Search Results (64)

Air pollution is linked to childhood mortality and morbidity in low- and middle-income countries globally. There is growing evidence linking air pollution to asthma and other respiratory diseases in children. Studies have shown that children are likely to experience asthma due to their narrow airways and their heightened sensitivity to environmental irritants. This study aims to investigate the relationship between ambient air pollution and respiratory diseases in children under the age of 5. The study will be conducted in the informal township of Alexandra, north of Johannesburg, South Africa. A quantitative approach will be used in this cross-sectional analytical study. Data will be collected using different tools that include a questionnaire to determine the prevalence of asthma and respiratory disease and potential risk factors. While environmental air pollution will be measured using Radiello passive samplers and Gillian pumps. Data will be analyzed using the latest version of the STATANow/MP 19.5 software. Furthermore, health risk assessment will be conducted for lifetime non-carcinogenic and carcinogenic risk estimation following the USEPA framework. The study will identify environmental triggers that exacerbate asthma and other respiratory conditions in other similar community settings and will contribute to the body of knowledge in public health. Ethical approval was obtained from the Research Ethics Committee, Faculty of Health Sciences at the University of Johannesburg. Full article

The reliability of passive samplers in measuring volatile organic compounds (VOCs) in indoor air depends on whether the uptake rate is constant given the environmental conditions and sampler exposure duration. The first phase of this study evaluated the performance of charcoal-based, solvent-extracted passive samplers (e.g., Radiello^® 130 passive samplers with white diffusive bodies) over exposure periods ranging from 1 week to 1 year in a test house with known vapor intrusion (VI). Chloroform %Bias values exceeded the ±30% acceptance criterion after 4 weeks exposure. Benzene, hexane, and trichloroethylene (TCE) concentrations were within the acceptance criterion for up to three months. Toluene and tetrachloroethylene (PCE), the two least volatile compounds, demonstrated uniform uptake rates over one year. In the second phase of this study, testing of the longer exposure times of 6 months and 1 year were evaluated with three additional passive samplers: Waterloo Membrane Sampler^TM (WMS^TM), SKC 575 with secondary diffusive cover, and Radiello^® 130 passive samplers with yellow diffusive bodies. The SKC 575 and Radiello^® 130 passive samplers produced acceptable results (%Bias ≤ 30%) over the 6-month exposure period, while the WMS^TM sampler results favored petroleum hydrocarbon more than chlorinated solvent uptake. After the 1-year exposure period, the passive sampler performances were acceptable under specific conditions of this study. The results suggest that all three samplers can produce acceptable results over exposure time periods beyond 30 days and up to a year for some compounds. Full article

The study at the Peggy Guggenheim Collection in Venice highlights critical interactions between indoor air quality, visitor dynamics, and microclimatic conditions, offering insights into preventive conservation of modern artworks. By analyzing pollutants such as ammonia, formaldehyde, and organic acids, alongside visitor density and environmental data, the research identified key patterns and risks. Through three seasonal monitoring campaigns, the concentrations of SO₂ (sulphur dioxide), NO (nitric oxide), NO₂ (nitrogen dioxide), NO_x (nitrogen oxides), HONO (nitrous acid), HNO₃ (nitric acid), O₃ (ozone), NH₃ (ammonia), CH₃COOH (acetic acid), HCOOH (formic acid), and HCHO (formaldehyde) were determined using passive samplers, as well as temperature and relative humidity data loggers. In addition, two specific short-term monitoring campaigns focused on NH₃ were performed to evaluate the influence of visitor presence on indoor concentrations of the above compounds and environmental parameters. NH₃ and HCHO concentrations spiked during high visitor occupancy, with NH₃ levels doubling in crowded periods. Short-term NH₃ campaigns confirmed a direct correlation between visitor numbers and the above indoor concentrations, likely due to human emissions (e.g., sweat, breath) and off-gassing from materials. The indoor/outdoor ratios indicated that several pollutants originated from indoor sources, with ammonia and acetic acid showing the highest indoor concentrations. By measuring the number of visitors and microclimate parameters (temperature and humidity) every 3 s, we were able to precisely estimate the causality and the temporal shift between these quantities, both at small time scale (a few minute delay between peaks) and at medium time scale (daily average conditions due to the continuous inflow and outflow of visitors). Full article

A novel temporally resolved settle-plate air sampler was developed using 3D printing technology to improve upon traditional passive air sampling methods. Conventional settle plates provide cumulative measurements of particle or microbial loads over an entire sampling period, lacking the temporal resolution necessary to identify specific contamination events. The described device integrates a petri plate within a 3D-printed housing featuring a narrow slit that exposes only a small portion of the plate to incoming particles. A rotary mechanism, driven by a mechanical clock motor, rotates the petri plate over 12 h, allowing for time-segmented sampling. Validation experiments demonstrated the device’s ability to accurately encode the temporal history of particle deposition using both aerosolized dyes and viable microbial spores. The device effectively correlated bioaerosol deposition with ambient wind conditions during outdoor sampling. The system is inexpensive (under USD 10), requires no specialized skills to assemble, and is compatible with existing settle plate methodologies. This innovation enhances the ability to conduct air quality assessments in critical environments, enabling data-driven decisions to mitigate contamination risks. Full article

A project to assess air pollution at the National Archeological Museum in Naples was carried out. The main goal of the project was to develop and test a reliable yet simple monitoring system to be adopted at the same time in several exposition rooms. Nitrogen dioxide, hydrogen chloride, nitrous acid, and sulphur dioxide were the chemical species addressed by the technique. Monitoring was simultaneously performed in five rooms, and pollutant concentrations were determined using two passive samplers. The sampling time was approximately one month per period. In addition to passive samplers, environmental data loggers were used to obtain temperature and relative humidity data. Results show high concentrations of nitrogen dioxide inside rooms, which were consistent with those found in outdoor environments and are close to the values calculated considering the air exchange rates, estimated through time gradients of ambient temperature. The minimum values were recorded in a basement room that had a low ventilation rate. The conversion of nitrogen dioxide to real surfaces produces nitric acid and nitrous acid. Large amounts of nitrous acid, up to 15 µg/m³, were found in exposition rooms, with maximum values in the basement room, where the air exchange rate is limited, and the surface-to-volume ratio is the highest among the monitored rooms. Data analysis demonstrated that the system could discriminate between nitrous acid and nitrogen dioxide. The results show that, for the first time, passive samplers can overcome the problem of mutual interference between nitrogen-containing species. Nitrates and nitrites found in the alkaline passive sampler were generally found not to be interfered by nitrogen dioxide. Nitric acid was also found in the gas phase, likely generated by dissociation of ammonium nitrate in particulate matter. Hydrogen chloride and sulphur dioxide were present at few µg/m³. Nitrous acid is the most relevant acidic species found indoors. The presence of pollutants was discussed in terms of the reliability of the analytical procedure and its significance for indoor air pollution. Full article

Evaluating the impact on roadside environments of NH₃ from vehicle emissions is important for protecting the ecosystem from air pollution by fine particulate matter and nitrogen deposition. This study used passive samplers to measure NH₃ and NO_X at multiple points near a major road to observe the distribution of these gases in the area. The impact of NH₃ emitted from vehicles on a major road on the environmental concentration of NH₃ at different distances from the roadside was found to be similar to that of NO_X and NO₂. The concentration of NH₃ rapidly decreased due to dilution and diffusion within approximately 50 m of the road, and after 100 m the concentration remained almost the same or decreased slowly. Furthermore, CO₂ observations taken in the same period along the roadside and in the background yielded a vehicular emission factor of 4–50 mg/km for NH₃, which is comparable with previous research. This emission factor level contributes 4–11 ppb to the NH₃ concentrations in roadside air through the dilution and diffusion process. A correlation was found between the emission factors of NH₃ and NO_X that was different from the trade-off relationship seen when single-vehicle exhaust is measured. Full article

This study presented a comprehensive comparison of soil gas sampling methodologies to monitor volatile organic compounds (VOCs) at two industrial sites in northern Italy. Utilizing active sampling techniques, such as stainless-steel canisters, vacuum bottles, and sorbent tubes, alongside passive methods like low-density polyethylene (PE) membranes, sorbent pens, and Waterloo Membrane Samplers (WMS), the research examines their effectiveness under varied environmental conditions. Five field campaigns were conducted in two areas of the industrial sites characterized by BTEX and chlorinated solvent contamination. The results highlighted that active sampling, while expensive, provides real-time, high-resolution VOC concentration data, often outperforming passive methods for heavier compounds (e.g., hexachlorobutadiene). However, using the active systems in certain campaigns, challenges such as high soil humidity or atmospheric air infiltration were observed, resulting in an underestimation of the soil gas concentrations. Passive sampling systems demonstrated cost-effective, efficient alternatives, offering consistent spatial and temporal coverage. These methods showed alignment with active techniques for lighter compounds (e.g., TCE and BTEX) but faced limitations in sorbent saturation and equilibrium time for heavier VOCs (e.g., hexachlorobutadiene), requiring adjustments in exposure duration to enhance accuracy. PE samplers provided results comparable to active methods, especially for BTEX and TCE, while WMS and sorbent pens exhibited lower sensitivity for certain analytes. This underscores the importance of optimizing sampler configurations and deployment strategies. The findings emphasize the value of integrating active and passive approaches to achieve robust VOC assessments in heterogeneous subsurface environments. Full article

Americans spend approximately 90% of their time indoors, with more than 66% of that time spent in residential buildings. Factors pertaining to household behavior or environmental factors may influence types of semi-volatile organic compounds (SVOC) found indoors. Paired indoor and outdoor passive samplers were deployed at twenty-four locations across the United States. Samples were analyzed for >1500 SVOCs to identify common patterns in exposure profiles and investigate influences of household behavior and environmental factors. Unique differences between indoor and outdoor profiles were identified, with indoor air typically having greater frequency and concentration of SVOCs relative to outdoor air. A significant relationship between fragrance chemicals and scented consumer products was identified. When considering a multifactorial approach, chemical exposures were most influenced by environmental and demographic factors. Our data highlights specific groups of chemicals identified at higher concentrations indoors and their potential influences, as well as the complexity of identifying specific sources of chemical exposures. Full article

Firefighters are occupationally exposed to many chemicals, including polycyclic aromatic hydrocarbons (PAHs), which are formed by the incomplete combustion of organic matter during fire response and training activities. However, due to the harsh environments in which firefighters work, as well as consideration for time and physical safety while wearing bulky equipment, traditional active sampling methods may not be feasible to measure PAH exposures. Silicone passive samplers offer an alternative approach to assess exposure during fire responses and live fire training due to their heat resistance and ease of deployment in remote or time-limited environments. In this study, the primary objective was to investigate and determine the statistical strength of the relationship between active air sampling methods and passive silicone samplers for PAHs. In this study, silicone wristbands were paired with active sampling devices in a series of burn experiments to compare PAH measurements. Silicone-based measurements correlated strongly with active air samples for the dominant PAHs found, naphthalene and phenanthrene; however, detection was limited in the wristbands when air concentrations were low in active samples. In situations where PAH levels are expected to be high and the potential for contaminant loss via off-gassing is low, silicone samplers may be a useful tool for industrial hygienists to measure PAHs in fire and other emergency responses in extreme environments. Full article

The relationship between indoor air quality and public health remains under-researched. WellHome is a transdisciplinary community-based study that will engage with residents to co-design feasible and acceptable research to quantify air pollution exposure in 100 homes in West London and examine its potential to exacerbate asthma symptoms in children. Sampling strategies such as using air quality monitors and passive samplers placed in kitchens, children’s bedrooms, and living rooms, will be developed in collaboration with local ambassadors and participating households to measure multiple physical, chemical, microplastic, and biological contaminants. This will provide a comprehensive understanding of indoor air quality across the city’s socio-economic gradient. Other data collected will include housing types and tenure, ventilation practices, occupant behaviours, time-activity, and airway symptoms. Epidemiological analysis will examine air pollution exposure impacts on children’s respiratory health. The particulate mixture’s relative hazard will be evaluated in toxicity studies based on source profiles and activity patterns of participants, focusing on asthma exacerbation related pathways. The study’s findings will be communicated to participants through co-designed reports and inform evidence-based recommendations for reducing indoor air pollution in London and urban areas worldwide. By raising awareness and providing actionable insights, WellHome seeks to contribute to global efforts to improve the health and well-being of vulnerable communities. Full article

It is well known that carbonyl compounds play an important role in air pollution and the formation of secondary pollutants, such as peroxyacetyl nitrates (PAN). Additionally, airborne carbonyls have been described as cytotoxic, mutagenic and carcinogenic. In this research, several carbonyl compounds, including aldehydes and ketones, as well as ozone, were monitored during a campaign conducted in July and September-October 2023 at Golf Ciudad Real, a golf course located in a non-industrial area of a south-central province in Spain. Extraction and analysis were carried out following procedures outlined by Radiello^®. Analyses were performed using HPLC-DAD and UV-Visible spectrophotometry. Ozone shows seasonal variation (temperature-dependent) concentrations displaying lower values in September/October. Among all the identified carbonyls, butanal was the most abundant, accounting for 40% of the total concentration. The C₁/C₂ and C₂/C₃ ratios were also calculated to provide information about the main emissions sources of the analyzed carbonyl compounds, indicating that mainly anthropogenic sources contribute to air quality in the area. The data were further supported by Quantitative Structure-Activity Relationship (QSAR) models using the ProtoPRED online server, which employs in silico methods based on European Chemicals Agency (ECHA) regulations to assess the (eco)toxicity of the measured carbonyl compounds. Full article

Background: Bioaerosols can represent a danger to health. During SARS-CoV-2 pandemic, portable devices were used in different environments and considered a valuable prevention tool. This study has evaluated the effectiveness of the air treatment device “AEROK 1.0^®” in reducing microbial, particulate, and pollen airborne contamination indoors, during normal activity. Methods: In an administrative room, airborne microbial contamination was measured using active (DUOSAS 360 and MD8) and passive sampling; a particle counter was used to evaluate particle concentrations; a Hirst-type pollen trap was used to assess airborne pollen and Alternaria spores. Statistical analysis was performed using SPSS 26.0; p values < 0.05 were considered statistically significant. Results: The airborne bacterial contamination assessed by the two different samplers decreased by 56% and 69%, respectively. The airborne bacterial contamination assessed by passive sampling decreased by 44%. For fungi, the reduction was 39% by active sampling. Airborne particles (diameters ≥ 1.0, 2.0 μm) and the ratio of indoor/outdoor concentrations of total pollen and Alternaria spp. spores significantly decreased. Conclusions: The results highlight the effectiveness of AEROK 1.0^® in reducing airborne contamination. The approach carried out represents a contribution to the definition of a standardized model for evaluating the effectiveness of devices to be used for air disinfection. Full article

Cured-in-place pipe (CIPP) lining is a widely adopted method for pipeline renewal, offering advantages such as rapid installation and cost-effectiveness. However, concerns regarding the environmental impacts of volatile organic compound (VOC) emissions during the installation process have raised issues regarding the CIPP method. The literature review conducted in this paper indicated the need for stringent monitoring and management practices to mitigate adverse effects, emphasizing the importance of safe installation protocols. This paper presents the initial results of a case study focusing on VOC emissions, specifically investigating non-styrene vinyl ester resins and water curing. To capture emissions from CIPP activities, the methodology involved air sampling using various equipment, including photoionization detectors (PID), summa canisters, passive worker sampler sorbent tubes, and method 13 cartridges. The preliminary findings indicate that non-styrene vinyl ester resins resulted in VOC emissions well below the exposure limits set by OSHA and USEPA, with the highest measured concentration being 2.54 ppm. This demonstrates that non-styrene resins can significantly reduce environmental and health risks. The future phases of this project will explore different resins and curing methods to further validate these findings and develop comprehensive guidelines for safe CIPP installations. Full article

Passive samplers have long been used to measure atmospheric pollutants in both indoor and outdoor environments. They are simple to operate, and can now monitor several chemical species. However, their use is limited because they usually require a long exposition time and provide a mean value that cannot control or evidence expected or non-expected events of environmental significance. A new apparatus specifically developed for exposing Analyst© passive samplers has been used to monitor ozone and nitrogen dioxide by automatically selecting a sampling duration of 8 h, as most legislation requires. The instrument was designed to accumulate ozone or NO₂ in one passive sampler for 8 h over each day, and in another passive sampler for the remaining hours. This allows for a long-time accumulation of the 8 h ozone or nitrogen dioxide in a dedicated sampler. Measurements were carried out NE of Rome at a rural site. A description of the experiments is given, with special emphasis on the quality controls. Very low uncertainties and good comparability of the data with the reference methods were obtained for both pollutants. Full article

This study assessed the cleaner and sustainable environment by measuring emission levels of benzene, toluene, ethylbenzene, and xylene (BTEX) from informal food traders using charcoal as the primary source of energy at a flea market in Fordsburg, Johannesburg. Volatile organic compounds (VOCs) were measured using a real-time monitor (MiniRae 3000 photoionization detector); an indoor air quality (IAQ) monitor was used to monitor environmental parameters and passive samplers in the form of Radiello badges, which were used to determine BTEX emissions from charcoal used during food preparation. Measurements were taken at 1.5 m above ground assuming the receptor’s breathing circumference using PID and Radiello. PID data were downloaded and analyzed using Microsoft Excel (Version 2019). Radiellos were sent to the laboratory to determine the BTEX levels from the total VOCs. The total volatile organic compound (TVOC) concentration over the combustion cycle was 306.7 ± 62.8 ppm. The flaming phase had the highest VOC concentration (547 ± 110.46 ppm), followed by the ignition phase (339.44 ± 40.6 ppm) and coking with the lowest concentration (24.64 ± 14.3). The average BTEX concentration was 15.7 ± 5.9 µg/m³ corresponding to the entire combustion cycle. BTEX concentrations were highest at the flaming phase (23.6 µg/m³) followed by the ignition (13.4 µg/m³) and coking phase (9.45 µg/m³). Ignition phase versus the flaming phase, there was a significant difference at 95% at a p-value of 0.09; ignition phase versus the coking phase, there was a significant difference at 95% at a p-value of 0.039; and coking phase versus the flaming phase, there was a significant difference at 95% at a p-value of 0.025. When compared to the occupational exposure limits (OELs), none of the exposure concentrations (BTEX) were above the 8 h exposure limit. The findings of this study suggest that charcoal, as a source of energy, can still be a useful and sustainable fuel for informal food traders. Shortening the ignition and flaming phase duration by using a fan to supply sufficient air can further reduce exposure to VOCs. Full article