Search Results (24)

The Cenozoic Nankang Basin in China records a complex series of tectonic, magmatic, metamorphic, and sedimentary events associated with the surrounding Shiwanshan, Liuwanshan, and Yunkaishan orogenic systems. The Nankang Basin is a critical location for studying the Cenozoic tectono–sedimentary evolution and strategic mineral resources of the southern Cathaysia Block. We used core samples from multiple boreholes and regional geological survey data to analyze the rock assemblages, sediment types, and sedimentary facies of the Nankang Basin. In addition, we analyzed the detrital zircon U–Pb geochronology, sandstone detrital compositions, heavy mineral assemblages, and major element geochemistry. The detrital zircon grains from Cenozoic sandstones in the Nankang Basin have age peaks at 2500–2000, 1100–900, 500–400, and 300–200 Ma, with most grains having ages of 500–400 or 300–200 Ma. The provenance analysis indicates that the 300–200 Ma zircon grains originated mainly from the Liuwanshan pluton; the 500–400 Ma zircon grains originated from the Ningtan pluton; and the 2500–2000 and 1100–900 Ma zircon grains originated from the Lower Silurian Liantan Formation and Middle Devonian Xindu Formation. This indicates that the provenance of Cenozoic sandstones in the Nankang Basin primarily originates from Paleozoic–Early Mesozoic igneous in the surrounding area, while the regional old sedimentary rocks possibly serve as intermediate sedimentary reservoirs. The detrital compositions of the sandstones and heavy mineral assemblages indicate a change in the tectonic setting during the deposition of the Nankang and Zhanjiang Formations, with a change in the source of the sediments due to the uplift of the Shizishan. During the deposition of the Nankang Formation, the sediment transport direction was to the NNW, whereas during the deposition of the Zhanjiang Formation, it was to the NNE. The uplift of the Shizishan most probably occurred during the late Neogene and early Quaternary, separating the Hepu and Nankang Basins. Full article

Divergent mid-Silurian (late Wenlock) and latest Silurian–earliest Devonian (Pridoli–Lochkovian) ages have been proposed for the strata bearing the millipede Pneumodesmus newmani, the oldest known undoubted air-breathing land animal, marking a significant event in the evolution of the first land biota. The late Wenlock age is based on physically correlating a non-marine section dated with spores and detrital zircon dates, across a fault, with a distinctly different non-marine section bearing the millipede. The Pridoli–Lochkovian ages are based on vertebrate fossils and detrital zircon dates from this latter section. A review of the available lithostratigraphic, petrological, and biostratigraphic data, plus detrital zircon dating of the basal Old Red Sandstone around Stonehaven, shows that the two dated sections have strata that are of different depositional environments, sources, and ages and that the totality of the evidence firmly dates the millipede-bearing strata as Pridoli–Lochkovian. Full article

The Junggar Basin basement comprises microcontinental blocks amalgamated through successive paleo-oceanic accretion events. Stratigraphic and provenance studies within the basin are crucial for reconstructing its evolution and understanding the closure of paleo-oceanic systems. This study presents an integrated petrographic and geochemical analysis of the Lower Jurassic Badaowan Formation sandstones in the Dongdaohaizi Depression, located in the eastern Junggar Basin. The results reveal a progressive decrease in lithic fragment content and an increase in quartz content from older to younger strata within the Badaowan Formation, indicating an increase in compositional maturity. Provenance analysis indicates that the sandstones are predominantly derived from tuffaceous rocks, granites, basalts, and minor metamorphic rocks. Heavy mineral assemblages, including zircon, chromian spinel, tourmaline, and garnet, suggest parent rocks consisting primarily of intermediate to acidic igneous rocks, mafic igneous rocks, and metamorphic rocks. Integrated petrographic and geochemical data from the surrounding areas of the Dongdaohaizi Depression confirm that the Badaowan Formation sandstones are primarily sourced from the eastern Kelameili Mountain. The continued uplift and migration of the Kelameili Mountain during the Early Jurassic played a dominant role in shaping the sedimentary provenance. LA-ICP-MS analyses reveal that the rare earth element (REE) concentrations in the Lower Jurassic sandstones are slightly lower than the average REE content of the upper continental crust. The sandstones exhibit weak differentiation between light and heavy REEs, reflecting a depositional environment characterized by anoxic reducing conditions. Geochemical results indicate a tectonic setting dominated by a passive continental margin and continental island arc in the source area. Synthesizing these findings with related studies, we propose that the Kelameili Ocean, as part of the Paleo-Asian Ocean, underwent a complex evolution involving multiple oceanic basins and microcontinental subduction–collision systems. From the Middle Ordovician to Late Silurian, the Kelameili region evolved as a passive continental margin. With the onset of subduction during the Middle Devonian to Early Carboniferous, the eastern Junggar Basin transitioned into a continental island arc system. This tectonic transition was likely driven by episodic or bidirectional subduction of the Kelameili Ocean. Full article

Lithuania is a Baltic European country which shares borders with Poland, Belarus, Latvia, and Russia and has a geothermal anomaly in the southwestern region. It consists of two main geothermal complexed, i.e., Devonian and Cambrian with a temperature of up to 40 °C (at a depth of 1000 m) and 96 °C (at a depth of 2000 m), respectively. The Devonian complex is composed of an unconsolidated sandstone formation with porosity and permeability in the range of 4–31% and 200 mD–6000 mD, respectively, and these make it a favorable candidate for a low enthalpy geothermal complex because of the high water production rates. This study evaluates the geothermal potential in the Devonian complex of the selected sites for commercial development. The study utilizes the mechanistic modelling approach including uncertainty management to forecast the water production rates and estimate the power generation capacity. Lastly, the study reveals that it is feasible to produce 6 MW to 60 MW of power from the existing vertical wells for a period of 25 years. Furthermore, reactive transport modelling also proves that there is dissolution and precipitation of the minerals near and away from the wellbore, respectively, which impairs the reservoir quality and further concludes that there is an effect of time on re-injection which should be considered to enhance the reservoir quality for future operations. In addition to that, no effect of the re-injection temperature of the produced water is observed. Full article

The Late Paleozoic strata on the northwestern margin of the Tarim Block provide valuable insights into the subduction and collision processes that formed the Southwest Tianshan Orogenic Belt. This study integrates detrital zircon U-Pb dating and sandstone geochemical analysis of the Balikelike and Kalundaer formations to examine sedimentary provenance and tectonic settings during the Cisuralian–Guadalupian Epoch in the Keping area on the northwestern margin of the Tarim Block. Three of five Precambrian detrital zircon U-Pb age populations, 2500–2300 and 2000–1800 Ma and 900–600 Ma, are likely related to the fragmentation of the Columbia supercontinent and Rodinia’s assembly, respectively. Two Paleozoic detrital zircons, 500–380 Ma, are associated with Paleozoic magmatism. Among them, ~295 Ma zircons are associated with post-collisional extension and emplacement of the Tarim Large Igneous Province. Geochemical analysis of sandstones, coupled with tectonic reconstruction, indicates a passive continental margin setting in the northwestern margin of the Tarim Block during the Silurian Period, later transitioned to a foreland basin from the Pennsylvanian to the Guadalupian Epochs. The crustal transformation from the Middle-late Devonian to Early Mississippian marked the closure of the South Tianshan Ocean (STO), involving a soft collision and significant uplift, with major orogenesis occurring in the Late Guadalupian. Five key stages are identified in the evolution of the foreland basin: (1) Middle-late Devonian to Early Mississippian initiation (remnant ocean basin stage); (2) Late Mississippian to Early Pennsylvanian early stage; (3) Late Pennsylvanian to Early Cisuralian middle stage; (4) the Late Cisuralian stage; and (5) the terminal Guadalupian stage. These findings provide new constraints on when STO closed and propose an innovative foreland basin evolution model during the late post-collisional phase from the Late Mississippian to Guadalupian. Collectively, the data advance our understanding of the tectonic processes that shaped the northwestern Tarim Block, with broader implications for Paleozoic geodynamics. Full article

Lithuania is located on the East of Baltic sedimentary basin and has a geothermal anomaly situated in the southwestern region of the country. There are two primary geothermal complexes within the anomaly, composed of Cambrian and Devonian aquifers. The Cambrian formation is composed of sandstones that have a reservoir temperature reaching up to 96 °C (depth > 2000 m). The Devonian aquifer is composed of unconsolidated sands of Parnu–Kemeri and has a reservoir temperature of up to 46 °C (depth > 1000 m). Historically, both formations have been investigated for geothermal energy production. In this article, we present a detailed literature review of the geothermal work carried out on both formations, including past, present, and some possible future studies. The study presented in this paper highlights the key findings of previous research work, summarizes the research gaps, and then elaborates on the possible applications of emerging technologies to bridge the research gaps and improve our understanding of geothermal complexes in Lithuania. Although it is not the main aim of this article, this article also touches upon the important need to develop 2D/3D numerical models, to quantify uncertainties, in the evaluation of the geothermal potential in Lithuania for commercial development. This study also highlights possibilities of extending geothermal development to depleted hydrocarbon reservoirs through repurposing the high-water-production wells. Moreover, from the literature review, it can be concluded that the Lithuanian geothermal aquifers are hyper-saline in nature and temperature changes lead to the deposition of salts both upstream and downstream of the reservoir. Therefore, there is a need for developing multiphysics thermo-mechanical–chemical (THMC) models for evaluation of reservoir behavior. The literature also describes the potential use and development of the THMC model as a part of future work that must be carried out. Full article

Lithuania has a geothermal anomaly situated in the southwestern region of the country. This anomaly is comprised of two primary geothermal complexes located in western Lithuania. The first complex is characterized by the Pärnu–Kemeri Devonian sandstone aquifers, which exhibit exceptionally good flow properties. However, the reservoir temperatures in this complex only reach up to 45 °C. The second complex encompasses Cambrian sandstone reservoirs. Although these Cambrian sandstone reservoirs exhibit high temperatures, with the highest reservoir temperatures reaching up to 96 °C, these Cambrian sandstone reservoirs have less favorable petrophysical properties. This study focuses on the high temperature Cambrian Geothermal sandstone reservoirs. The study aims to conduct a geological screening of the existing and depleted hydrocarbon reservoirs with high water production rates. After initial data gathering, numerical modeling is employed with the help of mechanistic box models to evaluate the geothermal potential of the selected sites for commercial development. Ultimately, the study identifies the top five screened sites, which could be developed further for techno-economical modelling. Full article

The properties of ancient magmatic arcs are crucial for understanding the tectonic evolution of the Central Asian Orogenic Belt. The Middle Devonian Kulumudi Formation in the Laofengkou area of West Junggar lacks accurate chronological data constraints, which hampers the knowledge of the nature of the Late Paleozoic magmatic arcs in the West Junggar and circum-Balkhash areas. In this contribution, samples of pyroclastic rocks and sedimentary rocks were collected from the volcano–sedimentary strata of the Kulumudi Formation. Petrography, zircon U-Pb-Hf isotopic analysis and whole-rock geochemistry were carried out to constrain the age and the tectonic setting of the Kulumudi Formation. The zircon U-Pb age of the lithic crystal tuff from the Kulumudi Formation on the northeast side of the Alemale Mountains was 386 ± 2 Ma, accurately indicating that this rock unit formed during the Middle Devonian. However, the fine sandstone near the Huojierte Mongolian Township, originally assigned as the “Kulumudi Formation”, yielded a maximum depositional age of 341 ± 3 Ma. Combined with the stratigraphic contact, this rock unit was redefined to belong to the Lower Carboniferous Jiangbasitao Formation. According to the whole-rock geochemistry study, the lithic crystal tuff of the Kulumudi Formation was characterized as medium potassium–calc–alkaline series rock, which is relatively enriched in light rare earth elements and large ion lithophile elements (i.e., Rb, Ba, K) and depleted in high-field-strength elements (i.e., Nb, Ta, Ti), showing similar geochemical characteristics to the volcanic arc rocks. By contrast, the fine sandstone from the Jiangbasitao Formation had Al₂O₃/SiO₂ (0.25–0.29) and K₂O/Na₂O (1.29–1.72) ratios close to those derived from the continental arc and active continental margin and was characterized as part of the continental arc field in the La-Th-Sc and Th-Sc-Zr/10 tectonic discrimination diagrams. Zircon Hf isotope analysis showed that the ε_Hf(t) values of the Kulumudi Formation were +5.6–+12.8, and those of the Jiangbasitao Formation were +11.43–+15.48, both of which show highly positive juvenile characteristics. The above data indicate that the Kulumudi Formation and Jiangbasitao Formation both formed in a juvenile arc setting with ocean–continent subduction. Combined with the previous work, it was concluded that the southward subduction of the ocean basin represented by the Darbut–Karamay ophiolitic mélanges beneath the newly accreted arc crustal segments produced a juvenile arc with positive Hf isotope characteristics. Full article

An assessment performed using raman spectroscopy has found space in the black shales of the Cisuralian-age rocks of the Karoo Basin in South Africa, particularly those from the Guadalupian Ripon, Cisuralian Whitehill and Prince Albert Formations. It is used in conjunction with geochemical screening techniques such as organic petrology and programmed pyrolysis. In turn, the combination of these techniques is used for the assessment of the thermal maturity of the sedimentary organic matter from the perspective of hydrocarbon generation, retention, and expulsion. To provide further understanding of the black shales in the Cisuralian-age rocks of the Karoo Basin in South Africa, this study focuses on the characterization of samples from the KWV−01 borehole drilled in the southeastern Karoo Basin. In addition, the USA Devonian/Carboniferous Berea Sandstone project samples were included for comparison, and were used as a quality assurance measure. Organic petrology was utilized to assess the organic quality and thermal maturity of the black shales. The results obtained showed that the Karoo Basin shales are overmature, containing an abundance of solid bitumen, and this often characterizes a shale reservoir with moveable hydrocarbons (shale gas). The programmed pyrolysis analysis conducted on the black shales of the Karoo Basin yielded artifact results, as they were determined from a very low and poorly defined S2 peak. This indicated the shales to be overmature and categorized them to be of poor hydrocarbon generation potential. Raman spectroscopy was used to gain insights about the molecular structure of the black shales and to assess if this technique could be used as a complimentary tool to determine the thermal maturity of the shale samples. Raman parameters such as G–D1 Band separation, G and D1 band full width at half maximum (G_fwhm and D1_fwhm) and G band position were successfully correlated with vitrinite reflectance (R_oV), demonstrating a good potential for Raman spectroscopy to predict the thermal maturity of the shales. Overall, the study provides valuable information and knowledge concerning black shale sample characterization (particularly the thermal maturity and molecular structural characterization) in the Karoo Basin, South Africa. Full article

The Xinghongpu Formation is very important for understanding the Devonian tectonic evolution of the South Qinling orogenic belt. Geochemical, detrital zircon U-Pb-Hf isotopic studies were carried out on the Late Devonian metasedimentary rocks of the Xinghongpu Formation to constrain the depositional age, the provenance, and the tectonic setting. The detrital zircon U-Pb dating results revealed that the depositional age of the Xinghongpu Formation of the Late Devonian was not earlier than 363.2 Ma. The whole-rock geochemistry suggested that (1) this suite of metasedimentary rocks was mainly derived from quartzose sediments of mature continental provenance, with a small contribution from mafic and intermediate igneous provenance, and (2) the metasedimentary sandstone of the Xinghongpu Formation from the Late Devonian was deposited in an active continental margin to continental arc setting. The detailed detrital zircon U-Pb dating showed that the age spectra of detrital zircon could be divided into four groups: (1) 416–480 Ma, accounting for about 23%; (2) 740–850 Ma, accounting for about 19%; (3) 889–1017 Ma, accounting for about 19%; and (4) 1072–1146 Ma, accounting for about 12%. It also contained a group of Early Proterozoic zircons. The age and Hf isotope of the detrital zircons suggested that the clastic sediment deposited in the Xinghongpu Formation mainly came from the South Qinling Orogenic Belt and the North Qinling Orogenic Belt. The detrital zircon Lu-Hf isotopes indicated that most zircons were the products of the ancient crustal remelting, and the mantle-derived magmatic sources contributed to the provenance. The Xinghongpu Fm. formed in an oceanic basin in a continental margin environment with arc systems. Full article

Copper, uranium, and rare earth element (REE) mineralisation occurs in hydrocarbon-bearing Devonian continental sandstones in southwest Orkney, Scotland. The aeolian Yesnaby Sandstone Formation and fluvial Harra Ebb Sandstone Formation were mineralised following oil emplacement. The REE-bearing APS mineral florencite is particularly associated with bituminous nodules, many of which contain brannerite. Subsequently hydrothermal copper and other sulphides, and barite, further mineralised the oil reservoir at a temperature of ~190 °C. Oil was mobilised through mineralised fractures at this stage. Biodegradation of the oil occurred later, following the Carboniferous-Permian uplift. The occurrence confirms that Cu-APS mineralisation is possible in relatively low-temperature regimes in sedimentary basins. Full article

Abundant hydrocarbon resources were discovered in the Xiazijie fan-delta in the Triassic Baikouquan Formation in Mahu sag, Junggar Basin. However, the maximum depositional age of Baikouquan Formation and provenance of this fan-delta are still unclear, which would be unfavourable for further hydrocarbon exploration. In this study, we used detrital zircon U-Pb dating and composition statistics of conglomerate clast and sandstone grain from Baikouquan Formation to constrain the maximum depositional age and provenance of the Xiazijie fan-delta. The results showed that (1) the conglomerate clast compositions of Xiazijie fan-delta mainly consisted of tuff and intermediate-felsic magmatic rocks, and sandstone samples could be classified as litharenite type with the lithic fragments were almost entirely volcanic lithic fragments; (2) the average Qt:F:L values of sandstone samples (M152-S1 and M152-S2) were 26:7:67 and 21:8:71, respectively, and they plotted in the magmatic arc domain in the Qt-F-L ternary diagram, indicating the tectonic setting of source area of Xiazijie fan-delta was magmatic arc; (3) M152-S1 yielded U-Pb ages ranging from 417 Ma to 253 Ma, with a dominant age peak at 313 Ma and two secondary age peaks at 411 Ma and 268 Ma, respectively, while M152-S2 yielded U-Pb ages ranging from 467 Ma to 256 Ma, with a dominant age peak at 307 Ma and two secondary date peaks at 405 Ma and 262 Ma; (4) the mean age of youngest two zircon grains of M152-S1 was 254.8 ± 4.7 Ma, while that of M152-S2 was 257.6 ± 3.8 Ma, suggesting the Baikouquan Formation might be deposited after the Changhsingian to Olenekian; (5) the magmatic rock ages of central West Junggar were distributed mostly between 450–260 Ma, with a dominant age peak at 307 Ma. The ages distribution between magmatic rock of central WJ and detrital zircons of M152-S1 and M152-S2 were similar, indicating the central WJ domain should be the major source area of the Xiazijie fan-delta; (6) the magmatic rock of Hakedun–Hongguleleng area in the Central WJ was characterized by a peak age at 305 Ma, which was consistent with the peak ages of M152-S1 and M152-S2, indicating the Hakedun-Hongguleleng area was likely to be their major source area; and (7) one minor peak age at 411 Ma and another at 405 Ma were obtained from M152-S1 and M152-S2, respectively, and a zircon grain with Middle Ordovician age at 467 Ma was obtained from M152-S2, indicating Late Silurian–Early Devonian Chagankule pluton in the Saier Mountain and Ordovician Honggleleng ophiolite mélange in the Sharburt mountain were the minor source areas. This research has significant implications for stratigraphic correlation in Junggar Basin and hydrocarbon exploration in the Xiazijie fan-delta conglomerate reservoir. Full article

A multi-proxy provenance study of Late Carboniferous to Middle Jurassic sandstones from the eastern Sverdrup Basin was undertaken employing optical petrography and heavy mineral analysis, chemical analysis of apatite, garnet and rutile grains, as well as detrital zircon U–Pb geochronology and Hf isotope analysis. Late Carboniferous to Middle Jurassic strata on the southern basin margin are inferred as being predominantly reworked from Silurian to Devonian strata within the adjacent Franklinian Basin succession. Higher-grade metamorphic detritus appeared during Middle to Late Triassic times and indicates exhumation and erosion of lower (Neoproterozoic to Cambrian) levels within the Franklinian Basin succession and/or a direct detrital input from the Canadian-Greenland Shield. The provenance of northern-derived sediments is more enigmatic owing to the subsequent opening of the Arctic Ocean. Northern-derived Middle Permian to Early Triassic sediments were likely derived from proximal areas of the Chukotkan part of the Arctic Alaska-Chukotka microplate. Late Triassic northern-derived sediments have different detrital zircon U–Pb age spectra from Middle Permian to Early Triassic ones and were likely derived from the Uralian orogenic belt and/or the Arctic Uralides. The loss of this sand input during latest Triassic times is interpreted to reflect drainage reorganisation farther upstream on the Barents Shelf. Middle Jurassic sands in the northern and axial parts of the basin were largely reworked from local northern-derived Late Triassic strata. This may have been facilitated by rift flank uplift of the northern basin margin in response to rifting in the adjacent proto-Amerasia Basin. Full article

Conventional and varietal heavy mineral studies of the earliest Eocene Hermod S2 Member (Mbr) sandstones in the Greater Alvheim area of the northern North Sea have revealed marked lateral variations and more subtle vertical evolution in provenance signature. Major variations are of geographic rather than stratigraphic nature as biostratigraphy reveals that all investigated sandstones are coeval. The provenance variations show an organized pattern, with sandstones in the north showing a different signature than those in the south. The position of the sandstones relative to the East Shetland Platform (ESP) is inferred to be the main control on provenance, with sediment input from at least two different point sources. Sediment supplied from both catchments is predominantly recycled in nature, given the mineralogical maturity of the heavy mineral assemblages, consistent with the evidence for widespread Permo-Triassic and Devonian sediments on the ESP. However, some direct supply from metasedimentary (Moine and Dalradian) basement is implied by the sporadic occurrence of unstable minerals. The southern catchment incorporated a greater exposure of Permo-Triassic sandstones than the northern catchment. The Permo-Triassic part of the catchment can be reconstructed as comprising equivalents of the Foula and Otter Bank sandstones present to the west of Shetland, with the majority of the Foula section having been stripped off prior to Hermod S2 deposition, exposing Otter Bank equivalents for erosion and redeposition. However, remnant Foula-like sandstones remained exposed further south on the ESP until at least the earliest Eocene since Foula-type garnet signatures are found in the Forties Sandstone Mbr of the central North Sea. In addition to lateral differences, stratigraphic evolution of provenance can also be detected in the Hermod S2 Mbr, with variations in key provenance-sensitive parameters related to a sea-level rise that reduced the extent of alluvial storage and altered the geological framework of the hinterland. Full article

This article is devoted to the study of the contents of zinc, cadmium, copper, and lead in lichen in the pastures of reindeer studs in the Timan and Bolshezemelskaya tundras. These areas are located in the Arctic part of Russia, to the west of the Polar Urals. These are areas where carbonate and sandstone rocks of the Permian–Mesozoic age dominate under the soil cover, as well as older deposits located in the western part of the research area (dated to the Cambrian–Devonian period). In these rocks, there is mineralization with metals, including copper. Research carried out in 2018 showed that in the surface layer of lichens, the concentration of metals was assessed differently in the upper, middle, and lower parts of the hill. On this basis, it was possible to identify clean and contaminated pastures. The high copper content in some pastures can be explained by the migration of metal ions from the parent rock. Due to the similar ionic radius of copper and the higher electrocativity in relation to zinc, the metal was probably displaced in the lichen. The observed concentrations can cause high levels of metals in the tissues and organs of deer. A high content of metals in lichens was found in samples collected near industrial enterprises, as well as at a considerable distance from them. At the same time, lichens at some locations near boiler houses or oil rigs are quite pure. In this regard, it has been suggested that the source of pollutants can be either natural factors (copper-bearing sands) or the ingress of metals from a remotely located source. Full article