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Keywords = temperature dependence of electroconductivity

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14 pages, 8581 KB  
Article
Analysis Based on a Two-Dimensional Mathematical Model of the Thermo-Stressed State of a Copper Plate During Its Induction Heat Treatment
by Roman Musii, Myroslava Klapchuk, Eugeniusz Koda, Ivan Kernytskyy, Inga Svidrak, Ruslan Humeniuk, Yaroslav Sholudko, Mykola Nagirniak, Joanna Andrzejak and Yuriy Royko
Symmetry 2025, 17(5), 754; https://doi.org/10.3390/sym17050754 - 14 May 2025
Cited by 1 | Viewed by 784
Abstract
A two-dimensional physical and mathematical model is proposed for determining the components of the stress tensor and stress intensity in an electroconductive plate of rectangular cross-section under the action of an unsteady electromagnetic field. The two-dimensional thermomechanics problem for such a plate is [...] Read more.
A two-dimensional physical and mathematical model is proposed for determining the components of the stress tensor and stress intensity in an electroconductive plate of rectangular cross-section under the action of an unsteady electromagnetic field. The two-dimensional thermomechanics problem for such a plate is formulated. The determining functions are the component of the magnetic field intensity vector tangent to the plate bases, temperature, and components of the stress tensor. The methodology for solving the formulated thermomechanics problem by approximating all the determining functions by the thickness variable with cubic polynomials is developed. As a result, the original two-dimensional problems related to the determining functions are reduced to one-dimensional problems on the integral characteristics of these functions. To solve the obtained systems of equations for the integral characteristics of the determining functions, a finite integral transformation in the transverse variable is used. During induction heating of a copper plate by a homogeneous quasi-steady-state electromagnetic field, the change in the stress intensity depending on the Fourier time, as well as its distribution across the plate cross-section depending on the parameters of induction heating and the Biot criterion, is numerically analyzed. Full article
(This article belongs to the Section B: Mathematics)
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23 pages, 5287 KB  
Article
Humidity- and Temperature-Sensing Properties of 2D-Layered Tungsten Di-Selenide (2H-WSe2) Electroconductive Coatings for Cotton-Based Smart Textiles
by Valentina Trovato, Rajashree Konar, Eti Teblum, Paolo Lazzaroni, Valerio Re, Giuseppe Rosace and Gilbert Daniel Nessim
Polymers 2025, 17(6), 752; https://doi.org/10.3390/polym17060752 - 12 Mar 2025
Cited by 8 | Viewed by 3599
Abstract
Electroconductive textiles (e-Textiles) are vital in developing wearable sensors that preserve the comfort and characteristics of textiles. Among two-dimensional (2D) transition metal dichalcogenides (TMDs), considered a promising option for sensor applications, tungsten di-selenide (WSe2) homostructures have been used as humidity- and [...] Read more.
Electroconductive textiles (e-Textiles) are vital in developing wearable sensors that preserve the comfort and characteristics of textiles. Among two-dimensional (2D) transition metal dichalcogenides (TMDs), considered a promising option for sensor applications, tungsten di-selenide (WSe2) homostructures have been used as humidity- and temperature-sensing materials for developing e-textiles, as mentioned in a first-of-its-kind report. Exfoliated chemical vapor deposition (CVD)-grown 2H-WSe2 nanosheets were dispersed in hydroalcoholic solutions using an amino-functionalized silane to improve dispersion. Acrylic thickener was added to create 2H-WSe2-based pastes, which were applied onto cotton using the knife-over-roll technique to obtain thin, flexible electroconductive coatings on textiles. Various characterization techniques confirmed the even distribution of 2D-WSe2-based coatings on fabrics and the maintenance of textile comfort and wearability. The conductivity of coated fabrics was measured at room temperature and ranged between 2.9 × 108 and 1.6 × 109 Ω sq−1. The WSe2-based textile sensors functioned well as resistance humidity detectors within 30–90% relative humidity (RH), revealing good repeatability and sensitivity after multiple exposure cycles. To a lesser extent, WSe2-based textile sensors act as temperature detectors within 20–60 °C with limited repeatability. The 2D-based textiles exhibited a quadratic dependence of resistance on temperature and a characteristic thermal hysteresis. This proposed strategy marks a significant milestone in developing scalable and flexible 2D TMD-based detectors with great potential for wearable sensing devices. Full article
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13 pages, 4799 KB  
Article
The Influence of Buffer Layer Type on the Electrical Properties of Metallic Layers Deposited on Composite Textile Substrates in the PVD Process
by Marcin Lebioda and Ewa Korzeniewska
Materials 2023, 16(13), 4856; https://doi.org/10.3390/ma16134856 - 6 Jul 2023
Cited by 5 | Viewed by 1694
Abstract
In the era of developing wearable electronics, the miniaturization of electronic systems and their implementation in the textile industry is one of the key issues. For this reason, it is important to select the appropriate textile substrates upon which it is possible to [...] Read more.
In the era of developing wearable electronics, the miniaturization of electronic systems and their implementation in the textile industry is one of the key issues. For this reason, it is important to select the appropriate textile substrates upon which it is possible to produce electroconductive structures, as well as their selection from the point of view of the electrical parameters’ stability. For this purpose, research related to the effect of heating a substrate on the resistance of the structures produced in the process of physical vacuum planting was conducted. Textile composites with a buffer layer made of polyurethane, Teflon, and acrylic were used as substrates in the tests. Such layers are an integral part of textile composites and a necessary element for producing structures with continuous electrical conductivity. The conducted tests showed that a buffer layer made of polyurethane (thermal conductivity, e.g., PERMACOL 5450 resin 0.16 W/mK) heated to 15 °C above room temperature was a layer that introduced changes into the surface resistance of the structures. The resistance values of the samples produced on a substrate containing a buffer layer of polyurethane varied in the range of 9–23%, depending on the manufacturer of the composite in the case of a self-heating mode, and in the case of an external heating mode, these changes were smaller and ranged from 8 to 16%. Such a phenomenon occurred regardless of the type of applied metal, and this was not observed in the case of composites with a Teflon or acrylic sublayer. For this reason, it is necessary to take into account the fact that textronic structures made on substrates containing a polyurethane layer may change the surface resistance depending on the temperature. The electrical parameters of such structures were checked by heating the structure using an external heater and self-heating mechanism. The same phenomenon was observed in both cases. Full article
(This article belongs to the Special Issue State of the Art: Surface and Coating Technologies)
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20 pages, 2237 KB  
Review
Review on Hydrogel-Based Flexible Supercapacitors for Wearable Applications
by Melkie Getnet Tadesse and Jörn Felix Lübben
Gels 2023, 9(2), 106; https://doi.org/10.3390/gels9020106 - 26 Jan 2023
Cited by 62 | Viewed by 9696
Abstract
Smart hydrogels with high electrical conductivity, which can be a real source of power while also collecting and storing the diverse sources of energy with ultrahigh stretchability, strong self-healability, low-temperature tolerance, and excellent mechanical properties, are great value for tailored wearable cloths. Considerable [...] Read more.
Smart hydrogels with high electrical conductivity, which can be a real source of power while also collecting and storing the diverse sources of energy with ultrahigh stretchability, strong self-healability, low-temperature tolerance, and excellent mechanical properties, are great value for tailored wearable cloths. Considerable effort has been dedicated in both scientific and technological developments of electroconductive hydrogels for supercapacitor applications in the past few decades. The key to realize those functionalities depends on the processing of hydrogels with desirable electrochemical properties. The various hydrogel materials with such properties are now emerging and investigated by various scholars. The last decade has witnessed the development of high-performance supercapacitors using hydrogels. Here, in this review, the current status of different hydrogels for the production of flexible supercapacitors has been discussed. The electrochemical properties such as capacitance, energy density and cycling ability has been given attention. Diverse hydrogels, with their composites such as carbon-based hydrogels, cellulose-based hydrogels, conductive-polymer-based hydrogels and other hydrogels with excellent electromechanical properties are summarized. One could argue that hydrogels have played a central, starring role for the assembly of flexible supercapacitors for energy storage applications. This work stresses the importance of producing flexible supercapacitors for wearable clothing applications and the current challenges of hydrogel-based supercapacitors. The results of the review depicted that hydrogels are the next materials for the production of the flexible supercapacitor in a more sustainable way. Full article
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18 pages, 6248 KB  
Article
All-Ceramic Passive Wireless Temperature Sensor Realized by Tin-Doped Indium Oxide (ITO) Electrodes for Harsh Environment Applications
by Kavin Sivaneri Varadharajan Idhaiam, Joshua A. Caswell, Peter D. Pozo, Katarzyna Sabolsky, Konstantinos A. Sierros, Daryl S. Reynolds and Edward M. Sabolsky
Sensors 2022, 22(6), 2165; https://doi.org/10.3390/s22062165 - 10 Mar 2022
Cited by 18 | Viewed by 5734
Abstract
In this work, an all-ceramic passive wireless inductor–capacitor (LC) resonator was presented for stable temperature sensing up to 1200 °C in air. Instead of using conventional metallic electrodes, the LC resonators are modeled and fabricated with thermally stable and highly electroconductive ceramic oxide. [...] Read more.
In this work, an all-ceramic passive wireless inductor–capacitor (LC) resonator was presented for stable temperature sensing up to 1200 °C in air. Instead of using conventional metallic electrodes, the LC resonators are modeled and fabricated with thermally stable and highly electroconductive ceramic oxide. The LC resonator was modeled in ANSYS HFSS to operate in a low-frequency region (50 MHz) within 50 × 50 mm geometry using the actual material properties of the circuit elements. The LC resonator was composed of a parallel plate capacitor coupled with a planar inductor deposited on an Al2O3 substrate using screen-printing, and the ceramic pattern was sintered at 1250 °C for 4 h in an ambient atmosphere. The sensitivity (average change in resonant frequency with respect to temperature) from 200–1200 °C was ~170 kHz/°C. The temperature-dependent electrical conductivity of the tin-doped indium oxide (ITO, 10% SnO2 doping) on the quality factor showed an increase of Qf from 36 to 43 between 200 °C and 1200 °C. The proposed ITO electrodes displayed improved sensitivity and quality factor at elevated temperatures, proving them to be an excellent candidate for temperature sensing in harsh environments. The microstructural analysis of the co-sintered LC resonator was performed using a scanning electron microscope (SEM) which showed that there are no cross-sectional and topographical defects after several thermal treatments. Full article
(This article belongs to the Special Issue Sensors for High Temperature Monitoring)
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22 pages, 11758 KB  
Article
The Influence of Electro-Conductive Compression Knits Wearing Conditions on Heating Characteristics
by Md. Reazuddin Repon, Ginta Laureckiene and Daiva Mikucioniene
Materials 2021, 14(22), 6780; https://doi.org/10.3390/ma14226780 - 10 Nov 2021
Cited by 15 | Viewed by 3775
Abstract
Textile-based heaters have opened new opportunities for next-generation smart heating devices. This experiment presents electrically conductive textiles for heat generation in orthopaedic compression supports. The main goal was to investigate the influence of frequent washing and stretching on heat generation durability of constructed [...] Read more.
Textile-based heaters have opened new opportunities for next-generation smart heating devices. This experiment presents electrically conductive textiles for heat generation in orthopaedic compression supports. The main goal was to investigate the influence of frequent washing and stretching on heat generation durability of constructed compression knitted structures. The silver coated polyamide yarns were used to knit a half-Milano rib structure containing elastomeric inlay-yarn. Dimensional stability of the knitted fabric and morphological changes of the silver coated electro-conductive yarns were investigated during every wash cycle. The results revealed that temperature becomes stable within two minutes for all investigated fabrics. The heat generation was found to be dependent on the stretching, mostly due to the changing surface area; and it should be considered during the development of heated compression knits. Washing negatively influences the heat-generating capacity on the fabric due to the surface damage caused by the mechanical and chemical interaction during washing. The higher number of silver-coated filaments in the electro-conductive yarn and the knitted structure, protecting the electro-conductive yarn from mechanical abrasion, may ensure higher durability of heating characteristics. Full article
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20 pages, 3757 KB  
Article
Investigations of LiNb1−xTaxO3 Nanopowders Obtained with Mechanochemical Method
by Leonid Vasylechko, Volodymyr Sydorchuk, Andrey Lakhnik, Yuriy Suhak, Damian Wlodarczyk, Stepan Hurskyy, Uliana Yakhnevych, Yaroslav Zhydachevskyy, Dmytro Sugak, Ihor I. Syvorotka, Ivan Solskii, Oleh Buryy, Andrzej Suchocki and Holger Fritze
Crystals 2021, 11(7), 755; https://doi.org/10.3390/cryst11070755 - 28 Jun 2021
Cited by 14 | Viewed by 3852
Abstract
Nanocrystalline compounds LiNb1−xTaxO3 of various compositions (x = 0, 0.25, 0.5, 0.75, 1) were synthesized by high-energy ball milling of the initial materials (Li2CO3, Nb2O5, Ta2O [...] Read more.
Nanocrystalline compounds LiNb1−xTaxO3 of various compositions (x = 0, 0.25, 0.5, 0.75, 1) were synthesized by high-energy ball milling of the initial materials (Li2CO3, Nb2O5, Ta2O5) and subsequent high-temperature annealing of the resulting powders. Data on the phase composition of the nanopowders were obtained by X-ray diffraction methods, and the dependence of the structural parameters of LiNb1−xTaxO3 compounds on the value of x was established. As a result of the experiments, the optimal parameters of the milling and annealing runs were determined, which made it possible to obtain single-phase compounds. The Raman scattering spectra of LiNb1−xTaxO3 compounds (x = 0, 0.25, 0.5, 0.75, 1) have been investigated. Preliminary experiments have been carried out to study the temperature dependences of their electrical conductivity. Full article
(This article belongs to the Special Issue New Trends in Lithium Niobate: From Bulk to Nanocrystals)
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