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Keywords = oceanic island basalt

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20 pages, 10834 KiB  
Article
Genesis of Basalts of the Raohe Subduction–Accretion Complex in the Wandashan Block, NE China, and Its Inspirations for Evolution of the Paleo-Pacific Ocean
by Qing Liu, Cui Liu, Jixu Liu, Jinfu Deng and Shipan Tian
Appl. Sci. 2025, 15(15), 8139; https://doi.org/10.3390/app15158139 - 22 Jul 2025
Viewed by 264
Abstract
The Raohe subduction–accretion complex (RSAC) in the Wandashan Block, NE China, comprises ultramafic rocks, gabbro, mafic volcanic rocks, deep-sea and hemipelagic sediments, and trench–slope turbidites. We investigate the basalts within the RSAC to resolve debates on its origin. Zircon U-Pb dating of pillow [...] Read more.
The Raohe subduction–accretion complex (RSAC) in the Wandashan Block, NE China, comprises ultramafic rocks, gabbro, mafic volcanic rocks, deep-sea and hemipelagic sediments, and trench–slope turbidites. We investigate the basalts within the RSAC to resolve debates on its origin. Zircon U-Pb dating of pillow basalt from Dadingzi Mountain yields a concordant age of 117.5 ± 2.1 Ma (MSWD = 3.6). Integrating previous studies, we identify three distinct basalt phases. The Late Triassic basalt (210 Ma–230 Ma) is characterized as komatites–melilitite, exhibiting features of island arc basalt, as well as some characteristics of E-MORB. It also contains high-magnesium lava, suggesting that it may be a product of a juvenile arc. The Middle Jurassic basalt (around 159 Ma–172 Ma) consists of a combination of basalt and magnesium andesite, displaying features of oceanic island basalt and mid-ocean ridge basalt. Considering the contemporaneous sedimentary rocks as hemipelagic continental slope deposits, it is inferred that these basalts were formed in an arc environment associated with oceanic subduction, likely as a result of subduction of the young oceanic crust. The Early Cretaceous basalt (around 117 Ma) occurs in pillow structures, exhibiting some characteristics of oceanic island basalt but also showing transitional features towards a continental arc. Considering the regional distribution of the rocks, it is inferred that this basalt likely formed in a back-arc basin. Integrating the formation ages, nature, and tectonic attributes of the various structural units within the RSAC, as well as previous research, it is inferred that subduction of the Paleo-Pacific Ocean had already begun during the Late Triassic and continued into the Early Cretaceous without cessation. Full article
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19 pages, 4764 KiB  
Article
Tectonic Evolution of the Hainan Island, South China: Geochronological and Geochemical Constraints from Late Permian to Early Triassic Basalts
by Jieting Ouyang, Guoyu Chen, Liya Yang, Wenqian Lu and Yun Zhou
Minerals 2025, 15(3), 293; https://doi.org/10.3390/min15030293 - 13 Mar 2025
Cited by 1 | Viewed by 686
Abstract
The tectonic evolution of Hainan Island during the Late Permian–Early Triassic period is still unclear. This study identified two types of basalts on the island and presented detailed geochronology, whole-rock geochemistry, and Hf isotope data of the Late Permian–Early Triassic basalts. U-Pb dating [...] Read more.
The tectonic evolution of Hainan Island during the Late Permian–Early Triassic period is still unclear. This study identified two types of basalts on the island and presented detailed geochronology, whole-rock geochemistry, and Hf isotope data of the Late Permian–Early Triassic basalts. U-Pb dating results indicated that baddeleyites and zircons of one sample from Group 1 basalts had formation ages of 256 ± 3 Ma and 255 ± 3 Ma, respectively, and two samples from Group 2 gave formation ages of 241 ± 2 Ma and 240 ± 3 Ma, respectively. Both groups are characterized by negative anomalies of Nb, Ta, and Ti, and enrichment in Ba, Th, U, and K. Group 1 belongs to sub-alkaline basalt and exhibited SiO2 contents ranging from 50.50% to 51.05%, with ΣREE concentration of 136–148 ppm. Hf isotope analysis showed that the εHf(t) values of baddeleyites and zircons were −10.56 to −4.70 and −14.94 to −6.95, respectively. Group 2 belongs to alkaline basalt and had a higher SiO2 content of 52.48%–55.49% and ΣREE concentration of 168–298 ppm. They showed more depleted Hf isotopic composition with εHf(t) values ranging from −2.82 to +4.74. These data indicate that the source area of Group 1 was an enriched mantle, likely derived from partial melting of spinel lherzolite mantle, and was modified by subduction-derived fluids. Group 2 was derived from depleted mantle, most likely originating from partial melting of garnet + spinel lherzolite mantle. They were contaminated by crustal materials and metasomatized by subduction-derived fluids with a certain degree of fractional crystallization. Comprehensive analysis suggests that Group 1 samples likely formed in an island arc tectonic setting, while Group 2 formed in a continental intraplate extensional (or initial rift) tectonic setting. Their formation was mainly controlled by the Paleo-Tethys tectonic domain. Group 1 basalts implied that subduction of the Paleo-Tethys oceanic crust lasted at least in the late Permian (ca. 255 Ma). Group 2 basalts revealed that the intra-plate extensional (or initial rift) stage occurred in the middle Triassic (ca. 240 Ma). Full article
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22 pages, 28128 KiB  
Article
Mafic Intrusions in the Cuona Area, Eastern Tethyan Himalaya: Early Kerguelen Mantle Plume Activity and East Gondwana Rifting
by Chunxi Shan, Zhiqiang Kang, Feng Yang, Chengyou Ma, Zedong Qiao, Zonghao Liu, Jizhong Mu, Lingling Wu and Lu Zhou
Minerals 2025, 15(3), 281; https://doi.org/10.3390/min15030281 - 10 Mar 2025
Viewed by 615
Abstract
The widespread occurrence of Mesozoic ocean island basalt (OIB)-like igneous rocks in the Southern Tibetan Himalayan Belt provides important constraints on the rifting of East Gondwana. This study undertook a petrological, geochronological, and geochemical investigation of mafic intrusive rocks in the Cuona area [...] Read more.
The widespread occurrence of Mesozoic ocean island basalt (OIB)-like igneous rocks in the Southern Tibetan Himalayan Belt provides important constraints on the rifting of East Gondwana. This study undertook a petrological, geochronological, and geochemical investigation of mafic intrusive rocks in the Cuona area of the eastern Tethyan Himalayan Belt. The mafic intrusions have OIB-type geochemical signatures, including diabase porphyrite, gabbro, and diabase. Zircon U–Pb dating indicates that the diabase porphyrite formed at 135.0 ± 1.6 Ma. The diabase porphyrite and gabbro are enriched in high-field-strength elements (Nb and Ti) and large-ion lithophile elements (Sr and Pb) and experienced negligible lithospheric mantle or crustal contamination. The diabase is enriched in large-ion lithophile elements (LILEs, e.g., La and Ce) and depleted in high-field-strength elements (HFSEs, e.g., Ru, Zr and Ti). In general, the mafic intrusions exhibit significant light REE enrichment and heavy REE depletion and have no Eu anomalies. Whole-rock neodymium (εNd(t) = 1.55) and zircon Hf (εHf(t) = 0.60–3.73) isotopic compositions indicate derivation of the magma from enriched type I mantle. We propose that the diabase porphyrite and diabase formed in a continental margin rift setting, influenced by the Kerguelen mantle plume, and represent magmatism related to the breakup of East Gondwana. However, the gabbro formed in a relatively stable continental intraplate environment, likely derived from deep magmatic processes associated with the Kerguelen mantle plume. Our results provide new constraints on the early activity of the Kerguelen mantle plume and offer insights into the breakup and tectonic evolution of East Gondwana. Full article
(This article belongs to the Special Issue Tectonic Evolution of the Tethys Ocean in the Qinghai–Tibet Plateau)
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28 pages, 2517 KiB  
Article
Petrography and Geochemistry of Lower Jurassic Sandstones in the Eastern Junggar Basin: Implications for Provenance and Tectonic Setting
by Furong Li, Zhi Zhang, Can Zhao, Jinqi Han, Jiaye Liu, Yaoyun Guo, Xinyu Tang, Chang Su, Xu Chang and Tong Wu
Minerals 2025, 15(3), 279; https://doi.org/10.3390/min15030279 - 9 Mar 2025
Cited by 1 | Viewed by 1221
Abstract
The Junggar Basin basement comprises microcontinental blocks amalgamated through successive paleo-oceanic accretion events. Stratigraphic and provenance studies within the basin are crucial for reconstructing its evolution and understanding the closure of paleo-oceanic systems. This study presents an integrated petrographic and geochemical analysis of [...] Read more.
The Junggar Basin basement comprises microcontinental blocks amalgamated through successive paleo-oceanic accretion events. Stratigraphic and provenance studies within the basin are crucial for reconstructing its evolution and understanding the closure of paleo-oceanic systems. This study presents an integrated petrographic and geochemical analysis of the Lower Jurassic Badaowan Formation sandstones in the Dongdaohaizi Depression, located in the eastern Junggar Basin. The results reveal a progressive decrease in lithic fragment content and an increase in quartz content from older to younger strata within the Badaowan Formation, indicating an increase in compositional maturity. Provenance analysis indicates that the sandstones are predominantly derived from tuffaceous rocks, granites, basalts, and minor metamorphic rocks. Heavy mineral assemblages, including zircon, chromian spinel, tourmaline, and garnet, suggest parent rocks consisting primarily of intermediate to acidic igneous rocks, mafic igneous rocks, and metamorphic rocks. Integrated petrographic and geochemical data from the surrounding areas of the Dongdaohaizi Depression confirm that the Badaowan Formation sandstones are primarily sourced from the eastern Kelameili Mountain. The continued uplift and migration of the Kelameili Mountain during the Early Jurassic played a dominant role in shaping the sedimentary provenance. LA-ICP-MS analyses reveal that the rare earth element (REE) concentrations in the Lower Jurassic sandstones are slightly lower than the average REE content of the upper continental crust. The sandstones exhibit weak differentiation between light and heavy REEs, reflecting a depositional environment characterized by anoxic reducing conditions. Geochemical results indicate a tectonic setting dominated by a passive continental margin and continental island arc in the source area. Synthesizing these findings with related studies, we propose that the Kelameili Ocean, as part of the Paleo-Asian Ocean, underwent a complex evolution involving multiple oceanic basins and microcontinental subduction–collision systems. From the Middle Ordovician to Late Silurian, the Kelameili region evolved as a passive continental margin. With the onset of subduction during the Middle Devonian to Early Carboniferous, the eastern Junggar Basin transitioned into a continental island arc system. This tectonic transition was likely driven by episodic or bidirectional subduction of the Kelameili Ocean. Full article
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25 pages, 85884 KiB  
Article
Petrogenesis and Geological Implications of the Qiaoqi Intrusion in Western Margin of the Yangtze Block, SW China: Evidence from Geochronology, Geochemistry, and Hf Isotopes
by Yingtao Chen, Jianting Zhu, Shaoni Wei, Xiaochen Zhao, Delu Li, Xufeng Yang and Yuhang Wang
Minerals 2025, 15(2), 190; https://doi.org/10.3390/min15020190 - 19 Feb 2025
Viewed by 486
Abstract
Late Permian–Early Triassic basic rocks, which are widespread in the western margin of the Yangtze block (SW China), provide critical information for regional tectonic evolution. The Qiaoqi intrusion, distributed in the western margin of the Yangtze block, is selected as a representative for [...] Read more.
Late Permian–Early Triassic basic rocks, which are widespread in the western margin of the Yangtze block (SW China), provide critical information for regional tectonic evolution. The Qiaoqi intrusion, distributed in the western margin of the Yangtze block, is selected as a representative for discussion in this paper. LA-ICP-MS zircon U-Pb dating results show that the Qiaoqi intrusion was formed at 245 ± 1 Ma. It belongs to the medium-K calc-alkaline and tholeiitic basalt series. It is characterized by high concentrations of Fe2O3T (11.53 wt. % to 15.50 wt. %), TiO2 (1.81 wt. % to 3.20 wt. %), Al2O3 (11.80 wt. % to 15.60 wt. %), and low concentrations of MgO (4.51 wt. % to 8.93 wt. %). The LREE and LILE (such as Cs, Rb, Ba and Th) are enriched, with insignificant Eu anomalies (Eu/Eu* = 0.92 to 1.13). The chondrite-normalized REE distribution diagram shows a right-leaning pattern, similar to ocean island basalts (OIB), displaying the geochemical characteristics of enriched mantle sources. The zircon εHf(t) values are relatively high (+12.7 to +15.5) and the single-stage Hf model ages are relatively young (tDM = 272 to 386 Ma). Modeling further reveals that the parent magma was derived from 13% to 19% partial melting of garnet peridotite. Comprehensive analysis shows that the geochemical characteristics of the Qiaoqi intrusion bear resemblance to those of the Emeishan basalts, which are attributed to volumetrically minor melting of the fossil Emeishan plume head beneath the Yangtze crust following the eruption of the Emeishan Large Igneous Province (ELIP). This understanding further constrains the duration of the Emeishan Large Igneous Province and provides new support for understanding the formation, evolution and distribution of the Emeishan Large Igneous Province. Full article
(This article belongs to the Section Mineral Geochemistry and Geochronology)
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35 pages, 18372 KiB  
Article
The Initial Subduction Time of the Proto-Tethys Ocean in the Eastern Section of the East Kunlun Orogen: The Constraints from the Zircon U-Pb Ages and the Geochemistry of the Kekesha Intrusion
by Jian Song, Xianzhi Pei, Zuochen Li, Ruibao Li, Lei Pei, Youxin Chen and Chengjun Liu
Minerals 2025, 15(2), 127; https://doi.org/10.3390/min15020127 - 27 Jan 2025
Cited by 1 | Viewed by 926
Abstract
The Cambrian period marks a crucial phase in the initial subduction of the Proto-Tethys Ocean beneath the East Kunlun Orogen. Studying the I-type granites and mafic–ultramafic rocks formed during this period can provide valuable insights into the early Paleozoic tectonic evolution of the [...] Read more.
The Cambrian period marks a crucial phase in the initial subduction of the Proto-Tethys Ocean beneath the East Kunlun Orogen. Studying the I-type granites and mafic–ultramafic rocks formed during this period can provide valuable insights into the early Paleozoic tectonic evolution of the region. This paper incorporates petrology, LA-ICP-MS zircon U-Pb geochronology, and whole-rock major and trace element data obtained from the Kekesha intrusion in the eastern section of the East Kunlun Orogen. The formation age, petrogenesis, and magmatic source region of the intrusion are revealed, and the early tectonic evolution process of the subduction of the Proto-Tethys Ocean is discussed. The Kekesha intrusion includes four main rock types: gabbro, gabbro diorite, quartz diorite, and granodiorite. The zircon U-Pb ages are 515.7 ± 7.4 Ma for gabbro, 508.9 ± 9.8 Ma for gabbro diorite, 499.6 ± 4.0 Ma for quartz diorite, and 502.3 ± 9.3 Ma and 501.6 ± 6.2 Ma for granodiorite, respectively, indicating that they were formed in the Middle Cambrian. The geochemical results indicate that the gabbro belongs to the high-Al calc-alkaline basalt series, the gabbro diorite belongs to the medium-high-K calc-alkaline basalt series, the quartz diorite belongs to the quasi-aluminous medium-high-K calc-alkaline I-type granite series, and the granodiorite belongs to the weakly peraluminous calc-alkaline I-type granite series, all of which belong to the medium-high-K calc-alkaline series that have undergone varying degrees of differentiation and contamination. Gabbro and gabbro diorite exhibit significant enrichment in light rare earth elements (LREEs), depletion in heavy rare earth elements (HREEs), and an enhanced negative anomaly in Eu (Europium). Compared to gabbro and gabbro diorite, quartz diorite and granodiorite exhibit more pronounced enrichment in LREEs, more significant depletion in HREEs, and an enhanced negative anomaly in Eu. All four rock types are enriched in large-ion lithophile elements (LILEs) such as Cs, Rb, Th, Ba, and U, and are depleted in high-field-strength elements (HFSEs) such as Nb, Ta, and Ti. This indicates that these rocks originated from the same or similar mixed mantle source regions, and that they are formed in the island-arc tectonic environment. This paper suggests that the gabbro and gabbro diorite are mainly derived from the basic magma formed by partial melting of the lithospheric mantle metasomatized by subducted slab melt in the oceanic crust subduction zone and mixed with a small amount of asthenosphere mantle material. Quartz diorite results from the crystal fractionation of basic magma and experiences crustal contamination during magmatic evolution. Granodiorite forms through the crystal fractionation of basic magma, mixed with partial melting products from quartz diorite. While the lithology of the intrusions differs, their geochemical characteristics suggest they share the same tectonic environment. Together, they record the geological processes associated with island-arc formation in the East Kunlun region, driven by the northward subduction of the Proto-Tethys Ocean during the Early Paleozoic. Based on regional tectonic evolution, it is proposed that the Proto-Tethys Ocean began subducting northward beneath the East Kunlun block from the Middle Cambrian. The Kekesha intrusion formed between 516 and 500 Ma, marking the early stages of Proto-Tethys Ocean crust subduction. Full article
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22 pages, 9743 KiB  
Article
Machine Learning-Based Tectonic Discrimination Using Basalt Element Geochemical Data: Insights into the Carboniferous–Permian Tectonic Regime of Western Tianshan Orogen
by Hengxu Li, Mengqi Gao, Xiaohui Ji, Zhaochong Zhang, Zhiguo Cheng and M. Santosh
Minerals 2025, 15(2), 122; https://doi.org/10.3390/min15020122 - 26 Jan 2025
Viewed by 1367
Abstract
Identifying the tectonic setting of rocks is essential for gaining insights into the geological contexts in which these rocks were formed, aiding in tectonic plate reconstruction and enhancing our comprehensive understanding of the Earth’s history. The application of machine learning algorithms helps identify [...] Read more.
Identifying the tectonic setting of rocks is essential for gaining insights into the geological contexts in which these rocks were formed, aiding in tectonic plate reconstruction and enhancing our comprehensive understanding of the Earth’s history. The application of machine learning algorithms helps identify complex patterns and relationships between big data that may be overlooked by binary or ternary tectonomagmatic discrimination diagrams based on basalt compositions. In this study, three machine learning algorithms, i.e., Support Vector Machine (SVM), Random Forest (RF), and eXtreme Gradient Boosting (XGBoost), were employed to classify the basalts from seven diverse settings, including intraplate basalts, island arc basalts, ocean island basalts, mid-ocean ridge basalts, back-arc basin basalts, oceanic flood basalts, and continental flood basalts. Specifically, for altered and fresh basalt samples, we utilized 22 immobile elements and 35 major and trace elements, respectively, to construct discrimination models. The results indicate that XGBoost demonstrates the best performance in discriminating basalts into seven tectonic settings, achieving accuracies of 85% and 89% for the altered and fresh basalt samples, respectively. A key innovation of our newly developed tectonic discrimination model is the establishment of tailored models for altered and fresh basalts. Moreover, by omitting isotopic features during model construction, the new models offer broader applicability in predicting a wider range of basalt samples in practical scenarios. The classification models were applied to investigate the Carboniferous to Permian evolution in the Western Tianshan Orogen (WTO), revealing that the subduction of Tianshan Ocean ceased at the end of Carboniferous and the WTO evolved into a post-collisional orogenesis during the Permian. Full article
(This article belongs to the Section Mineral Geochemistry and Geochronology)
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30 pages, 7272 KiB  
Article
A Genetic Model for the Biggenden Gold-Bearing Fe Skarn Deposit, Queensland, Australia: Geology, Mineralogy, Isotope Geochemistry, and Fluid Inclusion Studies
by Mansour Edraki, Alireza K. Somarin and Paul M. Ashley
Minerals 2025, 15(1), 95; https://doi.org/10.3390/min15010095 - 20 Jan 2025
Cited by 1 | Viewed by 1661
Abstract
The Biggenden gold-bearing Fe skarn deposit in southeast Queensland, Australia, is a calcic magnetite skarn that has been mined for Fe and gold (from the upper portion of the deposit). Skarn has replaced volcanic and sedimentary rocks of the Early Permian Gympie Group, [...] Read more.
The Biggenden gold-bearing Fe skarn deposit in southeast Queensland, Australia, is a calcic magnetite skarn that has been mined for Fe and gold (from the upper portion of the deposit). Skarn has replaced volcanic and sedimentary rocks of the Early Permian Gympie Group, which formed in different tectonic settings, including island arc, back arc, and mid-ocean ridge. This group has experienced a hornblende-hornfels grade of contact metamorphism due to the intrusion of the Late Triassic Degilbo Granite. The intrusion is a mildly oxidized I-type monzogranite that has geochemical characteristics intermediate between those of granitoids typically associated with Fe-Cu-Au and Sn-W-Mo skarn deposits. The skarn mineralogy indicates that there was an evolution from prograde to various retrograde assemblages. Prograde garnet (Adr11-99Grs1-78Alm0-8Sps0-11), clinopyroxene (Di30-92Hd7-65Jo0-9), magnetite, and scapolite formed initially. Epidote and Cl-bearing amphibole (mainly ferropargasite) were the early retrograde minerals, followed by chlorite, calcite, actinolite, quartz, and sulfides. Late-stage retrograde reactions are indicated by the development of nontronite, calcite, and quartz. Gold is mainly associated with sulfide minerals in the retrograde sulfide stage. The fluids in equilibrium with the ore-stage calcites had δ13C and δ18O values that indicate deposition from magmatically derived fluids. The calculated δ18O values of the fluids in equilibrium with the skarn magnetite also suggest a magmatic origin. However, the fluids in equilibrium with epidote were a mixture of magmatic and meteoric water, and the fluids that deposited chlorite were at least partly meteoric. δD values for the retrograde amphibole and epidote fall within the common range for magmatic water. Late-stage chlorite was deposited from metasomatic fluids depleted in deuterium (D), implying a meteoric water origin. Sulfur isotopic compositions of the Biggenden sulfides are similar to other skarn deposits worldwide and indicate that sulfur was most probably derived from a magmatic source. Based on the strontium (87Sr/86Sr) and lead (206Pb/204Pb, 207Pb/204Pb and 208Pb/204Pb) isotope ratios, the volcanic and sedimentary rocks of the Gympie Group may have contributed part of the metals to the hydrothermal fluids. Lead isotope data are also consistent with a close age relationship between the mineralization at Biggenden and the crystallization of the Degilbo Granite. Microthermometric analysis indicates that there is an overall decrease in fluid temperature and salinity from the prograde skarn to retrograde alterations. Fluid inclusions in prograde skarn calcite and garnet yield homogenization temperatures of 500 to 600 °C and have salinities up to 45 equivalent wt % NaCl. Fluid inclusions in quartz and calcite from the retrograde sulfide-stage homogenized between 280 and 360 °C and have lower salinities (5–15 equivalent wt % NaCl). In a favored genetic model, hydrothermal fluids originated from the Degilbo Granite at depth and migrated through the shear zone, intrusive contact, and permeable Gympie Group rocks and leached extra Fe and Ca and deposited magnetite upon reaction with the adjacent marble and basalt. Full article
(This article belongs to the Special Issue Geochemistry and Genesis of Hydrothermal Ore Deposits)
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19 pages, 17860 KiB  
Article
The Petrogenesis of Devonian Volcanism and Its Tectonic Significance in the Kalatag Area, Eastern Tianshan, Xinjiang, China
by Zhijie Ma, Fengmei Chai, Mingjian Cao, Xiaodong Song, Haipei Wang, Dongmei Qi and Qigui Mao
Minerals 2024, 14(12), 1195; https://doi.org/10.3390/min14121195 - 24 Nov 2024
Viewed by 1111
Abstract
The Kalatag mineralization belt is an important metallogenic belt of polymetallic mineral deposits in the northern part of eastern Tianshan, and its age and tectonic setting are still controversial. We identified a set of Devonian volcanic rocks hosted in the Early Palaeozoic package [...] Read more.
The Kalatag mineralization belt is an important metallogenic belt of polymetallic mineral deposits in the northern part of eastern Tianshan, and its age and tectonic setting are still controversial. We identified a set of Devonian volcanic rocks hosted in the Early Palaeozoic package of dominantly marine sediments with a small amount of terrestrial rocks. This study presents petrological, U–Pb geochronology, and geochemical data for the volcanic rocks. The ages of the rhyolite (407.2 ± 1.9 Ma) and basaltic andesite (380.4 ± 2.8 Ma) suggests that the Kalatag belt is a Devonian volcanic succession. These rocks consist mainly of marine calc–alkaline lava, tuff, pyroclastic rocks, and minor terrestrial basaltic andesite. The lavas are characterized by the enrichment of light rare earth elements and strongly depleted in Nb and Ta, typical of island arc magmatic rocks. The volcanic rocks probably originated from the partial melting of the mafic lower crust which was modified by subducted slab-related fluids. During their ascent through the crust, these volcanic rocks underwent variable extents of fractional crystallization (rhyolites) and crustal contamination (basaltic andesites). Combined with the results of previous studies, we suggest that the Devonian rocks formed in an island arc related to the northward subduction of the Northern Tianshan Ocean with a crustal thickness of ~35–40 km. Full article
(This article belongs to the Section Mineral Geochemistry and Geochronology)
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17 pages, 11844 KiB  
Article
Ecological and Human Health Risk Assessment Based on Stream Sediments from Coastal Oecusse (Timor)
by Victor A. S. Vicente, Marina Cabral Pinto, Pedro Dinis and João A. M. S. Pratas
Water 2024, 16(21), 3020; https://doi.org/10.3390/w16213020 - 22 Oct 2024
Cited by 1 | Viewed by 1640
Abstract
Timor Island is located in a geologically complex region strongly affected by the collision of the Australian margin with the Banda volcanic arc. In Oecusse, an enclave of East Timor in the western part of Timor, crop out several lithological units of the [...] Read more.
Timor Island is located in a geologically complex region strongly affected by the collision of the Australian margin with the Banda volcanic arc. In Oecusse, an enclave of East Timor in the western part of Timor, crop out several lithological units of the Banda Terrane that are associated with the obduction of oceanic crust and upper mantle on the Australian continental crust. This study reports the geochemistry of stream sediments from the coastal region of the Oecusse enclave, where the Banda Terrane is best represented, employing statistical analyses to discern the sources of metal(oid)s and assessing ecological and health risks. Arsenic, Cr, and Ni are the elements with higher potential ecological risk factors. The potential ecological risk index (PERI), which combines single indexes of ecological risk factors for multiple elements, is very high in a stream sourced by the Lolotoi-Mutis Complex. Significant risks for human health were found for As (sourced by the Lolotoi-Multis Metamorphic Complex and basalts of the Barique Formation), Mn (sourced by the Maubisse and Barique formations), and V (sourced by the Manamas Formation). The highest values of hazard index (HI), however, were determined with Cr, in particular for children (HI higher than 10 in 12 sediments sourced by ultramafic units and their covering sedimentary units). This investigation shows that high geogenic concentrations of several elements, particularly those derived from the oceanic crust and the upper mantle, raise significant cancer and non-carcinogenic risks. Full article
(This article belongs to the Special Issue Water Quality Monitoring and Public Health)
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30 pages, 15297 KiB  
Article
Geochronology and Geochemistry of Paleoproterozoic Mafic Rocks in Northern Liaoning and Their Geological Significance
by Jingsheng Chen, Yi Tian, Zhonghui Gao, Bin Li, Chen Zhao, Weiwei Li, Chao Zhang and Yan Wang
Minerals 2024, 14(7), 717; https://doi.org/10.3390/min14070717 - 16 Jul 2024
Cited by 4 | Viewed by 1610
Abstract
Petrological, geochronological, and geochemical analyses of mafic rocks in northern Liaoning were conducted to constrain the formation age of the Proterozoic strata, and to further study the source characteristics, genesis, and tectonic setting. The mafic rocks in northern Liaoning primarily consist of basalt, [...] Read more.
Petrological, geochronological, and geochemical analyses of mafic rocks in northern Liaoning were conducted to constrain the formation age of the Proterozoic strata, and to further study the source characteristics, genesis, and tectonic setting. The mafic rocks in northern Liaoning primarily consist of basalt, diabase, gabbro, and amphibolite. Results of zircon U-Pb chronology reveal four stages of mafic magma activities in northern Liaoning: the first stage of basalt (2209 ± 12 Ma), the second stage of diabase (2154 ± 15 Ma), the third stage of gabbro (2063 ± 7 Ma), and the fourth stage of magmatic protolith of amphibolite (2018 ± 13 Ma). Combined with the unconformity overlying Neoproterozoic granite, the formation age of the Proterozoic strata in northern Liaoning was found to be Paleoproterozoic rather than Middle Neoproterozoic by the geochronology of these mafic rocks. A chronological framework of mafic magmatic activities in the eastern segment of the North China Craton (NCC) is proposed. The mafic rocks in northern Liaoning exhibit compositional ranges of 46.39–50.33 wt% for SiO2, 2.95–5.08 wt% for total alkalis (K2O + Na2O), 6.17–7.50 wt% for MgO, and 43.32–52.02 for the Mg number. TiO2 contents lie between 1.61 and 2.39 wt%, and those of MnO between 0.17 and 0.21 wt%. The first basalt and the fourth amphibolite show low total rare earth element contents. Normalized against primitive mantle, they are enriched in large ion lithophile elements (Rb, Ba, K), depleted in high field strength elements (Th, U, Nb, Ta, Zr, Ti), and exhibit negative anomalies in Sr and P, as well as slight positive anomalies in Zr and Hf. The second diabase and the third gabbro have similar average total rare earth element contents. The diabase shows slight negative Eu anomalies (Eu/Eu* = 0.72–0.88), enrichment in large ion lithophile elements (Ba), depletion in Rb, and slight positive anomalies in high field strength elements (Th, U, Nb, Ta, Zr, Hf, Ti), with negative anomalies in K, Sr, and P. The gabbro is enriched in large ion lithophile elements (Rb, Ba, K), depleted in high field strength elements (Th, U, Nb, Ta, Zr, Hf), and exhibits positive anomalies in Eu (Eu/Eu* = 1.31–1.37). The contents of Cr, Co, and Ni of these four stages of mafic rocks are higher than those of N-MORB. The characteristics of trace element ratios indicate that the mafic rocks belong to the calc-alkaline series and originate from the transitional mantle. During the process of magma ascent and emplacement, it is contaminated by continental crustal materials. There are residual hornblende and spinel in the magma source of the first basalt. The other three magma sources contain residual garnet and spinel. The third gabbro was formed in an island arc environment, and the other three stages of mafic rocks originated from the Dupal OIB and were formed in an oceanic island environment. The discovery of mafic rocks in northern Liaoning suggests that the Longgang Block underwent oceanic subduction and extinction in both the north and south in the Paleoproterozoic, indicating the possibility of being in two different tectonic domains. Full article
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17 pages, 8826 KiB  
Article
The Middle Triassic Intermediate to Basic Rocks in the Eastern Kunlun Orogenic Belt, Northeast Tibet: Implication for the Paleo-Tethyan Ocean Closure
by Wei Du, Lei Pei, Zuochen Li, Ruibao Li, Youxin Chen, Chengjun Liu, Guochao Chen and Xianzhi Pei
Minerals 2024, 14(7), 667; https://doi.org/10.3390/min14070667 - 27 Jun 2024
Cited by 1 | Viewed by 997
Abstract
Large volumes of Early Mesozoic intermediate to basic igneous rocks related to the evolution of the Paleo-Tethys Ocean are exposed in the East Kunlun Orogenic Belt (EKOB). The petrography, geochemistry, and results of zircon U-Pb dating of Defusheng intermediate to basic rocks from [...] Read more.
Large volumes of Early Mesozoic intermediate to basic igneous rocks related to the evolution of the Paleo-Tethys Ocean are exposed in the East Kunlun Orogenic Belt (EKOB). The petrography, geochemistry, and results of zircon U-Pb dating of Defusheng intermediate to basic rocks from the eastern segment of the EKOB are presented in this report. Zircon U–Pb dating of the intermediate to basic rocks yields ages of 239–245 Ma (Middle Triassic). Defusheng intermediate to basic rocks have low TiO2 contents (0.80–1.47 wt.%) and widely varying MgO (3.14–6.08 wt.%), and are enriched in large ion lithophile elements and light rare earth elements, having a geochemical composition similar to that of island arc basalts. The variation diagrams of major elements indicate that the Defusheng intermediate to basic rocks underwent fractional clinopyroxene and olivine crystallization. Depletion of the high-field-strength elements Nb, Ta, and Ti may have been caused by the mantle wedge having been infiltrated by fluids derived from the subducted slab. The Defusheng intermediate to basic rocks represent magmatic records of the Early Mesozoic oceanic crust subduction in Eastern Kunlun. This indicates that the final closure of the Paleo-Tethyan Ocean and the beginning of collisional orogeny occurred after the Middle Triassic. Full article
(This article belongs to the Section Mineral Geochemistry and Geochronology)
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23 pages, 8624 KiB  
Article
Tracing the Origin and Magmatic Evolution of the Rejuvenated Volcanism in Santa Clara Island, Juan Fernández Ridge, SE Pacific
by Javier Reyes, Luis E. Lara, Vanessa Sutherland, Nicolás Aguirre, Carlos Orellana, Folkmar Hauff and Kaj Hoernle
Minerals 2024, 14(5), 524; https://doi.org/10.3390/min14050524 - 19 May 2024
Cited by 1 | Viewed by 1619
Abstract
Oceanic intraplate volcanoes sometimes experience late-stage eruptive activity known as rejuvenated volcanism, and contrasting interpretations for its petrogenesis depend on the compositional characteristics. In the Juan Fernández Ridge (JFR), a volcanic chain approximately 800 km in length emplaced on the Nazca Plate, some [...] Read more.
Oceanic intraplate volcanoes sometimes experience late-stage eruptive activity known as rejuvenated volcanism, and contrasting interpretations for its petrogenesis depend on the compositional characteristics. In the Juan Fernández Ridge (JFR), a volcanic chain approximately 800 km in length emplaced on the Nazca Plate, some subaerial occurrences of rejuvenated volcanism have been recognized on the Robinson Crusoe and Santa Clara Islands, both part of the same deeply eroded shield volcano complex. This study aims to understand the origin and magmatic evolution of rejuvenated volcanism on Santa Clara Island, emplaced after ~2.15 Ma of quiescence above the shield sequence, mainly via the analysis of unpublished geochemical and isotopic data. Field reconnaissance identified two nearly coeval rejuvenated sequences on Santa Clara Island: Bahía W (BW) and Morro Spartan (MS), both formed by basanitic and picro-basaltic lava flows with brecciated levels and local intercalations of sedimentary and pyroclastic deposits. In comparison to the chemical signature of the preceding shield-building stage (comprised mainly of basalts and picrites), the two rejuvenated sequences exhibit a notable enrichment in incompatible elements, but the Sr, Nd, and Pb isotopes are very similar to the FOZO mantle endmember, with an apparent additional contribution of HIMU and EM1 components. The geochemistry of lavas revealed the involvement of various processes, including contamination by ultramafic xenoliths, high-pressure fractional crystallization of olivine and clinopyroxene, and potential partial assimilation of oceanic lithospheric components. While the oceanic lithosphere has been considered as a potential source, the isotopic data from Santa Clara lies outside of the mixing curve between depleted mantle (DM, here represented by the North Chile Rise and the East Pacific Rise) and the previous shield stage, suggesting that a lithospheric mantle is not the primary source for the rejuvenated stage volcanism. Therefore, we favor an origin of the rejuvenated volcanism from the mantle plume forming the JFR, supported by similarities in isotopic signatures with the shield stage and high values of 208Pb/204Pb (only comparable to San Félix—San Ambrosio in the vicinity of JFR), implying the presence of a regional source with radiogenic 208Pb/204Pb isotope ratios. In addition, isotopic variations are subparallel to the mixing line between HIMU and EM1 components, whose participation in different proportions might explain the observed trends. In conclusion, we propose that the source of the rejuvenated volcanism on Santa Clara Island is a heterogeneous mantle plume, the same one that fed the shield stage. The rejuvenated volcanism is derived from a secondary melting zone away from the main axis of the plume. Full article
(This article belongs to the Section Mineral Geochemistry and Geochronology)
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15 pages, 9365 KiB  
Article
Petrogenesis and Geodynamic Implications of Cretaceous Nb-Enriched Mafic Dykes in the East Kunlun Orogen, Northern Tibet Plateau: Constraints from Geochronology, Geochemistry and Sr-Nd Isotopes
by Zhiqiang Chu, Hu Zhou, Mingchi Wang, Jiaming Zhou and Fuhao Xiong
Minerals 2024, 14(1), 89; https://doi.org/10.3390/min14010089 - 12 Jan 2024
Viewed by 1891
Abstract
There is a magmatic lull period in the East Kunlun orogen (EKO) during the Jurassic to the Cretaceous. However, due to the lack of records of magmatic activity restricts our understanding of the late Mesozoic magmatic-tectonic evolution of the EKO. Herein, an integrated [...] Read more.
There is a magmatic lull period in the East Kunlun orogen (EKO) during the Jurassic to the Cretaceous. However, due to the lack of records of magmatic activity restricts our understanding of the late Mesozoic magmatic-tectonic evolution of the EKO. Herein, an integrated study of geochronology, whole-rock geochemistry and Sr-Nd isotopes were conducted for the Cretaceous mafic dykes in the EKO, Northern Tibet Plateau, to reveal their petrogenesis and geodynamic implications. LA-ICP-MS Zircon U-Pb dating reveals that the studied mafic dykes comprising diabase and diabase porphyry emplaced at ca. 80.9 ± 0.8 Ma. The Cretaceous mafic dykes have low contents of SiO2 (46.36 wt.%~47.40 wt.%) but high contents of MgO (6.79 wt.%~7.38 wt.%), TiO2 (1.91 wt.%~2.13 wt.%), Nb (12.4~18.3 ppm) and Nb/U ratio (31~39), resembling Nb-enriched mafic dykes. They exhibit chondrite-normalized rare earth element (REE) and primitive mantle-normalized trace element patterns, remarkably similar but not identical to the oceanic island basalts (OIB). The moderate REE fractionation ((La/Yb)N = 3.55~5.37), weak negative Eu anomalies (δEu = 0.87~0.97) and relative enrichment of Rb, Ba, K, as well as high contents of Cr and Ni and slightly depleted Sr-Nd isotopes (εNd(t) = −0.18~1.33), suggest that the studied dykes originate from a partial melting of spinel lherzolite and a little of garnet which was previously modified by subducted sediments. Combined with other evidence, we propose that the studied Cretaceous Nb-enriched mafic dykes in the Northern Tibet Plateau were formed in the intraplate setting, which may be a partial melting of the enriched mantle in the lower lithosphere caused by the activity of the East Kunlun strike-slip fault. Full article
(This article belongs to the Special Issue Petrogenesis, Magmatism and Geodynamics of Orogenic Belts)
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23 pages, 16223 KiB  
Article
A Residual Middle Triassic Oceanic Island-Seamount in the Maoershan Area, Northwest Tibet: Implications for the Evolution of the Paleo-Tethys Ocean
by Chao Li, Junhao Wen, Zhongbao Zhao, Feng Yang, Jiaxin Yan, Ye Tian and Rong Su
Minerals 2023, 13(12), 1551; https://doi.org/10.3390/min13121551 - 15 Dec 2023
Viewed by 1743
Abstract
The assemblage of oceanic islands and seamounts, arising from the widespread presence of mature oceans, plays a crucial role in reconstructing the evolutionary history of the paleoocean. Oceanic islands or seamounts within the Longmuco-Shuanghu metamorphic complex, a remnant of the Paleo-Tethys Ocean in [...] Read more.
The assemblage of oceanic islands and seamounts, arising from the widespread presence of mature oceans, plays a crucial role in reconstructing the evolutionary history of the paleoocean. Oceanic islands or seamounts within the Longmuco-Shuanghu metamorphic complex, a remnant of the Paleo-Tethys Ocean in the central Tibetan Plateau, have seldom been reported due to their remoteness. This study has identified an oceanic island-seamount in the Maoershan area, situated to the west of the Longmuco-Shuanghu metamorphic complex, composed of basalt, diabase, limestone, and siliceous rocks. Based on field observations, petrology, zircon U-Pb dating, whole-rock geochemistry, and Sr-Nd isotopes analyses, we have identified a suite of mafic rocks with OIB affinity. The youngest zircon U-Pb age cluster was concentrated at ~243–241 Ma. The geochemical characteristics of the siliceous rocks indicate a mixture of terrigenous material, suggesting that they formed in a continental margin. In combination with regional geological data, we conclude that the Longmuco-Shuanghu Paleo-Tethys Ocean remained open during the Middle Triassic. Furthermore, a fraction of the oceanic island-seamounts underwent scraping and transformed into a metamorphic complex, while other segments experienced deep subduction, resulting in the formation of high-pressure metamorphic rocks. Collectively, these processes gave rise to the distinctive high-pressure metamorphic complex within the central Qiangtang terrane. Full article
(This article belongs to the Section Mineral Geochemistry and Geochronology)
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