Search Results (9)

In this study, we demonstrate the localized surface plasmon resonance (LSPR) in the visible range by using nanostructures on mirrors. The nanohemisphere-on-mirror (NHoM) structure is based on random nanoparticles that were obtained by heat-treating silver thin films and does not require any top-down nanofabrication processes. We were able to successfully tune over a wide wavelength range and obtain full colors using the NHoM structures, which realized full coverage of the Commission Internationale de l’Eclairage (CIE) standard RGB (sRGB) color space. Additionally, we fabricated the periodic nanodisk-on-glass (NDoG) structure using electron beam lithography and compared it with the NHoM structure. Our analysis of dark-field microscopic images observed by a hyperspectral camera showed that the NHoM structure had less variation in the resonant wavelength by observation points compared with the periodic NDoG structure. In other words, the NHoM structure achieved a high color quality that is comparable to the periodic structure. Finally, we proposed colorimetric sensing as an application of the NHoM structure. We confirmed the significant improvement in performance of colorimetric sensing using the NHoM structure and succeeded in colorimetric sensing using protein drops. The ability to fabricate large areas in full color easily and inexpensively with our proposed structures makes them suitable for industrial applications, such as displays, holograms, biosensing, and security applications. Full article

The extended application of device-dependent systems’ vision is growing exponentially, but these systems face challenges in precisely imitating the human perception models established by the device-independent systems of the Commission internationale de l’éclairage (CIE). We previously discussed the theoretical treatment and experimental validation of developing a calibrated integrated sphere imaging system to imitate the visible spectroscopy environment. The RGB polynomial function was derived to obtain a meaningful interpretation of color features. In this study, we dyed three different types of textured materials in the same bath with a yellow reactive dye at incremental concentrations to see how their color difference profiles tested. Three typical cotton textures were dyed with three ultra-RGB remozol reactive dyes and their combinations. The color concentration ranges of 1%, 2%, 3%, and 4% were chosen for each dye, followed by their binary and ternary mixtures. The aim was to verify the fundamental spectral feature mapping in various imaging color spaces and spectral domains. The findings are quite interesting and help us to understand the ground truth behind working in two domains. In addition, the trends of color mixing, CIE color difference, CIExy (chromaticity) color gamut, and RGB gamut and their distinguishing features were verified. Human perception accuracy was also compared in both domains to clarify the influence of texture. These fundamental experiments and observations on human perception and calibrated imaging color space could clarify the expected precision in both domains. Full article

Herein, we report the synthesis and characterization of two Pt(II) coordination compounds, the new platinum(II)[N,N′-bis(salicylidene)-3,4-diaminobenzophenone)] ([Pt(sal-3,4-ben)]) and the already well-known platinum(II)[N,N′-bis(salicylidene)-o-phenylenediamine] ([Pt(salophen)]), along with their application as guests in a poly [9,9-dioctylfluorenyl-2,7-diyl] (PFO) conjugated polymer in all-solution processed single-layer white organic light-emitting diodes. Completely different performances were achieved: 2.2% and 15.3% of external quantum efficiencies; 2.8 cd A⁻¹ and 12.1 cd A⁻¹ of current efficiencies; and 3103 cd m⁻² and 6224 cd m⁻² of luminance for the [Pt(salophen)] and [Pt(sal-3,4-ben)] complexes, respectively. The Commission Internationale de l’Eclairage (CIE 1931) chromaticity color coordinates are (0.33, 0.33) for both 0.1% mol/mol Pt(II):PFO composites at between approximately 3.2 and 8 V. The optoelectronic properties of doped and neat PFO films have been investigated, using steady-state and time-resolved photoluminescence. Theoretical calculations at the level of relativistic density functional theory explained these results, based on the presence of the Pt(II) central ion’s phosphorescence emission, considering spin-orbit coupling relationships. The overall results are explained, taking into account the active layer morphological properties, along with the device’s electric balance and the emitter’s efficiencies, according to deep-trap space-charge models. Considering the very simple structure of the device and the ease of synthesis of such compounds, the developed framework can offer a good trade-off for solution-deposited white organic light-emitting diodes (WOLEDs), with further applications in the field of lighting and signage. Full article

Red–green–blue phosphors excited by ultraviolet (UV) radiation for white light LEDs have received much attention to improve the efficiency, color rendering index (CRI), and chromatic stability. The spectral conversion of a rare-earth ion-doped nonstoichiometric LaO_0.65F_1.7 host was explored with structural analysis in this report. The nonstoichiometric structure of a LaO_0.65F_1.7 compound, synthesized by a solid-state reaction using La₂O₃ and excess NH₄F precursors, was analyzed by synchrotron X-ray powder diffraction. The crystallized LaO_0.65F_1.7 host, which had a tetragonal space group of P4/nmm, contained 9- and 10-coordinated La³⁺ sites. Optical materials composed of La_1−p−qBi_pTb_qO_0.65F_1.7 (p = 0 and 0.01; q = 0–0.2) were prepared at 1050 °C for 2 h, and the single phase of the obtained phosphors was indexed by X-ray diffraction analysis. The photoluminescence spectra of the energy transfer from Bi³⁺ to Tb³⁺ were obtained upon excitation at 286 nm in the nonstoichiometric host lattice. The desired Commission Internationale de l’Eclairage (CIE) values of the phosphors were calculated. The intense green La_0.89Bi_0.01Tb_0.1O_0.65F_1.7 phosphor with blue and red optical materials was fabricated on a 275 nm UV-LED chip, resulting in white light, and the internal quantum efficiency, CRI, correlated color temperature, and CIE of the pc LED were characterized. Full article

Underwater image segmentation is useful for benthic habitat mapping and monitoring; however, manual annotation is time-consuming and tedious. We propose automated segmentation of benthic habitats using unsupervised semantic algorithms. Four such algorithms––Fast and Robust Fuzzy C-Means (FR), Superpixel-Based Fast Fuzzy C-Means (FF), Otsu clustering (OS), and K-means segmentation (KM)––were tested for accuracy for segmentation. Further, YCbCr and the Commission Internationale de l’Éclairage (CIE) LAB color spaces were evaluated to correct variations in image illumination and shadow effects. Benthic habitat field data from a geo-located high-resolution towed camera were used to evaluate proposed algorithms. The Shiraho study area, located off Ishigaki Island, Japan, was used, and six benthic habitats were classified. These categories were corals (Acropora and Porites), blue corals (Heliopora coerulea), brown algae, other algae, sediments, and seagrass (Thalassia hemprichii). Analysis showed that the K-means clustering algorithm yielded the highest overall accuracy. However, the differences between the KM and OS overall accuracies were statistically insignificant at the 5% level. Findings showed the importance of eliminating underwater illumination variations and outperformance of the red difference chrominance values (Cr) in the YCbCr color space for habitat segmentation. The proposed framework enhanced the automation of benthic habitat classification processes. Full article

In this paper, we performed a feasibility study of using a water-based liquid scintillator (WbLS) for conducting imaging analysis with a digital camera. The liquid scintillator (LS) dissolves a scintillating fluor in an organic base solvent to emit light. We synthesized a liquid scintillator using water as a solvent. In a WbLS, a suitable surfactant is needed to mix water and oil together. As an application of the WbLS, we introduced a digital photo image analysis in color space. A demosaicing process to reconstruct and decode color is briefly described. We were able to estimate the emission spectrum of the fluor dissolved in the WbLS by analyzing the pixel information stored in the digital image. This technique provides the potential to estimate fluor components in the visible region without using an expensive spectrophotometer. In addition, sinogram analysis was performed with Radon transformation to reconstruct transverse images with longitudinal photo images of the WbLS sample. Full article

A set of new triple molybdates, Li_xNa_1-xCaGd_0.5(MoO₄)₃:Ho³⁺_0.05/Yb³⁺_0.45, was successfully manufactured by the microwave-accompanied sol–gel-based process (MAS). Yellow molybdate phosphors Li_xNa_1-xCaGd_0.5(MoO₄)₃:Ho³⁺_0.05/Yb³⁺_0.45 with variation of the Li_xNa_1-x (x = 0, 0.05, 0.1, 0.2, 0.3) ratio under constant doping amounts of Ho³⁺ = 0.05 and Yb³⁺ = 0.45 were obtained, and the effect of Li⁺ on their spectroscopic features was investigated. The crystal structures of Li_xNa_1-xCaGd_0.5(MoO₄)₃:Ho³⁺_0.05/Yb³⁺_0.45 (x = 0, 0.05, 0.1, 0.2, 0.3) at room temperature were determined in space group I4₁/a by Rietveld analysis. Pure NaCaGd_0.5Ho_0.05Yb_0.45(MoO₄)₃ has a scheelite-type structure with cell parameters a = 5.2077 (2) and c = 11.3657 (5) Å, V = 308.24 (3) ų, Z = 4. In Li-doped samples, big cation sites are occupied by a mixture of (Li,Na,Gd,Ho,Yb) ions, and this provides a linear cell volume decrease with increasing Li doping level. The evaluated upconversion (UC) behavior and Raman spectroscopic results of the phosphors are discussed in detail. Under excitation at 980 nm, the phosphors provide yellow color emission based on the ⁵S₂/⁵F₄ → ⁵I₈ green emission and the ⁵F₅ → ⁵I₈ red emission. The incorporated Li⁺ ions gave rise to local symmetry distortion (LSD) around the cations in the substituted crystalline structure by the Ho³⁺ and Yb³⁺ ions, and they further affected the UC transition probabilities in triple molybdates Li_xNa_1-xCaGd_0.5(MoO₄)₃:Ho³⁺_0.05/Yb³⁺_0.45. The complex UC intensity dependence on the Li content is explained by the specificity of unit cell distortion in a disordered large ion system within the scheelite crystal structure. The Raman spectra of Li_xNa_1-xCaGd_0.5(MoO₄)₃ doped with Ho³⁺ and Yb³⁺ ions were totally superimposed with the luminescence signal of Ho³⁺ ions in the range of Mo–O stretching vibrations, and increasing the Li⁺ content resulted in a change in the Ho³⁺ multiplet intensity. The individual chromaticity points (ICP) for the LiNaCaGd(MoO₄)₃:Ho³⁺,Yb³⁺ phosphors correspond to the equal-energy point in the standard CIE (Commission Internationale de L’Eclairage) coordinates. Full article

In this paper, the possibility of color controlling anodic titanium oxide by changing anodizing conditions of titanium in an ethanol-based electrolyte is demonstrated. Colored anodic titanium oxide was fabricated in an ethanol-based electrolyte containing 0.3 M ammonium fluoride and various amounts of deionized water (2, 3.5, 5, or 10 vol%), at voltages that varied from 30 to 60 V and at a constant anodization temperature of 20 °C. Morphological characterization of oxide layers was established with the use of a scanning electron microscope. Optical characterization was determined by measuring diffusion reflectance and calculating theoretical colors. The resulting anodic oxides in all tested conditions had nanotubular morphology and a thickness of up to hundreds of nanometers. For electrolytes with 3.5, 5, and 10 vol% water content, the anodic oxide layer thickness increased with the applied potential increase. The anodic titanium oxide nanotube diameters and the oxide thickness of samples produced in an electrolyte with 2 vol% water content were independent of applied voltage and remained constant within the error range of all tested potentials. Moreover, the color of anodic titanium oxide produced in an electrolyte with 2 vol% of water was blue and was independent from applied voltage, while the color of samples from other electrolyte compositions changed with applied voltage. For samples produced in selected conditions, iridescence was observed. It was proposed that the observed structural color of anodic titanium oxide results from the synergy effect of nanotube diameter and oxide thickness. Full article

To accurately extract cultivated land boundaries based on high-resolution remote sensing imagery, an improved watershed segmentation algorithm was proposed herein based on a combination of pre- and post-improvement procedures. Image contrast enhancement was used as the pre-improvement, while the color distance of the Commission Internationale de l´Eclairage (CIE) color space, including the Lab and Luv, was used as the regional similarity measure for region merging as the post-improvement. Furthermore, the area relative error criterion (δ_A), the pixel quantity error criterion (δ_P), and the consistency criterion (K_hat) were used for evaluating the image segmentation accuracy. The region merging in Red–Green–Blue (RGB) color space was selected to compare the proposed algorithm by extracting cultivated land boundaries. The validation experiments were performed using a subset of Chinese Gaofen-2 (GF-2) remote sensing image with a coverage area of 0.12 km². The results showed the following: (1) The contrast-enhanced image exhibited an obvious gain in terms of improving the image segmentation effect and time efficiency using the improved algorithm. The time efficiency increased by 10.31%, 60.00%, and 40.28%, respectively, in the RGB, Lab, and Luv color spaces. (2) The optimal segmentation and merging scale parameters in the RGB, Lab, and Luv color spaces were C for minimum areas of 2000, 1900, and 2000, and D for a color difference of 1000, 40, and 40. (3) The algorithm improved the time efficiency of cultivated land boundary extraction in the Lab and Luv color spaces by 35.16% and 29.58%, respectively, compared to the RGB color space. The extraction accuracy was compared to the RGB color space using the δ_A, δ_P, and K_hat, that were improved by 76.92%, 62.01%, and 16.83%, respectively, in the Lab color space, while they were 55.79%, 49.67%, and 13.42% in the Luv color space. (4) Through the visual comparison, time efficiency, and segmentation accuracy, the comprehensive extraction effect using the proposed algorithm was obviously better than that of RGB color-based space algorithm. The established accuracy evaluation indicators were also proven to be consistent with the visual evaluation. (5) The proposed method has a satisfying transferability by a wider test area with a coverage area of 1 km². In addition, the proposed method, based on the image contrast enhancement, was to perform the region merging in the CIE color space according to the simulated immersion watershed segmentation results. It is a useful attempt for the watershed segmentation algorithm to extract cultivated land boundaries, which provides a reference for enhancing the watershed algorithm. Full article