Search Results (64)

This study investigates the bond behavior of fabric-reinforced cementitious matrix (FRCM) composites with three common masonry substrates—solid clay bricks (SBs), perforated bricks (PBs), and concrete hollow blocks (HBs)—using knitted polyester grille (KPG) fabric. Through uniaxial tensile tests of the KPG fabric and FRCM system, along with single-lap and double-lap shear tests, the interfacial debonding modes, load-slip responses, and composite utilization ratio were evaluated. Key findings reveal that (i) SB and HB substrates predominantly exhibited fabric slippage (FS) or matrix–fabric (MF) debonding, while PB substrates consistently failed at the matrix–substrate (MS) interface, due to their smooth surface texture. (ii) Prism specimens with mortar joints showed enhanced interfacial friction, leading to higher load fluctuations compared to brick units. PB substrates demonstrated the lowest peak stress (69.64–74.33 MPa), while SB and HB achieved comparable peak stresses (133.91–155.95 MPa). (iii) The FRCM system only achieved a utilization rate of 12–30% in fabric and reinforcement systems. The debonding failure at the matrix–substrate interface is one of the reasons that cannot be ignored, and exploring methods to improve the bonding performance between the matrix–substrate interface is the next research direction. HB bricks have excellent bonding properties, and it is recommended to prioritize their use in retrofit applications, followed by SB bricks. These findings provide insights into optimizing the application of FRCM reinforcement systems in masonry structures. Full article

To investigate the microscopic mechanism of aging-induced “dewetting” at the matrix/filler interface in Nitrate Ester Plasticized Polyether (NEPE) propellant, this study decoupled the aging process into two factors: crosslinking density evolution and nitrate ester decomposition. Molecular dynamics (MD) simulations were employed to construct all-component matrix models and matrix/filler interface models with varying aging extents. Key parameters including crosslinking density, mechanical properties, free volume fraction, diffusion coefficients of the matrix, as well as interfacial binding energy and radial distribution function (RDF) were calculated to analyze the effects of both aging factors on “debonding”. The results indicate the following: 1. Increased crosslinking density enhances matrix rigidity, suppresses molecular mobility, and causes interfacial binding energy to initially rise then decline, peaking at 40% crosslinking degree. 2. Progressive nitrate ester decomposition expands free volume within the matrix, improves binder system mobility, and weakens nitrate ester-induced interfacial damage, thereby strengthening hydrogen bonding and van der Waals interactions at the interface. 3. The addition of a small amount of bonding agent improved the interfacial bonding energy but did not change the trend of the bonding energy with aging. Full article

The overall response of asphalt concrete under a subjected load is governed not only by the properties of its constituents but also by the interactions among them. In this paper, we focus on the numerical analysis of aggregate debonding, which is typically a phenomenon that precedes crack initiation. The interfacial transition zone plays a crucial role in the macroscopic performance of this material. Using image processing to reconstruct a specific sample microstructure, we carried out several finite element analyses to assess the impact of the debonding phenomenon on the general performance of asphalt concrete. Image segmentation algorithms were employed to accurately detect aggregate boundaries, followed by vectorization to describe their geometries. After applying a series of error-controlled geometry simplification procedures, the final microstructure was exported to the ABAQUS/Standard 2023 environment. A linear elastic solution for the reconstructed asphalt concrete sample was used as the reference solution. It was compared with linear viscoelastic solutions with a perfect bonding between constituents and, in the next step, with debonding allowed at aggregate–matrix interfaces. The latter phenomenon was analyzed by enforcing respective contact conditions between the aggregate and the bituminous matrix. It was found that introducing the viscoelastic material model for mastic resulted in a 142.72% increase in the vertical extreme displacement relative to the purely elastic solution. When debonding effects were additionally considered, this increase rose to 188.44%. The results confirm the necessity of debonding conditions to be introduced in reliable finite element analyses of asphalt concrete. Full article

Recycled carbon fiber, as a novel type of solid waste, possesses high tensile strength, structural stability, and low utilization rates. Recycling carbon fiber for use in cementitious materials presents an efficient solution. However, achieving good interfacial bonding between recycled carbon fiber and cementitious materials is crucial for its high-performance application in such materials. This study first characterizes the properties of recycled carbon fiber and, for the first time, tests the interfacial parameters between recycled carbon fiber and cement matrix through single-fiber pull-out tests. The results show that the surface of recycled carbon fiber, lacking active functional groups and being relatively smooth, leads to poorer interfacial bonding with the cement matrix compared to virgin carbon fiber. The interfacial bonding strength, interfacial friction bonding strength, and chemical debonding energy are 0.65 MPa, 0.47 MPa, and 0.36 J/m², respectively. Next, based on the theoretical model of interfacial mechanics, a single-fiber pull-out model was used to predict the bridging stress curve of recycled carbon fiber. The calculations show that the bridging stress of recycled carbon fiber at volume fractions of 0.16%, 0.3%, and 0.47% are 1.25 MPa, 2.18 MPa, and 3.40 MPa, respectively. Finally, tensile tests were conducted to investigate the tensile properties of cementitious materials reinforced with recycled carbon fiber. At various fiber contents, the recycled carbon fibers provided corresponding bridging stresses at crack sites, enhancing the tensile strength of the cementitious materials by 8.8~35.48%. Full article

Flexible pipe end fittings (EFs) transfer axial loads by embedding tensile armor within epoxy matrices. The integrity of bonding between the armor and resin profoundly influences the EF load-bearing capacity. This study investigated the debonding failure mechanism at the epoxy-resin–tensile-armor interface in flexible pipe end fittings through integrated experimental and numerical approaches. Combining tensile tests with digital image correlation (DIC) and cohesive zone modeling (CZM), the research quantified the impacts of interfacial defects and adhesive properties on structural integrity. Specimens with varying bond lengths (40–60 mm) and defect diameters (0–4 mm) revealed that defects significantly reduced load-bearing capacity, with larger defects exacerbating strain localization and accelerating failure. A dimensionless parameter, the defect-size-to-bond-length ratio ($\lambda =D/2L$), was proposed to unify defect impact analysis, demonstrating its nonlinear relationship with failure load reduction. High-toughness adhesives, such as Sikaforce^® 7752, mitigated defect sensitivity by redistributing stress concentrations, outperforming brittle alternatives like Araldite^® AV138. DIC captured real-time strain evolution and crack propagation, validating strain concentrations up to 3.2 at defect edges, while CZM simulations achieved high accuracy (errors: 3.0–7.2%) in predicting failure loads. Critical thresholds for λ (λ < 0.025 for negligible impact; λ > 0.05 requiring defect control or high-toughness adhesives) were established, providing actionable guidelines for manufacturing optimization and adhesive selection. By bridging experimental dynamics with predictive modeling, this work advances the design of robust deepwater energy infrastructure through defect management and material innovation, offering practical strategies to enhance structural reliability in critical applications. Full article

This study evaluates four widely used fracture simulation methods, comparing their computational expenses and implementation complexities within the finite element (FE) framework when employed on heterogeneous solids. Fracture methods considered encompass the intrinsic cohesive zone model (CZM) using zero-thickness cohesive interface elements (CIEs), the standard phase-field fracture (SPFM) approach, the cohesive phase-field fracture (CPFM) approach, and an innovative hybrid model. The hybrid approach combines the CPFM fracture method with the CZM, specifically applying the CZM within the interface zone. The finite element model studied is characterized by three specific phases: inclusions, matrix, and the interface zone. This case study serves as a potential template for meso- or micro-level simulations involving a variety of composite materials. The thorough assessment of these modeling techniques indicates that the CPFM approach stands out as the most effective computational model, provided that the thickness of the interface zone is not significantly smaller than that of the other phases. In materials like concrete, which contain interfaces within their microstructure, the interface thickness is notably small when compared to other phases. This leads to the hybrid model standing as the most authentic finite element model, utilizing CIEs within the interface to simulate interface debonding. A significant finding from this investigation is that within the CPFM method, for a specific interface thickness, convergence with the hybrid model can be observed. This suggests that the CPFM fracture method could serve as a unified fracture approach for multiphase materials when a specific interfacial thickness is used. In addition, this research provides valuable insights that can advance efforts to fine-tune material microstructures. An investigation of the influence of interfacial material properties, voids, and the spatial arrangement of inclusions shows a pronounced effect of these parameters on the fracture toughness of the material. Full article

Filler defects and matrix crosslinking degree are the main factors affecting the interfacial adhesion properties of propellants. Improving adhesion can significantly enhance debonding resistance. In this study, all-atom molecular dynamics (MD) simulations are employed to investigate the interfacial adsorption behavior and mechanisms between ammonium perchlorate (AP) fillers and a poly(3,3-bis-azidomethyl oxetane)-tetrahydrofuran (PBT) matrix. This study focuses on matrix crosslinking degree (70–90%), AP defects (width 20–40 Å), and temperature effects (200–1000 K) to analyze microscopic interfacial adsorption behavior, binding energy, and radial distribution function (RDF). The simulation results indicate that higher crosslinking of the PBT matrix enhances interfacial adsorption strength, but incomplete crosslinking reduces this strength. Defects on the AP surface affect interfacial adsorption by altering the contact area, and defects of 30 Å width can enhance adsorption. The analysis of temperature effects on binding energy and interface RDF reveals that binding energy and interface RDF fluctuate as the temperature increases. This study provides a microscopic perspective on the PBT matrix–AP interfacial adsorption mechanism and provides insights into the design of PBT azide propellant fuels. Full article

In order to investigate the interfacial bonding properties of high-strength steel stainless wire mesh-reinforced ECC (HSSWM-ECC) and concrete, a finite element model was established for two types of interfaces based on experimental research. The results show that the failure modes observed in the 21 groups of simulations can be classified into three categories: debonding failure, ECC extrusion failure and concrete splitting failure. The failure mode was mainly affected by the type of interface. The effective anchorage length is inversely proportional to the strength of the concrete and proportional to the stiffness and thickness of the HSSWM-ECC. The capacity of the roughening interface is positively correlated with the concrete strength and bonding length, but negatively correlated with the interfacial width ratio. Increasing both the number and width of grooves within the effective range enhances the interfacial capacity, whereas higher concrete strengths tend to reduce it. Based on the above results, calculation models for the effective anchorage length and bearing capacity were established separately for the two types of interfaces. The theoretical model for the interfacial bonding property between HSSWM-ECC and concrete has been refined. These advancements establish a theoretical groundwork for the design of concrete structures strengthened with HSSWM-ECC. Full article

This paper investigates the interface debonding behavior of graphene (G) on a calcium silicate hydrate (C-S-H) substrate using molecular dynamics (MD) simulations. The effect of interfacial water content on the debonding behavior of graphene on cement-based composites was studied. Simulation results reveal that there is only a van der Waals force between G and C-S-H; the interface bonding strength is weak; and the debonding properties (maximum peeling force (F_max) and work (W)) are low. The debonding energy of graphene decreases with an increase in interfacial water content, indicating that water intrusion will weaken the binding effect of G and C-S-H, and reduce the difficulty of graphene’s debonding on a C-S-H substrate. Exploring the adhesion behavior of graphene on C-S-H under the influence of humidity at the nanoscale is of great significance for understanding the basic adhesion mechanism, optimizing composite material properties, and promoting the development of related disciplines. Full article

Compacted graphite iron (CGI) attracts significant attention in the automotive industry thanks to its suitable thermomechanical properties and cost-effectiveness. A primary fracture mechanism at the microscale for CGI involves interfacial damage and debonding between graphite inclusions and its metallic matrix, which can occur under high-temperature service conditions due to a mismatch in the coefficients of thermal expansion between these two phases. Such microscopic interfacial damage can initiate macroscopic fractures in cast-iron components subjected to thermal loading. While this phenomenon was studied in various composites, there remains a lack of detailed information for CGI, especially related to the complex morphology of its graphite inclusions. This study investigates the influence of graphite morphology and type of matrix on the thermomechanical performance of CGI at high temperatures. A set of three-dimensional finite-element models were developed in the form of unit cells with a single graphite inclusion embedded within a cubic domain of the metallic matrix. Elastoplastic behaviour was assumed for both phases in the numerical simulations. The study is focused on the response of the constituents in CGI to pure thermal loading in order to explore the relationship between graphite morphology and fracture mechanisms. The findings aim to enhance understanding of how graphite morphology affects the behaviours of CGI under high-temperature conditions. Full article

The need for ending plastic waste and creating a circular economy has prompted significant interest in developing a new family of composite materials through recycling and recovery of waste resources (including bio-sourced materials). In this work, a family of natural fiber-reinforced plastic composites has been developed from paint pail waste recycled polypropylene (rPP) and waste wool fibers of different diameter and aspect ratio. Composites were fabricated by melt processing using polypropylene-graft-maleic anhydride as a compatibilizer. The internal morphology, interfacial and thermal characteristics, viscoelastic behavior, water sorption/wettability, and mechanical properties of composites were studied using electron microscopy, high-resolution synchrotron Fourier transform infrared microspectroscopy, thermal analysis, rheology, immersion test, contact angle measurement, tensile test and flexural test. The composite matrix exhibited an internal morphology of coalescent micro-droplets due to the presence of polyethylene and dry paint in the rPP phase. In general, the rheological and mechanical properties of the composites comprising higher-aspect-ratio (lower diameter) fibers exhibited relatively superior performance. About an 18% increase in tensile strength and a 39% increase in flexural strength were measured for composites with an optimal fiber loading of 10 wt.%. Interfacial debonding and fiber pull-out were observed as the main failure mechanism of the composites. The developed composites have potential for applications in automotive, decking, and building industries. Full article

This study aims to develop thermoplastic (TP) and thermoset (TS) based mixed matrix composite using design dependent physical compatibility. Using thermoplastic-based (PLA) skeletal lattices with diverse patterns (gyroid and grid) and different infill densities (10% and 20%) followed by infiltration of two different thermoset resin systems (epoxy and polyurethane-based) using a customized FDM 3D printer equipped with a resin dispensing unit, the optimised design and TP-TS material combination was established for best mechanical performance. Under uniaxial tensile stress, the failure modes of TP gyroid structures with polyurethane-based composites included ‘fiber pull-out’, interfacial debonding and fiber breakage, while epoxy based mixed matrix composites with all design variants demonstrated brittle failure. Higher elongation (higher area under curve) was observed in 20% infilled gyroid patterned composite with polyurethane matrix indicating the capability of operation in mechanical shock absorption application. Electron microscopy-based fractography analysis revealed that thermoset matrix properties governed the fracture modes for the thermoplastic phase. This work focused on the strategic optimisation of both toughness and stiffness of mixed matrix composite components for rapid fabrication of construction materials. Full article

Material extrusion (MEX) additive manufacturing has successfully fabricated assembly-free structures composed of different materials processed in the same manufacturing cycle. Materials with different mechanical properties can be employed for the fabrication of bio-inspired structures (i.e., stiff materials connected to soft materials), which are appealing for many fields, such as bio-medical and soft robotics. In the present paper, process parameters and 3D printing strategies are presented to improve the interfacial adhesion between carbon fiber-reinforced nylon (CFPA) and thermoplastic polyurethane (TPU), which are extruded in the same manufacturing cycle using a multi-material MEX setup. To achieve our goal, a double cantilever beam (DCB) test was used to evaluate the mode I fracture toughness. The results show that the application of a heating gun (assembled near the nozzle) provides a statistically significant increase in mean fracture toughness energy from 12.3 kJ/m² to 33.4 kJ/m². The underlying mechanism driving this finding was further investigated by quantifying porosity at the multi-material interface using an X-ray computed tomography (CT) system, in addition to quantifying thermal history. The results show that using both bead ironing and the hot air gun during the printing process leads to a reduction of 24% in the average void volume fraction. The findings from the DCB test and X-ray CT analysis agree well with the polymer healing theory, in which an increased thermal history led to an increased fracture toughness at the multi-material interface. Moreover, this study considers the thermal history of each printed layer to correlate the measured debonding energy with results obtained using the reptation theory. Full article

This study used a static bidirectional multifunctional loading system. The system conducted bidirectional compression tests on scaled specimens of slurry masonry schist under freeze–thaw cycling conditions. This study aimed to investigate the influence of bidirectional stress coupling with freeze–thaw cycles on the mechanical properties of slurry masonry schist. The results indicate that lateral pressure can increase the peak stress of slurry masonry schist, while freeze–thaw cycles have an adverse effect on the material’s internal pore structure, counteracting the gain effect of lateral pressure. This study also employed acoustic emission (AE) technology to analyze the evolution of slurry masonry schist failure characteristics. The findings reveal that freeze–thaw cycles accelerate the failure of slurry masonry schist during loading, and lateral pressure to some extent mitigates the damage development of slurry masonry schist. The synergistic effect of lateral pressure and freeze–thaw cycles alters the fracture mode of slurry masonry schist. Acoustic emission signal localization demonstrates numerous AE localization points in the interface transition zone, forming a coherent signal band where cracks propagate toward complete interface penetration. The crack extension process of the slurry masonry schist was investigated using the digital image correlation (DIC) method. The results indicated that macroscopic cracks formed in the strain localization zone, resulting in fracture damage to the specimens, with interfacial debonding identified as the primary failure mode for slurry masonry schist structures. Full article

This paper investigates the interfacial bonding behavior between high toughness resin concrete with steel wire mesh (HTRCS) and concrete. A total of five sets of fifteen double shear specimens were tested for parameters including concrete strength and material properties of HTRCS composites. The test results showed that the failure mode of DS1 specimens was partial debonding and fracture, and the rest of the specimens were the fracture of HTRCS. The concrete strength and reinforcement ratios of HTRCS composites were positively correlated with interfacial adhesion properties. When the concrete strength was increased from C30 to C40 and C50, the ultimate load increased by 43.4% and 43.2%, respectively. The ultimate load capacity increased by 32.1%, with the reinforcement ratio of HTRCS composites increasing from 1.05% to 1.83%. Moreover, the bonding slip model and the bearing capacity formula for the interface between HTRCS composites and concrete were proposed, and the calculation values were in good agreement with the test values, with an average value of 0.978. Full article