Search Results (7)

Sustainable bio-based epoxy technology is developed by using bio-based epoxy materials instead of conventional fossil-derived ones. Significant progress in new bio-based epoxy material development on bio-based epoxy resins, curing agents, and additives, as well as bio-based epoxy formulated products, has been achieved recently not only in fundamental academic studies but also in industrial product development. There are mainly two types of bio-based epoxy resins: conventional epoxy resins and novel epoxy resins, depending on the epoxy resin building-block type used. Bio-based conventional epoxy resins are prepared by using the bio-based epichlorohydrin to replace conventional fossil-based epichlorohydrin. Bio-based novel epoxy resins are usually prepared from epoxidation of renewable precursors such as unsaturated vegetable oils, saccharides, tannins, cardanols, terpenes, rosins, and lignin. Typical bio-based curing agents are bio-based polyamines, polyamides, amidoamines, and cardanol-based phenalkamine-type curing agents. Cardanol is a typical bio-based reactive additive available commercially. Certain types of partially bio-based formulated epoxy products have been developed and supplied for use in bonding, coating, casting, composite, and laminating applications. Full article

This study aims to reveal the effects of flexible chain lengths on rosin-based epoxy resin’s properties. Two rosin-based epoxy monomers with varying chain lengths were synthesized: AR-EGDE (derived from ethylene glycol diglycidyl ether-modified acrylic acid rosin) and ARE (derived from acrylic acid rosin and epichlorohydrin). Diethylenetriamine (DETA), triethylenetetramine (TETA), and tetraethylenepentamine (TEPA) with different flexible chain lengths were used as curing agents. The adhesion, impact, pencil hardness, flexibility, water and heat resistance, and weatherability of the epoxy resins were systematically examined. It was found that when the flexible chains of rosin-based epoxy monomers were grown from ARE to AR-EGDE, due to the increased space of rosin-based fused rings, the toughness, adhesion, and water resistance of the rosin-based epoxy resins were enhanced, while the pencil hardness and heat resistance decreased. However, when the flexible chains of curing agents were lengthened, the resin’s performance did not change significantly because the space between the fused rings changed little. This indicates that the properties of the rosin-based resins can only be altered when the introduced flexible chain increases the space between the fused rings. The study also compared rosin-based resins to E20, a commercial petroleum-based epoxy of the bisphenol A type. The rosin-based resins demonstrated superior adhesion, water resistance, and weatherability compared to the E20 resins, indicating the remarkable durability of the rosin-based resin. Full article

In order to develop a bio-based epoxy resin with high mechanical and thermal performance, cork particles and nanocellulose were introduced into the rosin-based epoxy resin to improve the toughness, stiffness and thermal stability. The flexural properties of the epoxy composites indicated that the strength and modulus were reduced when the content of cork particles was relatively high (>3%) due to the low stiffness and modulus of cork itself. However, the flexural performance was significantly improved after the addition of 1% nanocellulose. In contrast to the flexural properties, the impact toughness results showed the synergistic toughening effects of nanocellulose and cork particles on the rosin-based epoxy resin. The highest impact toughness of 13.35 KJ/m² was found in the epoxy composite with 1% cellulose nanofibers and 3% cork particles, an increase of 149.07% compared to the neat epoxy. Cork particle size also had a significant effect on the mechanical properties of the composites. Both the flexural and impact results showed first a rise and then a fall with a decrease in the cork size. TGA results indicated cork particles and nanocellulose could have a synergistic enhancing effect on the thermal stability of the rosin-based epoxy resin. This work can add value to rosin and cork waste and widen the industrial applications of the epoxy resin. Full article

Epoxy resin insulation materials are mainly derived from petrochemical materials which have the disadvantages of resource consumption and environmental pollution. In order to cure bisphenol A epoxy resin, a maleopimaric anhydride (MPA) curing agent was prepared from rosin, a renewable resource, and blended with a petroleum-based curing agent (methylhexahy-drophthalic anhydride). The influence of maleopimaric anhydride content on the initiation and growth characteristics of electrical trees was studied and analyzed in this paper using molecular dynamics simulation (MD) and electrical tree tests at an 18-kilovolt power frequency voltage. When the MPA content used was ≤10%, the free volume percentage of the curing system increased with MPA content, and thus the initiation voltage became lower; when the MPA content was ≥20%, the hydrogenated phenanthrene ring structure content increased significantly with increasing MPA content, and the rigidity of the curing system increased significantly; thus, the initiation voltage gradually increased. MPA4 had an 11.11% higher initiation voltage than the petroleum-based control group. The effect of the polar rigid structure within the curing system significantly inhibited the growth rate and length of electrical trees as MPA content increased. Electrical trees developed into light-colored, thin, and narrow dendritic structures when the MPA content reached 40%. The results show that curing epoxy resin with the rosin-based curing agent maleopimaric anhydride (MPA), in place of a petroleum-based curing agent, can produce environmentally friendly resins with excellent electrical tree resistance and potential application prospects. Full article

In this concept-proof study, a preform-based RTM (Resin Transfer Molding) process is presented that is characterized by first pre-loading the solid curing agent onto the preform, and then injecting the liquid nonreactive resin with an intrinsically low viscosity into the mold to infiltrate and wet the pre-loaded preform. The separation of resin and hardener helped to process inherently high viscosity resins in a convenient way. Rosin-sourced, anhydrite-cured epoxies that would normally be regarded as unsuited to liquid composite molding, were thus processed. Rheological tests revealed that by separating the anhydrite curing agent from a formulated RTM resin system, the remaining epoxy liquid had its flowtime extended. C-scan and glass transition temperature tests showed that the preform pre-loaded with anhydrite was fully infiltrated and wetted by the liquid epoxy, and the two components were diffused and dissolved with each other, and finally, well reacted and cured. Composite laminates made via this approach exhibited roughly comparable quality and mechanical properties with prepreg controls via autoclave or compression molding, respectively. These findings were verified for both carbon and ramie fiber composites. Full article

In this paper, the electrical conductivity and electromagnetic shielding effectiveness of two bio-composites are studied by experimental testing and numerical models. Two monolithic composites with partly bio-based content were manufactured. The first bio-composite is made of a carbon fiber fabric prepreg and a partly bio-based (rosin) epoxy resin (CF/Rosin). The second bio-composite is a combination of prepregs of carbon fiber fabric/epoxy resin and flax fiber fabric/epoxy resin (CF-Flax/Epoxy). A single line infusion process was used prior to the curing step in the autoclave. Both variants are exemplary for the possibility of introducing bio-based materials in high performance CFRP. In-plane and out-of-plane electrical conductivity tests were conducted according to Airbus standards AITM2 0064 and AITM2 0065, respectively. Electromagnetic shielding effectiveness tests were conducted based on the standard ASTM D 4935-10. Materials were prepared at the German Aerospace Center (DLR), while characterization tests were conducted at the University of Patras. In addition to the tests, numerical models of representative volume elements were developed, using the DIGIMAT software, to predict the electrical conductivity of the two bio-composites. The preliminary numerical results show a good agreement with the experimental results. Full article

Epoxy resins are one of the most widely used thermosets in different engineering fields, due to their chemical resistance and thermo-mechanical properties. Recently, bio-based thermoset resin systems have attracted significant attention given their environmental benefits related to the wide variety of available natural resources, as well as the resulting reduction in the use of petroleum feedstocks. During the last two decades, considerable improvement on the properties of bio-sourced resins has been achieved to obtain performances comparable to petroleum-based systems. This paper reviews recent advances on new bio-based epoxy resins, derived from natural oils, natural polyphenols, saccharides, natural rubber and rosin. Particular focus has been given to novel chemical formulations and resulting mechanical properties of natural derived- epoxies, curing agents or entire systems, constituting an interesting alternative for a large variety of engineering applications, including the aviation sector. The present work is within the scope of the ECO-COMPASS project, where new bio-sourced epoxy matrixes for green composites are under investigation. Full article