Search Results (4)

The paper considers an extended interpretation of the second law of thermodynamics and its implications to power conversion optimization in multidomain systems. First, a generalized, domain-independent version of the classical Gouy-Stodola theorem is derived for interconnected systems which satisfy the Clausius postulate of the second law. Mechanical, electrical and more general Hamiltonian systems do not satisfy this postulate, however the related property of energy cyclodirectionality may be satisfied. A generalized version of the Gouy-Stodola theorem is then obtained in inequality form for systems satisfying this property. The result defines average forms of entropy generation and lost work for multi-domain systems. The paper then formulates an optimal control problem for a representative electromechanical system, obtaining complete, closed-form solutions for the load power transfer and energy harvesting cases. The results indicate that entropy generation minimization is akin to the maximum power transfer theorem. For the power harvesting case, closed-loop stability is guaranteed and practical controllers may be designed. The approach is compared against direct minimization of losses, both theoretically and with Monte Carlo simulations. Full article

The review provides a pedagogical but comprehensive introduction to the foundations of a recently proposed statistical mechanics ($\mu$NEQT) of a stable nonequilibrium thermodynamic body, which may be either isolated or interacting. It is an extension of the well-established equilibrium statistical mechanics by considering microstates $\left\{{\mathfrak{m}}_k\right\}$ in an extended state space in which macrostates (obtained by ensemble averaging $\widehat{A}$) are uniquely specified so they share many properties of stable equilibrium macrostates. The extension requires an appropriate extended state space, three distinct infinitessimals $d_{\alpha }=(d,d_{\mathrm{e}},d_{\mathrm{i}})$ operating on various quantities q during a process, and the concept of reduction. The mechanical process quantities (no stochasticity) like macrowork are given by $\widehat{A}{d}_{\alpha }\mathsf{q}$, but the stochastic quantities ${\widehat{C}}_{\alpha }\mathsf{q}$ like macroheat emerge from the commutator ${\widehat{C}}_{\alpha }$ of $d_{\alpha }$ and $\widehat{A}$. Under the very common assumptions of quasi-additivity and quasi-independence, exchange microquantities $d_{\mathrm{e}}$q${}_k$ such as exchange microwork and microheat become nonfluctuating over $\left\{{\mathfrak{m}}_k\right\}$ as will be explained, a fact that does not seem to have been appreciated so far in diverse branches of modern statistical thermodynamics (fluctuation theorems, quantum thermodynamics, stochastic thermodynamics, etc.) that all use exchange quantities. In contrast, dq${}_k$ and $d_{\mathrm{i}}$q${}_k$ are always fluctuating. There is no analog of the first law for a microstate as the latter is a purely mechanical construct. The second law emerges as a consequence of the stability of the system, and cannot be violated unless stability is abandoned. There is also an important thermodynamic identity $d_{\mathrm{i}}Q\equiv d_{\mathrm{i}}W$$\ge 0$ with important physical implications as it generalizes the well-known result of Count Rumford and the Gouy-Stodola theorem of classical thermodynamics. The $\mu$NEQT has far-reaching consequences with new results, and presents a new understanding of thermodynamics even of an isolated system at the microstate level, which has been an unsolved problem. We end the review by applying it to three different problems of fundamental interest. Full article

Closed, steady or cyclic thermodynamic systems, which have temperature variations over their boundaries, can represent an extremely large range of plants, devices or natural objects, such as combined heating, cooling and power plants, computers and data centres, and planets. Energy transfer rates can occur across the boundary, which are characterized as heat or work. We focus on the finite time thermodynamics aspects, on energy-based performance parameters, on rational efficiency and on the environmental reference temperature. To do this, we examine the net work rate of a closed, steady or cyclic system bounded by thermal resistances linked to isothermal reservoirs in terms of the first and second laws of thermodynamics. Citing relevant references from the literature, we propose a methodology that can improve the thermodynamic analysis of an energy-transforming or an exergy-destroying plant. Through the reflections and analysis presented, we have found an explanation of the second law that clarifies the link between the Clausius integral of heat over temperature and the reference temperature of the Gouy–Stodola theorem. With this insight and approach, the specification of the environmental reference temperature in exergy analysis becomes more solid. We have explained the relationship between the Curzon Ahlborn heat engine and an irreversible Carnot heat engine. We have outlined the nature of subsystem rational efficiencies and have found Rant’s anergy to play an important role. We postulate that heat transfer through thermal resistance is the sole basis of irreversibility. Full article

All real processes generate entropy and the power/exergy loss is usually determined by means of the Gouy-Stodola law. If the system only exchanges heat at the environmental temperature, the Gouy-Stodola law gives the correct loss of power. However, most industrial processes exchange heat at higher or lower temperatures than the actual environmental temperature. When calculating the real loss of power in these cases, the Gouy-Stodola law does not give the correct loss if the actual environmental temperature is used. The first aim of this paper is to show through simple steam turbine examples that the previous statement is true. The second aim of the paper is to define the effective temperature to calculate the real power loss of the system with the Gouy-Stodola law, and to apply it to turbine examples. Example calculations also show that the correct power loss can be defined if the effective temperature is used instead of the real environmental temperature. Full article