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19 pages, 7447 KiB  
Article
Research on the Size and Distribution of TiN Inclusions in High-Titanium Steel Cast Slabs
by Min Zhang, Xiangyu Li, Zhijie Guo and Yanhui Sun
Materials 2025, 18(15), 3527; https://doi.org/10.3390/ma18153527 - 28 Jul 2025
Viewed by 248
Abstract
High-titanium steel contains an elevated titanium content, which promotes the formation of abundant non-metallic inclusions in molten steel at high temperatures, including titanium oxides, sulfides, and nitrides. These inclusions adversely affect continuous casting operations and generate substantial internal/surface defects in cast slabs, ultimately [...] Read more.
High-titanium steel contains an elevated titanium content, which promotes the formation of abundant non-metallic inclusions in molten steel at high temperatures, including titanium oxides, sulfides, and nitrides. These inclusions adversely affect continuous casting operations and generate substantial internal/surface defects in cast slabs, ultimately compromising product performance and service reliability. Therefore, stringent control over the size, distribution, and population density of inclusions is imperative during the smelting of high-titanium steel to minimize their detrimental effects. In this paper, samples of high titanium steel (0.4% Ti, 0.004% N) casting billets were analyzed by industrial test sampling and full section comparative analysis of the samples at the center and quarter position. Using the Particle X inclusions, as well as automatic scanning and analyzing equipment, the number, size, location distribution, type and morphology of inclusions in different positions were systematically and comprehensively investigated. The results revealed that the primary inclusions in the steel consisted of TiN, TiS, TiC and their composite forms. TiN inclusions exhibited a size range of 1–5 µm on the slab surface, while larger particles of 2–10 μm were predominantly observed in the interior regions. Large-sized TiN inclusions (5–10 μm) are particularly detrimental, and this problematic type of inclusion predominantly concentrates in the interior regions of the steel slab. A gradual decrease in TiN inclusion number density was identified from the surface toward the core of the slab. Thermodynamic and kinetic calculations incorporating solute segregation effects demonstrated that TiN precipitates primarily in the liquid phase. The computational results showed excellent agreement with experimental data regarding the relationship between TiN size and solidification rate under different cooling conditions, confirming that increased cooling rates lead to reduced TiN particle sizes. Both enhanced cooling rates and reduced titanium content were found to effectively delay TiN precipitation, thereby suppressing the formation of large-sized TiN inclusions in high-titanium steels. Full article
(This article belongs to the Special Issue Advanced Stainless Steel—from Making, Shaping, Treating to Products)
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24 pages, 3097 KiB  
Review
Advancements and Development Trends in Lead-Cooled Fast Reactor Core Design
by Cong Zhang, Ling Chen, Yongfa Zhang and Song Li
Processes 2025, 13(6), 1773; https://doi.org/10.3390/pr13061773 - 4 Jun 2025
Cited by 1 | Viewed by 1055
Abstract
Motivated by the growth of global energy demand and the goal of carbon neutrality, lead-cooled fast reactors, which are core reactor types of fourth-generation nuclear energy systems, have become a global research hotspot due to their advantages of high safety, nuclear fuel breeding [...] Read more.
Motivated by the growth of global energy demand and the goal of carbon neutrality, lead-cooled fast reactors, which are core reactor types of fourth-generation nuclear energy systems, have become a global research hotspot due to their advantages of high safety, nuclear fuel breeding capability, and economic efficiency. However, its engineering implementation faces key challenges, such as material compatibility, closed fuel cycles, and irradiation performance of structures. This paper comprehensively reviews the latest progress in the core design of lead-cooled fast reactors in terms of the innovation of nuclear fuel, optimization of coolant, material adaptability, and design of assemblies and core structures. The research findings indicate remarkable innovation trends in the field of lead-cooled fast reactor core design, including optimizing the utilization efficiency of nuclear fuel based on the nitride fuel system and the traveling wave burnup theory, effectively suppressing the corrosion effect of liquid metal through surface modification technology and the development of ceramic matrix composites; replacing the lead-bismuth eutectic system with pure lead coolant to enhance economic efficiency and safety; and significantly enhancing the neutron economy and system integration degree by combining the collaborative design strategy of the open-type assembly structure and control drums. In the future, efforts should be made to overcome the radiation resistance of materials and liquid metal corrosion technology, develop closed fuel cycle systems, and accelerate the commercialization process through international standardization cooperation to provide sustainable clean energy solutions for basic load power supply, high-temperature hydrogen production, ship propulsion, and other fields. Full article
(This article belongs to the Special Issue Process Safety Technology for Nuclear Reactors and Power Plants)
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27 pages, 6766 KiB  
Article
Void Reactivity Coefficient for Hybrid Reactor Cooled Using Liquid Metal
by Andrzej Wojciechowski
Energies 2025, 18(11), 2710; https://doi.org/10.3390/en18112710 - 23 May 2025
Viewed by 290
Abstract
A negative value of the void reactivity coefficient (αV) is one of the most important passive safety properties for the operation of nuclear reactor. Herein, are presented calculated values of the void reactivity coefficient for different geometries of reactors cooled by [...] Read more.
A negative value of the void reactivity coefficient (αV) is one of the most important passive safety properties for the operation of nuclear reactor. Herein, are presented calculated values of the void reactivity coefficient for different geometries of reactors cooled by liquid lead (LFR) and sodium (SFR) with U-238-Pu-239 and Th-232-U-233 fuels. The calculations were carried out for the reactors filled with either one or two types of fuel assemblies. The most interesting results are obtained for reactor filled with two different types of fuel assemblies (hybrid reactor). Hybrid reactors consist of central and peripheral types of fuel assemblies using low enrichment fuel and high enrichment fuel, respectively. Both hybrid reactors based on the uranium cycle (U-cycle) and the thorium cycle (Th-cycle) can maintain a negative void reactivity coefficient value for wide range of reactor parameters. The calculation results of the hybrid reactor matched those from FBR-IME reactor. Full article
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19 pages, 7297 KiB  
Article
Investigation on Designing and Development of a Selective Laser Melting Manufactured Gas Turbine Blade—Proof-of-Concept
by Mihaela Raluca Condruz, Tiberius Florian Frigioescu, Gheorghe Matache, Adina Cristina Toma and Teodor Adrian Badea
Inventions 2025, 10(3), 36; https://doi.org/10.3390/inventions10030036 - 15 May 2025
Viewed by 645
Abstract
In this study, a conceptual turbine blade model with internal cooling channels was designed and fabricated using the selective laser melting (SLM) process. The optimal manufacturing orientation was evaluated through simulations, and the results indicated that vertical orientation yielded the best outcomes, minimizing [...] Read more.
In this study, a conceptual turbine blade model with internal cooling channels was designed and fabricated using the selective laser melting (SLM) process. The optimal manufacturing orientation was evaluated through simulations, and the results indicated that vertical orientation yielded the best outcomes, minimizing support material usage and distortion despite increased manufacturing time. Two configurations were produced, namely, an entire-turbine blade model and a cross-sectional model. Non-destructive analyses, including 3D laser scanning for dimensional accuracy, surface roughness measurements, and liquid penetrant testing, were conducted. Visual inspection revealed manufacturing limitations, particularly in the cooling channels at the leading and trailing edges. The trailing edge was too thin to accommodate the 0.5 mm channel diameter, and the channels in the leading edge were undersized and potentially clogged with unmelted powder. The dimensional deviations were within the acceptable limits for the SLM-fabricated metal parts. The surface roughness measurements were aligned with the literature values for metal additive manufacturing. Liquid penetrant testing confirmed the absence of cracks, pores, and lack-of-fusion defects. The SLM is a viable manufacturing process for turbine blades with internal cooling channels; however, significant attention should be paid to the design of additive manufacturing conditions to obtain the best results after manufacturing. Full article
(This article belongs to the Section Inventions and Innovation in Advanced Manufacturing)
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22 pages, 2810 KiB  
Article
Thermodynamic Analysis of Nuclear Power Plants with External Steam Superheating
by Vladimir Kindra, Mikhail Ostrovsky, Igor Maksimov, Roman Zuikin and Nikolay Rogalev
Energies 2025, 18(9), 2317; https://doi.org/10.3390/en18092317 - 30 Apr 2025
Viewed by 540
Abstract
Increasing the efficiency and capacity of nuclear power units is a promising direction for the development of power generation systems. Unlike thermal power plants, nuclear power plants operate at relatively low temperatures of the steam working fluid. Due to this, the thermodynamic efficiency [...] Read more.
Increasing the efficiency and capacity of nuclear power units is a promising direction for the development of power generation systems. Unlike thermal power plants, nuclear power plants operate at relatively low temperatures of the steam working fluid. Due to this, the thermodynamic efficiency of such schemes remains relatively low today. The temperature of steam and the efficiency of nuclear power units can be increased by integrating external superheating of the working fluid into the schemes of steam turbine plants. This paper presents the results of a thermodynamic analysis of thermal schemes of NPPs integrated with hydrocarbon-fueled plants. Schemes with a remote combustion chamber, a boiler unit and a gas turbine plant are considered. It has been established that superheating fresh steam after the steam generator is an effective superheating solution due to the utilization of heat from the exhaust gases of the GTU using an afterburner. Furthermore, there is a partial replacement of high- and low-pressure heaters in the regeneration system, with gas heaters for condensate and steam superheating after the steam generator for water-cooled and liquid-metal reactor types. An increase in the net efficiency of the hybrid NPP is observed by 8.49 and 5.11%, respectively, while the net electric power increases by 93.3 and 76.7%. Full article
(This article belongs to the Section B4: Nuclear Energy)
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19 pages, 9207 KiB  
Article
Effect of Heat Treatments on the Microstructure, Corrosion Resistance and Wear Behaviour of Bainitic/Martensitic Ductile Iron Under Dry Sliding Friction
by Nugzar Khidasheli, Salome Gvazava, Garegin Zakharov, Mikheil Chikhradze, Andre Danonu Lignamnateh Batako, Juan Ignacio Ahuir-Torres, Ashwath Pazhani and Micheal Anthony Xavior
J. Manuf. Mater. Process. 2025, 9(5), 145; https://doi.org/10.3390/jmmp9050145 - 28 Apr 2025
Viewed by 609
Abstract
The development of high-strength cast irons with multiphase metal matrix structures is one of the new areas of modern materials science and mechanical engineering. This is so because of the high dissipative properties of such materials, which, in turn, ensure an improvement in [...] Read more.
The development of high-strength cast irons with multiphase metal matrix structures is one of the new areas of modern materials science and mechanical engineering. This is so because of the high dissipative properties of such materials, which, in turn, ensure an improvement in their functional characteristics. It is known that one of the effective methods for obtaining alloys with a heterogeneous structure is a multi-stage heat treatment. Therefore, this study aimed to enhance the corrosion and friction properties of high-strength cast irons by combining different processing methods to create a bainite-martensitic matrix. High-strength cast irons with high ductility micro-alloyed with boron were chosen as the object for research. The experiments studied the effect of various types of multi-stage heat treatment on the structural features, tribological properties, hardness and corrosion resistance. The cast irons were quenched in water or liquid nitrogen after a controlled duration of isothermal exposure at different temperatures. It was established that cooling of isothermally hardened samples in liquid nitrogen makes it possible to effectively engineer the morphology and amount of the formed martensitic phase. It was observed that the high-strength cast irons with 10–15% lower bainite, residual austenite and martensite have the best frictional characteristics. This innovative method allowed the quenching of cast iron directly into liquid nitrogen without violent cracking. Full article
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30 pages, 14074 KiB  
Review
Recent Advances in Wearable Thermal Devices for Virtual and Augmented Reality
by Minsu Park
Micromachines 2025, 16(4), 383; https://doi.org/10.3390/mi16040383 - 27 Mar 2025
Cited by 1 | Viewed by 1157
Abstract
Thermal technologies that effectively deliver thermal stimulation through skin-integrated systems and enable temperature perception via the activation of cutaneous thermoreceptors are key to enhancing immersive experiences in virtual and augmented reality (VR/AR) through multisensory engagement. However, recent advancements and commercial adoption have predominantly [...] Read more.
Thermal technologies that effectively deliver thermal stimulation through skin-integrated systems and enable temperature perception via the activation of cutaneous thermoreceptors are key to enhancing immersive experiences in virtual and augmented reality (VR/AR) through multisensory engagement. However, recent advancements and commercial adoption have predominantly focused on haptic rather than thermal technology. This review provides an overview of recent advancements in wearable thermal devices (WTDs) designed to reconstruct artificial thermal sensations for VR/AR applications. It examines key thermal stimulation parameters, including stimulation area, magnitude, and duration, with a focus on thermal perception mechanisms and thermoreceptor distribution in the skin. Input power requirements for surpassing thermal perception thresholds are discussed based on analytical modeling. Material choices for WTDs, including metal nanowires, carbon nanotubes, liquid metals, thermoelectric devices, and passive cooling elements, are introduced. The functionalities, device designs, operation modes, fabrication processes, and electrical and mechanical properties of various WTDs are analyzed. Representative applications illustrate how flexible, thin WTDs enable immersive VR/AR experiences through spatiotemporal, programmable stimulation. A concluding section summarizes key challenges and future opportunities in advancing skin–integrated VR/AR systems. Full article
(This article belongs to the Section E:Engineering and Technology)
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15 pages, 5700 KiB  
Article
Simulation Study on Directional Solidification of Titanium–Aluminum Alloy Based on Liquid Metal Cooling Method
by Feng Li, Hong Huang, Xiao Zong, Kehan Wang, Han Liu, Xuejun Liu and Xianfei Ding
Metals 2025, 15(4), 366; https://doi.org/10.3390/met15040366 - 26 Mar 2025
Viewed by 539
Abstract
In this study, the ProCast software (version 2014) incorporating the CAFE model is applied to conduct numerical simulation analysis of the directional solidification process of titanium–aluminium alloy cylindrical rods at varying withdraw rates. According to the analytical results, the withdraw rate is a [...] Read more.
In this study, the ProCast software (version 2014) incorporating the CAFE model is applied to conduct numerical simulation analysis of the directional solidification process of titanium–aluminium alloy cylindrical rods at varying withdraw rates. According to the analytical results, the withdraw rate is a critical parameter that affects the morphology of the solid–liquid interface and the grain growth behavior during the directional solidification process. An increase in the drawing rate facilitates nucleation undercooling within the rod, inducing a shift in grain morphology from columnar to equiaxed. At a drawing rate of 1 mm/min, the solid–liquid interface exhibits the most stable morphology, as characterized by a flat interface. As indicated by further analysis, at this drawing rate, specific grain orientations are eliminated during competitive growth with an increase in solid fraction, culminating in the formation of columnar grain structures. Additionally, the impact of drawing rate on grain size and number is investigated, with an increase observed in grain number with drawing rate and a decrease found in grain size. The findings of this study contribute to a deeper understanding of mechanisms behind the grain morphology evolution of titanium aluminide, providing crucial theoretical support for optimizing directional solidification processes. Full article
(This article belongs to the Special Issue Solidification and Casting of Metals and Alloys (2nd Edition))
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13 pages, 2242 KiB  
Article
Application of Catalytic H2O2-Mediated NOx Removal Process Leveraging Solid Waste Residues: Exemplified by Copper Slag
by Huidong Tang, Jiacheng Bao, Chen Liu, Yuwen Deng, Yixing Ma, Lei Shi, Shuangyou Bao, Kai Li, Ping Ning and Xin Sun
Sustainability 2025, 17(6), 2469; https://doi.org/10.3390/su17062469 - 11 Mar 2025
Viewed by 656
Abstract
In pursuing sustainable environmental solutions, the concept of ‘waste to treasure’ has emerged as a promising approach. In this study, a new process is proposed to combine solid copper slag with hydrogen peroxide (H2O2) to remove nitrogen oxides (NOx) [...] Read more.
In pursuing sustainable environmental solutions, the concept of ‘waste to treasure’ has emerged as a promising approach. In this study, a new process is proposed to combine solid copper slag with hydrogen peroxide (H2O2) to remove nitrogen oxides (NOx) from acidic exhaust gases, thus effectively utilizing waste materials. Firstly, different smelting slags were screened to determine the catalytic potential of copper slag for hydrogen peroxide. Subsequently, the catalytic activity of the copper slags at various stages of the copper smelting process was thoroughly evaluated and optimized. In addition, a multifactorial evaluation of slow-cooled copper slag catalysts for removing NOx was carried out. Preliminary indications are that the iron phase in the copper slag is identified as the main source of catalytic activity sites. The results suggest that Fe2+/Fe3+ sites on the surface of the Fe phase in the slow-cooled copper slag may be crucial in improving the NOx removal efficiency. The main reactive oxygen species detected in the system were ·OH, ·O2⁻, and 1O2. In addition, the transformation products, formation pathways, and reaction mechanisms of NO in the liquid phase were initially investigated and determined. This study provides a green and sustainable path for the utilization of solid waste and management of atmospheric fumes in the non-ferrous metal industry and offers new perspectives to address environmental challenges in industrial processes. Full article
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13 pages, 4536 KiB  
Proceeding Paper
Numerical Thermo-Structural Simulations for the Design of the Havar Beam Window of a Beryllium Target for Neutron Beam Production
by Roberta Dattilo
Eng. Proc. 2025, 85(1), 28; https://doi.org/10.3390/engproc2025085028 - 26 Feb 2025
Viewed by 279
Abstract
The present work was carried out as part of the PRIN 2022JCS2CN project “CoolGal”, which aims to design and manufacture a beryllium target cooled by Galinstan (a liquid metal alloy at room temperature) for the production of neutrons using energetic protons. The objective [...] Read more.
The present work was carried out as part of the PRIN 2022JCS2CN project “CoolGal”, which aims to design and manufacture a beryllium target cooled by Galinstan (a liquid metal alloy at room temperature) for the production of neutrons using energetic protons. The objective of the present work is to thermo-structurally design a beam window that encloses the environment in which the target is housed. The window consists of a Havar disk, the thickness of which must be minimized to absorb the least amount of proton beam power, while its diameter must be sufficient to avoid excessive beam loss. The window will then be embedded around its perimeter and will have to withstand two load conditions, applied individually: A mechanical load, due to the atmospheric pressure of 0.11 MPa during vacuuming, and a thermal load, due to heating during irradiation with the proton beam. Once a first-version window geometry was defined, a static structural finite element analysis (FEA) was carried out by activating geometric nonlinearities to assess the structural integrity of the window under mechanical loading. After that, a static thermal–mechanical FEA analysis was carried out to assess the structural integrity of the window under thermal loading. Given the compressive stress state induced by thermal loading and the slenderness of the window itself, a nonlinear buckling structural FEA analysis was also performed. Full article
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35 pages, 5019 KiB  
Review
Beyond Thermal Conductivity: A Review of Nanofluids for Enhanced Energy Storage and Heat Transfer
by Ali Mirahmad, Ravi Shankar Kumar, Breogán Pato Doldán, Cristina Prieto Rios and Javier Díez-Sierra
Nanomaterials 2025, 15(4), 302; https://doi.org/10.3390/nano15040302 - 16 Feb 2025
Cited by 2 | Viewed by 2461
Abstract
The development of nanofluids (NFs) has significantly advanced the thermal performance of heat transfer fluids (HTFs) in heating and cooling applications. This review examines the synergistic effects of different nanoparticles (NPs)—including metallic, metallic oxide, and carbonaceous types—on the thermal conductivity (TC) and specific [...] Read more.
The development of nanofluids (NFs) has significantly advanced the thermal performance of heat transfer fluids (HTFs) in heating and cooling applications. This review examines the synergistic effects of different nanoparticles (NPs)—including metallic, metallic oxide, and carbonaceous types—on the thermal conductivity (TC) and specific heat capacity (SHC) of base fluids like molecular, molten salts and ionic liquids. While adding NPs typically enhances TC and heat transfer, it can reduce SHC, posing challenges for energy storage and sustainable thermal management. Key factors such as NP composition, shape, size, concentration, and base fluid selection are analyzed to understand the mechanisms driving these improvements. The review also emphasizes the importance of interfacial interactions and proper NP dispersion for fluid stability. Strategies like optimizing NP formulations and utilizing solid–solid phase transitions are proposed to enhance both TC and SHC without significantly increasing viscosity, a common drawback in NFs. By balancing these properties, NFs hold great potential for renewable energy systems, particularly in improving energy storage efficiency. The review also outlines future research directions to overcome current challenges and expand the application of NFs in sustainable energy solutions, contributing to reduced carbon emissions. Full article
(This article belongs to the Topic Thermal Energy Transfer and Storage)
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12 pages, 6745 KiB  
Article
Influence of Heat Treatment on Microstructure and Wear Properties of TiC/FC250 Composites
by Yujin Lim, Jaeseong Choi, Seungchan Cho, Junghwan Kim, Sangmin Shin and Ilguk Jo
J. Compos. Sci. 2025, 9(2), 76; https://doi.org/10.3390/jcs9020076 - 8 Feb 2025
Viewed by 815
Abstract
Metal matrix composites (MMCs) produced through the unique liquid pressing infiltration (LPI) process exhibit significant industrial potential. In this study, TiC/FC250 metal matrix composites were fabricated using the liquid pressing infiltration process, and the effects of austempering and quenching–tempering heat treatments on the [...] Read more.
Metal matrix composites (MMCs) produced through the unique liquid pressing infiltration (LPI) process exhibit significant industrial potential. In this study, TiC/FC250 metal matrix composites were fabricated using the liquid pressing infiltration process, and the effects of austempering and quenching–tempering heat treatments on the microstructure and wear characteristics were investigated in comparison to as-cast specimens of both the FC250 gray cast iron matrix material and the TiC/FC250 metal matrix composites without heat treatment. The results indicated that the quenching–tempering heat treatment effectively enhanced the dry sliding friction and wear characteristics compared to the as-cast condition. The heat-treated specimens, under optimal conditions, demonstrated superior properties compared to other heat treatments and the matrix material. Although the metal matrix composites were successfully produced via the liquid pressing infiltration process and optimal heat treatment, some graphite morphology transformed from a flake to a spherical shape due to the high temperature and slow cooling rate during the process. With the quenching–tempering heat treatment, the wear resistance increased by approximately 41.53% in the matrix material and by 53.38% in the metal matrix composites compared to the as-cast specimens. The TiC/FC250 metal matrix composite heat-treated under optimal conditions exhibited an approximate 58.28% reduction in the friction coefficient compared to the FC250 gray cast iron. Full article
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17 pages, 76482 KiB  
Article
Study of Process, Microstructure, and Properties of Double-Wire Narrow-Gap Gas Metal Arc Welding Low-Alloy Steel
by Ning Xiao, Haoyu Kong, Qingjie Sun and Ninshu Ma
Materials 2024, 17(24), 6183; https://doi.org/10.3390/ma17246183 - 18 Dec 2024
Cited by 1 | Viewed by 873
Abstract
Narrow-gap arc welding is an efficient method that significantly enhances industrial production efficiency and reduces costs. This study investigates the application of low-alloy steel wire EG70-G in narrow-gap gas metal arc welding (GMAW) on thick plates. Experimental observations were made to examine the [...] Read more.
Narrow-gap arc welding is an efficient method that significantly enhances industrial production efficiency and reduces costs. This study investigates the application of low-alloy steel wire EG70-G in narrow-gap gas metal arc welding (GMAW) on thick plates. Experimental observations were made to examine the arc behavior, droplet transition behavior, and weld formation characteristics of double-wire welding under various process parameters. Additionally, the temperature field of the welding process was simulated using finite element software (ABAQUS 2020). Finally, the microstructure and microhardness of the fusion zone in a double-wire, single-pass filled joint under the different welding speeds were compared and analyzed. The results demonstrate that the use of double-wire GMAW in narrow-gap welding yielded positive outcomes. Optimal settings for wire feeding speed, welding speed, and double-wire lateral spacing significantly enhanced welding quality, effectively preventing side wall non-fusion and poor weld profiles in the welded joints. The microstructure of the fusion zone produced at a higher welding speed (11 mm/s) was finer, resulting in increased microhardness compared to welds obtained at a lower speed (8 mm/s). This is attributed to the shorter duration of the liquid molten pool and the faster cooling rate associated with higher welding speed. This research provides a reference for the practical application of double-wire narrow-gap gas metal arc welding technology. Full article
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13 pages, 700 KiB  
Review
Evaluating Nuclear Forensic Signatures for Advanced Reactor Deployment: A Research Priority Assessment
by Megan N. Schiferl, Jeffrey R. McLachlan, Appie A. Peterson, Naomi E. Marks and Rebecca J. Abergel
J. Nucl. Eng. 2024, 5(4), 518-530; https://doi.org/10.3390/jne5040032 - 15 Nov 2024
Viewed by 1965
Abstract
The development and deployment of a new generation of nuclear reactors necessitates a thorough evaluation of techniques used to characterize nuclear materials for nuclear forensic applications. Advanced fuels proposed for use in these reactors present both challenges and opportunities for the nuclear forensic [...] Read more.
The development and deployment of a new generation of nuclear reactors necessitates a thorough evaluation of techniques used to characterize nuclear materials for nuclear forensic applications. Advanced fuels proposed for use in these reactors present both challenges and opportunities for the nuclear forensic field. Many efforts in pre-detonation nuclear forensics are currently focused on the analysis of uranium oxides, uranium ore concentrates, and fuel pellets since these materials have historically been found outside of regulatory control. The increasing use of TRISO particles, metal fuels, molten fuel salts, and novel ceramic fuels will require an expansion of the current nuclear forensic suite of signatures to accommodate the different physical dimensions, chemical compositions, and material properties of these advanced fuel forms. In this work, a semi-quantitative priority scoring system is introduced to identify the order in which the nuclear forensics community should pursue research and development on material signatures for advanced reactor designs. This scoring system was applied to propose the following priority ranking of six major advanced reactor categories: (1) molten salt reactor (MSR), (2) liquid metal-cooled reactor (LMR), (3) very-high-temperature reactor (VHTR), (4) fluoride-salt-cooled high-temperature reactor (FHR), (5) gas-cooled fast reactor (GFR), and (6) supercritical water-cooled reactor (SWCR). Full article
(This article belongs to the Special Issue Nuclear Security and Nonproliferation Research and Development)
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14 pages, 10411 KiB  
Article
A Kinetic Model for Oxide–Carbonitride Inclusion Heterogeneous Nucleation and Precipitation during Superalloy Solidification
by Peng Zhao, Shulei Yang, Yu Gu, Wei Liu and Shufeng Yang
Metals 2024, 14(10), 1150; https://doi.org/10.3390/met14101150 - 9 Oct 2024
Cited by 1 | Viewed by 973
Abstract
Complex oxide–carbonitrides (MgO-Ti(CN), Al2O3-Ti(CN), and MgO·Al2O3-Ti(CN)) are the most common non-metallic inclusions presented in cast and wrought superalloys. In this work, a coupled kinetics model was proposed to predict the complex oxide–carbonitride inclusion’s precipitation behavior [...] Read more.
Complex oxide–carbonitrides (MgO-Ti(CN), Al2O3-Ti(CN), and MgO·Al2O3-Ti(CN)) are the most common non-metallic inclusions presented in cast and wrought superalloys. In this work, a coupled kinetics model was proposed to predict the complex oxide–carbonitride inclusion’s precipitation behavior during the solidification of superalloys. This model takes into account thermodynamics, micro-segregation, heterogeneous nucleation in the inter-dendritic liquid, and growth controlled by the diffusion of solute elements and kinetics of interfacial reaction. The results demonstrated that both the cooling rate and nitrogen content take significant effects on the final size of complex oxide–carbonitride inclusions, as the former controls the total growth time and the latter determines the initial precipitation temperature. In comparison, the particle size of primary oxides shows a negligible impact on the final size of complex inclusions. The practice of an industrial vacuum arc remelting confirmed that the inclusion size variation predicted by the present model is reasonably consistent with the experimental results. Full article
(This article belongs to the Special Issue Green Super-Clean Steels)
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