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Keywords = magnetic-sensitive rubber

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20 pages, 5404 KiB  
Article
Design and Optimization of the Bionic Flexible Gripper Based on Magnetically Sensitive Rubber
by Xianhua Bian, Yu Ding, Rui Li, Mengjie Shou and Pingan Yang
Actuators 2025, 14(3), 124; https://doi.org/10.3390/act14030124 - 5 Mar 2025
Cited by 1 | Viewed by 835
Abstract
Flexible grippers based on magnetically sensitive rubber have garnered significant research attention due to their high gripping adaptability and ease of control. However, current research designs often separate the excitation device from the flexible finger, which can lead to potential interference or damage [...] Read more.
Flexible grippers based on magnetically sensitive rubber have garnered significant research attention due to their high gripping adaptability and ease of control. However, current research designs often separate the excitation device from the flexible finger, which can lead to potential interference or damage to other electronic components in the working environment and an inability to simultaneously ensure safety and gripping performance. In this paper, we propose an integrated magnetically controlled bionic flexible gripper that combines the excitation device and the flexible finger. We derive a formula for calculating the magnetic field generated by the excitation device, model and simulate the device, and find that the optimal magnetic field effect is achieved when the core-to-coil size ratio is 1:5. Additionally, we fabricated flexible fingers with different NdFeB volume ratios and experimentally determined that a volume ratio of 20% yields relatively better bending performance. The integrated magnetically controlled bionic flexible gripper described in this paper can adaptively grasp items such as rubber, column foam, and electrical tape, achieving maximum grasping energy efficiency of 0.524 g per millitesla (g/mT). These results highlight its potential advantages in applications such as robotic end-effectors and industrial automatic sorting. Full article
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16 pages, 5585 KiB  
Article
Stretchable Magneto-Mechanical Configurations with High Magnetic Sensitivity Based on “Gel-Type” Soft Rubber for Intelligent Applications
by Vineet Kumar and Sang-Shin Park
Gels 2024, 10(1), 80; https://doi.org/10.3390/gels10010080 - 21 Jan 2024
Cited by 4 | Viewed by 1847
Abstract
“Gel-type” soft and stretchable magneto-mechanical composites made of silicone rubber and iron particles are in focus because of their high magnetic sensitivity, and intelligence perspective. The “intelligence” mentioned here is related to the “smartness” of these magneto-rheological elastomers (MREs) to tune the “mechanical [...] Read more.
“Gel-type” soft and stretchable magneto-mechanical composites made of silicone rubber and iron particles are in focus because of their high magnetic sensitivity, and intelligence perspective. The “intelligence” mentioned here is related to the “smartness” of these magneto-rheological elastomers (MREs) to tune the “mechanical stiffness” and “output voltage” in energy-harvesting applications by switching magnetic fields. Hence, this work develops “gel-type” soft composites based on rubber reinforced with iron particles in a hybrid with piezoelectric fillers such as barium titanate. A further aspect of the work relies on studying the mechanical stability of intelligence and the stretchability of the composites. For example, the stretchability was 105% (control), and higher for 158% (60 per 100 parts of rubber (phr) of barium titanate, BaTiO3), 149% (60 phr of electrolyte iron particles, EIP), and 148% (60 phr of BaTiO3 + EIP hybrid). Then, the magneto-mechanical aspect will be investigated to explore the magnetic sensitivity of these “gel-type” soft composites with a change in mechanical stiffness under a magnetic field. For example, the anisotropic effect was 14.3% (60 phr of EIP), and 4.4% (60 phr of hybrid). Finally, energy harvesting was performed. For example, the isotropic samples exhibit ~20 mV (60 phr of BaTiO3), ~5.4 mV (60 phr of EIP), and ~3.7 mV (60 phr of hybrid). However, the anisotropic samples exhibit ~5.6 mV (60 phr of EIP), and ~8.8 mV (60 phr of hybrid). In the end, the composites prepared have three configurations, namely one with electro-mechanical aspects, another with magnetic sensitivity, and a third with both features. Overall, the experimental outcomes will make fabricated composites useful for different intelligent and stretchable applications. Full article
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20 pages, 2123 KiB  
Article
Object Localization and Sensing in Non-Line-of-Sight Using RFID Tag Matrices
by Erbo Shen, Shanshan Duan, Sijun Guo and Weidong Yang
Electronics 2024, 13(2), 341; https://doi.org/10.3390/electronics13020341 - 12 Jan 2024
Cited by 5 | Viewed by 1842
Abstract
RFID-based technology innovated a new field of wireless sensing, which has been applied in posture recognition, object localization, and the other sensing fields. Due to the presence of a Fresnel zone around a magnetic field when the RFID-based system is working, the signal [...] Read more.
RFID-based technology innovated a new field of wireless sensing, which has been applied in posture recognition, object localization, and the other sensing fields. Due to the presence of a Fresnel zone around a magnetic field when the RFID-based system is working, the signal undergoes significant changes when an object moves through two or more different Fresnel zones. Therefore, the moving object can be sensed more easily, and most of the sensing applications required the tag to be attached to the moving object for better sensing, significantly limiting their applications. The existing technologies to detect static objects in agricultural settings are mainly based on X-ray or high-power radar, which are costly and bulky, making them difficult to deploy on a large scale. It is a challenging task to sense a static target without a tag attached in NLOS (non-line-of-sight) detection with low cost. We utilized RFID technologies to sense the static foreign objects in agricultural products, and take metal, rock, rubber, and clod as sensing targets that are common in agriculture. By deploying tag matrices to create a sensing region, we observed the signal variations before and after the appearance of the targets in this sensing region, and determined the targets’ positions and their types. Here, we buried the targets in the media of seedless cotton and wheat, and detected them using a non-contact method. Research has illustrated that, by deploying appropriate tag matrices and adjusting the angle of a single RFID antenna, the matrices’ signals are sensitive to the static targets’ positions and their properties, i.e., matrices’ signals vary with different targets and their positions. Specifically, we achieved a 100% success rate in locating metallic targets, while the success rate for clods was the lowest at 86%. We achieved a 100% recognition rate for the types of all the four objects. Full article
(This article belongs to the Special Issue RFID Technology and Its Applications)
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22 pages, 6487 KiB  
Article
Preparation Methods and Properties of CNT/CF/G Carbon-Based Nano-Conductive Silicone Rubber
by Shunqi Mei, Jian Wang, Jitao Wan and Xichun Wu
Appl. Sci. 2023, 13(11), 6726; https://doi.org/10.3390/app13116726 - 31 May 2023
Cited by 11 | Viewed by 2838
Abstract
Carbon-based nano-conductive silicone rubber is a kind of composite conductive polymer material that has good electrical and thermal conductivities and high magnetic flux. It has good application prospects for replacing most traditional conductive materials, but its mechanical and tensile strengths are poor, which [...] Read more.
Carbon-based nano-conductive silicone rubber is a kind of composite conductive polymer material that has good electrical and thermal conductivities and high magnetic flux. It has good application prospects for replacing most traditional conductive materials, but its mechanical and tensile strengths are poor, which limit its applications. In this study, carbon fiber (CF), graphene (G) and carbon nanotubes (CNT) are used as fillers to prepare carbon-based nano-conductive silicone rubber via solution blending, and the preparation methods and properties are analyzed. The results show that when the carbon fiber content is 7.5 wt%, the volume resistivity of carbon fiber conductive silicone rubber is 9.5 × 104 Ω·cm, the surface resistance is 2.88 × 105 Ω, and the tensile strength reaches 2.12 Mpa. When the graphene content is 5.5 wt%, the volume resistivity of graphene conductive silicone rubber is 8.7 × 104 Ω·cm, and the surface resistance is 2.4 × 106 Ω. When the carbon nanotube content is 1.25 wt%, the volume resistivity of carbon nanotube conductive silicone rubber is 1.34 × 104 Ω·cm, and the surface resistance is 1.0 × 106 Ω. The three conductive nano-fillers in the blended carbon nano-conductive silicone rubber form a stable three-dimensional composite conductive network, which enhances the conductivity and stability. When the tensile rate is 520%, the resistance of the blended rubber increases from 2.69 × 103 to 9.66 × 104 Ω, and the rubber maintains good resilience and tensile sensitivity under repeated stretching. The results show that the proposed blended carbon nano-conductive silicone rubber has good properties and great application prospects, verifying the employed research method and showing the credibility of the research results. Full article
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18 pages, 4358 KiB  
Article
Tailoring Triple Filler Systems for Improved Magneto-Mechanical Performance in Silicone Rubber Composites
by Vineet Kumar, Md Najib Alam, Manesh A. Yewale and Sang-Shin Park
Polymers 2023, 15(10), 2287; https://doi.org/10.3390/polym15102287 - 12 May 2023
Cited by 10 | Viewed by 1830
Abstract
The demand for multi-functional elastomers is increasing, as they offer a range of desirable properties such as reinforcement, mechanical stretchability, magnetic sensitivity, strain sensing, and energy harvesting capabilities. The excellent durability of these composites is the key factor behind their promising multi-functionality. In [...] Read more.
The demand for multi-functional elastomers is increasing, as they offer a range of desirable properties such as reinforcement, mechanical stretchability, magnetic sensitivity, strain sensing, and energy harvesting capabilities. The excellent durability of these composites is the key factor behind their promising multi-functionality. In this study, various composites based on multi-wall carbon nanotubes (MWCNT), clay minerals (MT-Clay), electrolyte iron particles (EIP), and their hybrids were used to fabricate these devices using silicone rubber as the elastomeric matrix. The mechanical performance of these composites was evaluated, with their compressive moduli, which was found to be 1.73 MPa for the control sample, 3.9 MPa for MWCNT composites at 3 per hundred parts of rubber (phr), 2.2 MPa for MT-Clay composites (8 phr), 3.2 MPa for EIP composites (80 phr), and 4.1 MPa for hybrid composites (80 phr). After evaluating the mechanical performance, the composites were assessed for industrial use based on their improved properties. The deviation from their experimental performance was studied using various theoretical models such as the Guth–Gold Smallwood model and the Halpin–Tsai model. Finally, a piezo-electric energy harvesting device was fabricated using the aforementioned composites, and their output voltages were measured. The MWCNT composites showed the highest output voltage of approximately 2 milli-volt (mV), indicating their potential for this application. Lastly, magnetic sensitivity and stress relaxation tests were performed on the hybrid and EIP composites, with the hybrid composite demonstrating better magnetic sensitivity and stress relaxation. Overall, this study provides guidance on achieving promising mechanical properties in such materials and their suitability for various applications, such as energy harvesting and magnetic sensitivity. Full article
(This article belongs to the Special Issue New Horizons in Nanofillers Based Polymer Composites II)
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18 pages, 5388 KiB  
Article
New Insight into Rubber Composites Based on Graphene Nanoplatelets, Electrolyte Iron Particles, and Their Hybrid for Stretchable Magnetic Materials
by Vineet Kumar, Md Najib Alam, Sang-Shin Park and Dong-Joo Lee
Polymers 2022, 14(22), 4826; https://doi.org/10.3390/polym14224826 - 9 Nov 2022
Cited by 8 | Viewed by 2132
Abstract
New and soft composites with good mechanical stretchability are constantly addressed in the literature due to their use in various industrial applications such as soft robotics. The stretchable magnetic materials presented in this work show a promising magnetic effect of up to 28% [...] Read more.
New and soft composites with good mechanical stretchability are constantly addressed in the literature due to their use in various industrial applications such as soft robotics. The stretchable magnetic materials presented in this work show a promising magnetic effect of up to 28% and improved magnetic sensitivity. The composites are soft in nature and possess hardness below 65. These composites were prepared by mixing silicone rubber with fillers such as graphene nanoplatelets (GNP), electrolyte-iron particles (EIP), and their hybrid via solution mixing. The final composites were cured at room temperature for 24 h and their isotropic and anisotropic properties were studied and presented. The mechanical properties under compressive and tensile strain were studied in detail. The results show that the compressive modulus was 1.73 MPa (control) and increased to 3.7 MPa (GNP) at 15 per hundred parts of rubber (phr), 3.2 MPa (EIP), and 4.3 MPa (hybrid) at 80 phr. Similarly, the mechanical stretchability was 112% (control) and increased to 186% (GNP) at 15 phr, 134% (EIP), and 136% (hybrid) at 60 phr. Thus, GNP emerges as a superior reinforcing filler with high stiffness, a high compressive modulus, and high mechanical stretchability. However, the GNP did not show mechanical sensitivity under a magnetic field. Therefore, the hybrids containing GNP and EIP were considered and an improved mechanical performance with magnetic sensitivity was noticed and reported. The mechanism involves the orientation of EIP under a magnetic field causing a magnetic effect, which is 28% for EIP and 5% for hybrid. Full article
(This article belongs to the Special Issue Advances in Functional Rubber and Elastomer Composites)
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13 pages, 6222 KiB  
Article
Portable Non-Destructive Magnetic Resonance Sensor for Assessing the Aging Status of Silicon Rubber Insulators
by Pan Guo, Liling Wang, Rui Wang, Bing Li and Zhirui Zhao
Nanomaterials 2022, 12(21), 3847; https://doi.org/10.3390/nano12213847 - 31 Oct 2022
Cited by 4 | Viewed by 1900
Abstract
Silicone rubber insulators (SRIs) are widely used in high-voltage power grids. Due to high-voltage fields and harsh environmental conditions, SRIs eventually deteriorate with use in the power grid, decreasing their insulating performance and operational life and contributing to transmission line failures. Therefore, quantitatively [...] Read more.
Silicone rubber insulators (SRIs) are widely used in high-voltage power grids. Due to high-voltage fields and harsh environmental conditions, SRIs eventually deteriorate with use in the power grid, decreasing their insulating performance and operational life and contributing to transmission line failures. Therefore, quantitatively assessing the aging status of SRIs is crucial. In this study, we evaluated the viability of the magnetic resonance method for assessing the age of SRIs at the level of chemical structure; we built and made a portable magnetic resonance sensor, and evaluated the sensor’s functionality. By measuring the SRI sheds at various service times, it was discovered that the equivalent transverse relaxation time, T2eff, can describe the degree of aging of the SRIs. The results of the magnetic resonance measurements were also compared with those of the static contact angle method, and the two measurement methods yielded the same conclusions. However, the magnetic resonance method was more sensitive than the one using the static contact angle method. Full article
(This article belongs to the Special Issue Mechanism and Performance of Nano/Micro Electronic Device)
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11 pages, 3727 KiB  
Article
Magnetic Field Influence on the Microwave Characteristics of Composite Samples Based on Polycrystalline Y-Type Hexaferrite
by Svetoslav Kolev, Borislava Georgieva, Tatyana Koutzarova, Kiril Krezhov, Chavdar Ghelev, Daniela Kovacheva, Benedicte Vertruyen, Raphael Closset, Lan Maria Tran, Michal Babij and Andrzej J. Zaleski
Polymers 2022, 14(19), 4114; https://doi.org/10.3390/polym14194114 - 30 Sep 2022
Cited by 5 | Viewed by 2696
Abstract
Here, we report results on the magnetic and microwave properties of polycrystalline Y-type hexaferrite synthesized by sol-gel auto-combustion and acting as a filler in a composite microwave-absorbing material. The reflection losses in the 1–20 GHz range of the Y-type hexaferrite powder dispersed homogeneously [...] Read more.
Here, we report results on the magnetic and microwave properties of polycrystalline Y-type hexaferrite synthesized by sol-gel auto-combustion and acting as a filler in a composite microwave-absorbing material. The reflection losses in the 1–20 GHz range of the Y-type hexaferrite powder dispersed homogeneously in a polymer matrix of silicon rubber were investigated in the absence and in the presence of a magnetic field. A permanent magnet was used with a strength of 1.4 T, with the magnetic force lines oriented perpendicularly to the direction of the electromagnetic wave propagation. In the case of using an external magnetic field, an extraordinary result was observed. The microwave reflection losses reached a maximum value of 35.4 dB at 5.6 GHz in the Ku-band without a magnetic field and a maximum value of 21.4 dB at 8.2 GHz with the external magnetic field applied. The sensitivity of the microwave properties of the composite material to the external magnetic field was manifested by the decrease of the reflected wave attenuation. At a fixed thickness, tm, of the composite, the attenuation peak frequency can be adjusted to a certain value either by changing the filling density or by applying an external magnetic field. Full article
(This article belongs to the Special Issue New Horizons in Nanofillers Based Polymer Composites II)
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15 pages, 4763 KiB  
Article
Soft Composites Filled with Iron Oxide and Graphite Nanoplatelets under Static and Cyclic Strain for Different Industrial Applications
by Vineet Kumar, Md Najib Alam and Sang Shin Park
Polymers 2022, 14(12), 2393; https://doi.org/10.3390/polym14122393 - 13 Jun 2022
Cited by 18 | Viewed by 2211
Abstract
Simultaneously exhibiting both a magnetic response and piezoelectric energy harvesting in magneto-rheological elastomers (MREs) is a win–win situation in a soft (hardness below 65) composite-based device. In the present work, composites based on iron oxide (Fe2O3) were prepared and [...] Read more.
Simultaneously exhibiting both a magnetic response and piezoelectric energy harvesting in magneto-rheological elastomers (MREs) is a win–win situation in a soft (hardness below 65) composite-based device. In the present work, composites based on iron oxide (Fe2O3) were prepared and exhibited a magnetic response; other composites based on the electrically conductive reinforcing nanofiller, graphite nanoplatelets (GNP), were also prepared and exhibited energy generation. A piezoelectric energy-harvesting device based on composites exhibited an impressive voltage of ~10 V and demonstrated a high durability of 0.5 million cycles. These nanofillers were added in room temperature vulcanized silicone rubber (RTV-SR) and their magnetic response and piezoelectric energy generation were studied both in single and hybrid form. The hybrid composite consisted of 10 per hundred parts of rubber (phr) of Fe2O3 and 10 phr of GNP. The experimental data show that the compressive modulus of the composites was 1.71 MPa (virgin), 2.73 (GNP), 2.65 MPa (Fe2O3), and 3.54 MPa (hybrid). Similarly, the fracture strain of the composites was 89% (virgin), 109% (GNP), 105% (Fe2O3), 133% (hybrid). Moreover, cyclic multi-hysteresis tests show that the hybrid composites exhibiting higher mechanical properties had the shortcoming of showing higher dissipation losses. In the end, this work demonstrates a rubber composite that provides an energy-harvesting device with an impressive voltage, high durability, and MREs with high magnetic sensitivity. Full article
(This article belongs to the Special Issue New Horizons in Nanofillers Based Polymer Composites II)
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16 pages, 6574 KiB  
Article
Constructing a Segregated Magnetic Graphene Network in Rubber Composites for Integrating Electromagnetic Interference Shielding Stability and Multi-Sensing Performance
by Jian Wang, Baohua Liu, Yu Cheng, Zhenwan Ma, Yanhu Zhan and Hesheng Xia
Polymers 2021, 13(19), 3277; https://doi.org/10.3390/polym13193277 - 26 Sep 2021
Cited by 22 | Viewed by 2808
Abstract
A flexible, wearable electronic device composed of magnetic iron oxide (Fe3O4)/reduced graphene oxide/natural rubber (MGNR) composites with a segregated network was prepared by electrostatic self-assembly, latex mixing, and in situ reduction. The segregated network offers the composites higher electrical [...] Read more.
A flexible, wearable electronic device composed of magnetic iron oxide (Fe3O4)/reduced graphene oxide/natural rubber (MGNR) composites with a segregated network was prepared by electrostatic self-assembly, latex mixing, and in situ reduction. The segregated network offers the composites higher electrical conductivity and more reliable sensing properties. Moreover, the addi-tion of Fe3O4 provides the composites with better electromagnetic interference shielding effectiveness (EMI SE). The EMI shielding property of MGNR composites is more stable under tensile deformation and long-term cycling conditions and has a higher sensitivity to stretch strain compared with the same structure made from reduced graphene oxide/natural rubber (GNR) composites. The EMI SE value of MGNR composites reduces by no more than 2.9% under different tensile permanent deformation, cyclic stretching, and cyclic bending conditions, while that of GNR composites reduces by approximately 16% in the worst case. Additionally, the MGNR composites have a better sensing performance and can maintain stable signals, even in the case of cyclic stretching with a very small strain (0.05%). Furthermore, they can steadily monitor the changes in resistance signals in various human motions such as finger bending, wrist bending, speaking, smiling, and blinking, indicating that the MGNR composites can be used in future wearable electronic flexibility devices. Full article
(This article belongs to the Special Issue Polymer Composites for Structural Applications)
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14 pages, 3720 KiB  
Article
The Effect of Microparticles on the Storage Modulus and Durability Behavior of Magnetorheological Elastomer
by Mohd Aidy Faizal Johari, Saiful Amri Mazlan, Nur Azmah Nordin, U Ubaidillah, Siti Aishah Abdul Aziz, Nurhazimah Nazmi, Norhasnidawani Johari and Seung-Bok Choi
Micromachines 2021, 12(8), 948; https://doi.org/10.3390/mi12080948 - 11 Aug 2021
Cited by 18 | Viewed by 3143
Abstract
This paper presents the effect of the micro-sized particles on the storage modulus and durability characteristics of magnetorheological elastomers (MREs). The initial phase of the investigation is to determine any associations among the microparticles’ weight percent fraction (wt%), structure arrangement, and the storage [...] Read more.
This paper presents the effect of the micro-sized particles on the storage modulus and durability characteristics of magnetorheological elastomers (MREs). The initial phase of the investigation is to determine any associations among the microparticles’ weight percent fraction (wt%), structure arrangement, and the storage modulus of MRE samples. In order to carry out this, both isotropic and anisotropic types of MRE samples consisting of the silicone rubber matrix and 50, 60, 70, 75, and 80 wt% microparticles of carbonyl iron fractions are prepared. It is identified from the magneto-rheometer that the increase in storage modulus and decrease in linear viscoelastic region limit are observed in varying consistency depending on wt% and particle arrangement. The consistency of this dependency feature is highlighted by superimposing all of the graphs plotted to create the proposed the samples’ behavior model. In response to increasing magnetic stimulation, a sample of 70 wt% microparticles with an isotropic arrangement is found to be significant and stable. The experimentally defined fraction is then used for the durability test as the second phase of the investigation. During this phase, the durability evaluation is subjected to stress relaxation for an extended period of time. After undergoing durability testing, storage modulus performance is decreased by 0.7–13% at various magnetic stimulation levels. This result directly indicates that the storage modulus characteristics of different forms of MRE are sensitive to the different iron particle fractions’ and microparticles’ alignment. Therefore, important treatments to alter the storage modulus can be undertaken before the practical implementation to accommodate any desired performance of MRE itself and MRE application systems. Full article
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25 pages, 792 KiB  
Article
Constitutive Model of Isotropic Magneto-Sensitive Rubber with Amplitude, Frequency, Magnetic and Temperature Dependence under a Continuum Mechanics Basis
by Bochao Wang and Leif Kari
Polymers 2021, 13(3), 472; https://doi.org/10.3390/polym13030472 - 2 Feb 2021
Cited by 13 | Viewed by 3405
Abstract
A three-dimensional nonlinear constitutive model of the amplitude, frequency, magnetic and temperature dependent mechanical property of isotropic magneto-sensitive (MS) rubber is developed. The main components of MS rubber are an elastomer matrix and magnetizable particles. When a magnetic field is applied, the modulus [...] Read more.
A three-dimensional nonlinear constitutive model of the amplitude, frequency, magnetic and temperature dependent mechanical property of isotropic magneto-sensitive (MS) rubber is developed. The main components of MS rubber are an elastomer matrix and magnetizable particles. When a magnetic field is applied, the modulus of MS rubber increases, which is known as the magnetic dependence of MS rubber. In addition to the magnetic dependence, there are frequency, amplitude and temperature dependencies of the dynamic modulus of MS rubber. A continuum mechanical framework-based constitutive model consisting of a fractional standard linear solid (SLS) element, an elastoplastic element and a magnetic stress term of MS rubber is developed to depict the mechanical behavior of MS rubber. The novelty is that the amplitude, frequency, magnetic and temperature dependent mechancial properties of MS rubber are integrated into a whole constitutive model under the continuum mechanics frame. Comparison between the simulation and measurement results shows that the fitting effect of the developed model is very good. Therefore, the constitutive model proposed enables the prediction of the mechanical properties of MS rubber under various operating conditions with a high accuracy, which will drive MS rubber’s application in engineering problems, especially in the area of MS rubber-based anti-vibration devices. Full article
(This article belongs to the Special Issue Magnetic Polymer Composites: Design and Application)
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29 pages, 17135 KiB  
Article
Clarification of Catalytic Effect on Large Stretchable and Compressible Rubber Dye-Sensitized Solar Cells
by Kunio Shimada, Hiroshige Kikura, Ryo Ikeda and Hideharu Takahashi
Energies 2020, 13(24), 6658; https://doi.org/10.3390/en13246658 - 17 Dec 2020
Cited by 1 | Viewed by 2172
Abstract
Rubber involving magnetic compound fluid (MCF) and TiO2 is effective in dye-sensitized solar cells (DSSCs) to create large efficacy. Wearable and portable solar cells made of MCF rubber are the most desirable as soft materials in robots or flexible devices, and they [...] Read more.
Rubber involving magnetic compound fluid (MCF) and TiO2 is effective in dye-sensitized solar cells (DSSCs) to create large efficacy. Wearable and portable solar cells made of MCF rubber are the most desirable as soft materials in robots or flexible devices, and they are further desirable because they have self-generated power and power supply with sensing. Therefore, we investigated the effect of TiO2 catalysts on the photovoltaic effect of MCF rubber DSSCs under large tension and compression. The characteristics of the built-in electricity and photoelectricity were clarified experimentally. The experimental results were explained by a chemical–photovoltaic mechanism involving the behavior of dye, electrolytes, water, and rubber molecules, as well as a catalytic effect of the metal component of the MCF on Ni, Fe3O4, and TiO2. Once we are able to produce solar cells that have large tension and compression, the present experimental results and the model of the chemical–photovoltaic mechanism will be of great interest. Full article
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16 pages, 25435 KiB  
Article
Structural, Magnetic and Microwave Characterization of Polycrystalline Z-Type Sr3Co2Fe24O41 Hexaferrite
by Svetoslav Kolev, Petya Peneva, Kiril Krezhov, Tanya Malakova, Chavdar Ghelev, Tatyana Koutzarova, Daniela Kovacheva, Benedicte Vertruyen, Raphael Closset, Lan Maria Tran and Andrzej Zaleski
Materials 2020, 13(10), 2355; https://doi.org/10.3390/ma13102355 - 20 May 2020
Cited by 9 | Viewed by 3854
Abstract
We report results on the structural and microwave properties and magnetic phase transitions in polycrystalline Sr3Co2Fe24O41 hexaferrite synthesized by sol-gel auto-combustion and acting as a filler in a composite microwave absorbing material. The zero-field-cooled (ZFC) and [...] Read more.
We report results on the structural and microwave properties and magnetic phase transitions in polycrystalline Sr3Co2Fe24O41 hexaferrite synthesized by sol-gel auto-combustion and acting as a filler in a composite microwave absorbing material. The zero-field-cooled (ZFC) and field-cooled (FC) magnetization curves revealed a change in the magnetization behavior at 293 K. The reflection losses in the 1–20 GHz range of the Sr3Co2Fe24O41 powder dispersed homogeneously in a polymer matrix of silicon rubber were investigated in both the absence and presence of a magnetic field. In the latter case, a dramatic rise in the attenuation was observed. The microwave reflection losses reached the maximum value of 32.63 dB at 17.29 GHz in the Ku-band. The sensitivity of the microwave properties of the composite material to the external magnetic field was manifested by the appearance of new reflection losses maxima. At a fixed thickness tm of the composite, the attenuation peak frequency can be adjusted to a certain value either by changing the filling density or by applying an external magnetic field. Full article
(This article belongs to the Special Issue Magnetic Materials and Applications)
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23 pages, 12379 KiB  
Article
Elastic MCF Rubber with Photovoltaics and Sensing on Hybrid Skin (H-Skin) for Artificial Skin by Utilizing Natural Rubber: 2nd Report on the Effect of Tension and Compression on the Hybrid Photo- and Piezo-Electricity Properties in Wet-Type Solar Cell Rubber
by Kunio Shimada
Sensors 2018, 18(6), 1848; https://doi.org/10.3390/s18061848 - 6 Jun 2018
Cited by 8 | Viewed by 3919
Abstract
In contrast to ordinary solid-state solar cells, a flexible, elastic, extensible and light-weight solar cell has the potential to be extremely useful in many new engineering applications, such as in the field of robotics. Therefore, we propose a new type of artificial skin [...] Read more.
In contrast to ordinary solid-state solar cells, a flexible, elastic, extensible and light-weight solar cell has the potential to be extremely useful in many new engineering applications, such as in the field of robotics. Therefore, we propose a new type of artificial skin for humanoid robots with hybrid functions, which we have termed hybrid skin (H-Skin). To realize the fabrication of such a solar cell, we have continued to utilize the principles of ordinary solid-state wet-type or dye-sensitized solar rubber as a follow-up study to the first report. In the first report, we dealt with both photovoltaic- and piezo-effects for dry-type magnetic compound fluid (MCF) rubber solar cells, which were generated because the polyisoprene, oleic acid of the magnetic fluid (MF), and water served as p- and n- semiconductors. In the present report, we deal with wet-type MCF rubber solar cells by using sensitized dyes and electrolytes. Photoreactions generated through the synthesis of these components were investigated by an experiment using irradiation with visible and ultraviolet light. In addition, magnetic clusters were formed by the aggregation of Fe3O4 in the MF and the metal particles created the hetero-junction structure of the semiconductors. In the MCF rubber solar cell, both photo- and piezo-electricity were generated using a physical model. The effects of tension and compression on their electrical properties were evaluated. Finally, we experimentally demonstrated the effect of the distance between the electrodes of the solar cell on photoelectricity and built-in electricity. Full article
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