Search Results (16)

The transition to cleaner energy sources, particularly in hard-to-abate industrial sectors, often requires the gradual integration of new technologies. Hydrogen, crucial for decarbonization, is explored as a fuel in blended combustions. Blending or replacing fuels impacts combustion stability and heat transfer rates due to differing densities. An extensive literature review examines blended combustion, focusing on hydrogen/methane mixtures. While industrial burners claim to accommodate up to 20% hydrogen, theoretical support is lacking. A novel thermodynamic analysis methodology is introduced, evaluating methane/hydrogen combustion using the Wobbe index. The findings highlight practical limitations beyond 25% hydrogen volume, necessitating a shift to “totally hydrogen” combustion. Blended combustion can be proposed as a medium-term strategy, acknowledging hydrogen’s limited penetration. Higher percentages require burner and infrastructure redesign. Full article

Global gas markets are changing as natural gas (NG) is replaced by biomethane. Biomethane is produced by upgrading biogas, which can have a molar concentration of methane to over 98%. This renewable energy has been injected into the pipeline networks of NG, which offers the possibility to increase its usage in industrial and residential applications. However, the expectation of the increase in biomethane proportion on the NG grids could increase the fluctuations on the composition of the NG–biomethane mixture in amplitude and frequency. In this context, the injection of biomethane into the existing network of NG raises a discussion about the extent to which variations in gas quality will occur and what permissible limits should exist, as variations in combustion characteristics can affect the operation of the combustion processes, with consequences for consumers, distributors and gas producers. This study describes a gas quality analysis with regard to the use of biomethane in industrial equipment, mixed or not mixed with NG, taking into account the indicators for gas interchangeability and provides a discussion on the necessary gas quality level to be achieved or maintained for efficient combustion in equipment originally designed to operate with NG. NG and biomethane real data collected for 92 consecutive days in 2022 and provided by two different companies in Brazil were used for this study. It is shown that the maximum deviation of the Wobbe Index (WI) of 5%, which is allowed for industrial plants, does not work for the operation of furnaces at temperatures of 1200 °C or more. In addition, it is shown that the WI, as defined in relation to the calorific value of the fuel, may allow inappropriate substitution of fuel gases, which is likely to reduce the range of blending of biomethane in NG pipelines. The results can be assessed to analyze how the addition of biomethane to NG grids will impact the WI and the equipment operation parameters such as the air-to-gas ratio, products-to-gas ratio, adiabatic flame temperature and furnace temperature. Full article

To meet the target of reducing greenhouse gas emissions, hydrogen as a carbon-free fuel is expected to play a major role in future energy supplies. A challenge with hydrogen is its low density and volumetric energy value, meaning that large tanks are needed to store and transport it. By injecting hydrogen into the natural gas network, the transportation issue could be solved if the hydrogen–natural gas mixture satisfies the grid gas quality requirements set by legislation and standards. The end consumers usually have stricter limitations on the gas quality than the grid, where Euromot, the European association of internal combustion engine manufacturers, has specific requirements on the parameters: the methane number and Wobbe index. This paper analyses how much hydrogen can be added into the natural gas grid to fulfil Euromot’s requirements. An average gas composition was calculated based on the most common ones in Europe in 2021, and the results show that 13.4% hydrogen can be mixed with a gas consisting of 95.1% methane, 3.2% ethane, 0.7% propane, 0.3% butane, 0.3% carbon dioxide, and 0.5% nitrogen. The suggested gas composition indicates for engine manufacturers how much hydrogen can be added into the gas to be suitable for their engines. Full article

The blending of hydrogen gas into natural gas pipelines is an effective way of achieving the goal of carbon neutrality. Due to the large differences in the calorific values of natural gas from different sources, the calorific value of natural gas after mixing with hydrogen may not meet the quality requirements of natural gas, and the quality of natural gas entering long-distance natural gas and urban gas pipelines also has different requirements. Therefore, it is necessary to study the effect of multiple gas sources and different pipe network types on the differences in the calorific values of natural gas following hydrogen admixing. In this regard, this study aimed to determine the quality requirements and proportions of hydrogen-mixed gas in natural gas pipelines at home and abroad, and systematically determined the quality requirements for natural gas entering both long-distance natural gas and urban gas pipelines in combination with national standards. Taking the real calorific values of the gas supply cycle of seven atmospheric sources as an example, the calorific and Wobbe Index values for different hydrogen admixture ratios in a one-year cycle were calculated. The results showed that under the requirement of natural gas interchangeability, there were great differences in the proportions of natural gas mixed with hydrogen from different gas sources. When determining the proportion of hydrogen mixed with natural gas, both the factors of different gas sources and the factors of the gas supply cycle should be considered. Full article

The development of hydrogen energetics is a possible way to reduce emissions of harmful substances into the atmosphere in the production of electricity. Its implementation requires the introduction of energy facilities capable of operating on environmentally safe fuel. At the same time, from a technological point of view, it is easier to implement a gradual shift to the use of hydrogen in power plants by burning methane–hydrogen blends. This paper presents the results of thermodynamic studies of the influence of the chemical composition of the methane–hydrogen blend on the performance of binary and trinary power units. It is shown that an increase in the hydrogen volume fraction in the fuel blend from 0 to 80% leads to a decrease in the Wobbe index by 16% and an increase in the power plant auxiliaries by almost 3.5 times. The use of a trinary CCGT unit with a single-circuit WHB and working fluid water condensation makes it possible to increase the net efficiency by 0.74% compared to a binary CCGT with a double-circuit WHB and a condensate gas heater. Full article

Several North American utilities are planning to blend hydrogen into gas grids, as a short-term way of addressing the scalable demand for hydrogen and as a long-term decarbonization strategy for ‘difficult-to-electrify’ end uses. This study documents the impact of 0–30% hydrogen blends by volume on the performance, emissions, and safety of unadjusted equipment in a simulated use environment, focusing on prevalent partially premixed combustion designs. Following a thorough literature review, the authors describe three sets of results: operating standard and “ultra-low NO_x” burners from common heating equipment in “simulators” with hydrogen/methane blends up to 30% by volume, in situ testing of the same heating equipment, and field sampling of a wider range of equipment with 0–10% hydrogen/natural gas blends at a utility-owned training facility. The equipment was successfully operated with up to 30% hydrogen-blended fuels, with limited visual changes to flames, and key trends emerged: (a) a decrease in the input rate from 0 to 30% H₂ up to 11%, often in excess of the Wobbe Index-based predictions; (b) NO_x and CO emissions are flat or decline (air-free or energy-adjusted basis) with increasing hydrogen blending; and (c) a minor decrease (1.2%) or increase (0.9%) in efficiency from 0 to 30% hydrogen blends for standard versus ultra-low NO_x-type water heaters, respectively. Full article

Hydrogen is increasingly receiving a primary role as an energy vector in ensuring the achievement of the European decarbonization goals by 2050. In fact, Hydrogen could be produced also by electrolysis of water using renewable sources, such as photovoltaic and wind power, being able to perform the energy storage function, as well as through injection into natural gas infrastructures. However, hydrogen injection directly impacts thermodynamic properties of the gas itself, such as density, calorific value, Wobbe index, sound speed, etc. Consequently, this practice leads to changes in metrological behavior, especially in terms of volume and gas quality measurements. In this paper, the authors present an overview on the impact of hydrogen injection in natural gas measurements. In particular, the changes in thermodynamic properties of the gas mixtures with different H₂ contents have been evaluated and the effects on the accuracy of volume conversion at standard conditions have been investigated both on the theoretical point of view and experimentally. To this end, the authors present and discuss the effect of H₂ injection in gas networks on static ultrasonic domestic gas meters, both from a theoretical and an experimental point of view. Experimental tests demonstrated that ultrasonic gas meters are not significantly affected by H₂ injection up to about 10%. Full article

Currently, offshore areas have become the hotspot of global gas and oil production. They have significant reserves and production potential. Offshore platforms are energy-intensive facilities. Most of them are equipped with gas turbine engines. Many technologies are used to improve their thermal efficiency. Thermochemical recuperation is investigated in this paper. Much previous research has been restricted to analyzing of the thermodynamic potential of the chemically recuperated gas turbine cycle. However, little work has discussed the operation issues of this cycle. The analysis of actual fuel gases for the steam reforming process taking into account the actual load of gas turbines, the impact of steam reforming on the Wobbe index, and the impact of a steam-fuel reforming process on the carbon dioxide emissions is the novelty of this study. The obtained simulation results showed that gas turbine engine efficiency improved by 8.1 to 9.35% at 100% load, and carbon dioxide emissions decreased by 10% compared to a conventional cycle. A decrease in load leads to a deterioration in the energy and environmental efficiency of chemically recuperated gas turbines. Full article

Biogas is a promising renewable energy source; however, it needs to be upgraded to increase its low calorific value. In this study, oxidative coupling of methane (OCM) was selected to convert it to a higher fuel standard. Prior to establishing the scaled-up OCM process, the effect of organic/inorganic binders on catalytic activity was examined. The selection of the binders and composition of the catalyst pellet influenced the pore structure, fracture strength, and catalytic activity of the catalyst pellets. It was also observed that the O₂ supply from the inorganic binder is a key factor in determining catalytic activity, based on which the composition of the catalyst pellets was optimized. The higher heating value increased from 39.9 (CH₄, Wobbe index = 53.5 MJ/Nm³) to 41.0 MJ/Nm³ (OCM product mixture, Wobbe index = 54.2 MJ/Nm³), achieving the fuel standard prescribed in many countries (Wobbe index = 45.5–55.0 MJ/Nm³). The reaction parameters (temperature, gas hourly space velocity, size of the reaction system, and the CH₄/O₂ ratio) were also optimized, followed by a sensitivity analysis. Furthermore, the catalyst was stable for a long-term (100 h) operation under the optimized conditions. Full article

The one of main quality requirements of natural gas as an engine fuel is the methane number (MN). This parameter indicates the fuel’s capability to avoid knocking in the engine. A higher MN value indicates a better natural gas quality for gas engines. Natural gas with higher methane content tends to have higher MN value. This study presents analysis of deviation of liquefied natural gas (LNG) composition and its impact on LNG quality as an engine fuel. The analysis of higher hydrocarbons and nitrogen content impact on LNG parameters was considered for several samples of LNG compositions. Most engine manufacturers want to set a new, lower limit value for methane number at 80. This fact causes significant restrictions on the range of variability in the composition of liquefied natural gas. The goal of this study was to determine the combination of the limit content of individual components in liquefied natural gas to achieve the strict methane number criterion (MN > 80). To fulfill this criterion, the methane content in LNG would have to exceed 93.7%mol, and a significant part of the LNG available on the market does not meet these requirements. The analysis also indicated that the methane number cannot be the only qualitative criterion, as its variability depends strongly on the LNG composition. To determine the applicability of LNG as an engine fuel, the simultaneous application of the methane number and Wobbe index criteria was proposed. Full article

The energy market is facing a major transition, in which natural gas and renewable gasses will play an important role. However, changing gas sources and compositions will force the gas transporters, gas engine manufacturers, and gas grid operators to monitor the gas quality in a more intensive way. This leads to the need for lower cost, smaller, and easy to install gas quality sensors. A new approach is proposed in this study that is based on the chemical interactions of the various gas components and responsive layers applied to an array of capacitive interdigitated electrodes. For Liquid Natural Gas (LNG), containing a relative high concentration of higher hydrocarbons, an array of ten capacitive chips is proposed, that is sufficient to calculate the full composition, and can be used to calculate energy parameters, such as Wobbe Index, Calorific Value, and Methane Number. A first prototype was realized that was small enough to be inserted in low and medium pressure gas pipes and LNG engine fuel lines. Adding the pressure and temperature data to the chip readings enables the determination of the concentrations of the various alkanes, hydrogen, nitrogen, and carbon dioxide, including small fluctuations in water vapor pressure. The sensitivity and selectivity of the new sensor is compared to a compact analyzer employing tunable filter infrared spectrometry. Full article

In China, it has become a more common practice to introduce natural gases from different sources into the same distribution system to improve supply security and reliability. Variable gas constituents may cause a negative impact on the performance of domestic gas appliances. This paper aims to study the CO emission of a Chinese gas cooker under different constituents of natural gas. A typical Chinese gas cooker with two burners, each of which has a nominal heat input of 3.8 kW, was selected. One of the burners was modified to a forced-mixed mode to replace primary air injection. Within operational ranges corresponding to the permissible Wobbe index—namely, primary air coefficients and heat inputs—the equivalence between original gas and the CH₄/C₃H₈/N₂ three-component mixture in terms of CO emission was experimentally validated. Then, different three-component mixtures were input into the other unmodified burner, which operates under injected primary air, to investigate how the CO emission changed with different gas constituents. It was found that the CO emission of a natural gas and a CH₄/C₃H₈/N₂ three-component mixture, in terms of CO emission, were equivalent. The combination of the two indexes, W and PN, can describe the CO emission from a gas cooker accurately. By means of a three-component mixture, the empirical formula, which can correlate CO and the gas property parameters, was proposed. A set of equal-CO lines was revealed for a given initial primary air adjustment. Finally, a feasible approach to manage gas quality management in China was put forward, and the conclusion can help control the CO emission of gas cookers and improve indoor air quality. Full article

In the energy transition from fossil to renewable resources, gas is foreseen to play an important role. However, the composition of the gas is expected to change due to a wider variation of sources. In order to mitigate potential challenges for distributors and end-users, a new low-cost gas composition sensor was developed that will be able to monitor the composition and energy content of these gas sources, ranging from biogas to liquid natural gas (LNG). Together with industrial and academic partners a gas sensor was realized that can be inserted in an existing gas grid. A first demonstrator was realized that was small enough to be used in low and medium pressure gas pipes (100 mbarg—8 barg). Adding the pressure and temperature data to the chip readings enables to determine the concentrations of methane, ethane, propane, butane, nitrogen and carbon dioxide, including small fluctuations in water vapor pressure and subsequently calculate the Calorific Value, Wobbe Index and Methane Number. Full article

The Danish government has set an ambitious target to achieve 100% fossil independence across all energy sectors, which demands optimum utilization of renewable energy sources, such as wind and biogas, by 2050. Biogas production has increased, and the upgrading of biogas offers a broad range of applications, such as transportation, and gas grid injection for downstream utilization. The biogas has to meet natural gas quality prior to injection into the gas grid system. The investment costs of the gas grid, upgrading cost, and gas compression costs are the major challenges for integrating the biogas into the existing gas infrastructure. In this investigation, the Wobbe index (WI) for raw biogas and upgraded biogas was measured to evaluate the scenario for biogas injection into the gas grid system. It was found that raw biogas has to improve its WI from 28.3 MJ/m³(n) to a minimum of 50.76 MJ/m³(n) via upgrading, and compressed to 40 bar system, to supply the gas grid system for trading. Then, yearly gas consumption by larger gas consumers was studied to evaluate the alternative approach of biogas utilization to save upgrading and compression costs for gas grid injection. Full article

The fast and reliable analysis of the natural gas composition requires the simultaneous quantification of numerous gaseous components. To this end, fiber-enhanced Raman spectroscopy is a powerful tool to detect most components in a single measurement using a single laser source. However, practical issues such as detection limit, gas exchange time and background Raman signals from the fiber material still pose obstacles to utilizing the scheme in real-world settings. This paper compares the performance of two types of hollow-core photonic crystal fiber (PCF), namely photonic bandgap PCF and kagomé-style PCF, and assesses their potential for online determination of the Wobbe index. In contrast to bandgap PCF, kagomé-PCF allows for reliable detection of Raman-scattered photons even below 1200 cm⁻¹, which in turn enables fast and comprehensive assessment of the natural gas quality of arbitrary mixtures. Full article