Search Results (65)

Carbon monoxide (CO) is a major toxic gas emitted from vehicle exhaust, industrial processes, and incomplete fuel combustion, posing serious environmental and health risks. Catalytic oxidation of CO into less harmful CO₂ is an effective strategy to reduce these emissions. In this study, we investigated the catalytic performance of platinum (Pt) single atoms doped on C₃N monolayers with various vacancy defects, including single carbon (C_V) and nitrogen (N_V) vacancies, using density functional theory (DFT) calculations. Our results demonstrate that Pt@N_V-C₃N exhibited the most favorable catalytic properties, with the highest O₂ adsorption energy (−3.07 eV). This performance significantly outperforms Pt atoms doped at other vacancies. It can be attributed to the strong binding between Pt and nitrogen vacancies, which contributes to its excellent resistance to Pt aggregation. CO oxidation on Pt@N_V-C₃N proceeds via the Eley–Rideal (ER2) mechanism with a low activation barrier of 0.41 eV for the rate-determining step, indicating high catalytic efficiency at low temperatures. These findings suggest that Pt@N_V-C₃N is a promising candidate for CO oxidation, contributing to developing cost-effective and environmentally sustainable catalysts. The strong binding of Pt atoms to the nitrogen vacancies prevents aggregation, ensuring the stability and durability of the catalyst. The kinetic modeling further revealed that the ER2 mechanism offers the highest reaction rate constants over a wide temperature range (273–700 K). The low activation energy barrier also facilitates CO oxidation at lower temperatures, addressing critical challenges in automotive and industrial pollution control. This study provides valuable theoretical insights for designing advanced single-atom catalysts for environmental remediation applications. Full article

This work systematically explores the impact of spark plug electrode number on engine performance and environmental effects, including noise, vibration, fuel consumption, and exhaust emissions. Indicators of combustion efficiency and mechanical health are engine vibration and noise; emissions directly affect ecological sustainability. Four-electrode spark plugs reduce vibration by 10%, noise by 5%, and fuel economy by 15%, according to experimental results showing they outperform single-electrode designs. Especially four-electrode designs also lower harmful hydrocarbon (HC) and carbon monoxide (CO) emissions by up to 20%, indicating more complete combustion and providing significant environmental benefits through lower air pollution and greenhouse gas emissions. Reduced exhaust temperatures of surface discharge plugs indicate better combustion efficiency and perhaps help with decarbonization. With poorer emission profiles, two- and three-electrode configurations raise fuel consumption, noise, and vibration. Reduced quenching effects, improved spark distribution, and accelerated flame propagation all help to explain enhanced combustion efficiency in multi-electrode designs and so affect the fundamental combustion chemistry. These results highlight the possibilities of four-electrode spark plugs to improve engine performance and reduce environmental impact, providing information for automotive engineers and legislators aiming at strict emissions standards (e.g., Euro 7) and sustainability targets. With an eye toward the chemical processes involved, additional study is required to investigate electrode geometry, material innovations, and lifetime environmental impacts. Full article

Motor vehicles in transport, as one of the important sectors of the economy, emit a significant amount of carbon dioxide and other products in the form of exhaust gases, which are harmful to human health. The emission of exhaust gases from motor vehicles is limited by appropriate regulations in accordance with environmental goals, such as the Paris Climate Agreement. Reduced emissions and fuel (energy) consumption is mainly achieved by applying modern technologies for the production of internal combustion engines; transitioning to cleaner fuels, such as renewable natural gas or biomethane; and using alternative propulsion systems. Biomethane stored in a liquid state in on-board reservoirs has advantages in truck transport, ships, and air traffic. The reason for this is due to the higher concentration of energy per unit volume of the reservoirs and the lower storage pressure and thus higher safety compared to the high-pressure storage option (compressed biomethane). The presented research is related to a proposition regarding the design of drive systems of city buses using biomethane as fuel in cases when fuel is stored on-board the vehicle as gas in a compressed aggregate state. In this study, the results of a calculation method regarding the roof-supporting structure of an experimental bus with gas reservoirs under higher pressure are discussed as well. This study also presents the possibility of reducing harmful emissions if biomethane is used instead of conventional fuels as a transitional solution to electric-powered vehicles. For the sake of comparison, it is suggested that the engaged energy and the amount of produced carbon dioxide emissions within the drive systems of different fuels are calculated according to the recommendations of the standard EN16258:2012. Full article

This study established a numerical model for ammonia leakage and diffusion in confined ship engine room spaces and validated its effectiveness through existing experiments. The research revealed the evolution patterns of ammonia cloud dispersion under various working conditions. Multi-parameter coupling analysis demonstrated that the combined effect of leakage source location and obstacle distribution alters the spatial configuration of gas clouds. When leakage jets directly impact obstacles, the resulting vortex structures maximize the coverage area of high-concentration ammonia near the ground. Ventilation system efficiency shows a significant negative correlation with hazardous zone volume. The hazardous zone volume was reduced by 50% when employing a bottom dual-side air intake combined with a top symmetric exhaust scheme, compared to the bottom single-side intake with an opposite-side top exhaust configuration. By enhancing the synergistic effect between longitudinal convection and top suction, harmful gas accumulation in lower spaces was effectively controlled. These findings not only provide a theoretical basis for ventilation system design in ammonia-fueled ships but also offer practical applications for risk prevention and control of maritime ammonia leakage. Full article

Limiting the fuel sulphur content (FSC) of ships can significantly reduce the harm caused by ship emissions, and analyzing ship exhaust gas to estimate FSC is a rapid, efficient, and low-cost monitoring method. To solve the difficulty in measuring FSC using sniffer equipment in a complex port area, a ship emission monitoring option for FSC measurement in complex environments is proposed here. First, the exhaust gas measurement data of a time series collected using the sniffer equipment were examined to determine the dataset that could be used to estimate FSC. Second, the background value of polluted gases in the environment was dynamically calculated to suppress the interference of various pollution sources. The gas-measured value series was then converted into a mean value series, and the peak points in the mean value series were automatically selected for the calculation of FSC. Finally, the wind speed, wind direction, automatic identification system information, plume diffusion model, and FSC results of ship targets around the equipment were correlated. Between June and August 2023, we conducted a field observation campaign at Ningbo Port, China, where 2624 ships were monitored. A comparison of the real and measured FSC values of eight ships showed that the system could accurately measure FSC at 0.10% (m/m) and 0.50% (m/m) levels despite measurement uncertainty that may be greater at a 0.01% (m/m) FSC level. The FSC statistics of 2624 ships showed that the FSC of small seagoing ships was relatively higher than that of other types of ships. This study proposes a monitoring option for ship emissions, designs and develops an associated system, and collects data to validate the effectiveness and accuracy of this option. This approach has been integrated into daily business operations within the maritime sector, significantly enhancing the efficiency of supervision in this field. Full article

Wastewater treatment plants traditionally dispose of sludge using the method of landfilling and incineration, with both being carbon-intensive and environmentally harmful. Converting sludge into energy or reusable materials avoids landfills or incineration, helping reduce the volume of waste and associated pollution. Sludge treatment with energy recovery can offset fossil fuel use, further reducing the carbon footprint of sewage treatment processes. This research explores ways to recover energy from sewage sludge, a byproduct of wastewater treatment that is often considered waste. Transforming sludge into valuable resources aligns with the principles of the circular economy, where waste streams are repurposed, minimizing environmental impact and enhancing resource efficiency. In this paper, a method is presented to reduce the volume of wastewater sludge by drying it in a hot flue gas stream at 700 °C. The energy of the exhaust gas is recovered in an organic Rankine cycle system, which powers the wastewater treatment facilities themselves, making them more self-sustaining. Full article

Nitrogen oxides are a kind of atmospheric pollutants that cause great harm to the environment and human body. The modified activated carbon fiber (ACF) has good adsorption performance for nitrogen oxides. The ACF was modified by nitric acid. The results of ACF modification were verified and evaluated by chemical and physical characterization of the materials. In the laboratory stage, the initial concentration of pollutants, the wind speed, the number of loading materials, and the number of regeneration times were used to explore the influence of modified ACF adsorption, and the change rule and the cause were analyzed. After procedures were carried out to study the adsorption of industrial exhaust gas, the concentration of nitrogen oxides before and after the modified ACF filter adsorption core was measured. The actual effect of industrial exhaust gas adsorption partially deviated from that of the laboratory. The results showed that the adsorption effect of nitric oxide increased with the increase in regeneration times, while the adsorption amount of nitric oxide by modified ACF in the laboratory stage gradually decreased with the increase in regeneration times. Full article

As stringent emission regulations and safety standards for explosion-proof diesel engines become more critical, the demand for efficient exhaust cooling systems has increased. Traditional cooling systems, typically relying on cooling and purification water tanks, have limitations in terms of safety, performance, and emissions control. To address these challenges, a novel dry exhaust gas cooling system was developed, incorporating a heat exchanger and exhaust dilution cooling device, replacing the conventional water-based cooling systems. This study explores the performance of the dry exhaust gas cooling system through a series of experiments including explosion-proof testing of the exhaust system, whole machine explosion-proof testing, exhaust temperature measurements, surface temperature evaluations, and exhaust gas composition analysis. The system’s performance was compared to both wet and combined dry + wet exhaust gas cooling systems. Results showed that the dry exhaust cooling system maintained its explosion-proof integrity during all tests, with the highest exhaust temperature at 68.5 °C and a surface temperature of 130.8 °C—both of which comply with safety standards. Notably, the dry exhaust system also demonstrated improved power output and reduced fuel consumption by over 4% compared to the other systems. Furthermore, it significantly lowered harmful exhaust emissions, reducing CO, HC, NOX, and CO₂ levels by 55%, 71%, 68%, and 82%, respectively, when compared to the wet exhaust cooling system. In comparison to the dry + wet system, these reductions were even more pronounced—63%, 75%, 66%, and 94%, respectively. The findings suggest that the dry exhaust gas cooling system offers a safer, more efficient, and environmentally friendly alternative to conventional exhaust cooling systems in explosion-proof diesel engines. Full article

With the rapid development of China’s economy, urban domestic sewage and industrial wastewater treatment efficiency has improved, resulting in a significant increase in sludge production. Thermal drying is essential for reducing, safely disposing of, and resourcefully utilizing sludge. However, this drying process inevitably releases harmful pollutants, posing potential environmental risks that necessitate careful management. This work focused on the thermal drying of municipal sludge at five temperature intervals (90–210 °C) and examined the impact of calcium oxide on sludge drying properties. The results indicated that higher temperatures increased sludge drying rates, with optimal efficiency achieved at a 15% calcium oxide addition. Online detection of NH₃, H₂S, CO, and CH₄ in the exhaust gas revealed that pollutant generation was temperature-dependent. While calcium oxide addition had no significant effect on CH₄ and CO emissions, it significantly inhibited the generation of H₂S and NH₃. This work provided crucial insights into optimizing sludge treatment, which improved drying efficiency and mitigated the release of hazardous pollutants, thereby reducing potential environmental and health risks associated with sludge disposal. Full article

This study investigates the chemical complexity and toxicity of volatile organic compounds (VOCs) emitted from national petrochemical industrial parks and their effects on air quality in an industrial area of Nanjing, China. Field measurements were conducted from 1 December 2022, to 17 April 2023, focusing on VOC concentrations and speciations, diurnal variations, ozone formation potential (OFP), source identification, and associated health risks. The results revealed an average total VOC (TVOC) concentration of 15.9 ± 12.9 ppb and an average OFP of 90.1 ± 109.5 μg m⁻³. Alkanes constituted the largest fraction of VOCs, accounting for 44.1%, while alkenes emerged as the primary contributors to OFP, comprising 52.8%. TVOC concentrations peaked before dawn, a pattern attributed to early morning industrial activities and nighttime heavy vehicle operations. During periods classified as clean, when ozone levels were below 160 μg m⁻³, both TVOC (15.9 ± 12.9 ppb) and OFP (90.4 ± 110.0 μg m⁻³) concentrations were higher than those during polluted hours. The analysis identified the key sources of VOC emissions, including automobile exhaust, oil and gas evaporation, and industrial discharges, with additional potential pollution sources identified in adjacent regions. Health risk assessments indicated that acrolein exceeded the non-carcinogenic risk threshold at specific times. Moreover, trichloromethane, 1,3-butadiene, 1,2-dichloroethane, and benzene were found to surpass the acceptable lifetime carcinogenic risk level (1 × 10⁻⁶) during certain periods. These findings highlight the urgent need for enhanced monitoring and regulatory measures aimed at mitigating VOC emissions and protecting public health in industrial areas. In the context of complex air pollution in urban industrial areas, policymakers should focus on controlling industrial and vehicle emissions, which can not only reduce secondary pollution, but also inhibit the harm of toxic substances on human health. Full article

The paper discusses a case study of obtaining an airline pilot license in integrated training—the so-called “from zero to Airline Transport Pilot License”. The environmental implications of simulator-based training were examined across multiple dimensions. Key areas of research include the reduction of harmful exhaust gases pollution associated with traditional flight training activities. Based on our analysis, it can be stated that increasing the use of Flight Simulation Training Devices in pilot training should be significant consideration. This approach brings many benefits, especially ecological ones. Changing the training program and increasing the use of flight simulators can result in a reduction of CO₂ emissions by up to 70%. Based on country specific electricity factors, CO₂ emissions during flight training in each EU country were calculated. Using Levelized Cost of Electricity average value to calculate training costs in EU countries depends on the mix of energy sources (wind, photovoltaics, carbon and gas). The findings highlight the significant ecological advantages of simulator-based training methods in mitigating the environmental footprint of aviation operations. By seeking to minimize environmental disruption and increase training efficiency, the adoption of simulators is a sustainable approach to pilot training that is consistent with global efforts to mitigate climate change and protect natural ecosystems. Full article

Phased injection of natural gas into internal combustion marine engines is a promising solution for optimizing performance and reducing harmful emissions, particularly unburned methane, a potent greenhouse gas. This innovative practice distinguishes itself from continuous injection because it allows for more precise control of the combustion process with only a slight increase in system complexity. By synchronizing the injection of natural gas with the intake and exhaust valve opening and closing times while also considering the gas path in the manifolds, methane release into the atmosphere is significantly reduced, making a substantial contribution to efforts to address climate change. Moreover, phased injection improves the efficiency of marine engines, resulting in reduced overall fuel consumption, lower fuel costs, and increased ship autonomy. This technology was tested on a single-cylinder, large-bore, four-stroke research engine designed for marine applications, operating in dual-fuel mode with diesel and natural gas. Performance was compared with that of the conventional continuous feeding method. Evaluation of the effect on equivalent CO₂ emissions indicates a potential reduction of up to approximately 20%. This reduction effectively brings greenhouse gas emissions below those of the diesel baseline case, especially when injection control is combined with supercharging control to optimize the air–fuel ratio. In this context, the boost pressure in DF was reduced from 3 to 1.5 bar compared with the FD case. Full article

As a highly energy-intensive and carbon-emitting industry with significant emissions of volatile organic compounds (VOCs), the petroleum and chemical industry is a major contributor to the global greenhouse effect and ozone layer destruction. Improper treatment of petrochemical waste gas (PWG) seriously harms human health and the natural environment. This study uses CiteSpace and VOSviewer to conduct a scientometric analysis of 1384 scholarly works on PWG and carbon sequestration published between 1981 and 2022, revealing the basic characteristics, knowledge base, research topic evolution, and research hotspots of the field. The results show the following: (1) In the early stages of the petrochemical industry, it was processed tail gas, plant leakage waste gas, and combustion flue gas that were investigated in PWG research. (2) Later, green environmental protection technology was widely studied in the field of PWG treatment, such as biotechnology, catalytic oxidation technology, membrane separation technology, etc., in order to achieve efficient, low energy consumption and low emissions of waste gas treatment, and the number of publications related to this topic has increased rapidly. In addition, researchers studied the internet of things and technology integration, such as the introduction of artificial intelligence, big data analysis, and other technologies, to improve the accuracy and efficiency of exhaust gas monitoring, control, and management. (3) The department has focused on how to reduce emissions by optimizing petrochemical process lines or improving energy efficiency. Emission reduction and low-carbon transition in the petrochemical industry will become the main trend in the future. Switching from renewable carbon to feedstock carbon derived from captured carbon dioxide, biomass, or recycled chemicals has become an attractive strategy to help curb emissions from the chemical industry. The results of our analysis can provide funding agencies and research groups with information to better understand the global trends and directions that have emerged in this field from 1981 to 2022 and serve as a reference for future research. Full article

This study aimed to investigate the interrelationships between key harmful emission components, nitrogen oxides (NO_x), and particulate numbers (PNs) in diesel engine exhaust and the control actuators of diesel engines. This research involved conducting a series of experiments under fixed parameters within an engine brake laboratory environment to elucidate these correlations. The objectives of this study were to conduct a comprehensive review of the relevant emissions technology literature and a comparative assessment of particle measurement methods based on dilution ratios and develop innovative aerosol preparation principles tailored to condensation particle measurement. Additionally, this research involved designing and implementing an aerosol preparation unit based on the newly developed principles, along with the creation of test cell control programs using the AVL PUMA Open TST editor interface and Visual Basic. Furthermore, this study was concerned with conducting evaluations of fixed-parameter engine dynamometer tests to explore the functional relationships between the emission of 10/23 nm particles, NO_x emissions, common rail pressure variations, and exhaust gas recirculation levels. This study aimed to enhance the understanding of diesel engine emissions dynamics and contribute valuable insights for developing more efficient and environmentally friendly engine control strategies. Full article

The usage of copper (Cu) ores containing low or no arsenic (As) has reduced, and Cu ores containing high levels of As have emerged as vital mineral resources for Cu extraction and processing. The quality of the Cu ores has decreased from 1.6% to approximately 1.0%. The proportion of As to Cu in 15% of Cu resources currently reaches 1:5. However, during the extraction and processing of Cu ores, As presents significant environmental harm. Hence, safely and effectively removing As is paramount in Cu smelting and processing, holding substantial importance in fostering environmentally sustainable practices within the Cu extraction and processing industry. This article consolidates the resource distribution of As-containing Cu (ACC) ores, comprehensively and systematically evaluates the present advancements in extracting techniques for these minerals, and identifies the challenges inherent in pyrometallurgical and wet processes for treating ACC deposits. Pyrometallurgy is a simple primary roasting technique and has widespread applicability in the treatment of various ACC minerals. Its disadvantages are the emission of exhaust gas and the high treatment costs associated with it. The wet arsenic removal method boasts advantages including minimal air pollution and a high resource recovery rate, significantly aiding in Cu concentrate recovery; its major drawback is the production of As-containing wastewater. The hydrometallurgical removal of As from ACC mines involves extracting As through leaching. Recently, biometallurgy has presented innovative solutions using specialized microorganisms to bioleach or bioabsorb As, but large-scale industrial applications still lack specific practical implementation. This review explores the underlying causes of the challenges encountered in processing ACC minerals. Additionally, it highlights pyrometallurgical roasting coupled with high-temperature filtration as a pivotal advancement in the extraction and processing of ACC ores. Full article