Search Results (7)

Both synthetic and natural rubber-like elastomers are widely employed in industrial applications (such as tires, seals, protective gloves, and damping absorbers) as well as in the food and animal husbandry industries. These materials should be regularly checked for contamination and the associated infectious risk since they frequently come into contact with food, animals, and people. Additionally, they could act as vehicle of microbes and, as a result, diseases. This pilot study investigates the antibacterial efficacy of novel elastomer formulations against Salmonella enterica subsp. enterica serovar Enteritidis and Legionella pneumophila, with possible applications in drinking water distribution systems (DWDSs). This study aims to evaluate the antimicrobial activity of two rubber and five silicone patented elastomers with antibacterial additives. Two microbiological concentrations (10³ and 10⁴ CFU/mL) were used to compare the efficacy of the elastomers. The results showed a significant decrease in bacterial load in several silicone formulations, with two of them showing the strongest bactericidal efficacy against L. pneumophila (0% and 3% survival rates for VMQ105 and VMQ500L formulations, respectively), despite the wide variations in S. Enteritidis inhibition. One rubber elastomer performed better than the other in terms of reducing bacterial survival for both pathogens (NBRCA) while NBROM showed a 0% survival rate only for L. pneumophila. The findings suggest that certain elastomer compositions might lessen the potential infectious risks in water systems or contaminated matrices. Future research may investigate in situ applications, particularly in hospitals or dental offices where these pathogens pose major health risks. Full article

This study explores the impact of butadiene rubber (BR) crystallization on the low-temperature properties of butadiene/silicone (VMQ) rubber blends (BR/VMQ) designed for Martian applications. Two types of BR, semi-crystalline high-cis Buna CB24 and amorphous Buna CB550, were blended with VMQ, and their mechanical and thermal properties were evaluated. Kinetics of vulcanization, static mechanical properties, dynamical mechanical analysis, thermal shrinkage, and differential scanning calorimetry were utilized. The research demonstrates that the semi-crystalline BR improves mechanical properties but induces greater shrinkage at low temperatures. Conversely, using amorphous BR provided more consistent mechanical properties across the Martian temperature range and reduced material shrink by 6.71% for samples with carbon black, by 8.36% for samples with silica, and by 11.63% for unfilled samples. Future research will be required to evaluate the impact of volume change on the sealing properties of the BR/VMQ blends. Full article

Flexible strain sensors have a wide range of applications in the field of health monitoring of seismic isolation bearings. However, the nonmonotonic response with shoulder peaks limits their application in practical engineering. Here we eliminate the shoulder peak phenomenon during the resistive-strain response by adjusting the dispersion of conductive nanofillers. In this paper, carbon black (CB)/methyl vinyl silicone rubber (VMQ) composites were modified by adding a silane coupling agent (KH550). The results show that the addition of KH550 eliminates the shoulder peak phenomenon in the resistive response signal of the composites. The reason for the disappearance of the shoulder peak phenomenon was explained, and at the same time, the mechanical properties of the composites were enhanced, the percolation threshold was reduced, and they had excellent strain-sensing properties. It also exhibited excellent stability and repeatability during 18,000 cycles of loading–unloading. The resistance-strain response mechanism was explained by the tunneling effect theoretical model analysis. It was shown that the sensor has a promising application in the health monitoring of seismic isolation bearings. Full article

Progressive urbanisation causes building users to be affected by increasing amounts of noise and vibrations that come from transportation and other building users. This article presents a test method that can be used to identify quantities of methyl vinyl silicone rubber (VMQ) necessary to carry out solid mechanics finite element method simulations such as Young’s modulus, Poisson ratio, and damping parameters. These parameters are necessary to model the vibration isolation used for protection against noise and vibration. The article uses an original combination of dynamic response spectrum and image processing methods to determine these quantities. The tests were carried out using one machine for the range of normal compressive stresses of 64–255 kPa with cylindrical samples of various shape factors in the range of 1–0.25. The parameters for the simulation of solid mechanics in statics were obtained from image processing based on the deformation of the sample under load; for dynamic solid mechanics, the parameters were obtained from the response spectrum of the tested system. The article shows the possibility of determining the given quantities using the original method of the synthesis of dynamic response and FEM-supported image analysis, which states the article’s novelty. Additionally, limitations and preferred ranges of sample deformation in terms of load stress and shape factor are presented. Full article

In order to realize effective monitoring for the working performance of seismic isolation structures, a multi-walled carbon nanotube (MWCNT)/methyl vinyl silicone rubber (VMQ) composite was prepared via mechanical blending using dicumyl peroxide (DCP) and 2,5-dimethyl-2,5-di(tert-butyl peroxy)hexane (DBPMH) as vulcanizing agents. The effects of the different vulcanizing agents on the dispersion of the MWCNT, electrical conductivity, mechanical properties, and resistance–strain response of the composites were investigated. The experimental results showed that the percolation threshold of the composites prepared with the two vulcanizing agents was low, while the DCP-vulcanized composites showed high mechanical properties and a better resistance–strain response sensitivity and stability, especially after 15,000 loading cycles. According to the analysis using scanning electron microscopy and Fourier infrared spectroscopy, it was found that the DCP contributed higher vulcanization activity, a denser cross-linking network, better and uniform dispersion, and a more stable damage–reconstruction mechanism for the MWCNT network during the deformation load. Thus, the DCP-vulcanized composites showed better mechanical performance and electrical response abilities. When employing an analytical model based on the tunnel effect theory, the mechanism of the resistance–strain response was explained, and the potential of this composite for real-time strain monitoring for large deformation structures was confirmed. Full article

Transferring wine is a common operation in most of the wineries in the world that depends mainly on the equipment and materials used. These contributions are widely unknown, and their knowledge is of vital importance to controlling the winemaking process. This work presents the results of characterizing the oxygen supply due to the use of hoses of different materials (Butyl Rubber, IIR; Nitrile Butadiene Rubber, NBR; Ethylene Propylene Diene Monomer rubber, EPDM; Ultra-high-molecular-weight polyethylene, UHMW; Natural Rubber, NR), dimensions (DN32; DN50), connectors (DIN 11851, Tri-CLAMP) with gaskets of different materials (NBR; EPDM; Fluorocarbon, FKM/FPM; silicone rubber, Q/VMQ; Polytetrafluoroethylene, PTFE). In addition, the use of different inert gases (N₂, CO₂, Ar, N₂ + CO₂ and Ar + CO₂) for air purging of hoses and tanks, as well as for ullage blanketing during tank-to-tank racking, and their economic impact were studied. The results indicated that the IIR hoses had the least amount of O₂ added to the liquid and that the Tri-clamp connectors were generally more airtight, with the FKM seals standing out. The most recommended inert gas was CO₂ when the type of wine allows it, N₂ being the most recommended in any case. When all these recommendations were used together the addition of O₂ during tank-to-tank racking was drastically reduced. Full article

Soft electronics based on various rubbers have lately been needed in many advanced applications such as soft robotics, wearable electronics, and remote health monitoring. The ability of a self-sensing material to be monitored in use provides a significant advantage. However, conductive fillers usually used to increase conductivity also change mechanical properties. Most importantly, the initial sought-after properties of rubber, namely softness and long elastic deformation, are usually compromised. This work presents full mechanical and electro-mechanical characterization, together with self-sensing abilities of a vinyl methyl silicone rubber (VMQ) and multi-walled carbon nanotubes (MWCNTs) composite, featuring conductivity while maintaining low hardness. The research demonstrates that MWCNT/VMQ with just 4 wt.% of MWCNT are as conductive as commercial conductive VMQ based on Carbon Black, while exhibiting lower hardness and higher elastic recovery (~20% plastic deformation, similar to pure rubber). The research also demonstrates piezo-resistivity and Raman-sensitivity, allowing for self-sensing. Using morphological data, proposed mechanisms for the superior electrical and mechanical behavior, as well as the in-situ fingerprint for the composite conditions are presented. This research novelty is in the full MWCNT/VMQ mechanical and electro-mechanical characterization, thus demonstrating its ability to serve as a sensor over large local strains, multiple straining cycles, and environmental damage. Full article