Search Results (3)

Polyimide aerogels (PAs) are ideal for applications in thermal protection, lightweight electronics, and energy devices due to their excellent mechanical properties, ultra-low density, extremely low thermal conductivity, and high thermal-oxidative stability. Conventional PA manufacturing involves a sol–gel process followed by post-processing (drying and imidization). However, PAs fabricated using this method are geometrically limited by the mold shape and are fragile, have poor sample machinability, and are prone to shrinkage and deformation. Direct ink writing (DIW) additive manufacturing (AM) overcomes these limitations of conventional manufacturing processes by extruding ink to construct architectural lattices with high dimensional fidelity, enabling the fabrication of complex, conformal, and multi-scale structures. DIW AM can produce PA components that are thermally and electrically stable, as well as geometric freedom, thus supporting high-precision and functional hierarchical design. This review provides the first overview of DIW AM of PAs. By summarizing printable ink formulations, printing parameters, drying routes and thermal/chemical imidization processes, as well as applications of printed samples, it comprehensively describes the current state of the art in DIW additive manufacturing of PAs and highlights key technical bottlenecks (printability vs. porosity trade-off, economic and environmental, etc.). It also outlines possible future research directions. Full article

Nowadays, edible materials such as polysaccharides have gained attention due to their valuable attributes, especially gelling property. Polysaccharide-based edible gels (PEGs) can be classified as (i) hydrogels, (ii) oleogels and bigels, (iii) and aerogels, cryogels and xerogels, respectively. PEGs have different characteristics and benefits depending on the functional groups of polysaccharide chains (e.g., carboxylic, sulphonic, amino, methoxyl) and on the preparation method. However, PEGs are found in the incipient phase of research and most studies are related to their preparation, characterization, sustainable raw materials, and applicability. Furthermore, all these aspects are treated separately for each class of PEG, without offering an overview of those already obtained PEGs. The novelty of this manuscript is to offer an overview of the classification, definition, formulation, and characterization of PEGs. Furthermore, the applicability of PEGs in the food sector (e.g., food packaging, improving food profile agent, delivery systems) and in the medical/pharmaceutical sector is also critically discussed. Ultimately, the correlation between PEG consumption and polysaccharides properties for human health (e.g., intestinal microecology, “bridge effect” in obesity, gut microbiota) are critically discussed for the first time. Bigels may be valuable for use as ink for 3D food printing in personalized diets for human health treatment. PEGs have a significant role in developing smart materials as both ingredients and coatings and methods, and techniques for exploring PEGs are essential. PEGs as carriers of bioactive compounds have a demonstrated effect on obesity. All the physical, chemical, and biological interactions among PEGs and other organic and inorganic structures should be investigated. Full article

Polyimide (PI)-based aerogels have been widely applied to aviation, automobiles, and thermal insulation because of their high porosity, low density, and excellent thermal insulating ability. However, the fabrication of PI aerogels is still restricted to the traditional molding process, and it is often challenging to prepare high-performance PI aerogels with complex 3D structures. Interestingly, renewable nanomaterials such as cellulose nanocrystals (CNCs) may provide a unique approach for 3D printing, mechanical reinforcement, and shape fidelity of the PI aerogels. Herein, we proposed a facile water-based 3D printable ink with sustainable nanofillers, cellulose nanocrystals (CNCs). Polyamic acid was first mixed with triethylamine to form an aqueous solution of polyamic acid ammonium salts (PAAS). CNCs were then dispersed in the aqueous PAAS solution to form a reversible physical network for direct ink writing (DIW). Further freeze-drying and thermal imidization produced porous PI/CNC composite aerogels with increased mechanical strength. The concentration of CNCs needed for DIW was reduced in the presence of PAAS, potentially because of the depletion effect of the polymer solution. Further analysis suggested that the physical network of CNCs lowered the shrinkage of aerogels during preparation and improved the shape-fidelity of the PI/CNC composite aerogels. In addition, the composite aerogels retained low thermal conductivity and may be used as heat management materials. Overall, our approach successfully utilized CNCs as rheological modifiers and reinforcement to 3D print strong PI/CNC composite aerogels for advanced thermal regulation. Full article