Search Results (66)

Diffusiophoresis of a weakly charged dielectric droplet in a cylindrical pore is investigated theoretically in this study. The governing fundamental electrokinetic equations are solved with a patched pseudo-spectral method based on Chebyshev polynomials, coupled with a geometric mapping scheme to take care of the irregular solution domain. The impact of the boundary confinement effect upon the droplet motion is explored in detail, which is most profound in narrow channels. We found, among other things, that the droplet moving direction may reverse with varying channel widths. Enhanced motion-inducing double-layer polarization due to the presence of a nearby channel wall is found to be responsible for it. In particular, an interesting and seemingly peculiar phenomenon referred to as the “solidification phenomenon” is observed here at some specific critical droplet sizes or electrolyte strengths in narrow channels, under which all the droplets move at identical speeds regardless of their viscosities. They move like a rigid particle without the surface spinning motions and the induced interior recirculating vortex flows. As the corresponding shear rate is zero at this point, the droplet is resilient to undesirable exterior shear stresses tending to damage the droplet in motion. This provides a helpful guideline in the fabrication of liposomes in drug delivery in terms of the optimal liposome size, as well as in the microfluidic and nanofluidic manipulations of cells, among other potential practical applications. The effects of other parameters of electrokinetic interest are also examined. Full article

The ongoing pursuit of enhanced efficiency and sustainability in power transformer cooling systems has spurred extensive research into the properties and performance of insulating fluids. This review explores the evolution of transformer cooling technologies, focusing on traditional mineral oils and the emerging roles of alternative fluids, such as natural and synthetic esters, and nanofluids. Mineral oils, though widely used, degrade over time, leading to a reduction in breakdown voltage (BDV) from 46 kV to 30 kV, exhibiting low fire resistance. Natural and synthetic esters provide improved biodegradability, fire safety but have higher viscosities—potentially limiting convective cooling. Nanofluids, have demonstrated BDV enhancements of up to 47.8%, reaching 88.7 kV in optimised formulations, alongside increases in partial discharge inception voltage (PDIV) of 20–23%. Additionally, thermal conductivity improvements of 5–20% contribute to enhanced heat dissipation. Moreover, it addresses challenges such as nanoparticle agglomeration, sedimentation, ageing, and compatibility with transformer materials. The analysis provides critical insights into the trade-offs between technical performance and economic feasibility. Concluding with an outlook on future research directions, the review identifies key parameters across various categories, establishing a roadmap for nanofluid integration with existing transformer systems. Full article

This study aimed to develop a cost-effective, environmentally sustainable, and technologically advanced dielectric fluid by utilizing the beneficial properties of natural ester-based vegetable oils, offering a promising alternative for transformer insulation and cooling applications. The novelty of this research lies in the formulation of a nanofluid that combines three distinct vegetable oils—castor, flaxseed, and blackseed—creating a unique base fluid. SiO₂ nanoparticles were incorporated into the fluid to leverage their multiple advantageous characteristics. Extensive experiments were conducted to evaluate the superior properties of the proposed nanofluid, focusing on key dielectric properties, such as relative permittivity (ε_r) and the dielectric dissipation factor (tan δ). Comparative analyses with conventional mineral oil, which was used as a benchmark, demonstrated the significant advantages of the vegetable oil-based nanofluid. The novel formulation outperformed all other tested samples, highlighting its exceptional performance. Additionally, three preparation methods were examined, with the green synthesis technique producing the nanofluid with better dielectric properties. Through a detailed presentation of empirical data and compelling arguments, this study confirms the potential of natural ester-based vegetable oil nanofluids as a highly promising alternative, driven by their intrinsic properties and the environmentally friendly synthesis method employed. Full article

The PAO/MgO nanofluids-based dielectric fluid DF(MgO-20) has significantly increased corrosion resistance as a coating. Electrochemical studies show that the DF(MgO-20) coating has protection efficiency of up to 99% for steel, copper, and aluminum. This coating is capable of providing corrosion protection for steel samples for up to 120 h in salt spray tests, and printed circuit boards (PCBs) for more than 20 days in salt spray tests in accordance with the ASTM B117 standard. The DF(MgO-20) coating fully meets the moisture resistance and fungal resistance standards required by the MIL-1-46058 C standard. The coating also demonstrates water displacement, meeting the requirements of the MIL-PRF-81309G standard. The DF(MgO-20) coating is able to protect electronic equipment working in underwater environment for up to 20 days. The aforementioned outstanding protection properties are achieved thanks to the nanofluid effect of the DF(MgO-20) dielectric fluid with the presence of MgO nano-additives that increase its overflow ability. The coating penetrates deeply and adheres tightly to the metal substrates, helping to separate them from moisturizing agents and corrosive agents. The research results aim to apply this coating to protect electronic equipment working in the tropical marine climate of Vietnam. Full article

Studies on dispersing nanoparticles in base fluid to elevate its essential and critical properties have evolved significantly in the recent decade. Alongside the conventional dispersion techniques used for nanofluid synthesis, microwave energy at 2.4 GHz frequency is irradiated onto the nanofluids is experimented with in this study. The effect of microwave irradiation on the electrical and thermal properties of semi-conductive nanofluids (SNF) is investigated and presented in this article. Titanium dioxide and zinc oxide are the semi-conductive nanoparticles used for this study to synthesize the SNF, viz., titania nanofluid (TNF) and zinc nanofluid (ZNF). Flash and fire points are the thermal properties verified, and dielectric breakdown strength, dielectric constant (${\epsilon }_r$), and dielectric dissipation factor (tan $\delta$) are the electrical properties verified in this study. AC breakdown voltage (BDV) of TNF and ZNF is improved by 16.78% and 11.25%, respectively, more than SNFs prepared without microwave irradiation. Results justify that the synergetic effect of stirring, sonication, and microwave irradiation in a rational sequence (microwave synthesis) exhibited better electrical and unaltered thermal properties. This microwave-applied nanofluid synthesis could be a simple and effective route to prepare the SNF with improved electrical properties. Full article

Polyalphaolefin (PAO) oil is widely used as a dielectric liquid due to its outstanding dielectric strength, high flash point, good oxidation resistance, and stability. The dispersion of MgO nanoparticles in PAO yields nanofluids with many properties superior to base oils. This study clarifies the influence of MgO nanoparticles on the dielectric properties (breakdown voltage, volume resistivity, and relative permittivity) and heat transfer properties of PAO/MgO nanofluids. Changes in the concentration and size and the modification of MgO nanoparticles with surfactants change the dielectric and thermal performance of PAO/MgO nanofluids. Using PAO/MgO nanofluids as raw material to prepare dielectric fluid obtains a product with higher dielectric strength and thermal conductivity than those using PAO. The results show that PAO/MgO nanofluid-based dielectric fluid has the potential to be applied as a soft coating to protect electronic equipment in industries. Full article

Metal–organic frameworks (MOFs) have been previously shown as an emerging modified class of epoxy resin. In this work, we report a simple strategy for preventing zeolitic imidazolate framework (ZIF-8) nanoparticles from agglomerating in epoxy resin (EP). Branched polyethylenimine grafted ZIF-8 in ionic liquid (BPEI-ZIF-8) nanofluid with good dispersion was prepared successfully using an ionic liquid as both the dispersant and curing agent. Results indicated that the thermogravimetric curve of the composite material had no noticeable change with increasing BPEI-ZIF-8/IL content. The glass transition temperature (T_g) of the epoxy composite was reduced with the addition of BPEI-ZIF-8/IL. The addition of 2 wt% BPEI-ZIF-8/IL into EP effectively improved the flexural strength to about 21.7%, and the inclusion of 0.5 wt% of BPEI-ZIF-8/IL EP composites increased the impact strength by about 83% compared to pure EP. The effect of adding BPEI-ZIF-8/IL on the T_g of epoxy resin was explored, and its toughening mechanism was analyzed in combination with SEM images showing fractures in the EP composites. Moreover, the damping and dielectric properties of the composites were improved by adding BPEI-ZIF-8/IL. Full article

According to the latest research, nanofluids as a possible future substitution for high-voltage equipment insulation have the potential to enhance the heat transfer and insulation properties of their base fluids. Dielectric properties are represented by breakdown strength (AC, DC, lightning) and dielectric performance as a set of quantities including dissipation factor, permittivity, and volume resistivity. In this study, natural and synthetic esters were mixed with C₆₀ nanoparticles. Samples were examined for dissipation factor, relative permittivity, and volume resistivity at temperatures between 25 °C and 140 °C to monitor changes in dielectric performance with rising temperature, in accordance with IEC 60247. In addition, the samples were tested for AC breakdown voltage (using mushroom-like electrodes with a gap distance of 1 mm) and evaluated using the Weibull distribution statistical method. These measurements allowed complex evaluation of the examined mixtures and the determination of optimal concentration for each ester-based nanofluid. Full article

The rise in power demand today necessitates its generation and transmission at high voltages. The efficient transmission of electric power requires transformers with an insulation system that exhibits excellent dielectric properties. In this paper ZnO and CuO nanomaterials are utilized to investigate the dielectric characteristics of pure synthetic ester oil and its related nanofluids (NFs) from room temperature up to 60 °C at increments of 20 °C, including AC breakdown voltage, Dielectric Dissipation factor, and DC resistivity. The breakdown testing is carried out in accordance with experimental IEC-60156 requirements. The DC resistivity and dissipation factor of oils are measured using the Dissipation Factor meter, resistivity meter, and a heating chamber with an oil cell that follows IEC 60247 standard. The statistical analysis is performed on the breakdown voltages test values using the Weibull probability distribution model for better accuracy. From the results, it has been found that ZnO nanofluid possesses a higher breakdown voltage among all the tested liquids. Furthermore CuO nanofluid gives a minimum value of dissipation factor even at higher temperatures. Full article

The interest in developing new fluids that can be used as dielectric liquids for transformers has driven the research on dielectric nanofluids in the last years. A number of authors have reported promising results on the electrical and thermal properties of dielectric nanofluids. Less attention has been paid to the interaction of these fluids with the cellulose materials that constitute the solid insulation of the transformers. In the present study, the dielectric strength of cellulose insulation is investigated, comparing its behavior when it is impregnated with transformer mineral oil and when it is impregnated with a dielectric nanofluid. The study includes the analysis of the AC breakdown voltage and the impulse breakdown voltage of the samples. Large improvements were observed on the AC breakdown voltages of the specimens impregnated with nanofluids, while the enhancements were lower in the case of the impulse tests. The reasons for the increase in AC breakdown voltage were investigated, considering the dielectric properties of the nanofluids used to impregnate the samples of cellulose. The analysis was completed with a finite element study that revealed the effect of the nanoparticles on the electric field distribution within the test cell, and its role in the observed enhancement. Full article

Improving the dielectric properties of liquid-insulating materials is a current problem in research into the insulation system of a power transformer. Modern optimization of insulating liquids involves the potential use of unique synthetic esters enriched with nanoparticles. This study presents the results of the dielectric response of liquefied gas-based (GTL) insulating liquids during accelerated thermal aging. The dielectric relaxation spectroscopy method was used in the frequency domain to point out power losses as an imaginary part of a complex electric modulus. The relaxation spectra express the validity of applying this complex dielectric parameter. The polarization processes of the base oil alternately change position in the low-frequency band during thermal aging. Fullerene nanofluid undergoes three phases of dielectric loss changes during thermal aging. In the case of magnetic nanofluid, the effect of electric double-layer polarization disappeared after 500 h of thermal aging. It was found that with the gradual increase in the thermal aging time, there is no gradual increase in the dielectric losses investigated in the measured frequency spectrum. This study shows that the concentration of the two types of nanoparticles independently causes a different dielectric response to an applied AC electric field in the GTL base fluid. Full article

This paper presents a detailed review of the streaming electrification phenomena of different insulating fluids for power transformers. The comparison of different techniques used to assess the charging tendency of fluids is discussed depending on the flow type (planar or centrifugal), volume of oil, and interface material. The charge separation between the insulating fluid and metallic/pressboard interfaces is explained in terms of the electrical double layer formation involving a fixed layer and diffuse layer. Based on the experimental results, the streaming electrification is observed to be a function of various factors such as speed, temperature, electric field, and surface roughness. Depending on the molecular structure of insulating liquids that come into contact with solid insulation at the interface, the streaming current can increase; hence, a suitable additive (benzotriazole, fullerene, Irgamet 39) is selected based on the type of fluid and charge polarity. The degradation of the insulating liquid upon ageing, which increases the streaming current and reclamation of such aged fluids using adsorbents (Fuller’s earth, activated carbon, bentonite, and alumina), is a possible method to suppress the static current through improving its dielectric properties. The nanofluids show a higher streaming current compared to base fluid with no change observed even after the reclamation process. The energization process using alternating current (AC) and direct current (DC) impacts the streaming phenomenon depending on its magnitude and polarity. The diffusion of sulfur compounds in the insulating liquid is another major hazard to transformers because the sulfide ions affect the physio-chemical reaction at the interface material, which is responsible for the formation of streaming current. Full article

Most power transformers are oil-immersed transformers for which its insulation system consists of oil and cellulosic solid. The insulation liquid impregnates the solid-covering air spaces, which improves the efficiency of the insulation system. Not only does the oil ensure electrical insulation but it also works as coolants transferring the heat generated during transformer operation to the exterior of the transformer. Throughout normal operation conditions, transformers experience multiple stresses that degrade their insulation. Since the lifetime of oil-immersed transformers is defined mainly by the state of the insulation paper, it is critical to understand the behavior and degradation mechanisms of new insulation systems that try to overcome the drawbacks of mineral oil as well as to improve power transformer performances. The current increased prevalence of the nonlinear loads additionally stresses power transformers, which generates their premature ageing or even failure. Consequently, new materials and assessment methods are required to guarantee the suitable management of power transformer populations. In this Special Issue “Experimental and Numerical Analysis of Thermal Ageing in Power Transformers”, four papers have been published. The guest editor also describes briefly some challenges involved beyond the coverage of this Special Issue. Full article

Amidst the new techniques facing the improvement of cooling and insulating efficiency and the design of electric transformers, constrained by the current technologies, one of the more promising is the substitution of traditional dielectric oils for nanofluids. Research on nanofluids for their application in transformers as a coolant and dielectric medium have been performed during the last two decades and continue today. This review tries to collect and analyze the available information in this field and to offer it already dissected to researchers, focusing on the preparation methods and how nanoparticles affect the main properties of the base fluids. Here we also addressed the influence of different parameters as particle characteristics or environmental conditions in nanofluids performance, the evolution with time of the measured properties, or the neighboring relationship of nanofluids with other transformer components. In this sense, the most reviewed articles reflect enhancements of thermal conductivity or dielectric strength, as well as an improvement of time evolution of these properties, with respect to those that are found in base fluids, and, also, a better interaction between these nanofluids and dielectric cellulosics. Thus, the use of dielectric nanofluids in transformers may allow these machines to work safer or over their design parameters, reducing the risk of failure of the electrical networks and enhancing their life expectancy. Nevertheless, these advantages will not be useful unless a proper stability of nanofluids is ensured, which is achieved in a small part of revised articles. A compendium of the preparation methodology with this aim is proposed, to be checked in future works. Full article

Exploring impressively effective dielectric nanofluids for transformers to improve dielectric strength and thermal stability is indispensable. It is crucial to determine the modification mechanism of dispersed nanomaterials in insulating oil for operative applications in power transformers. This paper aspires to authenticate the experimental evidence of the enhancing AC dielectric strength of synthetic ester Midel-7131 using two newly introduced semiconductive nanoparticles, CdS and Co₃O₄, and uncover the potential reasons for enhanced AC dielectric strength. The AC breakdown voltage (BDV) of synthetic ester and nanofluids was investigated and statistically evaluated. The mean AC breakdown voltage of SE/CdS and SE/Co₃O₄ was increased by 31.9% and 31.3%, respectively. The augmentation in AC breakdown strength is possibly due to the facilitated charge-scavenging ability owing to the large specific surface area and wide bandgap. Simultaneous thermogravimetric analysis, differential scanning calorimetry, and derivative thermogravimetry analyses (TGA–DSC–DTG) confirmed that the initial decomposition temperature was high and heat dissipation was low, indicating that the nanofluids were thermally stable in both air and nitrogen. Hence, emerging semiconductive CdS and Co₃O₄-based nanofluids of synthetic ester possess remarkable dielectric strength and thermal stability enhancement for their application in power transformers. Full article