Search Results (9)

Lead (Pb) is classified as a prevalent metallic pollutant, significantly impacting the ecological environment, especially human health. Consequently, it is crucial to develop adsorbent materials that are environmentally friendly, cost-effective, and which possess high selectivity. This study aims to fabricate a Pb(II)-imprinted acrylonitrile-co-acrylic acid composite material by using modified sand particles as the carrier, and then to investigate its properties. Through pretreatment of sand particles, acrylonitrile and acrylic acid were polymerized on the surface of modified sand particles, and Pb(II) served as a template ion for imprinting. A variety of characterization methods were used to verify the composite material and conduct an analysis of its morphology, chemical composition, and pore characteristics. The adsorption efficiency of this composite material for Pb(II) is comprehensively explored, with the process involving adsorption kinetics, adsorption isotherms, selective adsorption, and reuse experiments. Through static adsorption experiments, multiple elements influencing the adsorption ability of the composite material towards Pb(II) are investigated. It was demonstrated by the results that the composite material prepared possesses a rich pore structure and excellent Pb(II) recognition ability. The investigation on adsorption kinetics is in line with the quasi-first-order and quasi-second-order kinetic models, while the adsorption isotherm, obeys the Langmuir model. The ideal adsorption conditions were pH = 7, with the adsorption reaching equilibrium within 105 min. Even when multiple interfering ions were present, it still had high selectivity for Pb(II). The composite material showed an adsorption saturation capability reaching 41.83 mg·g⁻¹, considerably surpassing the non-imprinted counterpart. After being reused eight times, the composite material can still maintain an adsorption efficiency for Pb(II) that is above 79% and demonstrates high potential in the practical application environment. Full article

With the rapid development of industry, the discharge of heavy metal-containing wastewater poses a significant threat to aquatic and terrestrial environments as well as human health. This paper provides a brief introduction to the basic principles of ion-imprinted polymer preparation and focuses on the interaction between template ions and functional monomers. We summarized the current research status on typical heavy metal ions, such as Cu(II), Ni(II), Cd(II), Hg(II), Pb(II), and Cr(VI), as well as metalloid metal ions of the As and Sb classes. Furthermore, it discusses recent advances in multi-ion-imprinted polymers. Finally, the paper addresses the challenges faced by ion-imprinted technology and explores its prospects for application. Full article

Lead (Pb) is a hazardous metal that poses a significant threat to both the environment and human health. The presence of Pb in food products such as honey can pose a significant risk to human health and is therefore important to detect and monitor. In this study, we propose a voltammetric detection method using molecularly imprinted polymer (MIP) electrodes to detect Pb (II) ions in honey. Pb (II) ion-imprinted amino acid-based nanoparticles with magnetic properties on a carbon paste electrode (MIP-CPE) were designed to have high sensitivity and selectivity towards Pb (II) ions in the honey sample. Zetasizer measurements, electron spin resonance, and scanning electron microscopy were used to characterize magnetic polymeric nanoparticles. The results showed that the voltammetric detection method using MIP-CPE was able to accurately detect Pb (II) ions in honey samples with a low detection limit. The proposed method offers a simple, rapid, cost-effective solution for detecting Pb (II) ions in honey. It could potentially be applied to other food products to ensure their safety for human consumption. The MIP-CPE sensor was designed to have high sensitivity and selectivity towards Pb (II) ions in the honey sample. The results showed that the technique was able to deliver highly sensitive results since seven different concentrations were prepared and detected to obtain an R² of 0.9954, in addition to a low detection limit (LOD) of 0.0912 µM and a low quantification limit (LOQ) of 0.276 µM. Importantly, the analysis revealed no trace of Pb (II) ions in the honey samples obtained from Cyprus. Full article

This paper reports the successful development and application of an efficient method for quantifying Pb²⁺ in aqueous samples using a smartphone-based colorimetric device with an imprinted polymer (IIP). The IIP was synthesized by modifying the previous study; using rhodizonate, 2-acrylamido-2-methylpropane sulfonic acid (AMPS), N,N′-methylenebisacrylamide (MBA), and potassium persulfate (KPS). The polymers were then characterized. An absorption study was performed to determine the optimal conditions for the smartphone-based colorimetric device processing. The device consists of a black box (10 × 10 × 10 cm), which was designed to ensure repeatability of the image acquisition. The methodology involved the use of a smartphone camera to capture images of IIP previously exposed at Pb²⁺ solutions with various concentrations, and color channel values were calculated (RGB, YMK HSVI). PLS multivariate regression was performed, and the optimum working range (0–10 mg L⁻¹) was determined using seven principal components with a detection limit (LOD) of 0.215 mg L⁻¹ and R² = 0.998. The applicability of a colorimetric sensor in real samples showed a coefficient of variation (% RSD) of less than 9%, and inductively coupled plasma mass spectrometry (ICP–MS) was applied as the reference method. These results confirmed that the quantitation smartphone-based colorimetric sensor is a suitable analytical tool for reliable on-site Pb²⁺ monitoring. Full article

Lead contamination in aquatic products is one of the main hazard factors. The aptasensor is a promising detection method for lead ion (Pb(II)) because of its selectivity, but it is easily affected by pH. The combination of ion-imprinted polymers(IIP) with aptamers may improve their stability in different pH conditions. This paper developed a novel electrochemical biosensor for Pb(II) detection by using aptamer-imprinted polymer as a recognition element. The glassy carbon electrode was modified with gold nanoparticles and aptamers. After the aptamer was induced by Pb(II) to form a G-quadruplex conformation, a chitosan-graphene oxide was electrodeposited and cross-linked with glutaraldehyde to form an imprint layer, improving the stability of the biosensor. Under the optimal experimental conditions, the current signal change (∆I) showed a linear correlation of the content of Pb(II) in the range of 0.1–2.0 μg/mL with a detection limit of 0.0796 μg/mL (S/N = 3). The biosensor also exhibited high selectivity for the determination of Pb(II) in the presence of other interfering metal ion. At the same time, the stability of the imprinted layer made the sensor applicable to the detection environment with a pH of 6.4–8.0. Moreover, the sensor was successfully applied to the detection of Pb(II) in mantis shrimp. Full article

Cadmium is one of the many toxic elements for humans even at low concentrations, and it could exist in the environment for a long time. The ion imprinting technique has gained much attention due to its selective recognition performance. In this study, a cadmium ion imprinted maleic acid-co-acrylonitrile polymeric microsphere (Cd-I-MA-co-AN) was synthesized via precipitation polymerization using Cd(II) as a template ion, acrylonitrile and maleic acid as functional monomers, divinylbenzene as a cross-linker, and potassium persulfate as an initiator. UV–vis, SEM and FTIR were used for characterization, and the adsorption conditions were observed and optimized. The adsorption capacity and selectivity of Cd-I-MA-co-AN for Cd(II) were analyzed by flame atomic absorption spectrometry (FAAS). The results documented that the optimal pH, flow rate and eluent were 6, 2 mL min⁻¹ and 1 mol L⁻¹ nitric acid, respectively. Compared with the non-ion imprinted maleic acid-co-acrylonitrile polymeric microsphere (NI-MA-co-AN), Cd-I-MA-co-AN had a higher adsorption capacity. The saturated adsorption capacities of Cd-I-MA-co-AN and NI-MA-co-AN were 20.46 mg g⁻¹ and 7.64 mg g⁻¹, respectively. The adsorption behavior of Cd-I-MA-co-AN fitted with the Freundlich isotherm model. The relative selectivity coefficients of Cd-I-MA-co-AN for Cd(II) in the presence of Cu(II), Mn(II), Ni(II) and Pb(II) were 3.79, 3.39, 3.90 and 3.31, respectively. The Cd-I-MA-co-AN showed good selectivity for Cd(II). In addition, a reusability study showed that Cd-I-MA-co-AN can be recycled ten times and has high recovery in natural water samples. Full article

Heavy metal pollution is currently an increasing threat to the ecological environment, and the development of novel absorbents with remarkable adsorption performance and cost-effectiveness are highly desired. In this study, a cassava starch-based Pb(II)-imprinted thermo-responsive hydrogel (CPIT) had been prepared by using cassava starch as the bio-substrate, N-isopropyl acrylamide (NIPAM) as the thermo-responsive monomer, and Pb(II) as the template ions. Later, a variety of modern techniques including FTIR, DSC, SEM, and TGA were employed to comprehensively analyze the characteristic functional groups, thermo-responsibility, morphology, and thermal stability of CPIT. The obtained material exhibited superior performance in adsorption of Pb(II) and its maximum adsorption capacity was high—up to 114.6 mg/g under optimized conditions. Notably, the subsequent desorption (regeneration) process was fairly convenient by simply rinsing with cold deionized water and the highest desorption efficiency could be achieved as 93.8%. More importantly, the adsorption capacity of regenerated CPIT still maintained 88.2% of the value of starting material even after 10 recyclings. In addition, the excellence of CPIT in selective adsorption of Pb(II) should also be highlighted as its superior adsorption ability (97.9 mg/g) over the other seven interfering metal ions. Full article

Herein, we described the synthesis of a novel ion-imprinted membrane for the detection of palladium(II) prepared through the glutaraldehyde crosslinking of chitosan with a 4-[(4-Hydroxy)phenylazo]benzenesulfonic acid ligand trapped into the membrane. The imprinting technology was used to improve adsorption capacity and adsorption selectivity, and was combined with some advantages of the developed membrane, such as low cost and ease of preparation, water-friendly synthesis, and high biocompatible chitosan material. The membranes were characterized by Fourier Transform Infrared Spectroscopy (FTIR), Scanning Electron Microscopy (SEM), and Energy Dispersive X-ray Spectrometry (EDS). The results obtained showed a high swelling ratio with a maximum value of 16.4 (1640%) at pH 4 with a strong pH dependence. Batch rebinding experiments gave a maximum adsorption capacity of 101.6 mg of Pd(II) per gram of imprinted membrane. The Pd(II) adsorption behavior was well-described by a Langmuir model with a theoretical maximum adsorption capacity of 93.48 mg g⁻¹, similar to the experimental one. Finally, a selectivity study versus Ag(I), Pb(II), and Fe(III) ions demonstrated a good selectivity of chitosan-imprinted membrane towards Pd(II). Full article

Ion-imprinted polymers (IIPs) have received much attention in the fields of separation and purification. Nevertheless, selectivity of IIPs for trace target ions in complicated matrix remains a challenge. In this work, a cadmium magnetic ion-imprinted polymer (MIIP) was synthesized via surface imprinting, using methacrylic acid and acrylamide as dual functional monomers, vinyltrimethoxysilane as ligand, Fe₃O₄@SiO₂ as support, azodiisobutyronitrile as initiator, and ethylene glycol dimethacrylate as crosslinker. The MIIP was characterized by transmission electron microscopy, infrared spectroscopy, thermal gravimetric analysis, and a vibrating sample magnetometer. The maximum adsorption capacities of the MIIP and magnetic non-imprinted polymer for Cd(II) were 46.8 and 14.7 mg·g⁻¹, respectively. The selectivity factors of Pb(II), Cu(II), and Ni(II) were 3.17, 2.97, and 2.57, respectively, which were greater than 1. The adsorption behavior of Cd(II) followed the Freundlich isotherm and a pseudo second order model. The MIIP was successfully used for the selective extraction and determination of trace Cd(II) in representative rice samples. The limit of detection and recovery of the method was 0.05 µg·L⁻¹ and 80–103%, respectively, with a relative standard deviation less than 4.8%. This study shows that MIIP provides an attractive strategy for heavy metal detection. Full article