Search Results (22)

Mining activity in Peru generates environmental liabilities with the potential to release toxic metals into the environment. This study conducted a comprehensive physical, chemical, mineralogical, and toxicological characterization of ten active and inactive tailings samples from the Arequipa region in southern Peru. Particle size distribution analysis, inductively coupled plasma atomic emission spectroscopy (ICP-AES), scanning electron microscopy with energy-dispersive spectroscopy (SEM-EDS), and the Toxicity Characteristic Leaching Procedure (TCLP) followed by ICP-MS were employed. The results revealed variable particle size distributions, with the sample of Secocha exhibiting the finest granulometry. Chemically, 8 out of 10 samples exhibited concentrations of at least two metals surpassing the Peruvian Environmental Quality Standards (EQS) for soils with values reaching >6000 mg/kg of arsenic (Paraiso), 193.1 mg/kg of mercury (Mollehuaca), and 2309 mg/kg of zinc (Paraiso). Mineralogical analysis revealed the presence of sulfides such as arsenopyrite, cinnabar, galena, and sphalerite, along with uraninite in the Otapara sample. In the TCLP tests, 5 out of 10 samples released at least two metals exceeding the environmental standards on water quality, with concentrations up to 0.401 mg/L for mercury (Paraiso), 0.590 mg/L for lead (Paraiso), and 9.286 mg/L for zinc (Kiowa Cobre). These results demonstrate elevated levels of Potentially Toxic Elements (PTEs) in both solid and dissolved states, reflecting a critical geochemical risk in the evaluated areas. Full article

The study investigates the contribution of technology (TECH), quantified by Internet penetration, in influencing tourism performance (TP) among the top ten touristic nations in Europe: France, Spain, Italy, Turkey, the United Kingdom, Germany, Greece, Austria, Portugal, and the Netherlands. Using panel data from 2000–2022, the study includes additional structural controls like environment quality, gross domestic production (GDP) per capita, exchange rate (ER), and safety index (SI). The Method of Moments Quantile Regression (MMQR) is employed to capture heterogeneous effects at different levels of TP, and Driscoll–Kraay standard error (DKSE) correction is employed to make the analysis robust against autocorrelation as well as cross-sectional dependence. Spectral–Granger causality tests are also conducted to check short- and long-run dynamics in the relationships. Empirical results are that TECH and SI are important in TP at all quantiles, but with stronger effects for lower-performing countries. Environmental quality (EQ) and GDP per capita (GDPPC) exert increasing impacts at upper quantiles, suggesting their importance in sustaining high-level tourism economies. ER effects are limited and primarily short-term. The findings highlight the need for integrated digital, environmental, and economic policies to achieve sustainable tourism development. The paper contributes to tourism research by providing a comprehensive, frequency-sensitive, and distributional analysis of macroeconomic determinants of tourism in highly developed European tourist destinations. Full article

Circulating fluidized bed fly ash (CFBFA) stockpiles release alkaline dust, high-pH leachate, and secondary CO₂/SO₂—an environmental burden that exceeds 240 Mt yr⁻¹ in China alone. Yet, barely 25% is recycled, because the high f-CaO/SO₃ contents destabilize conventional cementitious products. Here, we presents a pressurized flue gas heat curing (FHC) route to bridge this scientific deficit, converting up to 85 wt% CFBFA into structural lightweight gravel. The gypsum dosage was optimized, and a 1:16 (gypsum/CFBFA) ratio delivered the best compromise between early ettringite nucleation and CO₂-uptake capacity, yielding the highest overall quality. The optimal mix reaches 9.13 MPa 28-day crushing strength, 4.27% in situ CO₂ uptake, 1.75 g cm⁻³ bulk density, and 3.59% water absorption. Multi-technique analyses (SEM, XRD, FTIR, TG-DTG, and MIP) show that FHC rapidly consumes expansive phases, suppresses undesirable granular-ettringite formation, and produces a dense calcite/needle-AFt skeleton. The FHC-treated CFBFA composite gravel demonstrates 30.43% higher crushing strength than JTG/TF20-2015 standards, accompanied by a water absorption rate 28.2% lower than recent studies. Its superior strength and durability highlight its potential as a low-carbon lightweight aggregate for structural engineering. A life-cycle inventory gives a cradle-to-gate energy demand of 1128 MJ t⁻¹ and a process GWP of 226 kg CO₂-eq t⁻¹. Consequently, higher point-source emissions paired with immediate mineral sequestration translate into a low overall climate footprint and eliminate the need for CFBFA landfilling. Full article

This study assesses the spatial distribution and contamination levels of some heavy metals (HMs), i.e., cadmium (Cd), chromium (Cr), copper (Cu), nickel (Ni), and lead (Pb), in seawater and surface sediments along the Romanian Black Sea coast (RBSC). Sampling was conducted at 40 stations across 12 transects during May–June 2021, and the measured levels of HM concentrations were compared with Environmental Quality Standards (EQS), i.e., maximum allowable concentration (MAC) values, for seawater and effects range-low (ERL) thresholds for sediments. HM concentrations were measured using high-resolution continuum source atomic absorption spectrometry (HR-CS AAS). In seawater, the levels of Cd, Cu, and Pb concentrations exceeded the MAC values at three stations located in areas influenced by the Danube River or anthropogenic activities. In sediments, exceedances of ERL thresholds were found for Ni at 11 stations, for Cu at three stations, and for Pb at one station. HM contamination of sediment samples collected from these stations can be caused by both natural and anthropogenic sources, e.g., the Danube River, rock/soil weathering and erosion, agricultural runoff, port and construction activities, maritime and road transport, coastal tourism, petrochemical industry, wastewater discharges, offshore oil and gas extraction. Principal Component Analysis (PCA) provided valuable information about the relationships between relevant variables, including water depth and HM concentrations in seawater and sediments, and potential sources of contamination. The results highlight the influence of fluvial inputs and localized human activities on HM contamination. While the overall chemical status of Romanian Black Sea waters and sediments remains favorable, targeted management strategies are needed to address localized pollution hotspots and mitigate potential ecological risks. These findings provide valuable insights for environmental monitoring and sustainable coastal management. Full article

Most drugs excreted in urine are not filtered by wastewater treatment plants and end up in aquatic systems. At concentrations measured in waters, toxic effects on species have been described. Second, most of the drug consumption is attributable to primary care prescriptions. We thus present here, an ecotoxicity classification of the most sold drugs in primary care in Switzerland. Three datasets were combined: (1) surveyed ecotoxic drugs by the Swiss National Surface Water Quality Monitoring Programme and its European equivalent, (2) the top 50 drugs by sale in primary care in Switzerland, and (3) active pharmaceutical ingredient (API) concentrations in Lake Geneva and the rivers of the canton of Vaud between 2017 and 2022. We classified APIs into five categories from the safest to the least safe: (1) APIs found in concentrations (C) <10× their environmental quality standard (EQS·10⁻¹), (2) EQS·10⁻¹ < C < EQS and not listed by the Swiss or the EU Watch List, (3) EQS·10⁻¹ < C < EQS and listed, (4) C > EQS and not listed, and (5) C > EQS and listed. We obtained full ecotoxicological data for 35 APIs. Fifteen APIs were designated as safe (category (1):paracetamol, tramadol, amisulpride, citalopram, mirtazapine, metformin, gabapentin, lamotrigine, primidone, candesartan, irbesartan, atenolol, hydrochlorothiazide, ofloxacin, sulfadiazine), eleven as intermediately safe, and nine were of concern (azithromycin, ciprofloxacin, clarithromycin, sulfamethoxazole, carbamazepine, diclofenac, ibuprofen, iomeprol, iopromide). Full data were available for only one-third of the drugs most sold in primary care. Where data do exist, we observed significant differences in environmental impact among the same class of drugs. Our classification could therefore help guide doctors to adopt more eco-friendly prescriptions. Full article

The effectiveness of thermal treatment technologies for the remediation of soils contaminated with heavy hydrocarbons has been extensively documented in the scientific literature. In general, high-concentration crude-oil-contaminated soil is treated with high-temperature thermal desorption (HTTD) in order to achieve high remediation efficiency. However, this process has the unintended consequence of destroying soil fertility. Low-temperature thermal desorption (LTTD) represents an alternative approach that has been developed with the objective of remediating heavily crude-oil-contaminated soil in a more rapid and cost-effective manner while simultaneously enhancing soil fertility. The thermal desorption unit (TDU) was employed using both LTTD and HTTD, operating at 300 °C and 500 °C, respectively, with a 30 min residence time in the kiln. The concentration of total petroleum hydrocarbons (TPH) in both the LTTD- and HTTD-treated soils was found to be less than 1% by weight, thereby below regulatory standards. The environmental impacts of both processes were assessed using the OpenLCA software version 2.0. The HTTD process exhibited a total abiotic depletion potential (ADP) impact of 1.63 × 10⁻⁴ MJ and a global warming potential (GWP) of 414 kg CO₂-eq. In contrast, LTTD demonstrated lower impacts, with an ADP of 1.29 × 10⁻⁴ MJ and a GWP of 278 kg CO₂-eq. The transition from HTTD to LTTD resulted in a notable reduction in ADP by 20.5% and in GWP by 32.9%. The application of LTTD-treated soil coated with coke or carbonized residues has been demonstrated to serve as an effective soil amendment, with the capacity to sequester approximately 50% of organic hydrocarbon contaminants. The results of this study illustrate the potential of LTTD for not only economical and rapid soil remediation but also the enhancement of soil quality through beneficial reuse. Full article

Although wood biomass is mostly used to produce solid biofuel pellets, it is important to evaluate the possibilities of using other types of biomass as well. It is not only important to obtain biofuel pellets of suitable quality but also to ensure a sustainable process of producing and using these pellets for energy production. This paper presents an evaluation of the quality characteristics of seven different biofuel pellets made from multi-crop plants (fibrous hemp, maize, and faba bean) and a life cycle assessment (LCA) of the heat production by burning these pellets. The physical-mechanical properties and elemental composition of the pellets are determined according to international standards, as indicated in the methodology section. The LCA was performed using the SimaPro 9.5 software. The complete life cycle from cradle-to-grave is assessed, i.e., from growing plants to spreading ash obtained from pellet burning. An analysis showed that in most cases the produced pellets met the requirements of the standard ISO 17225-6:2021. The lowest negative environmental impact associated with the production of 1 GJ of thermal energy was for pellets made from fibrous hemp and maize biomass (MIX2-1) and pellets made from fibrous hemp and faba bean biomass (MIX2-3). Production of pellets from maize biomass (S-Mz) was found to have the highest carbon footprint (29.1 CO_2eq GJ⁻¹) and was associated with the lowest crop yield compared to the other six scenarios. Full article

Marinas are semi-enclosed environments characterised by reduced hydrodynamic energy, high sedimentation rates, and reduced oxygen levels. The ongoing development of activities and infrastructure construction are leading to deterioration in the quality of coastal aquatic environments, creating environmental risks. Trace metal elements (TMEs) and organotins are significant contaminants, prompting this study to evaluate the added value of spatiotemporal monitoring compared to one-time sediment assessments. Two Mediterranean harbours, Port Camargue (PC) and Port Carnon (C), differing in morphology and size, were monitored for a year with regular water sampling, focusing on TMEs and organotins. Sediment contamination, notably in the technical zone, revealed concentrations of Cu (309 and 1210 mg kg⁻¹ for C and PC, respectively), Zn (242 and 425 mg kg⁻¹ for C and PC, respectively), and tributyltin (TBT) (198 and 4678 µg (Sn) kg⁻¹ for C and PC, respectively) surpassing the effect range medium (ERM), while other marina stations generally stayed below this threshold. Spatiotemporal water monitoring highlighted concentrations above environmental quality standards (EQS) at all stations of the larger marina. This exceedance was systematic for Cu and Zn in all samples, ranging respectively between 2.54 and 37.56 µg (Sn) L⁻¹ and 0.63 and 33.48 µg (Sn) L⁻¹. A notable temporal dynamic for TBT and Cu was also observed. Conversely, the open marina, connected to the open sea, rarely exhibited concentrations above EQS in water, despite sediment concentrations occasionally exceeding ERM values. This underscores that risk assessment in these ecosystems cannot rely solely on sediment characterisation. Full article

Measurement quality is about fulfilling analytical requirements, which should be based on the intended use of the results. Within the European Union, environmental requirements can be set in a directive based on the maximum allowable concentration of a substance in air, soil or water, e.g., an Environmental Quality Standard (EQS) or an Emission Limit Value (EVS); and the requirements on measurement quality, e.g., the limit of quantification (LOQ), within-laboratory reproducibility (s_Rw) or measurement uncertainty (MU). This presentation is about publicly available guidelines that can help the analytical chemist working in the laboratory by implementing a specific method to (1) set up internal quality control over the whole concentration range based on the requirements through the use of target control limits, (2) perform ongoing internal quality control based on only two rules, (3) plan method validation, and (4) estimate the MU based on quality control and validation data. Normally for instrumental methods, the MU is estimated as a relative uncertainty at higher concentrations and as an absolute uncertainty at lower concentrations close to the LOQ. For quality control and MU estimation, free open source software will be presented. Full article

When individual purchasing power increases in society, there is a trend toward a quantitative and qualitative increase in the consumption of products. Considering the magnitude of beef production in Brazil, environmental impacts are important factors for the domestic and international markets. This study assessed a Brazilian feedlot system characterized by high animal welfare standards that produces high-quality beef that is more marbled than that produced in grass-fed systems. We assessed the environmental impacts and compared premium and super-premium beef produced in a feedlot system using a partial Life Cycle Assessment (LCA). Data were collected directly on the property analyzed, considering environmental inputs and outputs and economic factors associated with the production stages of each line (premium versus super-premium). The results show that high-quality beef has, beyond a greater financial cost, an environmental cost, with the super-premium line producing a 286% higher carbon footprint, 297% more eutrophication, and three times higher acidification potential and land use than the premium line. The results of the environmental impacts agree with the results of production costs, reflecting a 282.82% higher production cost in super-premium than in premium animals. Footprints of 5.0323 kg, 4.7746 kg, and 8.8858 kg CO₂ eq./kg live weight gain at the feedlot were found in the three lines. Full article

For the first time, a macrophyte-based assessment of ecological status was related to the accumulated heavy metals and trace elements (Al, As, Cd, Co, Cr, Cu, Fe, Hg, Mn, Ni, Pb, Zn) in aquatic plants. Three moss and two vascular plant species were applied as biomonitors: Fontinalis antipyretica Hedw., Leptodictyum riparium (Hedw.) Warnst., Platyhypnidium riparioides (Hedw.) Dixon, invasive Elodea canadensis Michx., and Myriophyllum spicatum L. Three streams were assessed as good at a high ecological status which correlated with low contamination based on calculated contamination factors (CFs) and metal pollution index (MPI). Two sites evaluated in moderate ecological status were revealed to be in heavy trace element contamination. The most significant was the accumulation of moss samples from the Chepelarska River under mining impact. Mercury exceeded the environmental quality standard (EQS) for biota in three of the studied upland river sites. Full article

Due to potential pressure from industrial and municipal activities, urban water bodies are at risk of not achieving the environmental objectives of the Water Framework Directive (WFD) by 2027. This study comprised the quality assessment of water body “Kłodnica do Promnej (bez)” under a strong anthropogenic influence. The main potential sources of pollution in the catchment were identified and the related characteristic contaminants were analysed. The obtained values of pollutants were compared with the limit values for surface waters from Regulation (Journal of Laws 2021, item 1475). The results confirmed that the analysed water body located in highly urbanized area is characterized by poor water quality and chemical status below the good status. The main threat to the aquatic environment is high salinity associated with the presence of mine water discharges. Moreover, the priority substances, such as Cd, Ni and Pb, exceeded the environmental quality standards values (EQS) in most of the designated measurement points. Due to the fact that water ecosystems do not constitute stand-alone structures, but are included in a wider socio-ecological system, the implementation of an integrated approach to characterizing the existing status of the water bodies and estimating the risk posed to the aquatic ecosystem is a crucial element of the catchment management process in the context of the provisions of the WFD. Full article

One of the problematic sectors according to GHG (greenhouse gas) and ammonia (NH₃) emission quantities is agriculture. Without endangering food production (and intensifying), GHG emissions come from all sources in animal husbandry. The aim of this study was to comprehensively reduce GHG emissions by applying a holistic process management model to one of the most popular cowsheds in Lithuania (260-seat boxing cowshed, cows are milked on site, computerized management of technological processes, productivity of 8600 kg of milk, barn system, and liquid manure). Considering the cow keeping technology applied on the farm, the equipment used, and the feed production and ration system, a model for the management of technological parameters of production processes was prepared for the farm. This model balanced trade-offs among animal welfare, cow productivity, production costs, and GHG and NH₃ emissions. The aim of the research was the adaptation of the integrated model to fully control, manage, and optimize milk production processes through bio- and engineering innovations to implement climate-friendly feed production and feeding and feed rationing systems, to improve animal housing and working conditions, and to reduce GHG and NH₃ emissions without increasing production costs. The environmental impact assessment was performed with SimaPro 9.1 process modeling software. Data from milk production, biomass cultivation, and feed preparation, transportation, and equipment were used from the Ecoinvent v3 database. Based on the LML-I calculation methodology, the effect of processes was determined. To quantify the potential emissions in the dairy farm, the emission factors were estimated using a life cycle assessment method per functional unit—1000 kg—of standardized milk. Grass silage, maize silage, and feed concentrate were found to account for the largest share of gas emissions—26.09% (107.39 kg CO₂ eq. FU⁻¹), 22.70% (93.44 kg CO₂ eq. FU⁻¹), and 21.85% (89.92 kg CO₂ eq. FU⁻¹) of the total CO₂ emissions during the process, respectively. Considering the critical points of the classic SC scenario, the cultivation technology was adjusted, where 50% of N fertilizers were replaced by bioproducts (biological preparations). Both scenarios—classic SC (control variant) and Bio SC (variants using bioproducts)—were evaluated for comparison. The use of biopreparations in the categories reduced the environmental impact from 0.1% to 45.7% in dairy production technology grass silage, barley grain, hay production, and corn silage stocks. The carbon footprint of the sustainable bio-based milk production (0.393 kg CO₂ eq. kg⁻¹ FPCM (fat- and protein-adjusted milk)) was lower by 4.6% compared to the average Lithuanian classic dairy farm (0.412 kg CO₂ eq. kg⁻¹ FPCM). Based on this methodology, it is possible to assess many dairy farms and address critical points in an integrated way, which can help to improve the quality of dairy production and the environment. Full article

The circular economy will play an important role in the reduction of carbon emissions and poplar might be one of the winning choices according to sustainable development. As for agricultural crops, high-quality production is strictly related to genetic variability and best management practice. The main objective of this study was to analyze different stand management options to quantify differences on carbon emission and environmental impacts. Moreover, the study was focused on the assessment of differences between standard poplar management for veneer and poplar management according to sustainable production (such as the PEFC certification scheme). The system boundaries embraced fertilization (inorganic or organic), agricultural operations, machinery, and field emissions associated with poplar cultivation. The environmental impacts were quantified by a life cycle assessment (LCA) calculation using SIMAPRO software v8.0 with different databases. The primary data of poplar stands were collected during a decades-long Italian experience. A reduction of carbon emissions was observed in the stand managed with MSA clones (Case “Mezzi PEFC”), and negative emissions were observed due to organic fertilization (scenarios 7m-29 t CO₂-eq ha⁻¹ and 26M-129 t CO₂-eq ha⁻¹). In all cultivation scenarios, the environmental impacts were lower than conventional crops in the study area, such as corn. A higher impact was observed in the 26M scenario with oversized machinery for stand management. These data can also contribute to poplar stand modeling and represent a basis for future research developments in this field. Full article

The presence of ten metals (Cd, Ni, Pb, Cr, Cu, Zn, Al, Fe, Mn, and Co) was investigated in the final discharge of six facilities, including four wastewater treatment plants, which were continuously discharging treated wastewater to the coastal environment in Gran Canaria Island. A four-day sampling campaign was carried out at each facility in July 2020, in which both the spot samplings technique and the diffusive gradient in thin-film technique (DGT) were carried out to measure total dissolved metals and the in situ labile metal fraction, respectively. After the necessary sample preparation steps, measurements were carried out by ICP-MS for both samplings. Raw data referred to the spot total dissolved and DGT-labile metal concentrations were reported. In general, the average metal concentrations were dispersed in a broad range. As expected, the highest metal contents were found in those facilities with larger industrial contributions. The values of annual average environmental quality standards (AA-EQS) were used to assess the total dissolved metal concentrations for every metal in every final discharge. In only one of the studied facilities, some metals (Ni and Zn) exceeded these EQS within the receiving waterbody, highlighting the need for more efficient treatment targeted towards a specific discharging-water quality. In addition, the total dissolved and labile metal daily fluxes of discharge were calculated to estimate the contribution of every effluent to the receiving water bodies. Full article