Search Results (16)

Precise dating of prehistoric volcanic eruptions is essential for reconstructing eruption sequences and assessing volcanic hazards. The timing of the onset and termination of volcanic activity in the Xilinhot volcanic field (XVF) has been a topic of debate for years. Volcanic eruptions in this area began during the Pliocene, with the K-Ar (Ar-Ar) method providing reliable ages for early formed volcanic rocks; however, this method is less effective for dating younger volcanic events that occurred since the Late Pleistocene. For younger volcanoes, sediments baked by volcanic materials, organic sediments, and silty mudstones entrapped in lava serve as excellent geological carriers for dating. In this study, suitable samples collected from the XVF were dated using ¹⁴C and optically stimulated luminescence (OSL) methods. The ¹⁴C ages obtained for the Gezishan volcano are ~6.8 cal. ka BP, while its OSL age is ~7.8 ka. The ages dated by these two methods, combined with volcano–sedimentary stratigraphic relationships and volcanic topography, confirm the Holocene eruptions of the Gezishan volcano, categorizing it as a broadly active volcano. The upper boundary age of the sandy loam layer beneath the Gezishan lava flow is ~15.5 ka, indicating that the south lava of the Gezishan effusion occurred later than the late stage of the Late Pleistocene. Additionally, the OSL ages of baked sediments at the bottom of the base surge deposits from a Maar-type volcano and aeolian sand interlayers within a Strombolian-type scoria cone in the study area are ~50 ka and ~60 ka, respectively, representing eruptions in the middle Late Pleistocene. These findings demonstrate that volcanic activity in the XVF remained vigorous during the Late Pleistocene to Holocene. This study provides significant insights for reconstructing the evolutionary history of Xilinhot volcanic activity and assessing regional volcanic hazards. Full article

Fine aggregates are the main ingredients that control the success of the preparation and performance of strain-hardening cementitious composites (SHCCs). Worldwide deserts can be used as eternal sources of fine aggregates for the preparation of SHCCs. Arabian Peninsula desert sand spreads over the largest desert area in the world, covering an area of 2,300,000 km² among the Arabian Gulf countries. White and dune desert sands were procured for use in this study. The morphological structure is important in selecting the appropriate sand for use in the preparation of SHCCs. The utilization of microfibers such as polyvinyl alcohol (PVA) has become common practice for the preparation of SHCCs. The presence of desert sand is proven to enhance the dispersibility of PVA due to its spherical structure, which alleviates the friction among the ingredients forming SHCCs. Two mechanisms are defined under the tensile force at the interface of microfibers and natural sand, namely, a strong frictional force leading to rupture or a weaker force causing pullout. The synergy between fibers and fine aggregate grains depends on their surface characteristics, which can be modified using different types of mineral admixtures. In this research, the alignment of microfibers as an indication of the quality of dispersion could be evaluated using a proposed approach based on an advanced technique of microstructural analysis. PVA dispersion and its relation to strain-hardening properties are visually correlated to the surface interaction of the mineral admixture and dune sand. The microdurability and cost effectiveness of SHCCs could be assessed using the proposed approach, as depicted by the results obtained in this research work. Full article

The utilization of manufactured lightweight aggregates adds another dimension to the cost of the preparation of self-compacting concrete (SCC). The common practice of adding absorption water to the lightweight aggregates before concreting leads to inaccurate calculations of the water-to-cement ratio. Moreover, the absorption of water weakens this interfacial bond between aggregates and the cementitious matrix. A particular type of black volcanic rock with a vesicular texture known as scoria rocks (SR) is utilized. With an adapted sequence of additions, the occurrence of water absorption can be minimized to overcome the issue of calculating the true water content. In this study, the approach of preparing the cementitious paste first with adjusted rheology followed by the addition of fine and coarse SR aggregates enabled us to circumvent the need for adding absorption water to the aggregates. This step has improved the overall strength due to the enhanced bond between the aggregate and the cementitious matrix, rendering a lightweight SCC mix with a target compressive strength of 40 MPa at 28 days, which makes it appropriate for structural applications. Different mixes were prepared and optimized for the best cementitious system that achieved the goal of this study. The optimized quaternary cementitious system included silica fume, class F fly ash, and limestone dust as essential ingredients for low-carbon footprint concrete. The rheological properties and parameters of the optimized mix were tested, evaluated, and compared to a control mix prepared using normal-weight aggregates. The results showed that the optimized quaternary mix satisfied both fresh and hardened properties. Slump flow, T50, J-ring flow, and average V-funnel flow time were in the ranges of 790–800 mm, 3.78–5.67 s, 750–780 mm, and 9.17 s, respectively. Moreover, the equilibrium density was in the range of 1770–1800 kg/m³. After 28 days an average compressive strength of 42.7 MPa, a corresponding flexural load of over 2000 N, and a modulus of rupture of 6.2 MPa were obtained. The conclusion is then drawn that altering the sequence of mixing ingredients becomes a mandatory process with scoria aggregates to obtain high-quality lightweight concrete for structural applications. This process leads to a significant improvement in the precise control of the fresh and hardened properties, which was unachievable with the normal practice used with lightweight concrete. Full article

The Middle Atlas Volcanic Field (MAVF) covers an area of 1500 km², with a total erupted volume of solid products (e.g., Dense Rock Equivalent or DRE) estimated to be more than 80 km³. The MAVF comprises 87 monogenetic basaltic volcanoes of Tertiary-Quaternary age as scoria cones (71%) and maars (29%). These monogenetic basaltic volcanoes have various morphologies (e.g., circular, semi-elliptic, elliptic in map views). They can be isolated or form clustered monogenetic complexes. They are largely grouped in the Middle Atlas, in an intraplate geotectonic context forming two distinct major alignments (N160–170° and N40–50°), each closely associated with regional structural elements. By the best estimates, the preserved bulk pyroclastic products do not exceed 0.7 km³, and they show large textural and componentry diversity (e.g., bedded/unbedded, coarse/fine, dense/scoriaceous fallout and pyroclastic density current deposit, etc.). Lava flows also demonstrate great variety of preserved surface textures, including pāhoehoe, ‘a’ā, and clastogenic types. Morphostructural features of lava flows linked to lava flow dynamics have also been recognized, and the presence of hornitos, columnar jointed basaltic flow units, lava tubes, tumuli, and clastogenic lava flows have been recognized and mapped. Some half-sectioned dykes expose interior parts of magmatic shallow feeding pipes. The current morphology of the volcanoes of the MAVF reflects various syn- and post-eruptive processes, including (1) erosional features due to weathering, (2) gravitational instability during and after volcanic activity, (3) vegetation impact, and (4) successive burial of lava flows. The documented volcanic features of this typical monogenetic volcanic field form the core of the region’s geoheritage elements and are considered to be unique in the new African geoheritage context. Hence, they will likely form the basis of future geotourism, geoeducation, and geoconservation ventures. Full article

Two sources of natural scoria rocks were procured and ground for use in concrete as natural pozzolans (NP1 and NP2). The evaluation of their pozzolanic reactivity is carried out using different techniques and approaches. The primary goal of employing these techniques is to monitor the amount of portlandite (CH=Ca(OH)₂) consumed during steam curing at low or high pressure. The pozzolanicity of NP powders is determined either directly by monitoring CH variation or indirectly by compressive strength and microstructure development. Autoclave curing is known to stimulate the pozzolanicity of the inert siliceous and aluminosiliceous materials under its high-pressure steam conditions. Both steam-curing conditions were applied in this investigation. In this study, X-ray diffraction, scanning electron microscope, thermogravimetric, Fourier transform infrared, and isothermal analyzers were used. It is concluded that the nature and types of minerals in SR determine their pozzolanic reactivity as either low-pressure steam-reactive or high-pressure steam-reactive cementitious materials. Due to the nature of their silicate structures, notably single-chain or 3D-framework structures, plagioclase feldspars (albite-anorthite) minerals are high-pressure steam-reactive minerals, whereas pyroxene (enstatite and diopside) minerals are low-pressure steam-reactive minerals. Using high-pressure steam curing, varied replacement levels of up to 60% were achieved in NP1, with a consistent strength activity index (SAI) of 99%, while an SAI of 79% was obtained with NP2. During low-pressure steam curing, NP1 and NP2 consumed around 72 and 80% of portlandite, respectively, demonstrating their relative pozzolanic reactivity. When compared to the control concrete mix, the strength activity indices of NP1, NP2, and class F fly ash in their normal concrete mixes reached 74.3, 82, and 73.7%, respectively, after 56 days of normal curing conditions. Full article

We invert gravity and magnetic anomalies for basement relief at the Harrat Rahat Volcanic Field (HRVF) for the purpose of evaluating its geothermal energy prospects. HRVF is dominated by basaltic scoria cones and other volcanic rocks overlying the Proterozoic basement. The area considered for this study is located within the northern HRVF and consists mainly of alkali basalts with lesser amounts of benmoreite, mugearite, hawaiite, and trachyte. Our approach adopts a global optimization technique using Particle Swarm Optimization with automated parameter selection, and a two-dimensional gravity-magnetic (GM) forward modeling procedure. The results of the PSO-based approach indicate a depth to the basement at 0.10–624 m, with greater depths within the central region of a solitary anomalous density body in the HRVF. The obtained basement geometry is corroborated by the depth estimates obtained from other potential field inversion methods. The regions with higher prospects are mapped for a targeted future geothermal energy exploration at the HRVF, based on our inversion results. Full article

Many people worldwide are exposed to extreme levels of fluoride in drinking water. It is, therefore, critical to develop inexpensive, locally available, and environmentally friendly adsorbents for fluoride-laden water defluoridation. In the current study, virgin scoria (volcanic rock) from Ethiopia, was modified with zirconium oxide and used as an adsorbent in a fixed-bed column aiming at the removal of fluoride from water. The adsorption capability of zirconium oxide-coated scoria (ZrOCSc) was compared with unmodified virgin scoria (VSco). XRD, FTIR, XRF, SEM, ICP-OES, and the pH_PZC tests were evaluated to explore the adsorption mechanisms. Thermal analysis of VSco and ZrOCSc revealed lower total weight losses of 2.3 and 3.2 percent, respectively, owing to the removal of water molecules and OH species linked to metal oxides contained in the material. The effect of test conditions such as the pH of the solution and the influent flow rate on the adsorption capacity of the adsorbent was carefully studied. ZrOCSc exhibited the maximum removal capacity of 58 mg/kg, which was 4.46 times higher than the observations for VSco (13 mg/kg) at pH 2, and an initial flow rate of 1.25 mL/min. Breakthrough time increased with decreasing initial pH and flow rate. The adsorption experimental data under various test conditions were examined by the Thomas and Adams–Bohart models. Both models were found very effective in describing the experimental data with a correlation coefficient (R²) of ≥0.976 (ZrOCSc) and ≥0.967 (VSco). Generally, coating VSco with zirconium oxide improved the adsorption performance of VSco; hence, a ZrOCSc-packed fixed bed could be employed for the decontamination of high levels of fluoride from groundwater. However, further examination of the adsorbent using natural groundwater is advisable to produce a definitive conclusion. Full article

The Azoreans rely on an extensive network of rural roads for the most of the rural population’s activities (primary sector) and accessibility. To rehabilitate and maintain this network, asphalt concrete and crushed rock aggregate are usually used. However, in the region, the application of such paving technology can be extremely costly. It requires specialized contractors, dedicated equipment and raw materials that must be imported to most of the islands. Therefore, the use of locally available materials would result in more flexibility and fewer costs for planned interventions. In the Azores, known as bagacina, the volcanic scoria is a pyroclastic material, generally highly abundant in volcanic islands. This natural aggregate is inexpensive, easy to extract, and presents good geotechnical characteristics. However, due to its porous nature, it generally does not comply with the current specifications for pavement materials. Therefore, this study aims to evaluate cement-treated volcanic scoria to be used as low-traffic road pavement layers. The geotechnical properties and mechanical performance of the two types of scoriae were analyzed. As a result, both types of scoriae presented good behavior, according to the expected for a cement-treated material, and proved to be a suitable alternative for road pavements in the Azores Archipelago. Full article

This research provides a characterization of ancient Roman mortars from “Villa del Capo di Sorrento” (commonly known as “Villa di Pollio Felice” or “Bagni della Regina Giovanna”). A deepened analysis of cementitious binding matrix and aggregates was conducted with the aims of determining possible sources of raw materials and the mix recipe, and to evaluate the minerogenetic secondary processes. Twenty samples taken from the Villa were investigated by means of a multi-analytical approach, including polarized optical microscopy on thin sections, X-ray powder diffraction, scanning electron microscopy analysis, energy dispersed spectrometry, simultaneous thermal analyses, and mercury intrusion porosimetry. Bedding mortars were made with slaked lime mixed with volcanic materials, whereas coating mortars were made adding to previous recipe as ceramic fragments. All samples were classified as hydraulic mortars. Cementitious binding matrix was characterized by gel-like C-A-S-H, calcite, hydrocalumite, and gypsum, deriving from lime/pozzolanic material. Geomaterials used for mortar production had a local origin. Pozzolanic materials, such as volcanic fragments, scoriae, pumice, and crystal fragments derived from both pyroclastic rocks of the Campi Flegrei district and from rocks of the Somma-Vesuvio complex; porosity test suggest that the products related to minerogenetic secondary processes, make mortars more resistant. Full article

The contamination of surface and groundwater with phosphate originating from industrial and household wastewater remains a serious environmental issue in low-income countries. Herein, phosphate removal from aqueous solutions was studied using low-cost volcanic rocks such as pumice (VPum) and scoria (VSco), obtained from the Ethiopian Great Rift Valley. Batch adsorption experiments were conducted using phosphate solutions with concentrations of 0.5 to 25 mg·L⁻¹ to examine the adsorption kinetic as well as equilibrium conditions. The experimental adsorption data were tested by employing various equilibrium adsorption models, and the Freundlich and Dubinin-Radushkevich (D-R) isotherms best depicted the observations. The maximum phosphate adsorption capacities of VPum and VSco were calculated and found to be 294 mg·kg⁻¹ and 169 mg·kg⁻¹, respectively. A pseudo-second-order kinetic model best described the experimental data with a coefficient of correlation of R² > 0.99 for both VPum and VSco; however, VPum showed a slightly better selectivity for phosphate removal than VSco. The presence of competitive anions markedly reduced the removal efficiency of phosphate from the aqueous solution. The adsorptive removal of phosphate was affected by competitive anions in the order: HCO₃⁻ >F⁻ > SO₄⁻² > NO₃⁻ > Cl⁻ for VPum and HCO₃⁻ > F⁻ > Cl⁻ > SO₄⁻² > NO₃⁻ for VSco. The results indicate that the readily available volcanic rocks have a good adsorptive capacity for phosphate and shall be considered in future studies as test materials for phosphate removal from water in technical-scale experiments. Full article

Consumption of drinking water with a high concentration of fluoride (>1.5 mg/L) causes detrimental health problems and is a challenging issue in various regions around the globe. In this study, a continuous fixed-bed column adsorption system was employed for defluoridation of water using volcanic rocks, virgin pumice (VPum) and virgin scoria (VSco), as adsorbents. The XRD, SEM, FTIR, BET, XRF, ICP-OES, and pH Point of Zero Charges (pH_PZC) analysis were performed for both adsorbents to elucidate the adsorption mechanisms and the suitability for fluoride removal. The effects of particle size of adsorbents, solution pH, and flow rate on the adsorption performance of the column were assessed at room temperature, constant initial concentration, and bed depth. The maximum removal capacity of 110 mg/kg for VPum and 22 mg/kg for VSco were achieved at particle sizes of 0.075–0.425 mm and <0.075 mm, respectively, at a low solution pH (2.00) and flow rate (1.25 mL/min). The fluoride breakthrough occurred late and the treated water volume was higher at a low pH and flow rate for both adsorbents. The Thomas and Adams–Bohart models were utilized and fitted well with the experimental kinetic data and the entire breakthrough curves for both adsorbents. Overall, the results revealed that the developed column is effective in handling water containing excess fluoride. Additional testing of the adsorbents including regeneration options is, however, required to confirm that the defluoridation of groundwater employing volcanic rocks is a safe and sustainable method. Full article

Alteration in magmatic-hydrothermal systems leads to distinct changes in rock texture and mineralogy, and a strong redistribution of elements between fluid and rock. Here, we experimentally interacted andesite scoria with hyperacidic, high-sulfidation style fluids from Kawah Ijen volcano (Indonesia) at 25 and 100 °C, seeking to reproduce the textures observed in natural samples from this volcano, and to understand the element fluxes that accompany alteration. The susceptibility to alteration in the experiments is Cu–Fe-sulphide > calcic plagioclase > pyroxene > titano-magnetite > sodic plagioclase, with complete preservation of glass. Silicate minerals alter to opaline silica, and gypsum, barite and a Zr-phase precipitate. The selective alteration of the phenocryst minerals results in a preferential release of compatible elements, as the glass is the main incompatible element host. The experiments reproduce the alteration textures of the natural samples, including the preservation of glass, but the predicted compatible over incompatible element enrichment in the alteration element flux is not observed in the natural setting. This suggests that alteration at Kawah Ijen is dominated by lithologies that lack abundant glass, in particular lava flows where the glass has devitrified, despite these lava flows having a lower surface area compared to scoria. Full article

This paper is the first description of natural copper-rich oxide spinels. They were found in deposits of oxidizing-type fumaroles related to the Tolbachik volcano, Kamchatka, Russia. This mineralization is represented by nine species with the following maximum contents of CuO (wt.%, given in parentheses): a new mineral thermaerogenite, ideally CuAl₂O₄ (26.9), cuprospinel, ideally CuFe³⁺₂O₄ (28.6), gahnite (21.4), magnesioferrite (14.7), spinel (10.9), magnesiochromite (9.0), franklinite (7.9), chromite (5.9), and zincochromite (4.8). Cuprospinel, formerly known only as a phase of anthropogenic origin, turned out to be the Cu-richest natural spinel-type oxide [sample with the composition (Cu_0.831Zn_0.100Mg_0.043Ni_0.022)_Σ0.996(Fe³⁺_1.725Al_0.219Mn³⁺_0.048Ti_0.008)_Σ2.000O₄ from Tolbachik]. Aluminum and Fe³⁺-dominant spinels (thermaerogenite, gahnite, spinel, cuprospinel, franklinite, and magnesioferrite) were deposited directly from hot gas as volcanic sublimates. The most probable temperature interval of their crystallization is 600–800 °C. They are associated with each other and with tenorite, hematite, orthoclase, fluorophlogopite, langbeinite, calciolangbeinite, aphthitalite, anhydrite, fluoborite, sylvite, halite, pseudobrookite, urusovite, johillerite, ericlaxmanite, tilasite, etc. Cu-bearing spinels are among the latest minerals of this assemblage: they occur in cavities and overgrow even alkaline sulfates. Cu-enriched varieties of chrome-spinels (magnesiochromite, chromite, and zincochromite) were likely formed in the course of the metasomatic replacement of a magmatic chrome-spinel in micro-xenoliths of ultrabasic rock under the influence of volcanic gases. The new mineral thermaerogenite, ideally CuAl₂O₄, was found in the Arsenatnaya fumarole at the Second scoria cone of the Northern Breakthrough of the Great Tolbachik Fissure Eruption. It forms octahedral crystals up to 0.02 mm typically combined in open-work clusters up to 1 mm across. Thermaerogenite is semitransparent to transparent, with a strong vitreous lustre. Its colour is brown, yellow-brown, red-brown, brown-yellow or brown-red. The mineral is brittle, with the conchoidal fracture, cleavage is none observed. D(calc.) is 4.87 g/cm³. The chemical composition of the holotype (wt.%, electron microprobe) is: CuO 25.01, ZnO 17.45, Al₂O₃ 39.43, Cr₂O₃ 0.27, Fe₂O₃ 17.96, total 100.12 wt.%. The empirical formula calculated on the basis of 4 O apfu is: (Cu_0.619Zn_0.422)_Σ1.041(Al_1.523Fe³⁺_0.443Cr_0.007)_Σ1.973O₄. The mineral is cubic, Fd-3m, a = 8.093(9) Å, V = 530.1(10) ų. Thermaerogenite forms a continuous isomorphous series with gahnite. The strongest lines of the powder X-ray diffraction pattern of thermaerogenite [d, Å (I, %) (hkl)] are: 2.873 (65) (220), 2.451 (100) (311), 2.033 (10) (400), 1.660 (16) (422), 1.565 (28) (511) and 1.438 (30) (440). Full article

A natural ε-Fe₂O₃ nano-mineral (luogufengite) has been discovered in young basaltic rocks around the world. Transmission electron microscopy (TEM) observed euhedral or subhedral luogufengite nano-minerals with crystal sizes ranging from 10 to 120 nm in the basaltic rocks. The magnetic property of treated scoria sample (containing 75.3(5) wt % luogufengite) showed a saturation remanence of 11.3 emu g⁻¹ with a coercive field of 0.17 tesla (T) at room temperature. Luogufengite-like nano-domains were also observed in natural permanent magnets (lodestone) and Fe-Ti oxides (ilmenite-magnetite series) with strong remanent magnetization. The structure of luogufengite-like domains (double hexagonal close-packing) is associated with the interfaces between the (111) plane of cubic magnetite and the (0001) plane of rhombohedral hematite or ilmenite. Stacking faults and twin boundaries of magnetite/maghemite can also produce the luogufengite-like domains. The nano-domains oriented along the magnetic easy axis play an essential role in enhancing the magnetic coercivity of lodestone and Fe-Ti oxide. We conclude that the luogufengite nano-minerals and nano-domains provide an explanation for coercivity and strong remanent magnetization in igneous, metamorphic rocks and even some reported Martian rocks. These nano-scaled multilayer structures extend our knowledge of magnetism and help us to understand the diverse magnetic anomalies occurring on Earth and other planetary bodies. Full article

In different regions across the globe, elevated arsenic contents in the groundwater constitute a major health problem. In this work, a biopolymer chitosan has been blended with volcanic rocks (red scoria and pumice) for arsenic (V) removal. The effect of three blending ratios of chitosan and volcanic rocks (1:2, 1:5 and 1:10) on arsenic removal has been studied. The optimal blending ratio was 1:5 (chitosan: volcanic rocks) with maximum adsorption capacity of 0.72 mg/g and 0.71 mg/g for chitosan: red scoria (Ch–Rs) and chitosan: pumice (Ch–Pu), respectively. The experimental adsorption data fitted well a Langmuir isotherm (R² > 0.99) and followed pseudo-second-order kinetics. The high stability of the materials and their high arsenic (V) removal efficiency (~93%) in a wide pH range (4 to 10) are useful for real field applications. Moreover, the blends could be regenerated using 0.05 M NaOH and used for several cycles without losing their original arsenic removal efficiency. The results of the study demonstrate that chitosan-volcanic rock blends should be further explored as a potential sustainable solution for removal of arsenic (V) from water. Full article