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11 Results Found

  • Article
  • Open Access
56 Citations
5,157 Views
14 Pages

New Pyrazole-Hydrazone Derivatives: X-ray Analysis, Molecular Structure Investigation via Density Functional Theory (DFT) and Their High In-Situ Catecholase Activity

  • Khalid Karrouchi,
  • El Bekkaye Yousfi,
  • Nada Kheira Sebbar,
  • Youssef Ramli and ,
  • Jamal Taoufik,
  • Younes Ouzidan,
  • M’hammed Ansar,
  • Yahia N. Mabkhot,
  • Hazem A. Ghabbour and
  • Smaail Radi
  • + 5 authors+ 0 author

25 October 2017

The development of low-cost catalytic systems that mimic the activity of tyrosinase enzymes (Catechol oxidase) is of great promise for future biochemistry technologic demands. Herein, we report the synthesis of new biomolecules systems based on hydra...

(This article belongs to the Section Molecular Biophysics)
  • Article
  • Open Access
3 Citations
2,630 Views
11 Pages

Equilibrium Studies of Iron (III) Complexes with Either Pyrazine, Quinoxaline, or Phenazine and Their Catecholase Activity in Methanol

  • José J. N. Segoviano-Garfias,
  • Gabriela A. Zanor,
  • Fidel Ávila-Ramos and
  • Egla Yareth Bivián-Castro

Currently, catalysts with oxidative activity are required to create valuable chemical, agrochemical, and pharmaceutical products. The catechol oxidase activity is a model reaction that can reveal new oxidative catalysts. The use of complexes as catal...

(This article belongs to the Special Issue Stimuli-Responsive Chromophores and Luminophores)
  • Article
  • Open Access
9 Citations
4,610 Views
8 Pages

Quinoline Derivatives with Different Functional Groups: Evaluation of Their Catecholase Activity

  • Mohamed Moutaouakil,
  • Said Tighadouini,
  • Zainab M. Almarhoon,
  • Maha I. Al-Zaben and ,
  • Abir Ben Bacha,
  • Vijay H. Masand,
  • Jamal Jamaleddine and
  • Rafik Saddik
  • + 3 authors+ 0 author

18 November 2022

In this work, we are interested in finding new catalysts for catecholase, whose principle is based on the oxidation reaction of catechol to o-quinone. In this context, we have studied a series of seven quinoline-based compounds. The present work indi...

(This article belongs to the Section Biocatalysis)
  • Article
  • Open Access
11 Citations
3,900 Views
13 Pages

As the most abundant catecholamine neurotransmitter in the brain, dopamine plays an important role in the normal physiological process, and its level in urine also changes during human pathological processes. In clinic, the detection of dopamine in u...

(This article belongs to the Special Issue Nanoparticles in Chemical and Biological Sensing)
  • Article
  • Open Access
8 Citations
5,281 Views
12 Pages

Synthesis, Characterization, DFT, and Thermogravimetric Analysis of Neutral Co(II)/Pyrazole Complex, Catalytic Activity toward Catecholase and Phenoxazinone Oxidation

  • Mohamed El Boutaybi,
  • Nadia Bouroumane,
  • Mohamed Azzouzi,
  • Mohamed Aaddouz and ,
  • Said Bacroume,
  • Mohamed El Miz,
  • Rachid Touzani,
  • Zahra Bahari,
  • Abdelkader Zarrouk and
  • Ismail Warad
  • + 8 authors+ 3 authors

17 January 2023

The pyrazole-pyridin-2-amine, as a tridentate pyrazole ligand, and its neutral Co(II)/pyrazole complex were prepared using a direct method with a high yield. The desired pyrazole ligand and its complex were subjected to several physicochemical and th...

(This article belongs to the Special Issue New Trends in Crystals at Saudi Arabia (Volume II))
  • Article
  • Open Access
14 Citations
3,778 Views
13 Pages

Aerial Oxidation of Phenol/Catechol in the Presence of Catalytic Amounts of [(Cl)2Mn(RCOOET)], RCOOET= Ethyl-5-Methyl-1-(((6-Methyl-3-Nitropyridin-2-yl)Amino)Methyl)-1H-Pyrazole-3-Carboxylate

  • Mohamed El Boutaybi,
  • Abderrahim Titi,
  • Abdullah Y. A. Alzahrani,
  • Zahra Bahari and ,
  • Monique Tillard,
  • Belkheir Hammouti and
  • Rachid Touzani
  • + 2 authors+ 0 author

14 December 2022

In this work, we report on the catalytic activity of a manganese complex [(Cl)2Mn(RCOOET)], where RCOOET is ethyl-5-methyl-1-(((6-methyl-3-nitropyridin-2-yl)amino)methyl)-1H-pyrazole-3-carboxylate, in the oxidation of phenol or catechol by atmospheri...

  • Article
  • Open Access
17 Citations
4,899 Views
11 Pages

Synthesis, Structure and Catechol Oxidase Activity of Mono Nuclear Cu(II) Complex with Phenol-Based Chelating Agent with N, N, O Donor Sites

  • Trilochan Rakshit,
  • Bikramaditya Mandal,
  • Anwesha Haldar,
  • Dhrubajyoti Mondal and ,
  • Debdas Mandal and
  • Rakesh Ganguly
  • + 1 author+ 0 author

7 April 2022

A square-planar Cu(II) complex [Cu(L)Cl], 1, with sterically constrained tridentate phenol-based ligand (HL= N,N,N′-trimethyl-N′-(2-hydroxy-3,5-di-tert-butylbenzyl)-ethylenediamine) with N, N, O donor sites has been synthesized. The compl...

  • Review
  • Open Access
83 Citations
11,484 Views
20 Pages

Metal Complexes with Schiff Bases: Data Collection and Recent Studies on Biological Activities

  • Maria Stefania Sinicropi,
  • Jessica Ceramella,
  • Domenico Iacopetta,
  • Alessia Catalano and ,
  • Annaluisa Mariconda,
  • Camillo Rosano,
  • Carmela Saturnino,
  • Hussein El-Kashef and
  • Pasquale Longo
  • + 4 authors+ 0 author

27 November 2022

Metal complexes play a crucial role in pharmaceutical sciences owing to their wide and significant activities. Schiff bases (SBs) are multifaceted pharmacophores capable of forming chelating complexes with various metals in different oxidation states...

(This article belongs to the Special Issue Recent Advances in Coordination Chemistry of Metal Complexes Based on Schiff Base Ligands: Structure-Property Relationships and Applications)
  • Article
  • Open Access
10 Citations
8,375 Views
11 Pages

2-S-Lipoylcaffeic Acid, a Natural Product-Based Entry to Tyrosinase Inhibition via Catechol Manipulation

  • Raffaella Micillo,
  • Valeria Pistorio,
  • Elio Pizzo,
  • Lucia Panzella and ,
  • Alessandra Napolitano and
  • Marco D’Ischia
  • + 1 author+ 0 author

Conjugation of naturally occurring catecholic compounds with thiols is a versatile and facile entry to a broad range of bioinspired multifunctional compounds for diverse applications in biomedicine and materials science. We report herein the inhibiti...

(This article belongs to the Special Issue Bioinspired Catechol-Based Systems: Chemistry and Applications)
  • Article
  • Open Access
3 Citations
2,596 Views
22 Pages

Dinuclear Copper(II) Complexes of 2,6-Bis[(N-Methylpiperazine-1-yl)methyl]-4-Formyl Phenol Ligand: Promising Biomimetic Catalysts for Dye Residue Degradation and Drug Synthesis

  • Michaela Bártová,
  • Alan Liška,
  • Vendula Studená,
  • Pavel Vojtíšek and ,
  • Michal Kašpar,
  • Tomáš Mikysek,
  • Lenka Česlová,
  • Ivan Švancara and
  • Milan Sýs
  • + 4 authors+ 0 author

13 February 2025

In this study, three dinuclear copper(II) complexes of ligand 2,6-bis[(N-methyl-piperazine-1-yl)methyl]-4-formyl phenol (L1) and one of 2,6-bis[(N-methylpiperazine-1-yl)methyl]-4-formyl phenol dimethylacetal (L2) with copper(II) ions have been invest...

(This article belongs to the Section Materials Science)
  • Article
  • Open Access
16 Citations
4,149 Views
20 Pages

Vitiligo is a common chronic dermatological abnormality that afflicts tens of millions of people. Furocoumarins isolated from Uygur traditional medicinal material Psoralen corylifolia L. have been proven to be highly effective for the treatment of vi...

(This article belongs to the Special Issue Melanins and Melanogenesis 3.0: From Nature to Applications)