Search Results (23)

The Populus euphratica desert riparian forest, predominantly distributed along the Tarim River in northwestern China, has experienced significant degradation due to climate change and anthropogenic activities. Despite its ecological importance, systematic assessments of P. euphratica stand structure across the entire Tarim River remain scarce. This study employed terrestrial laser scanning (TLS) to capture high-resolution 3D structural data from 2741 individual trees across 30 plots within six transects, covering the 1300 km mainstream of the Tarim River. ANOVA, PCA, and RDA were applied to examine tree structure variation and environmental influences. Results revealed a progressive decline in key structural parameters from the upper to lower reaches of the river, with the lower reaches showing pronounced degradation. Stand density decreased from 440 to 257 trees per hectare, mean stand height declined from 9.3 m to 5.6 m, mean crown diameter reduced from 4.1 m to 3.8 m, canopy cover dropped from 62% to 42%, and the leaf area index fell from 0.51 to 0.29. Age class distributions varied along the river, highlighting population structures indicative of growth in the upper reaches, stability in the middle reaches, and decline in the lower reaches. Abiotic factors, including groundwater depth, soil salinity, soil moisture, and precipitation, exhibited strong correlations with stand structural parameters (p < 0.05, R² ≥ 0.69). The findings highlight significant spatial variations in tree structure, with healthier growth in the upper reaches and degradation in the lower reaches, enhance our understanding of forest development processes, and emphasize the urgent need for targeted conservation strategies. This comprehensive quantification of P. euphratica stand structure and its environmental drivers offer valuable insights into the dynamics of desert riparian forest ecosystems. The findings contribute to understanding forest development processes and provide a scientific basis for formulating effective conservation strategies to sustain these vital desert ecosystems, as well as for the monitoring of regional environmental changes. Full article

Based on tunable diode laser absorption spectroscopy (TDLAS), a water isotopes detection system was developed to detect the isotopic abundance of water vapor in the atmosphere. A single 1483.79 cm⁻¹ quantum cascade laser (QCL) and a 3120 cm optical path multi-pass cell (MPC) were adopted in the detection system. The selected spectral range, as well as the laser technology used, is particularly interesting for the real-time monitoring of water vapor isotopes in the atmosphere. In this study, a single laser can be used to perform high-sensitivity, rapid investigations of H₂O, H₂¹⁸O, H₂¹⁷O, and HDO absorption lines. Finally, we measured the abundance values of three isotopes of water vapor in the atmosphere and compared them with data from the Global Network of Isotopes in Precipitation (GNIP) website, dedicated to exploring the possibility of in situ monitoring of H₂O isotopes in the atmosphere. Full article

The Tianshan Mountains are known as the “Water Tower of Central Asia” and are of significant strategic importance for Xinjiang as well as the Central Asian region. Accurately monitoring the spatiotemporal distribution of precipitation in the Tianshan Mountains is crucial for understanding global water cycles and climate change. Raindrop Size Distribution (DSD) parameters play an important role in improving quantitative precipitation estimation with radar and understanding microphysical precipitation processes. In this study, DSD parameters in the Tianshan Mountains were evaluated on the basis of Global Precipitation Measurement mission (GPM) dual-frequency radar data (DPR) and ground-based laser disdrometer observations from 2019 to 2024. With the disdrometer observations as the true values, we performed spatiotemporal matching between the satellite radar and laser disdrometer data. The droplet spectrum parameters retrieved with the GPM dual-frequency radar system were compared with those calculated from the laser disdrometer observations. The reflectivity observations from the GPM DPR in both the Ku and Ka bands (ZKu and ZKa) were greater than the actual observations, with ZKa displaying a greater degree of overestimation than ZKu. In the applied single-frequency retrieval algorithm (SFA), the rainfall parameters retrieved from the Ka band outperformed those retrieved from the Ku band, indicating that the Ka band has stronger detection capability in the Tianshan Mountains area, where light rain predominates. The dual-frequency ratio (DFR), i.e., the differences in the reflectivity of the raindrop spectra obtained from both the Ku and Ka bands, fluctuated more greatly than those of the GPM DPR. DFR is a monotonically increasing function of the mass-weighted mean drop diameter (Dm). Rainfall rate (R) and Dm exhibited a strong positive correlation, and the fitted curve followed a power function distribution. Full article

Directed Energy Deposition Laser Beam (DED-LB) is a promising additive manufacturing technique that uses a laser source and a powder stream to build or repair metal components. Repair applications offer significant economic and environmental benefits but are more challenging to develop, especially for components that are difficult to process due to their intricate geometries and materials. Process conditions can change precipitously, and it is essential to implement monitoring systems that ensure high process stability and, consequently, superior end-product quality. In the present work, a mid-wave infrared coaxial camera was used to monitor the melt pool geometry. To simulate the challenging repair process conditions of the DED-LB process, experimental tests were carried out on substrates with different thicknesses. The stability of the deposition process on nickel-based superalloys was analyzed by means of MATLAB algorithms. Thus, the effect of open-loop and closed-loop monitoring with back control on laser power on the process conditions was assessed and quantified. Metallographic analysis of the produced samples was carried out to validate the analyses performed by the monitoring system. The occurrence of production defects (lack of fusion and porosity) related to parameters not directly controllable by monitoring systems, such as penetration depth and dilution, was determined. Full article

A series of copolymers containing a thermo-responsive biocompatible first block of poly[di(ethylene glycol) methyl ether methacrylate)-co-(oligo(ethylene glycol) methyl ether methacrylate], P(DEGMA-co-OEGMA) were chain-extended to incorporate either poly(N-isopropylacrylamide), PNIPAAm or poly(N-isopropylacrylamide-co-butyl acrylate), P(NIPAAm-co-BA) as second thermo-responsive block using reversible addition–fragmentation chain transfer (RAFT) polymerization. P(DEGMA-co-OEGMA)-b-PNIPAAm copolymers showed two response temperatures at 33 and 43 °C in an aqueous solution forming stable aggregates at 37 °C. In contrast, P(DEGMA-co-OEGMA)-b-P(NIPAAm-co-BA) copolymers showed aggregation below room temperature due to the shift in response temperature provoked by the presence of hydrophobic butyl acrylate (BA) units, and shrinkage upon heating up to body temperature, while maintaining the second response temperature above 40 °C. The terminal trithiocarbonate group of the block copolymers was modified to a thiol functionality and used to stabilize gold nanorods (GNRDs) via the “grafting to” approach. The Localized Surface Plasmon Resonance (LSPR) absorption band of GNRDs with an aspect ratio of 3.9 (length/diameter) was located at 820 nm after surface grafting with block copolymers showing a hydrodynamic diameter of 160 nm at 37 °C. On the other hand, the stability of the P(DEGMA-co-OEGMA)-b-PNIPAAm@GNRDs and P(DEGMA-co-OEGMA)-b-P(NIPAAm-co-BA)@GNRDs nanohybrids was monitored for 8 days; where the LSPR absorption band did not shift or show any broadening. Aqueous dispersed nanohybrids were irradiated with a near-infrared laser (300 mW), where the temperature of the surroundings increased 16 °C after 16 min, where conditions for no precipitation were determined. These tailored temperature-responsive nanohybrids represent interesting candidates to develop drug nanocarriers for photo-thermal therapies. Full article

Imaging disdrometers are widely used in field campaigns to provide information on the shape of hydrometeors, together with the diameter and the fall velocity, which can be used to derive information on the shape–size relations of hydrometeors. However, due to their higher price compared to laser disdrometers, their use is limited to scientific research purposes. The 3D stereo (3DS) is a commercial imaging disdrometer recently made available by Thies Clima and on which there are currently no scientific studies in the literature. The most innovative feature of the 3DS is its ability in capturing images of the particles passing through the measurement volume, crucial to provide an accurate classification of hydrometeors based on information about their shape, especially in the case of solid precipitation. In this paper. the performance of the new device is analyzed by comparing 3DS with the Laser Precipitation Monitor (LPM) from the same manufacturer, which is a known laser disdrometer used in many research works. The data used in this paper were obtained from measurements of the two instruments carried out at the Casale Calore site in L’Aquila during the CORE-LAQ (Combined Observations of Radar Experiments in L’Aquila) campaign. The objective of the comparison analysis is to analyze the differences between the two disdrometers in terms of hydrometeor classification, number and falling speed of particles, precipitation intensity, and total cumulative precipitation on an event basis. As regards the classification of precipitation, the two instruments are in excellent agreement in identifying rain and snow; greater differences are observed in the case of particles in mixed phase (rain and snow) or frozen phase (hail). Due to the different measurement area of the two disdrometers, the 3DS generally detects more particles than the LPM. The performance differences also depend on the size of the hydrometeors and are more significant in the case of small particles, i.e., D < 1 mm. In the case of rain events, the two instruments are in agreement with respect to the terminal velocity in still air predicted by the Gunn and Kinzer model for drops with a diameter of less than 3 mm, while, for larger particles, terminal velocity is underestimated by both the disdrometers. The agreement between the two instruments in terms of total cumulative precipitation per event is very good. Regarding the 3DS ability to capture images of hydrometeors, the raw data provide, each minute, from one to four images of single particles and information on their size and type. Their number and coarse resolution make them suitable to support only qualitative analysis of the shape of precipitating particles. Full article

Cylindrical Inconel 718 specimens were fabricated via a blown-powder, laser-directed energy deposition (DED-L) additive manufacturing (AM) process equipped with a dual thermal monitoring system to learn key process–structure relationships. Thermographic inspection of the heat affected zone (HAZ) and melt pool was performed with different layer-to-layer time intervals of ~0 s, 5 s, and 10 s, using an infrared camera and dual-wavelength pyrometer, respectively. Maximum melt pool temperatures were found to increase with layer number within a substrate affected zone (SAZ), and then asymptotically decrease. As the layer-to-layer time interval increased the HAZ temperature responses became more repetitive, indicating a desirable approach for achieving a more homogeneous microstructure along the height of a part. Microstructural variations in grain size and the coexistence of specific precipitate phases and Laves phases persisted among the investigated samples despite the employed standard heat treatment. This indicates that the effectiveness of any post DED-L heat treatment depends significantly on the initial, as-printed microstructure. Overall, this study demonstrates the importance of part size, part number per build, and time intervals on DED-L process parameter selection and post-process heat treatments for achieving better quality control. Full article

This work presents a biological remediation process for molybdenum-bearing wastewater which may lead to the fabrication of biogenic Mo chalcogenide particles with (photo)catalytic properties. The process is based on dissimilatory sulphate reduction, utilising sulphate-reducing bacteria (SRB), and reductive precipitation of molybdate which is the predominant species of molybdenum in oxygenated water/wastewater. The SRB culture was established in a biofilm reactor which was fed with synthetic solutions containing sulphate (17.7 mM), molybdate molybdenum (2 mM), divalent iron (1.7 mM) and ethanol as the carbon/electron donor. The performance of the bioreactor was monitored in terms of pH, sulphate and molybdenum (Mo(VI) and total) content. The presence of thiomolybdate species was studied by scanning UV-Vis absorbance of samples from the reactor outflow while the reactor precipitates were studied via electron microscopy coupled with energy dispersive spectrometry, X-ray diffractometry and laser light scattering. A molar molybdate/sulphate ratio of 1:12.5 proved effective for molybdate reduction and recovery by 76% in 96 h, whereas sulphate was reduced by 57%. Molybdenum was immobilised in the sulphidic precipitates of the bioreactor, presumably via two principal mechanisms: (i) microbially mediated reduction and precipitation, and (ii) thiomolybdate formation and sorption/incorporation into iron sulphides. Full article

An original method was proposed to reduce the quenching of the NIR fluorescence of colloidal solutions of 0.1 at. % Nd³⁺: LaF₃ nanoparticles (NPs) synthesized by aqueous co-precipitation method followed by hydrothermal microwave treatment. For this, an aqueous colloidal solution of NPs was precipitated by centrifugation and dissolved in the same volume of DMSO. The kinetics of static fluorescence quenching of Nd³⁺ donors of doped NPs dispersed in two solvents was analyzed to determine and to compare the concentrations of OH- quenching acceptors uniformly distributed throughout the volume of the NPs. The dependences of the relative fluorescence quantum yield φ of colloidal solutions on the concentration of OH- groups in the NPs were calculated and were also used to determine concentration of acceptors in the volume of NPs in different solvents. It was found that the concentration of OH- groups in NPs dispersed in DMSO is almost two times lower than in NPs dispersed in water. This gives an almost two-fold increase in the relative fluorescence quantum yield φ for the former. The sizes of synthesized NPs were monitored by common TEM and by applying a rapid procedure based on optical visualization of the trajectories of the Brownian motion of NPs in solution using a laser ultramicroscope. The use of two different methods made it possible to obtain more detailed information about the studied NPs. Full article

Snow plays a crucial role in the hydrological cycle and energy budget of the Earth, and remote sensing instruments with the necessary spatial coverage, resolution, and temporal sampling are essential for snowfall monitoring. Among such instruments, ground-radars have scanning capability and a resolution that make it possible to obtain a 3D structure of precipitating systems or vertical profiles when used in profiling mode. Radars from space have a lower spatial resolution, but they provide a global view. However, radar-based quantitative estimates of solid precipitation are still a challenge due to the variability of the microphysical, geometrical, and electrical features of snow particles. Estimations of snowfall rate are usually accomplished using empirical, long-term relationships between the equivalent radar reflectivity factor (Ze) and the liquid-equivalent snowfall rate (SR). Nevertheless, very few relationships take advantage of the direct estimation of the microphysical characteristics of snowflakes. In this work, we used a K-band vertically pointing radar collocated with a laser disdrometer to develop Ze-SR relationships as a function of snow classification. The two instruments were located at the Italian Antarctic Station Mario Zucchelli. The K-band radar probes the low-level atmospheric layers, recording power spectra at 32 vertical range gates. It was set at a high vertical resolution (35 m), with the first trusted range gate at a height of only 100 m. The disdrometer was able to provide information on the particle size distribution just below the trusted radar gate. Snow particles were classified into six categories (aggregate, dendrite aggregate, plate aggregate, pristine, dendrite pristine, plate pristine). The method was applied to the snowfall events of the Antarctic summer seasons of 2018–2019 and 2019–2020, with a total of 23,566 min of precipitation, 15.3% of which was recognized as showing aggregate features, 33.3% dendrite aggregate, 7.3% plates aggregate, 12.5% pristine, 24% dendrite pristine, and 7.6% plate pristine. Applying the appropriate Ze-SR relationship in each snow category, we calculated a total of 87 mm water equivalent, differing from the total found by applying a unique Ze-SR. Our estimates were also benchmarked against a colocated Alter-shielded weighing gauge, resulting in a difference of 3% in the analyzed periods. Full article

Rockfall is a frequent hazard in mountainous areas, but risks can be mitigated by the construction of protection structures and slope modification. In this study, two rock slopes along a highway in western Colorado were monitored monthly using Terrestrial Laser Scanning (TLS) before, during, and after mitigation activities were performed to observe the influence of construction and weather variables on rockfall activity. Between September 2020 and February 2021, the slopes were mechanically scaled and reinforced using rock bolts, wire mesh, and polyurethane resin injection. We used a state-of-the-art TLS monitoring workflow to process the acquired point clouds, including semi-automated algorithms for alignment, change detection, clustering, and rockfall-volume calculation. Our initial hypotheses were that the slope-construction activities would have an immediate effect on the rockfall rate post-construction and would exhibit a decreased correlation with weather-related triggering factors, such as precipitation and freeze-thaw cycles. However, our observations did not confirm this, and instead an increase in post-construction rockfall was recorded, with strong correlation to weather-related triggering factors. While this does not suggest that the overall mitigation efforts were ineffective in reducing rockfall hazard and risk of large blocks, we did not find evidence that mitigation efforts influenced the rockfall hazard associated with the release of small- to medium-sized blocks (<1 m³). These results can be used to develop improved and tailored mitigation methods for rock slopes in the future. Full article

The airflow velocity pattern generated by a widely used non-catching precipitation gauge (the Thies laser precipitation monitor or LPM) when immersed in a wind field is investigated using computational fluid dynamics (CFD). The simulation numerically solves the unsteady Reynolds-averaged Navier–Stokes (URANS) equations and the setup is validated against dedicated wind tunnel measurements. The adopted k-ω shear stress transport (SST) turbulence model closely reproduces the flow pattern generated by the complex, non-axisymmetric outer geometry of the instrument. The airflow pattern near the measuring area varies with the wind direction, the most intense recirculating flow and turbulence being observed when the wind blows from the back of the instrument. Quantitative parameters are used to discuss the magnitude of the airflow perturbations with respect to the ideal configuration where the instrument is transparent to the wind. The generated airflow pattern is expected to induce some bias in operational measurements, especially in strong wind conditions. The proposed numerical simulation framework provides a basis to develop correction curves for the wind-induced bias of non-catching gauges, as a function of the undisturbed wind speed and direction. Full article

The fluidic sprinkler, a relatively new type of rotating sprinkler, has been the subject of quite a lot of research about its structural parameters, hydraulic characteristics, and water distribution profile, albeit under indoor conditions. The fluidic sprinkler’s performance in terms of water distribution profile and droplet size distribution pattern in wind has seen little investigation. To obtain information about its droplet size distribution in wind, the Thiess Clima Laser Precipitation Monitor was employed. Drop diameter, drop velocity, and the number of drops at varying distances from the fluidic sprinkler were measured in both wind and no wind at three operating pressures of 250, 300, and 350 kPa. The logistic model was adopted to fit a relationship between the drop diameter and the cumulative numeric frequency (CNF) and the cumulative volumetric frequency (CVF) values resulting in very high correlation coefficient (R²) values of above 0.99 for all conditions. At 250, 300, and 350 kPa, drops traveled 0.6, 1.0, and 1.3 m, respectively, farther in wind than in no wind along the direction of throw. Drops exhibited a spectrum of velocities and diameters at a given radial distance from the sprinkler. Up to two-thirds of the radius of throw, the proportion of drops with diameters ranging from 0.125 mm to 1.00 mm were above 80% at 300 and 350 kPa. Full article

Due to the intrinsic side-looking geometry of synthetic aperture radar (SAR), time series interferometric SAR is only able to monitor displacements in line-of-sight (LOS) direction, which limits the accuracy of displacement measurement in landslide monitoring. This is because the LOS displacement is only a three dimensional projection of real displacement of a certain ground object. Targeting at this problem, a precise digital elevation model (DEM) assisted slope displacement retrieval method is proposed and applied to a case study over the high and steep slope of the Dagushan open pit mine. In the case study, the precise DEM generated by laser scanning is first used to minimize topographic residuals in small baseline subsets analysis. Then, the LOS displacements are converted to slope direction with assistance of the precise DEM. By comparing with ground measurements, relative root mean square errors (RMSE) of the estimated slope displacements reach approximately 12–13% for the ascending orbit, and 5.4–9.2% for the descending orbit in our study area. In order to validate the experimental results, comparison with microseism monitoring results is also conducted. Moreover, both results have found that the largest slope displacements occur on the slope part, with elevations varying from −138 m to −210 m, which corresponds to the landslide area. Moreover, there is a certain correlation with precipitation, as revealed by the displacement time series. The outcome of this article shows that rock mass structure, lithology, and precipitation are main factors affecting the stability of high and steep mining slopes. Full article

The response of very small glaciers to climate changes is highly scattered and little known in comparison with larger ice bodies. In particular, small avalanche-fed and debris-covered glaciers lack mass balance series of sufficient length. In this paper we present 13 years of high-resolution observations over the Occidentale del Montasio Glacier, collected using Airborne Laser Scanning, Terrestrial Laser Scanning, and Structure from Motion Multi-View Stereo techniques for monitoring its geodetic mass balance and surface dynamics. The results have been analyzed jointly with meteorological variables, and compared to a sample of “reference” glaciers for the European Alps. From 2006 to 2019 the mass balance showed high interannual variability and an average rate much closer to zero than the average of the Alpine reference glaciers (−0.09 vs. −1.42 m water equivalent per year, respectively). This behavior can be explained by the high correlation between annual balance and solid precipitation, which displayed recent peaks. The air temperature is not significantly correlated with the mass balance, which is main controlled by avalanche activity, shadowing and debris cover. However, its rapid increase is progressively reducing the fraction of solid precipitation, and increasing the length of the ablation season. Full article