Search Results (48)

The composition of wolframite from ores of the Porokhovskoe and Yugo-Konevskoe W greisen deposits in the Central Urals is studied using SEM-EDS and LA-ICP-MS analyses. The Porokhovskoe deposit is localized in a metamorphosed volcanosedimentary sequence of Lower Silurian age, and the Yugo-Konevskoe is enclosed in an eponymous granite pluton of Middle Permian–Lower Triassic age. Most studied wolframite grains belong to hűbnerite. The Fe/(Fe + Mn) value of wolframite varies in a range of 0.02–0.50. Wolframite from both deposits is enriched in Zn, Nb, and Mg. The wolframite from the Porokhovskoe deposit is enriched in V, Sc, Zn, and Mg and is depleted in Mo, U, rare earth elements (REEs), Nb, and Ta, compared to wolframite from the Yugo-Konevskoe deposit. It is suggested that this difference is due to the occurrence of ore veins in different rocks at different distance from the source of the ore-forming fluid, which cools down as it moves away from the source, leading to a decrease in the incorporation of trace elements by the lower-temperature wolframite. The predominance of heavy REEs over light REEs in all the studied wolframite is explained by the close ionic radii of heavy REEs to the main mineral-forming elements Fe and Mn. Full article

Siderite and baryte are common non-sulphide phases in sedimentary exhalative (SEDEX) deposits, but their formation remains poorly understood. Siderite is important as an exploration vector in some deposits, whereas baryte is important as a S source in some deposits. The past-producing Walton deposit (Nova Scotia, Canada) consists of two ore types: (1) a sulphide body primarily hosted by sideritised Viséan Macumber Formation limestone (0.41 Mt; head grade of 350 g/t Ag, 4.28% Pb, 1.29% Zn, and 0.52% Cu), and (2) an overlying massive baryte body of predominantly microcrystalline baryte (4.5 Mt of >90% baryte). This study used optical microscopy, SEM-EDS, cathodoluminescence (CL), LA-ICP-MS, and SIMS sulphur isotope analysis of siderite and baryte to elucidate their origin and role in deposit formation. Siderite replaces limestone and contains ≤9 wt. % Mn, is LREE-depleted (PAAS-normalised REEY diagrams), and has low (<20) Y/Ho ratios. Sideritisation occurred due to dissimilatory iron reduction (DIR) that led to the breakdown of Fe-Mn-oxyhydroxides and organic matter, as indicated by light δ¹³C_VPBD values and negative Y anomalies. The baryte body is dominated by a microcrystalline variety that locally develops a radial texture and coarsens to a tabular variety; it also occurs intergrown with, and as veins in, massive sulphides. Based on fluid inclusion data from previous studies, the coarser baryte types grew from a hot (>200 °C) saline (25 wt. % NaCl) fluid containing CO₂-CH₄ and liquid petroleum. Marine sulphate δ³⁴S_VCDT values typical of the Viséan (~15‰) characterise the baryte body and some tabular baryte types, whereas heavier (~20‰) and lighter (~10‰) values typify the remaining tabular types. The variations in tabular baryte relate to distinct zones identified by CL imaging and are attributed to the sulphate-driven anaerobic oxidation of methane (SDAOM) and oxidation of excess H₂S after sulphide precipitation. These results highlight the importance of hydrocarbons (methane and organic matter) in the formation of both the siderite and the baryte at Walton and that DIR and the SDAOM can be important contributing processes in the formation of SEDEX deposits. Full article

The Bozhushan in southeastern Yunnan is a composite granite body that was formed by multi-phase magmatic intrusion. The genesis of the tourmaline-supergroup minerals occurring therein remains uncertain, as it has been the subject of only a limited number of studies. This investigation employs an integrated analytical approach combining EPMA, LA-ICP-MS, and boron isotope geochemistry, supplemented by detailed field geological investigations and petrographic observations of tourmaline textural characteristics. This study aims to elucidate the genetic relationships between distinct tourmaline varieties, establish temporal correlations between mineral crystallization stages and magmatic–hydrothermal evolution processes, and evaluate the petrogenetic significance of tourmaline geochemical signatures for regional mineralization events. This study analyzes tourmaline-supergroup minerals in granitic pegmatites and aplites, which occur as nodular, radial, and columnar aggregates. Most tourmaline crystals exhibit well-defined rhythmic zoning patterns, which are clearly observable under cross-polarized light microscopy. Chemical composition analysis has identified two tourmaline species: schorl and dravite. The formation of tourmaline is primarily of magmatic origin and is characterized by a magmatic–hydrothermal transition. It predominantly belongs to the alkali subgroup and is formed in Li-poor granitoids and associated pegmatites and aplites, Ca-poor metapelites, metapsammites, and quartz-tourmaline rocks. The inter-ionic substitution mechanism in this system is predominantly governed by Fe²⁺Mg₋₁ and (X_vacAl)(NaR²⁺)₋₁ exchange equilibria. Additionally, geochemical evidence indicates that the primary ore-forming fluids originate from granitic magmas, which are likely sourced from the partial melting of metasedimentary rocks. During the late Yanshan period, the upwelling of granitic magma in the Bozhushan area introduced a substantial heat source and mineralizing fluids, which interacted with the Cambrian units to form tungsten–tin mineralization. The geochemical data on tourmaline indicate that the Bozhushan granite body has considerable potential for ore mineralization. Full article

Enhancing the thermal conductivity of fluids by using nanoparticles with outstanding thermophysical properties has acquired significant attention for heat-transfer applications. Nanofluids have the potential to optimize energy systems by improving heat-transfer efficiency. In this study, cobalt ferrite nanoparticles clusters with controlled mean sizes ranging from 97 to 192 nm were synthesized using a solvothermal method to develop novel nanofluids with enhanced thermal conductivity. These clusters were comprehensively characterized using transmission electron microscopy, X-ray diffraction, Raman spectroscopy, vibrating-sample magnetometry, and nitrogen physisorption. The CoFe₂O₄ cluster nanofluids were prepared using the two-step method with various base fluids (water, propylene glycol, and a mixture of both). Dynamic light scattering analyses of the average Z-size of the dispersed nanoadditives over time revealed that the stability of the dispersions is influenced by cluster size and the proportion of glycol in the base fluid. The thermal conductivity of the base fluid and nine different 0.5 wt% CoFe₂O₄ cluster nanofluids was measured using the transient hot wire method at temperatures of 293.15, 303.15, and 313.15 K, showing different temperature dependencies. The study also explores the relationships between the thermal conductivity, cluster size, and specific surface area of the nanoadditives. A maximum thermal conductivity enhancement of 4.2% was reported for the 0.5 wt% nanofluid based on propylene glycol containing 97 nm CoFe₂O₄ clusters. The findings suggest that the specific surface area of nanostructures is a more relevant parameter than size for describing improvements in thermal conductivity. Full article

The Guodian Fe deposit is representative of the newly discovered Qihe–Yucheng high-grade Fe skarn ore cluster, Luxi Block, eastern North China Craton (NCC). The age of the Pandian Fe deposit remains elusive, which hinders the understanding of its metallogenic tectonic background. Phlogopites are recognized in syn-ore stages, and they are closely associated with magnetite in the Guodian skarn Fe deposit. Here, we carried out ⁴⁰Ar/³⁹Ar dating of phlogopite, which can place a tight constraint on the timing of Guodian iron mineralization and shed light on the geodynamic framework under which the Guodian Fe deposit formed. Ore-related phlogopite ⁴⁰Ar/³⁹Ar dating yielded ⁴⁰Ar/³⁹Ar plateau ages of 131.6 ± 1.7 Ma at 890–1400 °C, with the corresponding isochron age being 131.1 ± 2.6 Ma. These two ages are consistent within the error, indicating that they can represent the formation age of the Guodian iron deposit. The mineralization age overlaps the zircon U-Pb age of 124.4 Ma for ore-related Pandian pluton. This age consistency confirms that the iron skarn mineralization is temporally and likely genetically related to Pandian diorite. The present results, coupled with existing isotopic age data, indicate the Guodian skarn Fe deposit formed contemporaneously with large-scale skarn iron mineralization over the Luxi Block in the Late Mesozoic. The available data demonstrated that the eastern NCC was “destructed” in the Late Mesozoic, as marked by voluminous igneous rocks, faulted-basin formation, high crustal heat flow, and widespread metamorphic core complexes in the eastern part of the NCC. It is thus suggested that the Guodian Fe skarn deposits, together with other deposits of similar ages in the Luxi Block and even in the eastern NCC, were products of this craton destruction. Lithospheric extension and extensive magmatism related to the craton destruction may have provided sufficient heat energy, fluid, chlorine, and Fe for the formation of the Fe deposit. Full article

The Wadi Ranga sulfidic jasperoids in the Southern Eastern Desert (SED) of Egypt are hosted within the Neoproterozoic Shadli metavolcanics as an important juvenile crustal section of the Arabian Nubian Shield (ANS). This study deals with remote sensing and geochemical data to understand the mechanism and source of pyritization, silicification, and hematization in the host metavolcanics and to shed light on the genesis of their jasperoids. The host rocks are mainly dacitic to rhyolitic metatuffs, which are proximal to volcanic vents. They show peraluminous calc-alkaline affinity. These felsic metatuffs also exhibit a nearly flat REE pattern with slight LREE enrichment (La/Yb = 1.19–1.25) that has a nearly negative Eu anomaly (Eu/Eu* = 0.708–0.776), while their spider patterns display enrichment in Ba, K, and Pb and depletion in Nb, Ta, P, and Ti, reflecting the role of slab-derived fluid metasomatism during their formation in the island arc setting. The ratios of La/Yb (1.19–1.25) and La/Gd (1.0–1.17) of the studied felsic metatuffs are similar to those of the primitive mantle, suggesting their generation from fractionated melts that were derived from a depleted mantle source. Their Nb and Ti negative anomalies, along with the positive anomalies at Pb, K, Rb, and Ba, are attributed to the influence of fluids/melt derived from the subducted slab. The Wadi Ranga jasperoids are mainly composed of SiO₂ (89.73–90.35 wt.%) and show wide ranges of Fe₂O₃t (2.73–6.63 wt.%) attributed to the significant amount of pyrite (up to 10 vol.%), hematite, goethite, and magnetite. They are also rich in some base metals (Cu + Pb + Zn = 58.32–240.68 ppm), leading to sulfidic jasperoids. Pyrite crystals with a minor concentration of Ag (up to 0.32 wt.%) are partially to completely converted to secondary hematite and goethite, giving the red ochre and forming hematization. Euhedral cubic pyrite is of magmatic origin and was formed in the early stages and accumulated in jasperoid by epigenetic Si-rich magmatic-derived hydrothermal fluids; pyritization is considered a magmatic–hydrothermal stage, followed by silicification and then hematization as post-magmatic stages. The euhedral apatite crystals in jasperoid are used to estimate the saturation temperature of their crystallization from the melt at about 850 °C. The chondrite (C1)-normalized REE pattern of the jasperoids shows slightly U–shaped patterns with a slightly negative Eu anomaly (Eu/Eu* = 0.43–0.98) due to slab-derived fluid metasomatism during their origin; these jasperoids are also rich in LILEs (e.g., K, Pb, and Sr) and depleted in HFSEs (e.g., Nb and Ta), reflecting their hydrothermal origin in the island arc tectonic setting. The source of silica in the studied jasperoids is likely derived from the felsic dyke and a nearby volcanic vent, where the resultant Si-rich fluids may circulate along the NW–SE, NE–SW, and E–W major faults and shear zones in the surrounding metavolcanics to leach Fe, S, and Si to form hydrothermal jasperoid lenses and veins. Full article

The Kaladawan iron deposit is located in the North Altyn Tagh and exhibits occurrences of iron ore bodies at the contact zone between Ordovician magmatic rocks (basalts, rhyolite, and granodiorite) and marble. However, controversy persists regarding the genetic classification and metallogenic mechanism of this deposit. Through a field investigation, single mineral in situ geochemical analysis, whole-rock geochemical analysis, and Fe isotope determination, the following conclusions are made: (1) Ti-(Ni/Cr) and (V/Ti)-Fe diagrams indicate that the magnetite from all studied rocks underwent hydrothermal metasomatism, while (Ni/(Cr + Mn))-(Ti + V) and (Ca + Al + Mn)-(Ti + V) diagrams suggest a skarn origin for these magnetites. Therefore, it can be inferred that the Kaladawan iron deposit is skarn-type. (2) The iron ore exhibits similar rare-earth-element characteristics to the altered basalt. Additionally, the altered basalts (δ⁵⁶Fe = 0.024~0.100‰) are more enriched in light Fe isotopes than the unaltered basalts (δ⁵⁶Fe = 0.129~0.197‰) at the same location, indicating that the ore-forming materials of the Kaladawan iron ore are mainly derived from basaltic rocks. (3) According to the law of mass conservation and the intermediate Fe isotopic composition of the iron ore between the granodiorite and basalt, the hydrothermal fluid for the formation of iron ores was inferred to be derived from the late intrusive granodiorite. Full article

The Ordovician thick dolostone in Shuntogol area of the Tarim Basin has the potential to form a large-scale reservoir, but its genesis and reservoir development model are still unclear. Starting from a sedimentary sequence, this study takes a batch of dolostone samples obtained from new drilling cores in recent years as the research object. On the basis of core observation and thin section identification, trace elements, cathodoluminescence, carbon and oxygen isotopes, rare earth elements, and X-ray diffraction order degree tests were carried out to discuss the origin of the dolomite and summarize the development model of the dolostone reservoir. The analysis results show that the Ordovician dolomite in the study area had a good crystalline shape, large thickness, high Fe and Mn values, and mostly showed bright red light or bright orange–red light under cathode rays. The ratio of δ¹⁸O values to seawater values at the same time showed a negative bias; the δCe values were negative anomalies, the δEu values were positive anomalies, and the order degree was high. This indicates that the dolomitization process occurred in a relatively closed diagenetic environment. The Ordovician carbonate rocks in the study area were low-lying during the sedimentary period, and with the rise of sea level, the open platform facies continued to develop. When the Middle and Lower Ordovician series entered the burial stage, the main hydrocarbon source rocks of the lower Cambrian Series entered the oil generation peak, and the resulting formation overpressure provided the dynamic source for the upward migration of the lower magnesium-rich fluid, and the dolomitization fluid entered the karst pore system in the target layer to produce all the dolomitization. This set of dolostone reservoirs is large in scale and can be used as a favorable substitute area for deep carbonate exploration for continuous study. Full article

Background: Amyotrophic lateral sclerosis (ALS) is an incurable disease. There are vigorous attempts to develop treatments to reduce the effects of this disease, and among these treatments is the transplantation of stem cells. This study aimed to retrospectively evaluate a mesenchymal stem cell (MSC) therapy cohort as a promising novel treatment modality by estimating some additional new parameters, such as immunological and biochemical factors. Methods: This study was designed as an open-label, one-arm cohort retrospective study to evaluate potential diagnostic biomarkers of repeated infusions of autologous-bone marrow-derived mesenchymal stem cells (BM-MSCs) in 15 confirmed patients with ALS, administered at a dose of 1 × ${10}^6$ cells/kg BW with a one-month interval, in equal amounts in both an intravenous (IV) and intrathecal (IT) capacity simultaneously, via various biochemical (iron (Fe), ferritin, total-iron-binding capacity (TIBC), transferrin, and creatine kinase (CK)) and immunological parameters (tumor necrosis factor-alpha (TNF-α), neurofilament light chain (NFL), and glial-cell-derived neurotrophic factor (GDNF) levels, evaluated during the three-month follow-up period in serum and cerebrospinal fluid (CSF). Results: Our study indicated that, in the case of immunological biomarkers, TNF-α levels in the CSF showed a significant decrease at month three after transplantation compared with levels at month zero, and the p-value was p < 0.01. No statistically significant changes were observed for other immunological as well as biochemical parameters and a p-value of p > 0.05. Conclusions: These results can indicate the potential benefit of stem cell transfusion in patients with ALS and suggest some diagnostic biomarkers. Several studies are required to approve these results. Full article

In this study, seventeen faceted gem-quality chrysoberyls exhibiting an attractive canary yellow color were investigated using a variety of gemological, spectral, and chemical methods. Microscopic observation revealed the presence of distinct growth lines and inclusions, including CO₂ fluids, carbon, and crystals of mineral such as calcite, quartz, sillimanite, and mica, identified by the Raman spectrum. The FTIR spectra showed the characteristic peaks of 2405 and 2160 cm⁻¹ and a 3223 cm⁻¹ peak in all samples, which can be accompanied by the 3112 cm⁻¹ shoulder, 3301, and 3412 and 3432 cm⁻¹ peaks. The UV-Vis spectra showed an Fe-related peak at 440 nm, along with the 650–660 nm band and the absorption band in the blue zone of visible light. Chemical analyses via EDXRF showed a composition poor in V and Cr and rich in Fe. The spectral and chemical results could help explain the origin of the canary yellow color, which originates from the abundant amount of Fe with very little influence from Cr and V. Full article

An integrated photocatalytic membrane system (IPMS) was developed for potential use in the remediation of naproxen using real water samples from a drinking water treatment plant. Key parameters such as time, pH, water matrix, mixing speeds, flow rate, and light intensity undeniably affected photocatalytic and membrane separation processes. The system optimization was based on improving irradiation to generate a more reactive species and mass transfer to increase the reaction rate. Upon optimization, IPMS achieved 99% naproxen removal efficiency. Computational fluid dynamics (CFD) simulated the flow patterns and radiation distribution inside the photocatalytic membrane reactor to improve irradiation and mass transfer during operation. The simulated flow field revealed the presence of dead zones with different velocities in the photocatalytic membrane reactor; this limited the mass transfer of reactive species in the reactor, resulting in uneven distribution of reactive radicals. The dead zones were mitigated by increasing the mixing speed, and as a result, convective mass flow improved process performance. The governing parameters (flow patterns and radiation distribution) of the simulated and experimental data were in agreement. The absorption of irradiation by the active site of the membranes improved with light intensity; at higher light intensities, the light irradiated deeper into the membrane. As such, the CoFe₂O₄ nanoparticles incorporated inside the membrane pores became highly activated, thus enhancing degradation. The obtained space–time yield (STY) (1.23 × 10¹¹ mol/cm².s) and photocatalytic space–time yield (PSTY) (4.39 × 10¹¹ mol/W.s) showed that the developed IPMS was efficient regarding energy intensiveness and throughput for treatment of pollutants in water. Full article

Many regions of the United States contain manganese deposits economically valuable in New England, Appalachian, and Piedmont regions in the Eastern United States, in Northern Arkansas, and, to a small extent, in Central–Western California. Mn oxide/hydroxide (commonly referred to as Mn oxide minerals) are found in a wide variety of geological settings and occur as fine-grained aggregates, veins, marine and freshwater nodules and concretions, crusts, dendrites, and coatings on rock surfaces (e.g., desert varnish). How manganese oxides form and what mechanisms determine which oxides are likely to form are limited and still debated. This paper focuses on Mn oxides collected at the southern bound of the abandoned open-pit site called Crimora Mine (Augusta County, Virginia). This study uses mineralogical and chemical features to shed light on the origin of manganese deposits in Crimora along the western foot of the Blue Ridge in South–West Virginia. We report the first detailed study on the genesis of the Crimora manganese deposit conducted since the mine was closed in the 1950s. Crimora Mine sample is dark black fine- to medium-grained round and oblong nodules coated with a fine-grained intermix of yellowish earthy limonite, clays, and quartz. Scanning electron microscopy (SEM) revealed that the Crimora Mn-oxides exhibit concentric layering, breccia-like matrices, and veins. X-ray powder diffraction (XRPD) identified the set of Mn minerals as hollandite and birnessite. The concentration and range of dissolved chemical species in freshwater, seawater, and hydrothermal depositional fluids impart a geochemical signature to the Mn-oxides, providing a diagnostic tool to shed light on their genetic origin. Inductively coupled plasma optical emission spectroscopy (ICP-OES) analysis of the Crimora manganese oxides shows Mn, Fe, and Ti, as well as trace elements such as Co, Ba, Y, Zn, Cr, Ni, Tl, La, V, and Li. A bivariate analysis based on the geochemical correlation of Mn and other common substituting cations (e.g., Fe, Co, Ti) shows a mixed genesis in different environments with varying biological and sedimentary supergene (freshwater and marine) conditions. These data suggest that the Mn-rich deposit in Crimora, VA, was formed in a continental margin environment of surficial deposits and reprecipitated in mixed biogenic and supergene conditions. Full article

The Changpo–Tongkeng tin polymetallic deposit in Dachang, Guangxi, is a world-class, superlarge, polymetallic tin deposit consisting of lower skarn zinc–copper ore bodies and upper tin polymetallic ore bodies. Garnet is the main gangue mineral in the skarn zinc–copper ore bodies and has a granular texture. Based on hand specimens and microscopic observations, the existing garnet can be divided into two generations: an early generation (Grt I) and a late generation (Grt II). The results of electron probe microanalysis (EPMA) and laser ablation-inductively coupled plasma-mass spectrometry (LA-ICP-MS) in situ microanalysis show that the contents of SiO₂ and CaO in the garnets from the two generations present limited variations, while the FeO^T and Al₂O₃ contents vary significantly, indicating the grossular–andradite solid solution series (Gro_29–82And_12–69). Compared with Grt I (Gro₇₂And₂₅), Grt II (Gro₃₉And₅₉) is Fe-enriched and oscillatory zoning is developed. The total rare earth element (REE) contents in the two generations of garnet are relatively low, showing light rare earth element (LREE) depletion and heavy rare earth element (HREE) enrichment patterns. Grt II has higher REE content than Grt I and exhibits significant negative Eu anomalies (δEu = 0.18–0.44). The contents and variation characteristics of the major and trace elements in the two generations of garnet suggest that there were variable redox conditions and water/rock ratios in the hydrothermal system during the crystallization process of garnet. In the early stage, skarnization was in a relatively closed and low-oxygen fugacity system, with hydrothermal diffusion metasomatism being dominant, forming homogeneous Grt I lacking well-developed zoning. In the late stage of skarnization, the oxygen fugacity of the ore-forming fluids increased, with infiltration metasomatism being dominant, forming Grt II with well-developed oscillatory zoning. The contents of Sn, As, W, In, and Ge in the garnets are relatively high and increase with the proportion of andradite. Sn in zinc–copper ore bodies mainly exists in the form of isomorphic substitution in garnet, which may be the main reason for the lack of tin ore bodies during the skarn stage. This paper compares the trace element contents in garnets from domestic skarn deposits. The results indicate that the Sn content and δEu in garnet can be used to evaluate the tin-forming potential of skarn deposits. Full article

The early Cambrian Takab iron ore deposit is situated in the northern part of the Sanandaj-Sirjan zone, western Iran. It consists of banded, nodular and disseminated magnetite hosted in folded micaschists. Trace element and Fe and O isotopic experiments reveal various hydrothermal precipitation environments under reduced to slightly oxidizing conditions. Disseminated magnetite has high Ti (945–1940 ppm) positively correlated with Mg + Al + Si, and heavy Fe (+0.76 to +1.86‰) and O (+1.0 to +4.07‰) isotopic compositions that support a magmatic/high-T hydrothermal origin. Banded magnetite has low Ti (15−200 ppm), V (≤100 ppm), Si and Mg (mostly ≤300 ppm) and variable Al. The ∂⁵⁶Fe values vary from −0.2‰ to +1.12‰ but most values also support a magmatic/high-T hydrothermal origin. However, variable ∂¹⁸O (−2.52 to +1.22‰) values provide evidence of re-equilibration with lower-T fluid at ~200–300 °C. Nodular magnetite shows high Mn (≤1%), and mostly negative ∂⁵⁶Fe values (average, −0.3‰) indicative of precipitation from an isotopically light hydrothermal fluid. Re-equilibration with carbonated rocks/fluids likely results in a negative Ce anomaly and higher ∂¹⁸O (average, +6.30‰). The Takab iron ore deposit has, thus, experienced a complex hydrothermal history. Full article

Herein, we report a procedure for separating and preconcentrating antibiotics from human serum using a novel adsorbent of magnetic graphene oxide (MGO) and cadmium sulfide (CdS) nanoparticles. The adsorbent (MGO@CdS) was characterized using Fourier transformed infrared spectrometry (FT-IR), energy dispersive X-ray spectroscopy (EDX), and field emission scanning electron microscopy (FE-SEM). The effective parameters for extraction efficiency were investigated, including the desorption solvent’s nature, pH, adsorbent dose, salt concentration, extraction time, and volume of sample solution and desorption solvent. The proposed procedure proved to be fast (20 min), simple (two stages), and cost-effective (20 mg of nanoparticles). Under the optimum conditions, satisfactory linearity (R2 > 0.992) was obtained, and limits of detection (LOD) were estimated as 4.5 µg L⁻¹ (for tetracycline) and 5.7 µg L⁻¹ (for penicillin) and a linear dynamic range (LDR) from 20 to 200 µg L⁻¹. The magnetic solid phase extraction (MSPE) method based on MGO@CdS has achieved a satisfactory recovery (71.5–109.5%) in human serum for the selected antibiotics. Finally, the antibiotic’s release was studied in simulated fluids of the gastric (pH = 1.2) and intestine (pH = 7.4). In this light, we demonstrate that the newly introduced adsorbent can be used in drug extraction from different biological media. Full article