visible transient absorption spectroscopy revealed the dynamic processes occurring in the excited state, including PET to the acceptor species. This was indicated by the spectral features of the anthraquinone radical anion that appeared on a timescale of 30 ps in polar solvents. Time-resolved infrared (TRIR) spectroscopy of the alkyne vibration (CC stretch) of the ethyne bridge provided insight into electronic structural changes in the metal-to-ligand charge transfer (MLCT) state and along the PET reaction coordinate. The observed spectral shift and enhanced transition dipole moment of the CC stretch demonstrated that there was already partial delocalization to the anthraquinone acceptor following MLCT excitation, verified by DFT calculations. An additional excited-state TRIR signal unrelated to the vibrational mode highlighted delocalization between the phenanthroline ligands in the MLCT state. This signal decayed and the CC stretch narrowed and shifted towards the ground-state frequency following PET, indicating a degree of localization onto the acceptor species. This study experimentally elucidates charge redistribution during PET in a Cu(I) diimine D-B-A system, yielding important information on the ligand design for optimizing PET reactions. Full article

Recently, research and development in the field of dye-sensitized solar cells has been actively advanced, as the technology constitutes a potential alternative to silicon-based photovoltaic devices. Modification of the molecular structure of the dye can enhance the adsorption on the TiO₂ surface, improve the light absorption capacity, suppress the charge recombination, increase the electron injection rate, and thereby improve the overall performance of the solar cell. Carbazole and phenothiazine are rigid heterocyclic compounds containing nitrogen as a heteroatom with large π-conjugated skeletons. Phenothiazine differs from carbazole by the presence of sulfur as an additional electron-rich heteroatom. The inclusion of this heteroatom in the structure of the compounds can indeed improve the electron-donating properties, affect the conjugation, and thus affect the optical, electronic, and electrochemical properties of the chromophores as a whole. The difference in planarity when comparing carbazole with phenothiazine can be useful from several points of view. The planar structure of carbazole increases the degree of conjugation and the electron transfer capacity, which can increase the photocurrent of the cell. The nonplanar structure of phenothiazine helps to prevent π-stacking aggregation. This review comprehensively summarizes the progress in the field of synthesis of organic dyes for solar cells with an emphasis on the comparative analysis of two electron-donating moieties, carbazole and phenothiazine. In addition, the review describes in detail the relationship between the structure of the compounds (dyes), their properties, and the performance of solar cells. Full article

Organic violet-blue fluorescent materials have garnered significant interest for a broad spectrum of applications. A series of triazine-based molecules, that is, 2,4,6-tri(9H-carbazol-9-yl)-1,3,5-triazine (TCZT), 2,4,6-tri(1H-indol-1-yl)-1,3,5-triazine (TIDT), and 2,4,6-tris(3,6-di-tert-butyl-9H-carbazol-9-yl)-1,3,5-triazine (TDBCZT), exhibiting violet-blue emission were synthesized via a catalyst-free aromatic nucleophilic substitution reaction. These compounds possess a non-planar and twisted structure with favorable charge-transfer characteristics, demonstrating excellent thermal stability (decomposition temperatures of 370 °C, 384 °C, and 230 °C, respectively). Cyclic voltammetry analysis, combined with time-dependent density functional theory (TD-DFT) calculations at the B3LYP/6-31G(d) level, offered detailed insights into their electronic structures and electrochemical properties. Optical properties were systematically characterized using Ultraviolet–visible (UV–Vis) absorption and photoluminescence (PL) spectroscopy. The compounds exhibited violet-blue luminescence with emission peaks located at 397 nm, 383 nm, and 402 nm in toluene, respectively. In their respective films, the compounds exhibited varying degrees of spectral shifts, with emission peaks at 408 nm, 381 nm, and 369 nm. Moreover, the CIE (Commission Internationale de l’Éclairage) coordinates of TIDT in toluene were (0.155, 0.067), indicative of excellent violet purity. These compounds demonstrated significant two-photon absorption (TPA) properties, with cross-sections of 4.6 GM, 15.3 GM, and 7.4 GM, respectively. Notably, they exhibited large molar absorptivities and substantial photoluminescence quantum yields (PLQYs), suggesting their potential for practical applications as violet-blue fluorescent materials. Full article

With the increasing global emphasis on sustainable energy, wave energy has gained recognition as a significant renewable marine resource, drawing substantial research attention. However, the efficient conversion of low-frequency, random, and low-energy wave motion into electrical power remains a considerable challenge. In this study, an advanced hybrid generator design is introduced which enhances wave energy harvesting by optimizing wave–body coupling characteristics and incorporating both a triboelectric nanogenerator (TENG) and an electromagnetic generator (EMG) within the shell. The optimized asymmetric trapezoidal shell (ATS) improves output frequency and energy harvesting efficiency in marine environments. Experimental findings under simulated water wave excitation indicate that the accelerations in the x, y, and z directions for the ATS are 1.9 m·s⁻², 0.5 m·s⁻², and 1.4 m·s⁻², respectively, representing 1.2, 5.5, and 2.3 times those observed in the cubic shell. Under real ocean conditions, a single TENG unit embedded in the ATS achieves a maximum transferred charge of 1.54 μC, a short-circuit current of 103 μA, and an open-circuit voltage of 363 V, surpassing the cubic shell by factors of 1.21, 1.24, and 2.13, respectively. These performance metrics closely align with those obtained under six-degree-of-freedom platform oscillation (0.4 Hz, swing angle range of ±6°), exceeding the results observed in laboratory-simulated waves. Notably, the most probable output frequency of the ATS along the x-axis reaches 0.94 Hz in ocean trials, which is 1.94 times the significant wave frequency of ambient sea waves. The integrated hybrid generator efficiently captures low-quality wave energy to power water quality sensors in marine environments. This study highlights the potential of combining synergistic geometric shell design and generator integration to achieve high-performance wave energy harvesting through improved wave–body coupling. Full article

The microstructures of the as-cast and annealed Zr₅₆Cu₁₉Ni₁₁Al₉Nb₅ were investigated by X-ray diffraction (XRD) and scanning electron microscopy (SEM), their microhardness values were tested, and their corrosion behaviours in Hank solution were studied. XRD results and SEM analysis showed that the as-cast sample was amorphous, and crystallisation occurred in the samples annealed at 923 K for 5–30 min with crystals of Zr₂Cu and Zr₂Ni. Microhardness gradually increased and then levelled off, due to higher crystallisation degree with longer annealing time. Passivation occurred for all the samples in Hank solution. Prolonged annealing time leads to the initial rise and then a drop in corrosion resistance. Annealing for 5 min resulted in the highest corrosion resistance, with high corrosion potential E_corr at −0.007 V_SCE, versus saturated calomel electrode (SCE), i.e., 0.234 V_SHE, versus standard hydrogen electrode (SHE), the smallest corrosion current density i_corr at 2.20 × 10⁻⁷ A·cm⁻², the highest pitting potential E_pit at 0.415 V_SCE (i.e., 0.656 V_SHE), the largest passivation region E_pit–E_corr at 0.421 V_SHE, the largest arc radius, and the largest sum of charge transfer resistance and film resistance R_ct + R_f at 15489 Ω·cm². Annealing for 30 min led to the lowest corrosion resistance, with low E_corr at −0.069 V_SCE (i.e., 0.172 V_SHE), large i_corr at 1.32 × 10⁻⁶ A·cm⁻², low E_pit at −0.001 V_SCE (i.e., 0.240 V_SHE), small E_pit − E_corr at 0.068 V_SHE, the smallest arc radius, and the smallest R_ct + R_f at 4070 Ω·cm². When the annealing time was appropriate, the homogeneous microstructure of nanocrystals in an amorphous matrix resulted in improved passivation film, leading to the rise of corrosion resistance. However, if the annealing time was prolonged, the inhomogeneous microstructure of larger crystals in an amorphous matrix resulted in a drop in corrosion resistance. Localised corrosion was observed, with corrosion products of ZrO₂, Cu₂O, CuO, Ni(OH)₂, Al₂O₃, and Nb₂O₅. Full article

A novel fluoride ion fluorescent probe is designed by introducing the strong electron-withdrawing triazine groups into the triarylboron/acridine conjugation system. The A-D-A′ molecular configuration endows this molecule with multiple charge-transfer channels; upon reaction with F⁻, the triazine groups act as primary acceptors within the molecule, facilitating charge transfer between the acridine units and the triazine groups. During fluoride ion detection, changes in the triarylboron moiety lead to a significant bathochromic-shift in fluorescence emission from green to yellow. Theoretical calculations attribute this phenomenon to a reduction in the molecular S₁ state energy level upon fluorination, resulting in a pronounced visible color change and chromogenic response during detection. Based on fluorescence intensity changes with varying degrees of F⁻ coordination, a detection limit as low as 10⁻⁷ M was determined for TB-1DMAc-2TRZ, demonstrating the high sensitivity of this probe. Full article

Vehicle-to-vehicle dynamic wireless charging (V2V-DWC) represents a modern advancement in electrified transportation, where a specialized charging vehicle delivers power to another vehicle on the move. The rising popularity of this technology can be attributed to the gradual advancements in energy storage technologies and the scarcity of plug-in charging infrastructure. V2V wireless power transfer provides a solution for electric vehicles (EVs) to recharge their batteries while in transit. The existing literature confirms the empirical validation of this concept through analytical and experimental studies, yet the challenge of misalignment remains insufficiently explored. Achieving optimal power transfer in V2V systems necessitates precise alignment of the inductive coils. Lateral misalignment (LTM) occurs due to the deviation of the coils from the proper alignment, leading to significant energy losses. Additionally, the development of effective controllers to address the V2V misalignment problem remains inadequate. This study proposes the development of a neural network-based adaptive fuzzy logic controller (ANFIS) to alleviate the misalignment issues in V2V-DWC systems. A comparative analysis is conducted between the proposed ANFIS controller and the conventional fuzzy logic controller (FLC) to evaluate their performance across various degrees of LTM. The performance of the proposed ANFIS controller is evaluated through simulations in MATLAB/Simulink, supplemented by experimental testing. The results indicate that the proposed ANFIS controller surpasses the FLC in both simulation and experimental contexts in addressing the V2V misalignment challenge. Full article

Poly-CPDTBT, as typical low-band gap copolymers, have potential applications in organic bulk heterojunction solar cells. To have a clear picture of its excited-state processes, the first task is to understand their excited states, in particular, electronic character and relevant optical absorption. Herein, the low-lying singlet excited states of Poly-CPDTBT oligomers were investigated via Algebraic Diagrammatic Construction Second Order (ADC(2)) and time-dependent density functional theory (TDDFT) method with several functionals. Six CPDTBT_N (N = 1–6) oligomers were taken as prototypes to study their excited states in detail. The results provide interesting clues to extrapolate the photophysical properties of such polymers with potential applications in photovoltaic materials. The result provided by ωB97XD functional gives good agreement with the experiment result. The vertical excitation energies of the four lowest excited states decrease almost linearly with increasing polymerization degree (N) for CPDTBT_N (N = 1–6). The transition density analysis indicates that the local excitations (LE) and the short-distance charge transfer (CT) excitations between two adjacent CPDT and BT units are dominant for low-lying excited states for short oligomers. For the long-chain oligomers (trimer to hexamer), the transition density shows a ladder (or zigzag) pattern along the diagonal blocks at the planar geometry. For long oligomers, the whole chain is involved in the transitions, and the CT excitations only exist between two adjacent CPDT and BT units. The present work provides a valuable basis for understanding the excited-state processes of Poly-CPDTBT and other conjugated polymers that conduct solar energy conversions, which has great significance for the development of new solar cells. Full article

We introduce a theoretical model for the photocurrent-voltage (I-V) characteristics designed to elucidate the interfacial phenomena in photoelectrochemical cells (PECs). This model investigates the sources of voltage losses and the distribution of photocurrent across the semiconductor–electrolyte interface (SEI). It calculates the whole exchange current parameter to derive cell polarization data at the SEI and visualizes the potential drop across n-type cells. The I-V model’s simulation outcomes are utilized to distinguish between the impacts of bulk recombination and space charge region (SCR) recombination within semiconductor cells. Furthermore, we develop an advanced deep neural network model to analyze the electron–hole transfer dynamics using the I-V characteristic curve. The model’s robustness is evaluated and validated with real-time experimental data, demonstrating a high degree of concordance with observed results. Full article

Vapor compression heat pump technology is a widely utilized method for energy conversion. Lubricating oil plays a crucial role in the heat pump system cycle by effectively reducing wear on the compressor’s moving parts and preventing refrigerant leakage. However, it can also create an oil film in the heat exchange equipment, which increases thermal resistance and diminishes heat transfer efficiency. This study utilizes a vapor compression heat pump system test bench to investigate factors influencing the system’s oil circulation rate, the two-phase flow patterns of refrigerant and lubricating oil, and the impact of oil circulation on system performance. The findings reveal that as the compressor speed increases, the oil circulation rate initially decreases before increasing again. Additionally, a decrease in the evaporator’s heat load leads to a reduction in oil circulation at high temperatures, while it increases at low temperatures. Furthermore, increasing the opening of the electronic expansion valve results in a gradual decrease in the oil circulation rate, whereas an increase in the refrigerant charge correlates with a rise in the oil circulation rate. The oil return flow pattern can primarily be categorized into three states: slow oil return, oil film flow, and high-speed oil return. These patterns are closely related to the degree of superheat, with lower superheat levels intensifying oil return. Full article

Air pollutants are usually formed by easily spreading small molecules, representing a severe problem for human health, especially in urban centers. Despite the efforts to stem their diffusion, many diseases are still associated with exposure to these molecules. The present study focuses on modeling and designing two-dimensional systems called Layered Double Hydroxides (LDHs), which can potentially trap these molecules. For this purpose, a Density Functional Theory (DFT) approach has been used to study the role of the elemental composition of LDHs, the type of counterion, and the ability of these systems to intercalate NO₂ and SO₂ between the LDH layers. The results demonstrated how the counterion determines the different possible spacing between the layers, modulating the internalization capacity of pollutants and determining the stability degree of the system for a long-lasting effect. The variations in structural properties, the density of states (DOS), and the description of the charge transfer have been reported, thus allowing the investigation of aspects that are difficult to observe from an experimental point of view and, at the same time, providing essential details for the effective development of systems that can counteract the spread of air pollutants. Full article