Search Results (6)

The transport of chloride ions in concrete is often affected by electric fields, and its concentration distribution is generally evaluated using the Nernst–Planck equation. The Nernst–Planck theory can only effectively predict the mass electromigration in ideal porous media. However, under an electric field, cementitious materials still have a certain binding ability to chloride ions. This causes the transport model to have significant prediction errors, and the specific value of the electromigration coefficient cannot be accurately measured. This article systematically investigated the transfer rate of chloride ions in cementitious material under different current densities. An analytical solution of the Nernst–Planck equation containing an independent electromigration coefficient was presented, and its value was quantitatively measured and discussed. The results indicated that the relationship between the electromigration and the apparent diffusion coefficient of chloride ions needs to be fitted in segments corresponding to various electric voltage intensities; but the electromigration coefficient shows a highly linear relationship with the pure effective diffusion coefficient. This work can provide assistance and valuable data support for the evaluation of mass transport in non-ideal porous media, such as cementitious materials, using the Nernst–Planck theory. Full article

Aqueous sources like salt lake brines and seawater are the most abundant source for lithium ions and might contribute to the growing demand for lithium for energy storage. By coupling with the increasingly relevant reverse osmosis systems, nanofiltration can provide a promising process alternative to conventional methods such as water evaporation and salt precipitation from ores or brines for this purpose. One possible model for nanofiltration is the solution-diffusion-electromigration model (SDEM). First, the model was parametrized by determining the permeances from simple electrolyte mixtures containing two salts. Then, the SDEM was used to predict the rejections of complex multi-electrolyte solutions that mimic seawater and reverse osmosis brine, without fitting additional parameters to experimental data of this complex mixture. This allowed predicting ion rejections satisfactorily. Negative rejections due to spontaneously generated electric fields in the membrane could also be qualitatively described. In summary, this SDEM modeling can provide an important contribution to the purification of Li⁺ from aqueous sources. Full article

Nanofiltration is well suited to separate monovalent ions from multivalent ions, such as the separation of Li⁺ and Mg²⁺ from seawater, a potential lithium source for the production of lithium-ion batteries. To the best of our knowledge, there is no existing work on the optimization of a multi-stage membrane plant that differentiates between different ions and that is based on a validated transport model. This study presents a method for modeling predefined membrane interconnections using discretization along the membrane length and across the membrane thickness. The solution-diffusion–electromigration model was used as the transport model in a fundamental membrane flowsheet, and the model was employed to optimize a given flowsheet with a flexible objective function. The methodology was evaluated for three distinct separation tasks, and optimized operating points were found. These show that permeances and feed concentrations might cause negative rejections and positive rejections (especially for bivalent ions) depending on the ions’ properties and fluxes, thereby allowing for a favorable separation between the ions of different valence at optimized conditions. In an application-based case study for the separation of Li⁺ and Mg²⁺ from seawater, the method showed that under optimal conditions, the mol-based ratio of Mg²⁺/Li⁺ can be reduced from 2383 to 2.8 in three membrane stages. Full article

Electrokinetic remediation has, in recent years, shown great potential in remediating polluted environments. The technology can efficiently remove heavy metals, chlorophenols, polychlorinated biphenyls, phenols, trichloroethane, benzene, toluene, ethylbenzene, and xylene (BTEX) compounds and entire petroleum hydrocarbons. Electrokinetic remediation makes use of electrolysis, electroosmosis, electrophoresis, diffusion, and electromigration as the five fundamental processes in achieving decontamination of polluted environments. These five processes depend on pH swings, voltage, electrodes, and electrolytes used in the electrochemical system. To apply this technology at the field scale, it is necessary to pursue the design of effective processes with low environmental impact to meet global sustainability standards. It is, therefore, imperative to understand the roles of the fundamental processes and their interactions in achieving effective and sustainable electrokinetic remediation in order to identify cleaner alternative solutions. This paper presents an overview of different processes involved in electrokinetic remediation with a focus on the effect of pH, electrodes, surfactants, and electrolytes that are applied in the remediation of contaminated soil and how these can be combined with cleaner technologies or alternative additives to achieve sustainable electrokinetic remediation. The electrokinetic phenomenon is described, followed by an evaluation of the impact of pH, surfactants, voltage, electrodes, and electrolytes in achieving effective and sustainable remediation. Full article

In microelectronic packaging technology for three-dimensional integrated circuits (3D ICs), Cu-to-Cu direct bonding appears to be the solution to solve the problems of Joule heating and electromigration (EM) in solder microbumps under 10 $\mathsf{\mu }\mathrm{m}$ in diameter. However, EM will occur in Cu–Cu bumps when the current density is over ${10}^6 \mathrm{A}/{\mathrm{cm}}^2$. The surface, grain boundary, and the interface between the Cu and TiW adhesion layer are the three major diffusion paths in EM tests, and which one may lead to early failure is of interest. This study showed that bonding strength affects the outcome. First, if the bonding strength is not strong enough to sustain the thermal mismatch of materials during EM tests, the bonding interface will fracture and lead to an open circuit of early failure. Second, if the bonding strength can sustain the bonding structure, voids will form at the passivation contact area between the Cu–Cu bump and redistribution layer (RDL) due to current crowding. When the void grows along the passivation interface and separates the Cu–Cu bump and RDL, an open circuit can occur, especially when the current density and temperature are severe. Third, under excellent bonding, when the voids at the contact area between the Cu–Cu bump and RDL do not merge together, the EM lifetime can be more than 5000 h. Full article

For effective use of advanced engineering models of nanofiltration quality of experimental input is crucial, especially in electrolyte mixtures where simultaneous rejections of various ions may be very different. In particular, this concerns the quantitative control of concentration polarization (CP). This work used a rotating disklike membrane test cell with equally accessible membrane surface, so the CP extent was the same over the membrane surface. This condition, which is not satisfied in the conventional membrane test cell, made possible correcting for CP easily even in multi-ion systems. Ion rejections were studied experimentally for several dominant salts (NaCl, MgCl₂, Na₂SO₄ and MgSO₄) and trace ions (Na⁺, NH₄⁺, Cl⁻ and NO₃⁻) using NF270 membrane. The solution–diffusion–electro–migration model was used to obtain ion permeances from the experimental measurements. The model could well fit the experimental data except in the case of NH₄⁺. The correlations between the ion permeances and type of dominant salt are discussed in the context of the established mechanisms of NF such as Donnan and dielectric exclusion. The obtained information contributes to the systematic transport characterization of NF membranes and may be ultimately useful for computational fluid dynamics simulations of the performance of the membranes in various applications. Full article