Search Results (5)

Under the premise of using the solid-phase method to pre-sinter Bi₂O₃ and Sb₂O₃ into BiSbO₄ as a substitute for equal amounts of Bi₂O₃ and Sb₂O₃ in the formula, the effects of co-doping with In(NO₃)₃, Al(NO₃)₃, and Y(NO₃)₃ on the microstructure and electrical properties of ZnO varistors were studied. The experimental results show that with an increase in In³⁺-doped molar concentration, the leakage current of the ZnO varistor shows a rapid decrease and then a slow increase trend. However, the nonlinear coefficient is the opposite of it. With the combined effect of the rare earth element Y³⁺, the average grain size is significantly reduced, which leads to an increase in the voltage gradient. At the same time, a certain amount of doped In³⁺ and Al³⁺ is dissolved into the grains, resulting in a decrease in grain resistance and thus a low level of residual voltage. The varistor with 0.6 mol% In³⁺, 0.1 mol% Al³⁺, and 0.9 mol% Y³⁺ doping ratios exhibits excellent overall performance. The nonlinear coefficient is 62.2, with the leakage current being 1.46 µA/cm² and the voltage gradient being 558 V/mm, and the residual voltage ratio is 1.73. The prepared co-doped ZnO varistors will provide better protection for metal oxide surge arresters. Full article

The development of active, selective, and stable multicrystalline catalytic coatings on the inner surface of microcapillary reactors addresses environmental problems of fine organic synthesis, in particular by reducing the large quantities of reagents and byproducts. Thin-film nanosized bimetallic catalysts based on mesoporous pure titania and doped with zirconia, ceria, and zinc oxide, for use in microreactors, were developed, and the regularities of their formation were studied. The efficiency of PdZn/Ti_xM_1−xO_2±y (M = Ce, Zr, Zn) in the hydrogenation of 2-methyl-3-butyn 2-ol was studied with an emphasis on the stability of the catalyst during the reaction. The catalytic parameters depend on the adsorption properties and activity of PdZn and Pd(0) active centers. Under reaction conditions, resistance to the decomposition of PdZn is a factor that affects the stability of the catalyst. The zinc-doped coating proved to be the most selective and stable in the reaction of selective hydrogenation of acetylenic alcohols in a microcapillary reactor. This coating retained a high selectivity of 98.2% during long-term testing up to 168 h. Modification of the morphology and electronic structure of the active component, by doping titania with Ce and Zr, is accompanied by a decrease in stability. Full article

In recent years, cobalt ferrite has attracted considerable attention due to its unique physical properties. The present study aimed to produce cobalt ferrite magnetic nanoparticles doped with zinc and vanadium using the sol-gel auto-combustion method. For this purpose, Co_1−xZn_xFe_2−yV_yO₄ (where x = 0.0, 0.1, 0.2, 0.5 and y = 0.00, 0.05, 0.15, 0.25) precursors were calcined at 800 °C for 3 h. The prepared samples were characterized with the X-ray diffraction (XRD) method in combination with Rietveld structure refinement, field emission scanning electron microscopy (FE-SEM), Fourier transform infrared spectroscopy (FT-IR), and vibrating sample magnetometery (VSM). The XRD patterns confirmed the formation of crystalline spinel structure for all samples. However, the diffraction peaks of hematite and iron vanadium oxide phases were observed in the patterns of some doped samples. The average crystallite size for all the synthesized samples was found to be in the range of ~45–24 nm, implying that it decreased by simultaneously doping cobalt ferrite with Zn and V. The FT-IR spectrum confirmed the formation of the spinal structure of ferrite through the observed vibrational bands assigned to the tetrahedral (υ₂) and octahedral (υ₁) interstitial complexes in the spinel structure. The FE-SEM images showed that morphology, average grain size, and agglomeration of the synthesized powders were affected by doping, which was due to the interactions of the magnetic surface of nanoparticles. The VSM curves demonstrated that saturation magnetization and coercivity values changed in the range of 30–83 emu/g and from 27–913 Oe, respectively. These changes occurred due to the alteration in cation distribution in the spinel structure. This can be attributed to the change in superexchange interactions between magnetic ions by co-substitution of Zn and V ions in Cobalt ferrite and the changes in magnetocrystalline anisotropy. Full article

The highly sensitive ultra-violet (UV) photodiode was demonstrated on the organic-inorganic hybrid heterostructure of β-phase p-type polyfluorene (PFO)/n-type yttrium-doped zinc oxide nanorods (YZO-NRs). The device was fabricated through a simple fabrication technique of β-phase PFO coating onto YZO-NRs that had been directly grown on graphene by the hydrothermal synthesis method. Under UV illumination (λ = 365 nm), the device clearly showed excellent photoresponse characteristics (e.g., high quantum efficiency ~690%, high photodetectivity ~3.34 × 10¹² cm·Hz^1/2·W⁻¹, and fast response time ~0.17 s). Furthermore, the ratio of the photo current-to-dark current exceeds 10³ even under UV illumination with a small optical power density of 0.6 mW/cm². We attribute such superb photoresponse characteristics to both Y incorporation into YZO-NRs and conformation of β-phase PFO. Namely, Y dopants could effectively reduce surface states at YZO-NRs, and β-phase PFO might increase the photocarrier conductivity in PFO. The results suggest that the β-phase p-PFO/n-YZO-NR hybrid heterostructure holds promise for high-performance UV photodetectors. Full article

Zinc oxide nanoparticles codoped with Co²⁺ and Mn²⁺ ions (Zn_(1−x−y)Mn_xCo_yO NPs) were obtained for the first time by microwave solvothermal synthesis. The nominal content of Co²⁺ and Mn²⁺ in Zn_(1−x−y)Mn_xCo_yO NPs was x = y = 0, 1, 5, 10 and 15 mol % (the amount of both ions was equal). The precursors were obtained by dissolving zinc acetate dihydrate, manganese (II) acetate tetrahydrate and cobalt (II) acetate tetrahydrate in ethylene glycol. The morphology, phase purity, lattice parameters, dopants content, skeleton density, specific surface area, average particle size, average crystallite size, crystallite size distribution and magnetic properties of NPs were determined. The real content of dopants was up to 25.0% for Mn²⁺ and 80.5% for Co²⁺ of the nominal content. The colour of the samples changed from white to dark olive green in line with the increasing doping level. Uniform spherical NPs with wurtzite structure were obtained. The average size of NPs decreased from 29 nm to 21 nm in line with the increase in the dopant content. Brillouin type paramagnetism and an antiferromagnetic interaction between the magnetic ions was found for all samples, except for that with 15 mol % doping level, where a small ferromagnetic contribution was found. A review of the preparation methods of Co²⁺ and Mn²⁺ codoped ZnO is presented. Full article