Search Results (87)

Managing excessive water production in oil fields during primary, secondary, or enhanced recovery remains challenging. It increases costs and reduces hydrocarbon recovery, particularly in reservoirs with high-conductivity pathways such as high-permeability zones and fractures. Hydrogels are commonly used for water blocking and retention; however, their effectiveness diminishes at higher flow rates due to mechanical weaknesses and structural limitations. These problems are intensified under harsh environmental conditions, including high temperatures, salinity, and hardness. In this study, we investigate how altering the molecular suprastructure of preformed particle gel (PPG) can improve its effectiveness in shear-responsive water-blockage treatments, particularly when traditional PPGs cannot control rising flow rates. We enhance the shear-responsive mechanical properties of a composite PPG by increasing the density and diversity of intermolecular interactions. We use two different strategies: first, incorporating cationic groups into the polymer backbone to form a polyampholyte network with stronger electrostatic interactions; second, adding a linear anionic polymer to generate a secondary interpenetrating network that can undergo a coil–stretch transition under thermal and shear stimuli, thereby enhancing its own solvation and whole-network expansion. Molecular simulations provide an interpretation of the experimentally observed shear-thickening response and enhanced disproportionate permeability reduction at high flow rates. The water residual resistance factor of the improved PPGs deviates from the typical shear-thinning power-law behavior (n < 1) observed in conventional PPG, showing shear-thickening (n > 1). Tests reveal a strong ability to preferentially reduce water flow over oil, with Disproportionate Permeability Reduction increasing from 8 to 117 in the high-flow-rate zone. The enhanced strength and thermal stability also improve resistance to washout under high-pressure gradients. This research provides a novel approach to tailoring the microscopic architecture of PPGs to achieve selective, robust water blockage, offering a high-efficiency solution for complex reservoir environments. Full article

Marine energy technologies offer renewable alternatives to conventional energy sources by harnessing ocean-based resources such as wave motion, tides, temperature, and salinity gradients. They are particularly promising for coastal and island regions. This paper presents a literature-based assessment of the technical potential and limitations of these resources, with a focus on the Adriatic Sea as a model for low-energy, semi-enclosed basins. Resource availability and technological maturity are systematically reviewed. Results indicate that wave energy offers the highest regional potential, with peak annual mean wave power reachig up to 2.784 kW/m near the southern offshore regions of the Adriatic. However, current resource levels limit feasibility to down-scaled, modular installations. Tidal and thermal energy are constrained by the Adriatic’s microtidal regime and limited temperature gradients. Although still in early development, salinity gradient systems may become viable near major river mouths such as those of the Po and Neretva. In addition to technical analysis, broad environmental and socio-economic considerations are reviewed to inform responsible marine energy development. These findings help define strategic development and research priorities for marine renewables in enclosed seas and other resource-constrained marine environments. Full article

Estuaries are dynamic environments that influence the transport of metals and nutrients from land to sea, with suspended particulate matter (SPM) serving as a key vehicle for them. Laser-Induced Breakdown Spectroscopy (LIBS) offers a rapid, versatile, and non-destructive approach for multi-element analysis of SPM, allowing their direct measurement on collected filters without complex sample preparation. In this study, LIBS was applied to evaluate the spatio-temporal variability of major and trace elements (Si, Fe, Al, Ti, Na, Li, K, Rb, Ca, and Mg) along the Pacoti River estuary, Brazil, during rainy and dry seasons. Elemental patterns generally reflected the salinity gradient and tidal dynamics, highlighting element-specific behaviors with most elements showing inverse correlations with salinity, while Ca and Mg displayed positive correlations. These findings confirm the potential of LIBS as a powerful tool for environmental monitoring, providing rapid, high-throughput characterization of SPM and enabling an improved understanding of biogeochemical processes in estuarine systems. Full article

The occurrence of salt wedge intrusion is a common phenomenon in microtidal Mediterranean river mouths, particularly during summer, when reduced river discharge occurs. In the Strymon River, upstream saltwater intrusion affects both the hydrodynamic functioning of the system and the estuarine ecosystem. This study investigates the integrated ecohydrological management of river mouths characterized by salt wedge intrusion, aiming to both limit upstream saltwater penetration and exploit the salinity gradient between seawater and river water for renewable energy production. The study examines the operation of a Salinity Gradient Energy power plant based on Pressure Retarded Osmosis (PRO) technology, with a nominal capacity of 1 MW, located at the Strymon River mouth. A dynamically coupled hydrodynamic and energy production model is developed to assess four operational scenarios with different seawater and freshwater intake locations along the river channel. The results show that, in all scenarios, salt wedge intrusion is restricted to a distance of less than 2000 m from the river mouth, while salt wedge salinity is reduced by up to 35% compared to reference conditions. At the same time, annual energy production exceeds 1.03 GWh in all scenarios, corresponding to the electricity demand of approximately 824 to 1045 households, depending on the operational configuration. Overall, the study demonstrates that salinity gradient energy exploitation can be effectively combined with ecological control of salt wedge intrusion, providing a novel and sustainable framework for the management of Mediterranean estuarine systems. Full article

Recycling water offers a powerful way to lower the environmental water impact of mining activities. Pressure-retarded osmosis (PRO) represents a promising pathway for simultaneous water reuse and clean energy generation from salinity gradients. In this study, the performance of a thin-film nanocomposite (TFN) membrane containing functionalized multi-walled carbon nanotubes (fMWCNTs) within a polyacrylonitrile (PAN) support layer, followed by polydopamine (PDA) surface modification, was investigated under a PRO operation using pretreated gold mining wastewater as the feed solution. Unlike most previous studies that rely on synthetic feeds, this work evaluates the membrane performance under a PRO operation using a real mining wastewater stream. The membrane with fMWCNTs and PDA exhibited a maximum power density of 25.22 W/m² at 12 bar, representing performance improvements of 23% and 68% compared with the pristine thin-film composite (TFC) and commercial cellulose triacetate (CTA) membranes, respectively. A high water flux of 75.6 L·m⁻²·h⁻¹ was also obtained, attributed to enhanced membrane hydrophilicity and reduced internal concentration polarization. The optimized membrane, containing 0.3 wt% fMWCNTs in the support layer and a PDA coating on the active layer, produced a synergistic enhancement in the PRO performance, resulting in a lower reverse salt flux and an improved flux–selectivity trade-off. Furthermore, the ultrafiltration (UF) and nanofiltration (NF) pretreatment effectively reduced the hardness and ionic content, enabling a stable PRO operation with real mining wastewater over a longer period of time. Overall, this study demonstrates the feasibility of achieving both reusable water and enhanced osmotic power generation using modified TFN membranes under realistic mining wastewater conditions. Full article

Marine renewable energy technologies (MRE-T), which capture energy from oceans and seas, represent a pivotal area for sustainable energy development. These technologies, including wave energy converters, tidal energy systems, ocean thermal energy conversion, and salinity gradient power, offer the potential to diversify energy sources, reduce reliance on fossil fuels, and mitigate climate change impacts. Despite its vast potential, marine renewable energy currently constitutes only a small fraction of global electricity generation, highlighting the challenges and complexities associated with its development and deployment. This paper builds on original research undertaken in 2019 by the authors exploring the barriers for companies attempting to enter the Marine Renewable Energy-Supply Chain (MRE-SC). The aim of this paper is to adopt the Theory of Constraints (ToC) approach to develop a Future Reality Tree (FRT) which creates a roadmap to enable companies to successfully enter the MRE-SC. This will enable academics and practitioners to visualize the cause-and-effect relationships around market entry into MRE-SCs for companies, whilst outlining the future goals, and the pathways to achieving the desired results within a holistic system. Therefore, the FRT provides a bridge between current and future visions and provides a valuable strategic perspective on the way companies can transition into the MRE-SC, thereby enabling a future state to be described, guiding the identification of changes that are required to establish an effective change management approach. Full article

Solar-driven interfacial evaporation desalination technology offers a feasible solution to the global shortage of freshwater resources. However, previous interfacial evaporation technologies have often only focused on the production of freshwater resources, without fully utilizing the high-energy photons in sunlight and the salinity gradient generated after seawater evaporation. In this work, a solar-driven water–hydrogen–electricity (SWHE) co-production system integrated by solar-driven interfacial evaporation (SIE), interface photocatalytic hydrogen evolution (IPHE), and reverse electrodialysis (RE) was proposed. The aim is to enhance the efficiency of solar energy utilization and achieve simultaneous production of freshwater, hydrogen, and electricity. Under 2-sun irradiation, the SWHE device achieved a water generation rate of 0.77 kg m⁻² h⁻¹, a hydrogen generation rate of 8.57 mmol m⁻² h⁻¹, and a highest power density of 2.9 mW m⁻². Outdoor tests demonstrate that the cumulative water production reached 1.6 kg m⁻² over 6 h, with a total hydrogen yield of 12.22 mmol m⁻² and a highest power density of 0.095 mW m⁻², which validated the environmental adaptability of SWHE system. This novel design strategy is expected to provide a novel form of freshwater resources and energy supply for human society. Full article

This paper presents a novel batch Forward Osmosis (FO) process for hydropower generation. It focuses on analyzing the parameters needed to make the proposed osmotic power plant implementable with currently available technology. Starting from the solution–diffusion model and using flow and mass balance equations, the equations that describe the behavior of the system over time are obtained. Membrane orientation, concentration polarization, reverse solute flux, and membrane fouling are not considered. The equations for calculating the operation time for the charging and discharging stages are obtained. Also, an equation for calculating the required membrane area to make the duration of the two stages the same is obtained. The results indicate that a volume of approximately $30.4 {\mathrm{m}}^3$ discharging through a $0.84 \mathrm{i}\mathrm{n}\mathrm{c}\mathrm{h}$ diameter outflow jet towards a turbine could generate an energy of $25 \mathrm{k}\mathrm{w}·\mathrm{h}.$ The discharging stage would take $12 \mathrm{h}$, and with a membrane with a water permeability constant $A_m=1.763·{10}^{-12} \mathrm{m}/(\mathrm{s}·\mathrm{P}\mathrm{a})$, the charging stage would require a membrane superficial area ${Ar}_m=1·{10}^4 {\mathrm{m}}^2$ to have the same duration. The proposed osmotic power plant, whose working principle is based on volume change over time, contrary to pressure retarded osmosis, whose working principle requires expending energy to extract energy from the salinity gradient, could deliver greater net produced energy with comparatively lower operational costs as it does not require high-pressure pumps or energy recovery devices as are required in pressure-retarded osmosis. The use of several tanks that charge and discharge alternatively can make the system generate energy as if it were a continuous process. Full article

Low-cost ocean monitoring systems are increasingly needed to address data gaps in coastal environments, particularly in regions where traditional research infrastructure is limited. This paper presents the design, development, and field deployment of a biophysical ocean buoy (BOB)—a compact, solar-powered autonomous buoy system capable of measuring sea surface temperature, salinity (via electrical conductivity), total dissolved solids, pH, and GPS position. The system features real-time data transmission via the Iridium satellite, local data logging, and modular sensor integration. The BOB was deployed for three missions in the Seto Inland Sea, Japan, ranging from 26–56 h in duration. The system successfully recorded high-resolution environmental data, revealing coastal gradients, diurnal heating cycles, and tidal current reversals. Over 95% of the measurements were successfully recovered, and the Iridium communications exceeded 90% reliability. The temperature and salinity data captured fine-scale variations consistent with freshwater plume interactions and tidal forcing. With a total system cost under USD 2000 and minimal deployment requirements, the BOB offers a scalable solution for distributed ocean monitoring. Its performance suggests strong potential for use in aquaculture monitoring, coastal hazard detection, and climate change research, especially in data-sparse regions. This work contributes to the growing field of democratized ocean observation, combining affordability with operational reliability. Full article

Ion-exchange membranes (IEMs) are widely used in reverse-electrodialysis (RED) technology, which can collect the salinity gradient energy between concentrated and diluted solutions and convert it into electromotive force (EMF) to drive power generation and hydrogen production. Recent studies have indicated that the permselectivity of IEMs is vital to determining the performance of an RED stack. In this study, the influences of solution concentration, ion species, and solution temperature on the permselectivity of IEMs were experimentally investigated. The results demonstrate that the permselectivity of IEMs decreases with increasing concentrations of KAc, LiCl, and LiBr solutions for both concentrated solutions (3–5 M) and dilute solutions (0.02–0.2 M). Further, through comparing the LiBr and KBr solutions as well as the LiCl, KCl, and NH₄Cl solutions, respectively, K⁺ demonstrates a higher permselectivity than Li⁺, and both of which are smaller than NH₄⁺ under the same cation and concentration conditions. Moreover, another test was conducted using three potassium salt solutions with different anions, and the experimental permselectivity order is Ac⁻ > Br⁻ > Cl⁻. A slight increase in solution temperature enhances the permselectivity of IEMs due to the increase in ionic mobility. However, an excessive temperature is detrimental to membrane stability and thus reduces permselectivity. It can be seen that ions with low hydration energy, a small hydration radius, and high mobility show a higher permselectivity. Full article

Artificial reservoirs in arid regions provide unique ecological environments for studying the spatial and functional dynamics of plankton communities under the combined stressors of climate change and anthropogenic activities. This study conducted a systematic investigation of the phytoplankton community structure and its environmental drivers in 17 artificial reservoirs in the Ili region of Xinjiang in August and October 2024. The Ili region is located in the temperate continental arid zone of northwestern China. A total of 209 phytoplankton species were identified, with Bacillariophyta, Chlorophyta, and Cyanobacteria comprising over 92% of the community, indicating an oligarchic dominance pattern. The decoupling between numerical dominance (diatoms) and biomass dominance (cyanobacteria) revealed functional differentiation and ecological complementarity among major taxa. Through multivariate analyses, including Mantel tests, principal component analysis (PCA), and redundancy analysis (RDA), we found that phytoplankton community structures at different ecological levels responded distinctly to environmental gradients. Oxidation-reduction potential (ORP), dissolved oxygen (DO), and mineralization parameters (EC, TDS) were key drivers of morphological operational taxonomic unit (MOTU). In contrast, dominant species (SP) were more responsive to salinity and pH. A seasonal analysis demonstrated significant shifts in correlation structures between summer and autumn, reflecting the regulatory influence of the climate on redox conditions and nutrient solubility. Machine learning using the random forest model effectively identified core taxa (e.g., MOTU1 and SP1) with strong discriminatory power, confirming their potential as bioindicators for water quality assessments and the early warning of ecological shifts. These core taxa exhibited wide spatial distribution and stable dominance, while localized dominant species showed high sensitivity to site-specific environmental conditions. Our findings underscore the need to integrate taxonomic resolution with functional and spatial analyses to reveal ecological response mechanisms in arid-zone reservoirs. This study provides a scientific foundation for environmental monitoring, water resource management, and resilience assessments in climate-sensitive freshwater ecosystems. Full article

As society continues to develop, the demand for, and dependence on, energy for production and daily life activities are constantly increasing. Driven by environmental awareness and limited land resource, people have begun to reduce their dependence on fossil fuels and turn to the ocean for energy. Oceans contain vast and abundant energy resources, such as waves, tides, temperature differences and salinity gradients, all of which can be used for power generation. These resources are clean, efficient, renewable and inexhaustible, making them reliable “blue energy sources”. In addition, they are also generally not limited by land use areas, meeting the need for sustainable energy development. This article summarizes the technical characteristics of ocean energy, such as wave, tidal curre1nt, tidal, temperature difference and salinity gradient energies, and combs through the technological forms of different ocean energies, respectively. It also summarizes the development status of the ocean energy industry, and analyzes the industrial maturity of wave energy, tidal energy, etc, predicts future ocean energy development trends, and highlights the influence of ocean energy on sustainable development. We hope that this article provides a reference for scholars and institutions that dedicated to the research and development of ocean energy. Full article

Osmotic energy provides an emerging renewable alternative by leveraging the salinity gradient between two solutions. Among these technologies, pressure-retarded osmosis (PRO) has attracted attention; however, its deployment is hindered by obstacles resulting from impurities in feed and draw solutions and lack of suitable membranes. This review explores the integration of membrane-based pretreatments with PRO, highlighting their influence on resolving the technical drawbacks of standalone PRO systems. Membrane-based pretreatments have shown considerable potential to overcome these challenges by improving the quality of water, reducing membrane fouling and enhancing its performance, and ultimately contributing to recovery of energy, resulting in higher power density. Additionally, the use of different nanomaterials has been proposed for membrane modification to optimize PRO performance. Moreover, the study investigates recent advancements in hybrid configurations for harnessing existing infrastructure and to enhance energy efficiency. Offering a comprehensive review on this integrated approach contributes to valuable insights for advancing membrane-based hybrid systems toward commercial viability. Consequently, investment in developing advanced computational modeling and experimental validation, utilization of advanced membrane materials with higher fouling resistance, and optimization of system configurations by using dual-stage and multi-stage designs are required to overcome these limitations. Full article

Salinity gradient power (SGP) technologies, including pressure-retarded osmosis (PRO) and reverse electrodialysis (RED), have the potential to be utilized for the purpose of harvesting energy from the difference in salinity between two water streams. One challenge associated with SGP is a reduction in power density due to membrane fouling when impaired water is utilized as a low-salinity water stream. Accordingly, this study sought to explore the feasibility of membrane capacitive deionization (MCDI), a low-energy water treatment technique, as a novel pretreatment method for SGP. Laboratory-scale experiments were conducted to evaluate the impact of MCDI pretreatment on the performance of PRO and RED. The low-salinity water was obtained from a brackish water reverse osmosis (BWRO) plant, while the high-salinity water was a synthetic seawater desalination brine. The removal efficiency of organic and inorganic substances in brackish water reverse osmosis (BWRO) brine by MCDI was estimated, as well as theoretical energy consumption. The results demonstrated that MCDI attained removal efficiencies of up to 88.8% for organic substances and 78.8% for inorganic substances. This resulted in a notable enhancement in the lower density for both PRO and RED. The power density of PRO exhibited a notable enhancement, reaching 3.57 W/m² in comparison to 1.14 W/m² recorded for the BWRO brine. Conversely, the power density of RED increased from 1.47 W/m² to 2.05 W/m². Given that the energy consumption by MCDI is relatively low, it can be surmised that the MCDI pretreatment enhances the overall efficiency of both PRO and RED. However, to fully capitalize on the benefits of MCDI pretreatment, it is recommended that further process optimization be conducted. Full article

Ocean energy, e.g., waves, tidal current, and thermal and salinity gradient, can be used to produce electricity. These marine-based renewable energy technologies are at relatively early stages of development and potentially deployed at various sea conditions. In the past, numerous studies were undertaken to explore the feasibility of harvesting of the marine energy in Malaysia; however, those studies were limited to a specific location (i.e., the east coast of Peninsular Malaysia and East Malaysia) and the consideration of sea level rise effect was not studied. This study assessed the potential of tidal and wave energy resources in Malaysia’s waters with the effect of projected sea level rise and was undertaken through numerical modeling using MIKE 21 software. The research outcomes were tidal and wave energy contours for Malaysia’s waters with an inclusion of the sea level rise projection for 2060 and 2100, as well as a potential site determined for tidal and wave energy harvesting. The simulation results highlight the significant potential of tidal and wave energy in specific locations around Malaysia and its coastal regions, as well as in the South China Sea’s offshore regions. By incorporating sea level rise projections into tidal and wave simulations, we revealed a notable increase in tidal and wave power. Full article