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13 pages, 4342 KiB  
Article
Wholesale Destruction Inside a Marine Protected Area: Anchoring Impacts on Sciaphilic Communities and Coralligenous Concretions in the Eastern Mediterranean
by Carlos Jimenez, Magdalene Papatheodoulou, Vasilis Resaikos and Antonis Petrou
Water 2025, 17(14), 2092; https://doi.org/10.3390/w17142092 - 14 Jul 2025
Viewed by 590
Abstract
The marine habitats of the world’s oceans are being driven beyond their resilience. The ongoing biodiversity crisis is happening fast, within the lifespan of researchers trying to produce the information necessary for the conservation of habitats and marine ecosystems. Here, we report on [...] Read more.
The marine habitats of the world’s oceans are being driven beyond their resilience. The ongoing biodiversity crisis is happening fast, within the lifespan of researchers trying to produce the information necessary for the conservation of habitats and marine ecosystems. Here, we report on the destruction of sciaphilic sessile communities and coralligenous concretions produced by the anchoring of a high-tonnage vessel inside a Marine Protected Area in Cyprus. The damage from the anchors and the chains consisted of the dislodgement of large boulders that were dragged or rolled over the seafloor, increasing the breakage and further dislodgement of more boulders; many were left upside-down. The biological communities that thrived in the dark environments below the boulders were directly exposed to high irradiance levels and went through a slow mortality and decaying process, most probably due to a combination of several deterioration agents, such as exposure to direct sunlight, predation, mucilage aggregates, and cyanobacterial blooms. The enforcement of regulatory measures for anchoring and transit in the MPA is necessary to prevent similar destruction. Given the extent of the irreversible damage to these sciaphilic communities, our study is, unfortunately, another environmental post-mortem contribution. Full article
(This article belongs to the Special Issue Effect of Human Activities on Marine Ecosystems)
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30 pages, 5513 KiB  
Article
Quantitative Biofacies Analysis of Upper Oligocene Reef-Coral Neritic Carbonates (Southern Pakistan)
by Luca Mariani, Giovanni Coletti, Mubashir Ali, Mahmood Iqbal, Muhammad Shumail, Hafiz Ahmed Raza Hassan and Francesca R. Bosellini
Geosciences 2025, 15(4), 129; https://doi.org/10.3390/geosciences15040129 - 1 Apr 2025
Viewed by 694
Abstract
This study examines four shallow-water, reef-coral-bearing carbonate successions belonging to the Jhill Limestone Unit of the Gaj Formation, exposed in the area near Karachi (southern Pakistan). Sixty-two samples were collected for the quantitative analysis of the skeletal and foraminiferal assemblages. The analysis of [...] Read more.
This study examines four shallow-water, reef-coral-bearing carbonate successions belonging to the Jhill Limestone Unit of the Gaj Formation, exposed in the area near Karachi (southern Pakistan). Sixty-two samples were collected for the quantitative analysis of the skeletal and foraminiferal assemblages. The analysis of large benthic foraminifera suggests a placement within the late Oligocene, characterized by the setup of the Late Oligocene Warming Event. Thanks to quantitative analyses and multivariate statistics, three biofacies were identified: (1) the reef coral biofacies (BFA), indicative of a sheltered, shallow-water environment above fair-weather wave base; (2) the coralline algal biofacies (BFB), deposited within a mesophotic setting and representing the deepest biofacies among the three recognized ones; and (3) the large benthic foraminiferal and coralline algal biofacies (BFC), subdivided into two sub-biofacies, namely (a) the miogypsinid, thin and flat large benthic foraminiferal and coralline algal sub-biofacies (BFC1), indicative of deeper setting, comprised between BFA and BFB, and (b) the miogypsinid and coralline algal sub-biofacies (BFC2), indicative of shallower settings than BFC1, and bearing evidence of paleo-seagrass meadows. All these biofacies were developed within the photic zone, in a relatively flat seafloor punctuated by patch reefs and seagrass meadows and characterized by a notable nutrient influx. Foraminiferal-based experimental paleobathymetric parameters, including the lepidocyclinids/miogypsinids, the flat nummulitids/lepidocyclinids, and the hyaline/porcelaneous foraminifera ratios, were tested and confirmed as reliable tools for paleodepth and paleoenvironmental reconstructions. Full article
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28 pages, 26849 KiB  
Article
Taphonomy of a Mysticete Whale from the Lower Pliocene of the Coast of Cádiz (Spain)
by Giulia Bosio, Ildefonso Bajo-Campos, Alberto Collareta, Sergio Ros-Montoya, Daniel de la Torre, Giovanni Coletti and Giovanni Bianucci
J. Mar. Sci. Eng. 2024, 12(1), 17; https://doi.org/10.3390/jmse12010017 - 20 Dec 2023
Viewed by 3883
Abstract
A fossil mysticete was discovered along the southwestern coast of Spain, occurring in a block detached from the Neogene deposits exposed along a coastal cliff at the locality of Conil de la Frontera (Cádiz, Spain). These deposits range from Pliocene to Pleistocene in [...] Read more.
A fossil mysticete was discovered along the southwestern coast of Spain, occurring in a block detached from the Neogene deposits exposed along a coastal cliff at the locality of Conil de la Frontera (Cádiz, Spain). These deposits range from Pliocene to Pleistocene in age and include shallow-marine, mixed carbonate–siliciclastic sediments, with the whale being found in occurrence of a stratigraphic unconformity marked by Thalassinoides burrows. 87Sr/86Sr analyses on oyster shells associated with the skeleton suggest an Early Pliocene age, in agreement with the age of the lowermost unit cropping out at the study site. The studied cetacean specimen consists of an articulated, almost complete balaenopteroid skeleton exposed in the field dorsal side up; being contained in an upside-down block, however, it is preserved in ventral disposition. Bones exhibit a low degree of preservation of the cortical bone tissue, which locally features shark bite marks and Osedax traces as well as abundant encrustations of barnacles and ostreids. Two shark teeth were also found near the skeleton. Bones have preserved their main histological features, even though they locally exhibit microcracks, dissolution, substitution by Fe oxides, and microborings. Sediment particles and late diagenetic cements fill the medullary cavities. We propose that the whale carcass experienced refloating before sinking to the seafloor and that the skeleton was probably exposed on the seafloor for some time before being eventually buried. Full article
(This article belongs to the Section Geological Oceanography)
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21 pages, 10837 KiB  
Article
Holocene Glaucony from the Guadiana Shelf, Northern Gulf of Cadiz (SW Iberia): New Genetic Insights in a Sequence Stratigraphy Context
by Adrián López-Quirós, Francisco José Lobo, Isabel Mendes and Fernando Nieto
Minerals 2023, 13(2), 177; https://doi.org/10.3390/min13020177 - 26 Jan 2023
Cited by 8 | Viewed by 2904
Abstract
Glaucony occurrences have been reported both from exposed transgressive and overlying highstand system tracts. However, its occurrences within highstand deposits are often invoked as the result of underlying condensed section reworking. Detailed textural, mineralogical and geochemical reports of glaucony grains in highstand deposits [...] Read more.
Glaucony occurrences have been reported both from exposed transgressive and overlying highstand system tracts. However, its occurrences within highstand deposits are often invoked as the result of underlying condensed section reworking. Detailed textural, mineralogical and geochemical reports of glaucony grains in highstand deposits remain elusive. The northern Gulf of Cadiz shelf (SW Iberia) offers a unique opportunity to investigate late Holocene glaucony authigenesis in a well-documented time-stratigraphic context, where transgressive deposits are locally exposed on the seafloor and are laterally draped by highstand muddy deposits. In this study, glaucony grains extracted from a core retrieved from a highstand muddy depocenter off the Guadiana River were investigated by means of digital microscopy, X-ray diffraction (XRD), and electron microscopic methods (FESEM-EDX and TEM-HRTEM). To better constrain the glaucony origin (autochthonous vs. allochthonous) in highstand muddy deposits, glaucony grains from surficial samples—taken from exposed transgressive deposits—were also investigated. Glauconitization in the studied core can be largely attributed to the replacement of faecal pellets from c. ~4.2–1.0 cal. ka BP. Both XRD and TEM-HRTEM analyses indicate that glaucony consists mainly of an R1, with a minor presence of R0, smectite-rich (nontronite) glauconite-smectite mixed-layer silicate, made up of 35–75% glauconitic layers and 65–25% of interstratified smectite layers. At the mineral lattice level, minor individual 7Å layers (berthierine) were also identified by HRTEM. Shallow radial cracks at the pellet surface, along with globular and vermiform-like biomorphic to low packing density lamellar-flaky nanostructures, mineralogical properties, and K-poor content (average 0.4 atoms p.f.u.) indicate a scarcely mature glauconitization process, attesting to formation of the grains in situ (autochthonous). Glaucony grains from exposed transgressive deposits, i.e., in the tests of calcareous benthic foraminifera, do not share a genetic relationship with the grains investigated in the highstand deposits, thus supporting the autochthonous origin of glaucony within the highstand deposits. Our combined dataset provides evidence of a multiphase history for autochthonous glaucony formation in the Guadiana shelf, as its genesis is traced to both transgressive and highstand conditions. While eustatic sea-level changes favoured glaucony formation under transgressive conditions, factors such as protracted low sediment supply and the establishment of a strong nutrient-rich upwelling system in the study area promoted glaucony development during late Holocene highstand conditions. Full article
(This article belongs to the Special Issue Formation and Evolution of Glauconite. New Scale Approach)
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24 pages, 12299 KiB  
Article
New Data for the Internal Structure of Ultramafic Hosted Seafloor Massive Sulfides (SMS) Deposits: Case Study of the Semenov-5 Hydrothermal Field (13°31′ N, MAR)
by Anna Firstova, Georgy Cherkashov, Tamara Stepanova, Anna Sukhanova, Irina Poroshina and Victor Bel’tenev
Minerals 2022, 12(12), 1593; https://doi.org/10.3390/min12121593 - 12 Dec 2022
Cited by 9 | Viewed by 2816
Abstract
The internal structure of Seafloor Massive Sulfides (SMS) deposits is one of the most important and complex issues facing the study of modern hydrothermal ore systems. The Semenov-5 hydrothermal field is a unique area where mass wasting on the slope of the oceanic [...] Read more.
The internal structure of Seafloor Massive Sulfides (SMS) deposits is one of the most important and complex issues facing the study of modern hydrothermal ore systems. The Semenov-5 hydrothermal field is a unique area where mass wasting on the slope of the oceanic core complex (OCC) structure exposes the subsurface portion of the deposit and offers an exceptional opportunity to observe massive sulfides that have formed not only on the seafloor but in sub-seafloor zones as well. This paper examines the internal structure of the OCC-related Semenov-5 hydrothermal field along with analysis of the mineralogy and chemistry of different parts of sulfide deposit. The seafloor deposit is comprised of pyrite, marcasite, hematite, goethite, lepidocrocite, rare pyrrhotite, isocubanite and Co-rich pyrite. Sulfide chemistry indicates the prevailing influence of ultramafics on their composition irrespective of the spatial relation with basalt lavas. Sub-seafloor mineralization is associated with ultramafic rocks and is represented by massive and disseminated sulfides. Pyrrhotite, isocubanite, pyrite, chalcopyrite, Co-rich pyrite, quartz with rutile, quarts with hematite and Cr-spinels are fixed in massive subseafloor mineralization. The presence of Cr-spinels as well as a very high Cr content are regarded as indicators of the metasomatic nature of this part of the deposit that had formed as a result of ultramafic replacement. As a result, three zones of a hydrothermal ore-forming system have been described: massive sulfides precipitated from hot vents on the surface of the seafloor, massive sulfides formed due to replacement of ultramafics below the seafloor and disseminated sulfide mineralization-filled cracks in hosted rocks which have formed stockwork around metasomatic massive sulfides. Despite differences in the mineral and geochemical composition of sub-seafloor and seafloor mineralization, all minerals subject to the sample formed as a consequence of fluid circulation in ultramafic rocks and were linked by a common ore-forming process. Full article
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22 pages, 3552 KiB  
Article
Allopatric Lineage Divergence of the East Asian Endemic Herb Conandron ramondioides Inferred from Low-Copy Nuclear and Plastid Markers
by Kuan-Ting Hsin, Hao-Chih Kuo, Goro Kokubugata, Michael Möller, Chun-Neng Wang and Yi-Sheng Cheng
Int. J. Mol. Sci. 2022, 23(23), 14932; https://doi.org/10.3390/ijms232314932 - 29 Nov 2022
Viewed by 2009
Abstract
The evolutionary histories of ornamental plants have been receiving only limited attention. We examined the origin and divergence processes of an East Asian endemic ornamental plant, Conandron ramondioides. C. ramondioides is an understory herb occurring in primary forests, which has been grouped [...] Read more.
The evolutionary histories of ornamental plants have been receiving only limited attention. We examined the origin and divergence processes of an East Asian endemic ornamental plant, Conandron ramondioides. C. ramondioides is an understory herb occurring in primary forests, which has been grouped into two varieties. We reconstructed the evolutionary and population demography history of C. ramondioides to infer its divergence process. Nuclear and chloroplast DNA sequences were obtained from 21 Conandron populations on both sides of the East China Sea (ECS) to explore its genetic diversity, structure, and population differentiation. Interestingly, the reconstructed phylogeny indicated that the populations should be classified into three clades corresponding to geographical regions: the Japan (Honshu+Shikoku) clade, the Taiwan–Iriomote clade, and the Southeast China clade. Lineage divergence between the Japan clade and the Taiwan–Iriomote and Southeast China clades occured 1.14 MYA (95% HPD: 0.82–3.86), followed by divergence between the Taiwan–Iriomote and Southeast China clades approximately 0.75 MYA (95% HPD: 0.45–1.3). Furthermore, corolla traits (floral lobe length to tube length ratios) correlated with geographical distributions. Moreover, restricted gene flow was detected among clades. Lastly, the lack of potential dispersal routes across an exposed ECS seafloor during the last glacial maximum suggests that migration among the Conandron clades was unlikely. In summary, the extant Conandron exhibits a disjunct distribution pattern as a result of vicariance rather than long-distance dispersal. We propose that allopatric divergence has occurred in C. ramondioides since the Pleistocene. Our findings highlight the critical influence of species’ biological characteristics on shaping lineage diversification of East Asian relic herb species during climate oscillations since the Quaternary. Full article
(This article belongs to the Special Issue From Functional Genomics to Biotechnology in Ornamental Plant)
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25 pages, 6343 KiB  
Article
Estimation of Scour Propagation Rates around Pipelines While Considering Simultaneous Effects of Waves and Currents Conditions
by Mohammad Najafzadeh, Giuseppe Oliveto and Farshad Saberi-Movahed
Water 2022, 14(10), 1589; https://doi.org/10.3390/w14101589 - 16 May 2022
Cited by 11 | Viewed by 2619
Abstract
Seabed offshore pipelines are widely applied to carry fluid over long distances of the seafloor. The design of offshore pipelines is conducted to bear quite a few environmental loading circumstances in order to provide a well-guarded and reliable fluid transition. Fluid leakage and [...] Read more.
Seabed offshore pipelines are widely applied to carry fluid over long distances of the seafloor. The design of offshore pipelines is conducted to bear quite a few environmental loading circumstances in order to provide a well-guarded and reliable fluid transition. Fluid leakage and pipeline vibration due to a failure of the pipeline are the prime causes of accidental catastrophes. Scour phenomena occur around offshore pipelines due to currents and/or wave conditions, consequently causing the susceptibility to pipeline failure. Then, scouring propagation rates require to be studied in three dimensions, namely beneath and normal to the offshore pipeline and the longitudinal direction of itself. In this research, Artificial Intelligent (AI) models are used to derive new regression equations based on the laboratory data for the estimation of 3D scour propagation patterns while seafloor offshore pipelines are exposed to simultaneous impacts of currents and waves. In this way, chiefly based on the experimental investigations conducted by Cheng and colleagues, seven sets of dimensional parameters were given in terms of the Shields’ parameter due to currents and waves, the Keulegan–Carpenter number, the ratio of embedment depth to pipeline diameter, the ratio of orbital velocity to current velocity, and the wave/current angle of attack. Dimensionless parameters were used to provide regression-based equations to evaluate scour propagation rates in three dimensions. The performance of AI models was evaluated by various statistical measures. The model based on our proposed equations performed better than the reported models in the literature. Even more importantly, we indicated that our model inherently has a reliable physical consistency for variations of dimensionless parameters against the scour propagation patterns. Full article
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13 pages, 3767 KiB  
Article
Monitoring and Mapping of Soil Salinity on the Exposed Seabed of the Aral Sea, Central Asia
by Zihao Duan, Xiaolei Wang and Lin Sun
Water 2022, 14(9), 1438; https://doi.org/10.3390/w14091438 - 30 Apr 2022
Cited by 21 | Viewed by 3990
Abstract
The incredible drying of the Aral Sea has resulted in a large area of exposed seafloor with saline soils, which has led to catastrophic consequences. This study investigated ground-truth soil salinity data and used Landsat data to map the soil salinity distribution of [...] Read more.
The incredible drying of the Aral Sea has resulted in a large area of exposed seafloor with saline soils, which has led to catastrophic consequences. This study investigated ground-truth soil salinity data and used Landsat data to map the soil salinity distribution of the exposed seabed of the Aral Sea from 1960 onwards. The soil salinity distribution, with the depth from 0 cm to 100 cm, was analyzed. The correlation analysis was applied to find the best performance index in describing soil salinity changes. The results showed that ground-truth data of topsoil salinity (depth of 0−5 cm) exhibited a significantly strong correlation with soil salinity index 4 (SI4) among seven indices, where the Pearson correlation coefficient (r) was up to 0.92. Based on the relationship between soil salinity sampling data and SI4, a linear regression model was employed to determine the capability of evaluating the soil salinity distribution of the Aral Sea with the coefficient of determination (R2), root mean squared error (RMSE), and ratio of performance to deviation (RPD) values of 0.84 and 0.86 dS m−1 and 2.36, respectively. The SI4 performed well and was used to predict the soil salinity distribution on the exposed seabed. The distribution showed that soil salinity increased from the former to current shoreline. In the North Aral Sea, compared to 1986, the water area remained stable, accounting for 50.3% in 2020, and the soil salinization level was relatively low. However, the moderately and slightly saline areas dominated 73.8% and 7.5% of the South Aral Sea in 2020, with an increase of 53% and 6% transformed from the water area. The area of salinized soils dramatically increased. The strongly and extremely saline areas were mainly located in the northeastern part of the eastern basin and western part of Vozrozhdeniya Island, respectively, and were the main source of salt-dust storms. These results support the dynamic monitoring and distribution patterns of soil salinization in the Aral Sea. Full article
(This article belongs to the Section Soil and Water)
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16 pages, 3189 KiB  
Article
New Insights into a Mediterranean Sea Benthic Habitat: High Diversity of Epiphytic Bryozoan Assemblages on Phyllophora crispa (Rhodophyta) Mats
by Felix Ivo Rossbach, Edoardo Casoli, Julia Plewka, Neele Schmidt and Christian Wild
Diversity 2022, 14(5), 346; https://doi.org/10.3390/d14050346 - 28 Apr 2022
Cited by 3 | Viewed by 2808
Abstract
With its geographically isolated location and geological history, the Mediterranean Sea harbors well-known biodiversity hotspots, such as Posidonia oceanica seagrass meadows. Recently, long-living mats formed by the fleshy red alga Phyllophora crispa have been described to be associated with a high diversity of [...] Read more.
With its geographically isolated location and geological history, the Mediterranean Sea harbors well-known biodiversity hotspots, such as Posidonia oceanica seagrass meadows. Recently, long-living mats formed by the fleshy red alga Phyllophora crispa have been described to be associated with a high diversity of sessile invertebrates in the Tyrrhenian Sea. One of the key taxa among these sessile invertebrates are bryozoans: their abundance, diversity, and spatial distribution in P. crispa mats represent a gap in scientific knowledge. Thus, we conducted a pilot study on bryozoan assemblages associated with P. crispa mats around Giglio Island (Tuscan Archipelago, Italy) in 2018, followed by a comparative study on four sites distributed around the island in the subsequent year, 2019. We compared these findings to bryozoan abundance and diversity on P. oceanica shoots and leaves during the second expedition. The findings revealed more than 46 families, with a significantly higher number of taxa identified in P. crispa mats (33) than in P. oceanica meadows (29). The Shannon diversity index was similar between P. crispa and P. oceanica shoots, while Pielou’s evenness index was lower in P. crispa mats. The most abundant families reported across all habitats were Crisiidae, Aetidae, and Lichenoporidae; but the most abundant family on P. crispa was Chlidoniidae (Chlidonia pyriformis). The assemblages associated with P. crispa differed among sites, with higher abundances but lower diversity on the exposed southernmost site. The total bryozoan abundance was significantly higher on P. crispa (average 2.83 × 106 ± 1.99 × 106 colonies per m2 seafloor) compared to P. oceanica meadows (average 0.54 × 106 ± 0.34 × 106 colonies per m2 seafloor). Our results show a high diversity of bryozoans on P. crispa thalli compared to P. oceanica meadows, which was consistent throughout the study. These findings confirm the value of the red alga-generated habitat for associated bryozoans and may have implications for future biodiversity assessments and conservation measures. Full article
(This article belongs to the Special Issue Marine Biodiversity and Ecosystems Management)
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24 pages, 2991 KiB  
Review
Vestiges of the Pre-Caledonian Passive Margin of Baltica in the Scandinavian Caledonides: Overview, Revisions and Control on the Structure of the Mountain Belt
by Torgeir B. Andersen, Johannes Jakob, Hans Jørgen Kjøll and Christian Tegner
Geosciences 2022, 12(2), 57; https://doi.org/10.3390/geosciences12020057 - 25 Jan 2022
Cited by 9 | Viewed by 4121
Abstract
The Pre-Caledonian margin of Baltica has been outlined as a tapering wedge with increasing magmatism towards the ocean–continent transition. It is, however, well known that margins are complex, with different and diachronous evolution along and across strike. Baltica’s vestiges in the Scandes have [...] Read more.
The Pre-Caledonian margin of Baltica has been outlined as a tapering wedge with increasing magmatism towards the ocean–continent transition. It is, however, well known that margins are complex, with different and diachronous evolution along and across strike. Baltica’s vestiges in the Scandes have complexities akin to modern margins. It included a microcontinent and magma-poor hyperextended and magma-rich segments. It was probably up to 1500 km wide before distal parts were affected by plate convergence. Characteristic features are exhumed mantle peridotites and their detrital equivalents, some exposed to the seafloor by the pre-orogenic hyperextension. A major change in the architecture of the mountain belt occurred across the NW–SE trending Sveconorwegian front in the Baltican basement. This coincided with the NE termination of the Jotun-Lindås-Dalsfjord basement nappes, the remains of the Jotun Microcontinent (JMC) formed by hyperextension prior to the orogeny. Mantle with ophicalcite breccias exhumed by hyperextension are covered by deep-marine sediments and local conglomerates. Baltican basement slivers are common in the transitional crust basins. Outboard the JMC, the margin was magma-rich. The main break-up magmatism at 605 ± 10 Ma was part of the vast Central Iapetus Magmatic Province. The along-strike heterogeneity of the margin controlled diachronous and contrasting tectonic evolution during the later Caledonian plate convergence and collision. Full article
(This article belongs to the Special Issue Evolution of Modern and Ancient Orogenic Belts)
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24 pages, 19382 KiB  
Article
A Multidisciplinary Approach for the Mapping, Automatic Detection and Morphometric Analysis of Ancient Submerged Coastal Installations: The Case Study of the Ancient Aegina Harbour Complex
by Nikos Georgiou, Xenophon Dimas, Elias Fakiris, Dimitris Christodoulou, Maria Geraga, Despina Koutsoumpa, Kalliopi Baika, Pari Kalamara, George Ferentinos and George Papatheodorou
Remote Sens. 2021, 13(21), 4462; https://doi.org/10.3390/rs13214462 - 6 Nov 2021
Cited by 10 | Viewed by 4492
Abstract
The documentation of underwater cultural heritage (UCH) is the basis for sustainable maritime development including its protection, preservation, and incorporation in coastal zone management plans. In this study, we present a multidisciplinary, non-intrusive downscale approach for the documentation of UCH implemented on the [...] Read more.
The documentation of underwater cultural heritage (UCH) is the basis for sustainable maritime development including its protection, preservation, and incorporation in coastal zone management plans. In this study, we present a multidisciplinary, non-intrusive downscale approach for the documentation of UCH implemented on the coastal area of Aegina Island, Greece, where a unique submerged harbour complex is preserved. This approach succeeded in obtaining information that serves both geomorphological and archaeological purposes in a time- and cost-effective way, while obtaining information of centimeters to millimeters scale. The geomorphology of the area was mapped in detail through marine geophysical means while ancient submerged conical rubble structures and breakwaters were documented using automatic seafloor segmentation techniques, revealing previously unknown sites of archaeological interest. The structures’ parameters were extracted from the acoustic data to analyze their morphometry, while photogrammetry was realized using a Remotely Operated Vehicle to expose their micro-structure. The spatial distribution of the structures revealed the construction of a well-planned harbour complex with multiple passages and different possible functionalities. Finally, through the structures’ morphometric analysis (geometry and terrain statistical parameters) their preservation status was revealed, demonstrating the anthropogenic impact on the submerged ancient structures due to the modern harbor activity. Full article
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19 pages, 39646 KiB  
Article
Pre-Alpine Tectono-Stratigraphic Reconstruction of the Jurassic Tethys in the High-Pressure Internal Piedmont Zone (Stura di Viù Valley, Western Alps)
by Marcello De Togni, Marco Gattiglio, Stefano Ghignone and Andrea Festa
Minerals 2021, 11(4), 361; https://doi.org/10.3390/min11040361 - 30 Mar 2021
Cited by 13 | Viewed by 2651
Abstract
We present a detailed description of the tectono-stratigraphic architecture of the eclogite-facies Internal Piedmont Zone (IPZ) metaophiolite, exposed in the Lanzo Valleys (Western Alps), which represents the remnant of the Jurassic Alpine Tethys. Seafloor spreading and mantle exhumation processes related to the Alpine [...] Read more.
We present a detailed description of the tectono-stratigraphic architecture of the eclogite-facies Internal Piedmont Zone (IPZ) metaophiolite, exposed in the Lanzo Valleys (Western Alps), which represents the remnant of the Jurassic Alpine Tethys. Seafloor spreading and mantle exhumation processes related to the Alpine Tethys evolution strongly conditioned the intra-oceanic depositional setting, which resulted in an articulated physiography and a heterogeneous stratigraphic succession above the exhumed serpentinized mantle. “Complete” and “reduced” successions were recognized, reflecting deposition in morphological or structural lows and highs, respectively. The “complete” succession consists of quartzite, followed by marble and calcschist. The “reduced” succession differs for the unconformable contact of the calcschist directly above mantle rocks, lacking quartzite and gray marble. The serpentinite at the base of this succession is intruded by metagabbro and characterized at its top by ophicalcite horizons. Mafic metabreccia grading to metasandstone mark the transition between the “complete” and “reduced” successions. The character of the reconstructed succession and basin floor physiography of the IPZ metaophiolite is well comparable with the Middle Jurassic–Late Cretaceous succession of both the Queyras Complex (External Piedmont Zone) and the Internal Ligurian Units (Northern Apennines) and with modern slow-spreading mid-ocean ridges. Full article
(This article belongs to the Special Issue The Western Alpine Ophiolites)
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19 pages, 10967 KiB  
Article
Miocene Seep-Carbonates of the Northern Apennines (Emilia to Umbria, Italy): An Overview
by Stefano Conti, Claudio Argentino, Chiara Fioroni, Aura Cecilia Salocchi and Daniela Fontana
Geosciences 2021, 11(2), 53; https://doi.org/10.3390/geosciences11020053 - 28 Jan 2021
Cited by 16 | Viewed by 3525
Abstract
The natural emission of methane-rich fluids from the seafloor, known as cold seepage, is a widespread process at modern continental margins. The studies on present-day cold seepages provide high-resolution datasets regarding the fluid plumbing system, biogeochemical processes in the sediment, seafloor seepage distribution [...] Read more.
The natural emission of methane-rich fluids from the seafloor, known as cold seepage, is a widespread process at modern continental margins. The studies on present-day cold seepages provide high-resolution datasets regarding the fluid plumbing system, biogeochemical processes in the sediment, seafloor seepage distribution and ecosystems. However, the long-term (hundreds of thousands to millions of years) evolution of cold seepage remains elusive. The identification and study of outcrop analogous now exposed on land represent a valuable method for better understanding the effects of geological processes and climate forcing on the development of cold seepage systems. Here, we provide an overview on Miocene seep-carbonate deposits of the northern Apennines (from Emilia to the Umbria-Marchean sector, Italy), based on decades of field research integrated with detailed sedimentological and geochemical investigations. We report a total of 13 seep-carbonate outcrops, which formed in three different structural settings of the paleo-accretionary wedge corresponding to wedge-top basins, outer slope and intrabasinal highs at the deformational front. We discuss the recurring lithostratigraphic occurrence of seep deposits and the main compositional features (carbonate facies, carbon and oxygen stable isotopes) in order to interpret the seepage dynamics, duration and infer the contribution of methane-rich fluids released by paleo-gas hydrates. The datasets presented in this study represent a valuable complete record of cold seepage spanning ~12 Myr, that can be used to better understand factors controlling the regional-scale spatial and temporal evolution of cold seepage systems at modern active continental margins. Full article
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27 pages, 16099 KiB  
Article
Acoustic Mapping of Submerged Stone Age Sites—A HALD Approach
by Ole Grøn, Lars Ole Boldreel, Morgan F. Smith, Shawn Joy, Rostand Tayong Boumda, Andreas Mäder, Niels Bleicher, Bo Madsen, Deborah Cvikel, Björn Nilsson, Arne Sjöström, Ehud Galili, Egon Nørmark, Changqing Hu, Qunyan Ren, Philippe Blondel, Xing Gao, Petra Stråkendal and Antonio Dell’Anno
Remote Sens. 2021, 13(3), 445; https://doi.org/10.3390/rs13030445 - 27 Jan 2021
Cited by 13 | Viewed by 8141
Abstract
Acoustic response from lithics knapped by humans has been demonstrated to facilitate effective detection of submerged Stone Age sites exposed on the seafloor or embedded within its sediments. This phenomenon has recently enabled the non-invasive detection of several hitherto unknown submerged Stone Age [...] Read more.
Acoustic response from lithics knapped by humans has been demonstrated to facilitate effective detection of submerged Stone Age sites exposed on the seafloor or embedded within its sediments. This phenomenon has recently enabled the non-invasive detection of several hitherto unknown submerged Stone Age sites, as well as the registration of acoustic responses from already known localities. Investigation of the acoustic-response characteristics of knapped lithics, which appear not to be replicated in naturally cracked lithic pieces (geofacts), is presently on-going through laboratory experiments and finite element (FE) modelling of high-resolution 3D-scanned pieces. Experimental work is also being undertaken, employing chirp sub-bottom systems (reflection seismic) on known sites in marine areas and inland water bodies. Fieldwork has already yielded positive results in this initial stage of development of an optimised Human-Altered Lithic Detection (HALD) method for mapping submerged Stone Age sites. This paper reviews the maritime archaeological perspectives of this promising approach, which potentially facilitates new and improved practice, summarizes existing data, and reports on the present state of development. Its focus is not reflection seismics as such, but a useful resonance phenomenon induced by the use of high-resolution reflection seismic systems. Full article
(This article belongs to the Special Issue Remote Sensing of Archaeology)
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14 pages, 2689 KiB  
Article
Electrochemical Study of Galena Weathering in NaCl Solution: Kinetics and Environmental Implications
by Lei Zha, Heping Li and Ning Wang
Minerals 2020, 10(5), 416; https://doi.org/10.3390/min10050416 - 8 May 2020
Cited by 6 | Viewed by 3827
Abstract
Exploitation of seafloor massive sulfide deposits exposes galena and other metal sulfides to weathering factors. Galena weathering process leads to release of toxic metals into the water column. Although galena weathering has an impact on the environment, the mechanisms and kinetics of galena [...] Read more.
Exploitation of seafloor massive sulfide deposits exposes galena and other metal sulfides to weathering factors. Galena weathering process leads to release of toxic metals into the water column. Although galena weathering has an impact on the environment, the mechanisms and kinetics of galena oxidation under seawater conditions are rarely studied. In this work, several electrochemical experimental methods were combined to examine the kinetics of galena weathering in NaCl solution to simulate the effects of Cl in seawater, and the effects of sodium chloride concentration and pH on it were studied. The results show that galena weathering can lead to mineral surface passivation. More chloride ions can accelerate the dissolution of galena. Higher acidity and alkalinity promote the dissolution of galena in NaCl solution. Galena will release Pb2+ at a rate of 2.849 × 10−2 g m−2 d−1 in the near neutral NaCl mediums, and the amount increases to 5.705 × 10−2 g m−2 d−1 at pH 1.0 and even up to 7.569 × 10−1 g m−2 d−1 at pH 13.0. The results of polarization curves are consistent with the impedance spectrum data. Based on the dissolution kinetics of galena, the environmental significance of galena weathering is proposed. Full article
(This article belongs to the Section Mineral Processing and Extractive Metallurgy)
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