Search Results (32)

Both synthetic and natural rubber-like elastomers are widely employed in industrial applications (such as tires, seals, protective gloves, and damping absorbers) as well as in the food and animal husbandry industries. These materials should be regularly checked for contamination and the associated infectious risk since they frequently come into contact with food, animals, and people. Additionally, they could act as vehicle of microbes and, as a result, diseases. This pilot study investigates the antibacterial efficacy of novel elastomer formulations against Salmonella enterica subsp. enterica serovar Enteritidis and Legionella pneumophila, with possible applications in drinking water distribution systems (DWDSs). This study aims to evaluate the antimicrobial activity of two rubber and five silicone patented elastomers with antibacterial additives. Two microbiological concentrations (10³ and 10⁴ CFU/mL) were used to compare the efficacy of the elastomers. The results showed a significant decrease in bacterial load in several silicone formulations, with two of them showing the strongest bactericidal efficacy against L. pneumophila (0% and 3% survival rates for VMQ105 and VMQ500L formulations, respectively), despite the wide variations in S. Enteritidis inhibition. One rubber elastomer performed better than the other in terms of reducing bacterial survival for both pathogens (NBRCA) while NBROM showed a 0% survival rate only for L. pneumophila. The findings suggest that certain elastomer compositions might lessen the potential infectious risks in water systems or contaminated matrices. Future research may investigate in situ applications, particularly in hospitals or dental offices where these pathogens pose major health risks. Full article

In this study, high-performance gloves were developed from core–sheath yarn. Different materials were used in the core, while Kevlar fibers were used in the sheath. The filaments used in the core included glass, ultra-high-molecular-weight polyethylene (UHMWPE), and stainless steel filaments with 100D and 200D linear densities. Seamless gloves were developed from these yarns with varying characteristics to observe their effect on the performance of seamless gloves. The factors examined were the areal density (GSM) of the gloves, linear density of sheath fibers, core material, and plied structure. The mechanical behavior of the gloves was evaluated by different tests such as blade cut resistance, coupe cut resistance, tear resistance, and puncture resistance. The results demonstrated that the sheath fiber characteristics, core material type, yarn’s plied structure, and fabric’s areal density are statistically significant factors affecting the properties of gloves in relation to mechanical risk. The selection of appropriate levels of these parameters is crucial for better achievement of desired properties in workwear protection applications. Full article

This study presents a new approach to developing protective material structures for personal protective equipment (PPE), and in particular for protective gloves, with the use of ultrasonic and contact welding processes. The goal was to assess the quality of joints (welds) obtained between a synthetic polyamide knitted fabric (PA) and selected polymers (PLA, ABS, PET-G) in the developed materials using X-Ray microtomography (micro-CT). Quantitative and qualitative analyses were performed to determine the joint area produced by the selected welding methods for the examined materials. In this article, we assumed that obtaining a greater contact area seems to be the most promising from the point of view of future PPE utility tests characterizing protective glove structures. This research is a continuation of our previous study focused on functional 3D-printed polymeric materials for protective gloves. Full article

The paper explains how nano exposure is assessed in the construction field and focuses on the production of fire-resistant insulation panels with nanoclay. Utilizing the commercial ANSYS CFX^® software, a preliminary theoretical simulation was conducted on nano exposure in the workplace, which revealed that particle dispersion is primarily driven by diffusion. Panel post-processing through drilling results in the highest inhalation exposure, followed by mixing and grinding activities. Compared to a state of ‘no activity’, each activity resulted in an exposure increase by a factor of min. 1000. An overall assessment suggests that the use of nanoparticles in construction materials may not significantly heighten workers’ exposure to nanopowders when considering particle concentration alone as opposed to using traditional micro-scale materials. However, the issue persists when it comes to blending powders or performing finishing tasks on panels, with concentration levels being significantly higher for drilling, grinding, and mixing powders at 2.4 times above the standard reference value (40,000 particles/cm³); this is unacceptable, even for brief durations. Examination of dermal contact with gloves and masks worn by workers revealed no nanoparticle penetration. Safety measures were proposed for workers based on decision trees to enhance their safety. Ten categories of protection strategies have been devised to combat the impact of nanoparticles, which are tailored to specific technical situations, but they must be modified for various types of nanoparticles despite potential shared health implications. Full article

Given the mechanical hazards occurring in the workplace, cut resistance is a particularly important protective parameter. 3D printing is an innovative technology that has recently garnered great interest. It enables the creation of functional polymeric materials with metal reinforcement for use in cut-resistant gloves. The present study characterized and tested 3D-printed polymeric materials intended for such applications. The materials were made from commercially available 3D printing polymer filaments. Metallic reinforcement (stainless steel wire with a diameter of 0.04 mm) was added to the two selected materials (thermoplastic polyurethane and FiberFlex30D). Tests have shown that materials containing metallic reinforcement demonstrate higher mechanical resistance. Cut resistance increased by 70%, and the force needed to tear the sample increased by over 20% compared to the pure polymer. The presence of metallic reinforcement strengthens the structure of the material and changes the cracking mechanism. The tearing occurs in the test area, not in the bell area. These findings demonstrate the feasibility of applying functional 3D-printed polymeric materials with metal reinforcement in cut-resistant gloves. Full article

At a time of growing epidemic hazards caused by a very rapid evolution of dangerous pathogens, there is a pressing demand for bioactive textiles. Therefore, the development of high-quality knitted structures that could be used as bioactive protective materials has become a priority. This publication describes the fabrication of functional knitted structures from previously prepared antibacterial cellulose fibers containing nanosilica with immobilized silver nanoparticles. The structural and physical parameters of knitted fabrics made from them were studied with a view to their potential application in bioactive protective gloves. Tests of the basic structural and physical parameters of the knitted fabrics did not show that the nanomodifier applied in fibers significantly impacts the physical properties of the resulting fabrics. Moreover, water vapor permeability, cut resistance, and pH test results relevant to the functional and protective properties of interest and to user comfort showed that the obtained fabrics can be used in the production of bioactive protective gloves. Full article

Personal protective equipment (PPE)—especially face masks, face shields, and gloves—was used to minimize the spread of COVID-19. PPE is primarily made of plastic materials with various plastic additives, such as phthalate plasticizers. Phthalates are linked with various adverse health effects. Therefore, this study investigated the amounts of six commonly used phthalates (DBP, BBP, DEHP, DnOP, DINP, and DIDP) in different types of PPE samples collected during the pandemic. Gas chromatography–mass spectrometry (GC–MS) was used to detect six selected phthalates and other organic chemicals in PPE samples. The quality of data was ensured using certified reference materials, internal standards, procedural blanks, and replicate analyses. The total phthalate content found in face shields and face masks was in the range of 0.29 µg/g to 942.60 µg/g, with DBP, DEHP, and DINP detected most frequently. A health risk assessment concluded that the determined levels were not expected to pose adverse health effects on the wearer. However, the findings of this study suggest that chronic daily intakes of phthalates from two vinyl glove samples with phthalate content exceeding 11% and 14% (w/w) of the glove’s weight may potentially increase the risk of cancer in humans. In addition to the target phthalates, flame retardants and other plasticizers (e.g., organophosphates and dioctyl isophthalate) were tentatively identified in various PPE samples. Full article

Medical gloves, along with masks and gowns, serve as the initial line of defense against potentially infectious microorganisms and hazardous substances in the health sector. During the COVID-19 pandemic, medical gloves played a significant role, as they were widely utilized throughout society in daily activities as a preventive measure. These products demonstrated their value as important personal protection equipment (PPE) and reaffirmed their relevance as infection prevention tools. This review describes the evolution of medical gloves since the discovery of vulcanization by Charles Goodyear in 1839, which fostered the development of this industry. Regarding the current market, a comparison of the main properties, benefits, and drawbacks of the most widespread types of sanitary gloves is presented. The most common gloves are produced from natural rubber (NR), polyisoprene (IR), acrylonitrile butadiene rubber (NBR), polychloroprene (CR), polyethylene (PE), and poly(vinyl chloride) (PVC). Furthermore, the environmental impacts of the conventional natural rubber glove manufacturing process and mitigation strategies, such as bioremediation and rubber recycling, are addressed. In order to create new medical gloves with improved properties, several biopolymers (e.g., poly(vinyl alcohol) and starch) and additives such as biodegradable fillers (e.g., cellulose and chitin), reinforcing fillers (e.g., silica and cellulose nanocrystals), and antimicrobial agents (e.g., biguanides and quaternary ammonium salts) have been evaluated. This paper covers these performance-enhancing materials and describes different innovative prototypes of gloves and coatings designed with them. Full article

Personnel using X-ray devices, the main source of radiation in medical institutions, are primarily affected by scattered rays. When interventionists use radiation for examinations/treatments, their hands may enter the radiation-generating area. The shielding gloves used for protection against these rays restrict movement and cause discomfort. Here, a shielding cream that directly adheres to the skin was developed and examined as a personal protective device; further, its shielding performance was verified. Bismuth oxide and barium sulfate were selected as shielding materials and comparatively evaluated in terms of thickness, concentration, and energy. With increasing wt% of the shielding material, the protective cream became thicker, resulting in improved protection. Furthermore, the shielding performance improved with increasing mixing temperature. Because the shielding cream is applied to the skin and has a protective effect, it must be stable on the skin and easy to remove. During manufacturing, the bubbles were removed, and the dispersion improved by 5% with increasing stirring speed. During mixing, the temperature increased as the shielding performance increased by 5% in the low-energy region. In terms of the shielding performance, bismuth oxide was superior to barium sulfate by approximately 10%. This study is expected to facilitate the mass production of cream in the future. Full article

Concerning large game in Portugal, there is an epidemiological risk area for tuberculosis where the pressure of tuberculosis infection in wild animals is high. Hunters and other people involved in managing carcasses (evisceration and/or initial examination) of these animals should be considered as a high-risk population for sporadic occupational zoonotic infection. This study aims to evaluate and indicate these stakeholders’ main risk practices. The survey was carried out in two phases: a first phase with an anonymous survey to hunters about self-consumption of game meat and carcass handling practices, and a second phase of evaluation in loco of the practices carried out at collection points after driven hunts. As the main results suggested in this study, bad practices and improper handling of hunted carcasses potentially infected with tuberculosis were marked in both phases of the survey, mostly related to the lack of recognition of tuberculosis-like lesions and the non-use of individual protection material, such as gloves and masks. It is evident that stakeholders are interested in learning more about how to perform initial examination properly and what kind of biosecurity measures can be adopted to minimize zoonotic infection risk. Full article

Background and Objectives: The global trend toward increased protection of medical personnel from occupational radiation exposure requires efforts to promote protection from radiation on a societal scale. To develop effective educational programs to promote radiation protection, we clarify the actual status and stage of behavioral changes of spine surgeons regarding radiation protection. Materials and Methods: We used a web-based questionnaire to collect information on the actual status of radiation protection and stages of behavioral change according to the transtheoretical model. The survey was administered to all members of the Society for Minimally Invasive Spinal Treatment from 5 October to 5 November 2020. Results: Of 324 members of the Society for Minimally Invasive Spinal Treatment, 229 (70.7%) responded. A total of 217 participants were analyzed, excluding 12 respondents who were not exposed to radiation in daily practice. A trunk lead protector was used by 215 (99%) participants, while 113 (53%) preferred an apron-type protector. Dosimeters, thyroid protector, lead glasses, and lead gloves were used by 108 (50%), 116 (53%), 82 (38%), and 64 (29%) participants, respectively. While 202 (93%) participants avoided continuous irradiation, only 120 (55%) were aware of the source of the radiation when determining their position in the room. Regarding the behavioral change stage of radiation protection, 134 (62%) participants were in the action stage, while 37 (17%) had not even reached the contemplation stage. Conclusions: We found that even among the members of the Society for Minimally Invasive Spinal Treatment, protection of all vulnerable body parts was not fully implemented. Thus, development of educational programs that cover the familiar risks of occupational radiation exposure, basic protection methods in the operating room, and the effects of such protection methods on reducing radiation exposure in actual clinical practice is warranted. Full article

There are two types of dimensional allowance (inner and external) related to two distinct areas of occupational health and safety: those being a measure of fit of personal protective equipment (PPE) and those determining the safe and comfortable human interaction with tools and machines, e.g., the latter ones result from wearing PPE increasing the dimensions of the human body and generating limitations in the work environment. In this paper, they are taken to mean the difference between the dimensions of a bare and gloved hand (including glove construction and materials). Dimensional allowances are important in designing the work environment, e.g., machine control panels and tools. The absolute and relative maximum values of dimensional allowances determined in this study for a hand in a firefighter’s protective glove for the main anthropometric data are: 16.90 mm (5.90%) for length, 12.00 mm (13.77%) for width, and 15.70 mm (7.96%) for circumference. The obtained results are useful for designers, and especially for designing keys on control panels and LCD touch displays and monitors integrated with machines. Full article

Textiles-fibres, yarns and fabrics are omnipresent in our daily lives, with unique mechanical properties that fit the design specifications for the tasks for which they are designed. The development of yarns and fabrics with negative Poisson’s ratio (NPR) is an area of current research interest due to their potential for use in high performance textiles (e.g., military, sports, etc.). The unique braiding technology of interlacement for preparation of braided helically wrapped yarns with NPR effect with later development of auxetic woven fabric made it possible to avoid the slippage of the wrapped component from the core. The applied geometrical configuration and NPR behaviour of the braided helical yarn structure with seven different angles comprising of monofilament elastomeric polyurethane (PU) core with two wrap materials that include multifilament ultra-high molecular weight polyethylene (UHMWPE) and polyethylene terephthalate (PET) fibres were investigated and analysed. The mechanically stable 2D woven textile auxetic fabrics (AF) with various weave patterns such as 2/2 matt and 3/1 twill were developed from the auxetic yarn with PU elastomer core having maximum NPR effect of −1.70 using lower wrapped angle of 9° to study and compare their mechanical responses. The auxetic yarn was used in weft direction and multifilament UHMWPE yarn in warp direction, using semi-automatic loom. Auxeticity of AF was analysed and its various mechanical properties such tensile strength, impact energy absorption, in-plane, and out-of-plane auxeticity, and puncture resistance were studied. Higher energy absorption of 84 Nm for matt fabric was seen compared to twill fabric having an energy of 65 Nm. The puncture resistance capability of matt fabric was better than twill fabric. While twill fabric exhibited better auxetic effect in both in-plane and out-of-plane mode compared to matt fabric. In short, both the twill and matt design AF’s showed unique characteristics which are beneficial in making various protective textiles such as protective helmets, bullet proof shields, cut resistance gloves, blast resistant curtains, and puncture tolerant elastomeric composites. Full article

The disposal of personal protective equipment (PPE) is a main concern of researchers. In recent years, the COVID-19 pandemic made this issue worse, so the production and use of large quantities of disposable gloves in recent years and the lack of a suitable solution for the disposal of these recycled materials are some of the consequences of this pandemic. To address this issue, the present study performed a comprehensive experimental program to determine the possibility of using recycled latex and vinyl gloves as recycled fibers within extrusion-based 3D printing concrete. Moreover, a graphene oxide (GO) nanomaterial was also used to compensate for some undesired properties of mixtures. Flow table, buildability, and mechanical tests were performed in this study. Results show that the synergic effect of recycled fibers and GO significantly improved the 3D printing characteristics of mortar. Although very promising results were obtained in this study, findings show that using a high content of recycled fibers reduces the concrete compressive strength. However, the addition of GO significantly compensates for this reduction. Full article

The article presents research on ergonomics, biophysical comfort and safety of protective clothing. The resistance of the structural, thermal and mechanical properties of five fabrics (CBXS400, GG200T, Twaron CT736, Dyneema HB26 and T1790C), differing in geometry and raw material composition used in space suits, to dangerous ionizing radiation (β and γ) occurring in space was tested. For both types of radiation, four identical one-time doses in the range of 25–100 kGy were used. The effect of the applied absorbed doses of β and γ radiation on the parameters of textiles influencing ergonomics and safety of the cosmonaut’s work was verified by structural tests (micro-computed tomography and optical microcopy), thermal resistance tests (sweating guarded-hotplate) and strength tests (tensile testing machine). Experimental studies of thermal properties are supplemented with heat transport simulations using the finite volume method performed with 3D models of real textiles. The greatest reduction of thermal resistance for Twaron CT736 (−0.0667 m²·°C·W⁻¹ for 100 kGy of β-radiation) and Dyneema HB26 (−0.0347 m²·°C·W⁻¹ for 50 kGy of β-radiation) is observed. Strength tests have shown that all tested textiles are resistant to both types of radiation. Three textiles were selected to create a three-layer assembly with potential application in a cosmonaut’s glove (Extravehicular Activity—EVA). Full article