Search Results (9)

The properties of compatibilized blends of polyethylene (PE) and polypropylene (PP), having reduced macromolecular entanglements, were studied. The density of PP macromolecular entanglements was controlled by prior disentangling in solution. The polymer ratio in the blend was 4:1 or 1:4. An ethylene–octene copolymer was used as a compatibilizer. The melt blending process resulted in good dispersion of the minority component, with slightly larger inclusions when more disentangled PP was used. Rheological studies confirmed the achievement of different entanglement densities of PP macromolecules in the blends. The partial disentanglement did not affect the thermal stability of the blends. During the isothermal crystallization studies, faster growth of PP spherulites was observed in the blend with reduced entanglements, which also influenced the entire crystallization process. The recovery time of equilibrium entanglement was investigated and it turned out to be 45 min if the blend was annealed at 190 °C, which was shorter than in the analogous homopolymer. Studies of tensile properties showed that in blends with a majority share of polyethylene, the elongation at break increased with the disentanglement of the minority component, due to better bonding of the blend components and thus the reduction in microcavitation. Full article

This research explores how varying proportions of virgin polyethylene terephthalate (vPET) and recycled polyethylene terephthalate (rPET) in vPET-rPET blends, combined with preform thermal conditions during the stretch blow molding (SBM) process, influence PET bottles’ microscopic characteristics. Key metrics such as viscosity, density, crystallinity, amorphous phase relaxation, and microcavitation were assessed using response surface methodology (RSM). Statistical analysis, including Analysis of variance (ANOVA) and its power, supported the interpretation of results. The first part of the work details the experimental design and statistical methods. Positron annihilation lifetime spectroscopy (PALS) and amorphous phase density analysis revealed reduced free volume size, a substantial increase in free volume quantity, and a transformation toward ellipsoidal geometries, highlighting significant structural changes in the material. At the same time, the intrinsic viscosity (IV) and PALS studies indicate that the solid-state post-condensation effect (SSPC) is linked with microcavitation through post-condensation product diffusion. The conclusions, which resulted from the microstructure analysis, affected the material’s mechanical strength and were validated by pressure resistance tests of the bottles. Full article

Polyethylene terephthalate (PET) is widely used in bottle production by stretch blow molding processes (SBM processes) due to its cost-effectiveness and low environmental impact. The presented literature review focuses on microcavitation and solid-state post-condensation effects that occur during the deformation of PET in the SBM process. The literature review describes cavitation and microcavitation effects in PET material and solid-state post-condensation of PET on the basis of a three-phase model of the PET microstructure. A three-phase model of PET microstructure (representing the amorphous phase in two ways, depending on the ratio of the trans-to-gauche conformation of the PET macromolecule and the amount of free volume) with a nucleation process, a crystallization process, and the use of positron annihilation lifetime spectroscopy (PALS) to analyze PET microstructure are discussed in detail. The conceptual model developed based on the literature combines solid-state post-condensation with microcavitation via the diffusion of the post-condensation product. This review identifies the shortcomings of the developed conceptual model and presents them with five hypotheses, which will be the basis for further research. Full article

Polyethylene terephthalate (PET) is widely used in bottle production due to its cost-effectiveness and low environmental impact. The first part of this article describes the research and statistical analysis methodology of the influence of the virgin PET (vPET) and recycled PET (rPET) content in the vPET-rPET blend, as well as the preform heating/cooling conditions in the stretch blow molding (SBM) process on the microscopic bottle properties. Microscopic properties such as crystallinity, density, viscosity, relaxation degree of the amorphous phase, and microcavitation in PET were examined. This study reveals that microcavity and solid-state post-condensation effects occur during PET deformation in the SBM process. The increase in free volume, indicating microcavitation, was confirmed by measuring positron annihilation lifetime spectroscopy (PALS). PALS and density of the amorphous phase studies prove a reduction in the dimensions of the free volumes, with a simultaneous significant increase in their number and ellipsoidization. It can be associated with crystallite rotation in a temperature-dependent non-crystalline matrix. The occurrence of solid-state post-condensation effects was confirmed by measuring the intrinsic viscosity. The conclusions resulting from the analysis of the microstructure affecting the mechanical strength of the material were validated by pressure resistance tests of the bottles. Full article

Background and Objectives: The aim was to introduce an innovative, easy and cheap clinical approach for the control of multiple proximal non-cavitated lesions via the application of 38% silver fluoride after placement of orthodontic separators in the permanent dentition in high-caries-risk children. Materials and Methods: The case series describes the management of initial proximal carious lesions using silver fluoride (SF) products in the permanent dentition of two adolescent patients with prior proximal caries progression. Both presented with multiple asymptomatic carious lesions that were identified through the use of bitewing radiographs and classified according to the ADA proximal caries classification system. Using orthodontic separators prior to the planned application of SF, most of the surfaces could then be quickly directly examined to check for surface integrity. Follow-up examinations were conducted clinically and radiographically for at least one year to monitor lesion progression. Results: None of the 25 enamel lesions (E1/E2) exhibited signs of progression after single SF application, while 2 out of 11 dentine lesions (D1) showed progression and required restorative intervention. The progressed lesions potentially had non-cleansable micro-cavitations that were either clinically undetected or not fully reached with the micro-brush in SF application. Thus, this should have been repeated or combined with SF application via soaked superfloss to potentially achieve better results. Conclusions: Single application of 38% silver fluoride directly onto active enamel lesions in juvenile permanent teeth with the prior use of orthodontic separators combined with a caries-risk-specific prevention program appears to be highly effective and should be considered as a viable minimally invasive option for patients and clinicians due to its cost-effectiveness and time efficiency. Full article

The current study aimed to implement and validate an automation system to detect carious lesions from smartphone images using different one-stage deep learning techniques. 233 images of carious lesions were captured using a smartphone camera system at 1432 × 1375 pixels, then classified and screened according to a visual caries classification index. Following data augmentation, the YOLO v5 model for object detection was used. After training the model with 1452 images at 640 × 588 pixel resolution, which included the ones that were created via image augmentation, a discrimination experiment was performed. Diagnostic indicators such as true positive, true negative, false positive, false negative, and mean average precision were used to analyze object detection performance and segmentation of systems. YOLO v5X and YOLO v5M models achieved superior performance over the other models on the same dataset. YOLO v5X’s mAP was 0.727, precision was 0.731, and recall was 0.729, which was higher than other models of YOLO v5, which generated 64% accuracy, with YOLO v5M producing slightly inferior results. Overall mAPs of 0.70, precision of 0.712, and recall of 0.708 were achieved. Object detection through the current YOLO models was able to successfully extract and classify regions of carious lesions from smartphone photographs of in vitro tooth specimens with reasonable accuracy. YOLO v5M was better fit to detect carious microcavitations while YOLO v5X was able to detect carious changes without cavitation. No single model was capable of adequately diagnosing all classifications of carious lesions. Full article

In this work, the transfer matrix method (TMM) is employed to investigate the optical properties of one-dimensional periodic and quasiperiodic photonic crystals containing nematic liquid crystal (NLC) layers. This structure is expressed as (ABC)J(CBA)J and made of alternated layers of isotropic dielectrics SiO₂ (A), BGO (B) and nematic liquid crystal (C). The simulation study shows that the proposed ternary configuration exhibits tunable defect mode within the photonic band gap (PBG) that can be manipulated by adjusting the thicknesses of NLC layers in order of the periodic lattice. In addition, the optimized structure permits for strong confinement light giving rise to an optical microcavity. The application of an applied voltage into NLC layers enables improving the sensitivity by guiding the local defect mode. It has been also shown that by applying quasiperiodic inflation according to Rudin Shapiro Sequence (RSS) scheme to main periodic structure, several tunable resonant modes appear within the PBG. The presence of such sharp resonant peaks reflects that the quasiperiodic NLC-based structure behaves like multiple microcavites with strong light-matter coupling. Full article

Frictional performances of different textures, including axisymmetric and directional patterns, have been tested in the mixed and the hydrodynamic lubrication regimes. Experimental results, corroborated by numerical simulations, show that the leading parameter is the geometrical pattern void ratio since a large number of dimples offers, at low speed, a trap for debris whereas, at high speed, due to the flow expansion in each micro-hole, fosters a fluid pressure drop, the consequent insurgence of micro-cavitation and, ultimately, the reductions of the shear stresses. Furthermore, in this paper, it is shown that, by means of directional textures, equivalent hydrodynamic wedges can be built up, thus establishing different friction performances depending on the flow direction. Full article

A two-scale method for modelling the Elastohydrodynamic Lubrication (EHL) of tilted-pad bearings is derived and a range of solutions are presented. The method is developed from previous publications and is based on the Heterogeneous Multiscale Methods (HMM). It facilitates, by means of homogenization, incorporating the effects of surface topography in the analysis of tilted-pad bearings. New to this article is the investigation of three-dimensional bearings, including the effects of both ideal and real surface topographies, micro-cavitation, and the metamodeling procedure used in coupling the problem scales. Solutions for smooth bearing surfaces, and under pure hydrodynamic operating conditions, obtained with the present two-scale EHL model, demonstrate equivalence to those obtained from well-established homogenization methods. Solutions obtained for elastohydrodynamic operating conditions, show a dependency of the solution to the pad thickness and load capacity of the bearing. More precisely, the response for the real surface topography was found to be stiffer in comparison to the ideal. Micro-scale results demonstrate periodicity of the flow and surface topography and this is consistent with the requirements of the HMM. The means of selecting micro-scale simulations based on intermediate macro-scale solutions, in the metamodeling approach, was developed for larger dimensionality and subsequent calibration. An analysis of the present metamodeling approach indicates improved performance in comparison to previous studies. Full article