Search Results (4)

In this paper, we present the synthesis and luminescent spectra of rare-earth (RE)-doped aluminum and lanthanum borates intended to serve as narrow excitation–emission band fluorescent markers. We perform a detailed 3D excitation–emission matrix (EEM) analysis of their spectra, compare the measurements from both standard and mobile phone spectrometers, and outline the basic differences and advantages of each method. While smartphones have a different and non-uniform spectral response compared to standard spectrometers, it is shown that they offer a number of advantages such as contactless interrogation, efficient suppression of the UV excitation light, and simultaneous spectral analysis of spatially arranged arrays of fluorescent markers. The basic emission peaks have been observed and their corresponding electronic transitions identified. The obtained results show that the rare-earth-doped La and Al borates feature excitation–emission bandwidths as low 15 nm/12 nm, which makes them particularly appropriate for use as luminescent markers with UV LED excitation and smartphone interrogation. Full article

Rare-earth aluminum borates, RAl₃(BO₃)₄ (where R = Y, Pr–Lu), are of great interest because of their attractive multifunctional properties, depending on their structure and composition. The combination of desirable physical and chemical characteristics makes them promising materials for lasers and nonlinear optics. Research focusing on RAl₃(BO₃)₄ (RAB) compounds and their solids solutions has continued for more than five decades and has been reflected in numerous articles and several reviews. The last decade’s enhanced interest is being conducted towards epitaxial layers because of the availability of other possible applications, for instance, as scintillators, visible emitting phosphors or optical waveguides and waveguide lasers. On the other hand, the tendency of borate melts to form glasses makes them attractive for research of micro-crystallization processes in these systems and can be effortless towards finding relatively inexpensive optical glass–ceramic materials with similar composition as alternative components to laser systems. This article reviews the recent progress carried out hitherto on epitaxial layers and glass–ceramic composites of huntite-type rare-earth aluminum borates. Full article

As previously shown for lutetium and yttrium, 1,2,3,4,5-pentamethylcyclopentadienyl (C₅Me₅ = Cp*)-bearing rare-earth metal dimethyl half-sandwich complexes [Cp*LnMe₂]₃ are now also accessible for holmium, dysprosium, and terbium via tetramethylaluminato cleavage of [Cp*Ln(AlMe₄)₂] with diethyl ether (Ho, Dy) and tert-butyl methyl ether (TBME) (Tb). C–H-bond activation and ligand redistribution reactions are observed in case of terbium and are dominant for the next larger-sized gadolinium, as evidenced by the formation of mixed methyl/methylidene clusters [(Cp*Ln)₅(CH₂)(Me)₈] and metallocene dimers [Cp*₂Ln(AlMe₄)]₂ (Ln = Tb, Gd). Applying TBME as a “cleaving” reagent can result in both TBME deprotonation and ether cleavage, as shown for the formation of the 24-membered macrocycle [(Cp*Gd)₂(Me)(CH₂OtBu)₂(AlMe₄)]₄ or monolanthanum complex [Cp*La(AlMe₄){Me₃Al(CH₂)OtBu}] and monoyttrium complex [Cp*Y(AlMe₄)(Me₃AlOtBu)], respectively. Complexes [Cp*Ln(AlMe₄)₂] (Ln = Ho, Dy, Tb, Gd) and [Cp*LnMe₂]₃ (Ln = Ho, Dy) are applied in isoprene and 1,3-butadiene polymerization, upon activation with borates [Ph₃C][B(C₆F₅)₄] and [PhNHMe₂][B(C₆F₅)₄], as well as borane B(C₆F₅)₃. The trans-directing effect of AlMe₃ in the binary systems [Cp*Ln(AlMe₄)₂]/borate is revealed and further corroborated by the fabrication of high-cis-1,4 polybutadiene (97%) with “aluminum-free” [Cp*DyMe₂]₃/[Ph₃C][B(C₆F₅)₄]. The formation of multimetallic active species is supported by the polymerization activity of pre-isolated cluster [(Cp*Ho)₃Me₄(CH₂)(thf)₂]. Full article

Achieving a “carbon neutral” world by 2100 or earlier in a context of economic growth implies a drastic and profound transformation of the way energy is supplied and consumed in our societies. In this paper, we use life-cycle inventories of electricity-generating technologies and an integrated assessment model (TIMES Integrated Assessment Model) to project the global raw material requirements in two scenarios: a second shared socioeconomic pathway baseline, and a 2 °C scenario by 2100. Material usage reported in the life-cycle inventories is distributed into three phases, namely construction, operation, and decommissioning. Material supply dynamics and the impact of the 2 °C warming limit are quantified for three raw fossil fuels and forty-eight metallic and nonmetallic mineral resources. Depending on the time horizon, graphite, sand, sulfur, borates, aluminum, chromium, nickel, silver, gold, rare earth elements or their substitutes could face a sharp increase in usage as a result of a massive installation of low-carbon technologies. Ignoring nonfuel resource availability and value in deep decarbonation, circular economy, or decoupling scenarios can potentially generate misleading, contradictory, or unachievable climate policies. Full article