Search Results (8)

Marine coral sand–clay mixtures (MCCM) are promising green fill materials in civil engineering projects, where their strength characteristics play a vital role in ensuring structural safety and stability. To investigate these properties, a series of triaxial shear tests were performed under diverse conditions, including variations in asperity spacing, asperity height, the number of reinforcement layers, confining pressure, and axial strain. This experimental campaign yielded a robust strength dataset for MCCM. Utilizing this dataset, several predictive models were developed, including a standard Support Vector Machine (SVM), an SVM optimized via Genetic Algorithm (GA-SVM), an SVM enhanced by Particle Swarm Optimization (PSO-SVM), and a hybrid model incorporating Logical Development Algorithm preprocessing a SVM model (LDA-SVM). Among these models, the LDA-SVM model exhibited the best performance, achieving a test RMSE of 1.67245 and a correlation coefficient (R) of 0.996, demonstrating superior prediction accuracy and strong generalization ability. Sensitivity analyses revealed that asperity spacing, asperity height, and confining pressure are the most influential factors affecting MCCM strength. Moreover, an explicit empirical equation was derived from the LDA-SVM model, allowing practitioners to estimate strength without relying on complex machine learning tools. The results of this study offer practical guidance for the optimized design and safety evaluation of MCCM in civil engineering applications. Full article

Coral reefs are vital ecosystems facing rapid degradation. This research explores architectural design solutions for bio-enhancing modular prototypes to support coral attachment and growth. Inspired by coral polyps, nine biomimetic designs were created using Maya and Rhinoceros 3D to optimise surfaces for coral settlement. A total of 75 prototypes (15 × 15 cm) were fabricated, incorporating four materials—PETG, concrete, oyster concrete, and clay—and seven colour variations—sand, translucent green, translucent brown, red, pink, grey, and reddish. The findings indicate that 3D printing with PETG was the most efficient fabrication method but required structural support and long-term underwater testing, while oyster concrete demonstrated potential for self-sustaining structures. This study highlights the role of architectural design in marine restoration, promoting biodiversity and resource-efficient solutions. By integrating corals into the design, these structures can self-grow and adapt, reducing material consumption and long-term maintenance. Full article

Clay mineral authigenesis at continental margins plays an important role in global marine element cycles. However, despite being increasingly used as tracers for both modern and past oceanographic conditions, the behavior of the rare earth elements (REEs) and their isotopes during marine clay authigenesis still remains poorly known. In this study, we report on a detailed geochemical investigation of glauconite from the West African continental shelf, near the mouth of the Congo River. Elemental, neodymium, and hafnium isotope analyses were conducted on both acid leachate and separated clay-size fractions of glauconite pellets, in order to investigate the behavior of REE during the formation of authigenic clays. Our data indicate that kaolinite dissolution and subsequent Fe-bearing clay authigenesis act as a net source of REEs to seawater. We show that enhanced glauconitization, as inferred from increasing Fe and K contents, is accompanied by significant decoupling of the REE toward markedly LREE-enriched shale-normalized patterns in neoformed clay separates. Using both Nd and Hf isotopes and SEM observations, we rule out any seawater influence and argue that this shift primarily reflects the progressively overwhelming presence of insoluble nanocrystals of detrital LREE-rich phosphates, which are known to occur in close association with kaolinite in tropical soils. Due to their marked insolubility in surface environments, such nanocrystals can be preserved during kaolinite dissolution and subsequently incorporated into the aggregates of authigenic green clays forming the peloids. Most strikingly, we show that the combined influence of net REE loss (due to kaolinite dissolution) and decoupling (due to subsequent entrapment of inherited LREE-bearing accessory phases into neoformed clay minerals) is accompanied by preferential release of a dissolved REE fraction characterized by seawater-like distribution patterns. These findings reinforce the emerging view that clay mineral dissolution and authigenesis at continental margins possibly play a major role in marine REE cycling. Full article

The late Paleocene–early Eocene warm greenhouse conditions, characterized by elevated pCO₂ levels in the atmosphere and a dramatic increase in sea surface temperature, prompted abundant authigenic glauconite formation within the shallow marine sediments worldwide by lowering the net sedimentation rate, increasing organic productivity and expanding the oxygen minimum zones to shallow oceans. The early Eocene marginal marine Cambay Shale Formation experienced episodes of marine inundation represented by limestone–green shale alternations. The shales host abundant authigenic light-green, dark-green, and brown pellets. A detailed characterization of the pellets of the Valia and Vastan lignite mines, integrating the sedimentological, petrographical, mineralogical, and mineral geochemical data, suggests two distinct varieties of Fe–silicate formation, viz. glauconite and chamosite. While the glauconitic green pellets are ubiquitous to Valia and Vastan mines, brown chamosite pellets are confined within the basal part of the green shale facies alternating with fossiliferous limestone in the Vastan mine. The glauconites of the Valia mine manifest a ‘nascent’ to ‘slightly evolved’ maturation stage of glauconitization, whereas the glauconites of the Vastan mine represent the ‘evolved’ type. The limestone–green shale alternation in the Valia mine is overlain by a ~4 m-thick spherulitic mudstone facies comprising monomineralic sideritic spherulites, reflecting a pure FeCO₃ composition. The glauconites in the Cambay Shale Formation transformed from kaolinite-rich clay pellets under dys-oxic depositional conditions. The increasing anoxicity within the microenvironment, possibly amplified by the rapid oxidation of continent-derived organic matter, facilitated chamosite formation instead of glauconite. The increased freshwater influx into the marginal marine depositional environment resulted in immature, K-poor glauconites of the Valia mine. The formation of siderite spherulites overlying the limestone–green shale alternation relates to the beginning of the regressive phase of sedimentation. Full article

Ten detailed sections have been logged and studied from the “Infra-Cenomanian’’ to the Cenomanian–Turonian deposits in the Errachidia–Boudnib–Erfoud Basin between Tazzouguerte and Anounizme(SE Morocco). They show variations in their lithology and microfacies that reflect changes in the depositional environment from the base to the top of the sedimentary record. Indeed, depositional setting grades from a fluvial environment marked by sandstone deposits of the Ifezouane Formation to an alluvial plain and coastal lagoon environment comprising an alternation of red clay, gypsum, and green marl beds of the Aoufous Formation and, finally, towards shallow to moderately deep marine environments with the deposition of the carbonates of the Akrabou Formation. Correlations between the studied sections show variations in the thickness of strata throughout the basin. The variations recorded in the so-called “Infra-Cenomanian” series may be related to the structuration of the basement. The Cenomanian–Turonian carbonate platform shows deeper marine and thicker sediments towards the east, while it thins towards the west until its disappearance in Anounizme. This reflects the global Cenomanian–Turonian transgression in the Errachidia–Boudnib–Erfoud Basin from the eastern Tethyan realm towards the west. The regional correlation of the Errachidia–Boudnib–Erfoud Basin with the Ouarzazate and Agadir basins shows an eastward thinning of the Cenomanian–Turonian marine deposits of Agadir. This suggests the presence of a paleorelief at the Anounizme locality. This could be the boundary between the Errachidia–Boudnib–Erfoud Basin, with Tethyan influence, to the east and those of Ouarzazate and Agadir, with Atlantic affinity, to the west. Full article

Reaching the land-related UN Sustainable Development Goals (SDGs) and similar goals articulated by the EU Green Deal (GD) by 2030 presents a major challenge and requires a pragmatic approach focused on joint learning by land users (mostly farmers), researchers and other stakeholders in “Living Labs” and system experiments at experimental farms of research organizations. Defining specific indicators and thresholds for ecosystem services in line with land-related SDGs is crucial to establish “Lighthouses” that can act as inspiring examples if they meet the various thresholds. This exploratory paper discusses indicators and thresholds for an arable farm operating on marine, calcareous light clay soils in the Netherlands. Studies of a system experiment are used to discuss and test operational methodology to be widely applied when characterizing many “Living Labs” in future, as planned by the European Union. The important role of soils in contributing to ecosystem services is discussed in terms of soil health. Recommendations are made for innovative methodology to be associated with all land-related SDGs. Satisfying the thresholds of ecosystem services, which will vary by soil type, region and farm type, can be the basis for farm subsidies, such as the Common Agricultural Policy (CAP). Research on Living Labs and in system experiments has to be judged by different criteria than those associated with traditional linear research. The important contributions of soils to achieve ecosystem services are framed in terms of soil health and are the most effective way to promote soil science in a by now widely desired inter- and transdisciplinary context. Full article

An outbreak of harmful algal blooms (HABs) often leads to the death of fish and other marine organisms and causes serious losses to human economic activities. Modified clay (MC) technology is an effective way to control HABs. Although the material and preparation process are based on the premise of green and safety, the potential eco-environmental impacts of MC on non-target organisms should still have to receive attention before field applications can occur. Therefore, the effects of one commonly used modified clay, polyaluminum chloride-modified clay (PAC-MC), on the survival, growth, and oxidative stress of the marine medaka (Oryzias melastigma) were studied. The toxicity test results showed that the 96-h median lethal concentration (96-h LC₅₀) of PAC-MC for newly hatched medaka larvae was 5.204 g/L, which was much higher than the concentration used on site (4–10 t/km²). Within the concentration range of PAC-MC used in this experiment (≤2 g/L), the morphology, heart rate, growth, and aluminum content of larvae did not change with the increase in the modified clay concentration. Low concentrations of PAC-MC (≤0.5 g/L) did not significantly affect catalase (CAT) activity, superoxide dismutase (SOD) activity, peroxidase (POD) activity, and the content of malondialdehyde (MDA), but higher concentrations of PAC-MC (such as 2 g/L) caused oxidative damage to the larvae and increased the antioxidant enzyme activity of the larvae. The present study revealed that under an effective dosage for treating harmful algal blooms on site, PAC-MC had no adverse effects on the survival, growth, oxidative stress, and aluminum content of the newly hatched marine medaka, which provides a scientific basis for the field application of modified clay. Full article

Glaucony is a significant green marine facies in the northwestern passive margin of the Guadalquivir Basin (Spain), where glauconite formed authigenically on a sediment-starved continental shelf, with fecal pellets and benthic foraminiferal tests being the main glauconitized substrates. Results from a study using XRD, TGA-DSC, SEM-EDS, and EPMA have revealed that glauconite is remarkably heterogeneous in mineral composition and chemical maturity, even in a single grain, reflecting a complex interaction of micro-environmental factors, substrate influences and post-depositional alterations. In its early stage, the glauconitization process is consistent with the slow precipitation of a Fe-rich smectite phase, most likely intergrade between nontronite and Fe-montmorillonite end-members, which evolved to a regularly interstratified glauconite-smectite (Gl/S). The Fe-smectite-to-Gl/S transformation is interpreted as a diffusion-controlled reaction, involving sufficient Fe availability in pore water and the constant diffusive transport of seawater K⁺ and Mg²⁺ ions towards the substrate. The pelletal glauconite is actually a highly evolved Gl/S consisting almost totally of mica layers, with 0.74 ± 0.05 apfu of K⁺ in the interlayer, while the Gl/S occurring as replacements of foraminiferal tests contains a mean of 7% of expandable layers in the walls and 16% in the chamber fillings, due to rate-limited ion diffusion. Full article