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Keywords = Al2O3 FP

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19 pages, 3653 KB  
Article
Impact of Phosphorus Fertilization on Leaching, Accumulation, and Microbial Cycling in New Apple Orchards
by Yuwen Shen, Haitao Lin, Rui Xue, Yanan Ma and Yan Song
Agronomy 2025, 15(4), 952; https://doi.org/10.3390/agronomy15040952 - 14 Apr 2025
Cited by 1 | Viewed by 2079
Abstract
Field experiments spanning five years were conducted to convert barren mountainous land into apple orchards, testing five phosphorus (P) fertilization schemes: no inorganic P (NP0K), superphosphate (FP), water-soluble inorganic P (WSF), superphosphate with alkaline soil conditioner (SC), and superphosphate with grass interplanting (GC). [...] Read more.
Field experiments spanning five years were conducted to convert barren mountainous land into apple orchards, testing five phosphorus (P) fertilization schemes: no inorganic P (NP0K), superphosphate (FP), water-soluble inorganic P (WSF), superphosphate with alkaline soil conditioner (SC), and superphosphate with grass interplanting (GC). Fertilizer solubility and soil pH were found to significantly impact P leaching and accumulation. Among the schemes, WSF exhibited the highest P leaching loss (3.65–3.87%), while SC (2.17–2.79%) and GC (2.79–3.25%) minimized such losses. As soil pH declined over time, aluminum P (Al-P) replaced calcium P (Ca-P) as the dominant inorganic P fraction, while occluded P (O-P) increased, resulting in reduced P bioavailability. Soil organic carbon (SOC) and acid phosphatase activity positively influenced inorganic P fractions, whereas prolonged orchard establishment decreased fixed inorganic P content. Microbial P cycling genes were less abundant and showed negative correlations with soil nitrate-N, electrical conductivity, available P (Olsen P), and SOC. These findings highlight that grass interplanting with superphosphate (GC) is an optimal strategy to minimize phosphorus leaching, enhance soil phosphorus bioavailability, and reduce environmental risks, making it a sustainable approach for orchard management. Full article
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15 pages, 6607 KB  
Article
Effect of Particle Size on Physical Properties, Dissolution, In Vitro Antioxidant Activity, and In Vivo Hepatoprotective Properties of Tetrastigma hemsleyanum Diels et Gilg Powders
by Zhiwen Zhang, Yun Chen, Shaoxian Wang, Zheren Tong, Fujia Luan, Binghong Jiang, Faxiang Pu, Zhangfu Xie, Ping Wang and Zijin Xu
Pharmaceutics 2024, 16(11), 1352; https://doi.org/10.3390/pharmaceutics16111352 - 23 Oct 2024
Cited by 3 | Viewed by 2233
Abstract
Objective: The aim of this study was to analyze the effects of different particle sizes of Tetrastigma hemsleyanum Diels et Gilg (TDG) powders on physical properties, dissolution, in vitro antioxidant activity, and in vivo hepatoprotective properties. Methods: The particle size of TDG coarse [...] Read more.
Objective: The aim of this study was to analyze the effects of different particle sizes of Tetrastigma hemsleyanum Diels et Gilg (TDG) powders on physical properties, dissolution, in vitro antioxidant activity, and in vivo hepatoprotective properties. Methods: The particle size of TDG coarse powders (TDG-CP), TDG fine powders (TDG-FP), and TDG micro powders (TDG-MP) were measured by a laser particle size analyzer. The physical properties were measured according to the latest version of the Chinese Pharmacopoeia (Committee Chinese Pharmacopoeia 2020). The content of the total flavonoids, total polysaccharides, kaempferol-3-O-rutinoside, and rutin of TDG powders were determined using the NaNO2-Al (NO3)3 colorimetric method, the sulphate-phenol colorimetric method, and HPLC, respectively. In vitro dissolution and antioxidant activity were determined by the paddle method in phosphate buffer (pH 6.8) and the DPPH radical scavenging method, respectively. In addition, the liver tissue pathology was evaluated by hematoxylin and eosin staining (H&E), and the AST and ALT activities were measured by automatic biochemical analyzer. The superoxide dismutase (SOD), catalase (CAT), and glutathione (GSH) activities were measured by using commercial analysis kits. Results: As the particle size decreases, the fluidity of TDG powders decreased and the porosity increased. In addition, there were no significant differences in physical properties between low temperature pulverized powders and room temperature pulverized powders. The final dissolution rates of the four bioactive ingredients in TDG-MP were found to be 85.06%, 85.61%, 83.88%, and 83.26%, respectively, whereas in TDG-CP, the dissolution rates were significantly lower at 18.79%, 17.96%, 22.46%, and 24.35%. The EC50 values of TDG-CP, TDG-FP, and TDG-MP on DPPH scavenging activity were 0.82, 0.31, and 0.10 mg/mL, respectively. The AST and ALT activities of the TDG-FP group and the TDG-MP group were significantly decreased and the SOD, CAT, and GSH activities were significantly increased when compared with that of the model group. The inflammatory cell infiltration and vacuolar degeneration of liver cells in the TDG-FP group and the TDG-MP group were significantly improved. Conclusions: The particle size of TDG powders had a significant effect on the physical properties and in vivo bioactivity. TDG pulverized to a fine particle size or smaller is a promising approach for clinical applications with improved physicochemical and biological properties. Full article
(This article belongs to the Section Physical Pharmacy and Formulation)
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15 pages, 6250 KB  
Article
High Absorptivity and Ultra-Wideband Solar Absorber Based on Ti-Al2O3 Cross Elliptical Disk Arrays
by Yuanjian Zhang, Yingting Yi, Wenxin Li, Shiri Liang, Jing Ma, Shubo Cheng, Wenxing Yang and Yougen Yi
Coatings 2023, 13(3), 531; https://doi.org/10.3390/coatings13030531 - 28 Feb 2023
Cited by 148 | Viewed by 4176
Abstract
Perfect metamaterial absorbers have attracted researchers’ attention in solar energy harvesting and utilization. An ideal solar absorber should provide high absorption, be ultra-wideband, and be insensitive to polarization and incident angles, which brings challenges to research. In this paper, we proposed and optimized [...] Read more.
Perfect metamaterial absorbers have attracted researchers’ attention in solar energy harvesting and utilization. An ideal solar absorber should provide high absorption, be ultra-wideband, and be insensitive to polarization and incident angles, which brings challenges to research. In this paper, we proposed and optimized an ultra-wideband solar absorber based on Ti-Al2O3 cross elliptical disk arrays to obtain the ultra-wideband absorption of solar energy. The addition of a cavity greatly improves the energy-absorbing effect in the operating band, which has research value. The absorption spectrum and field distribution were analyzed by the finite difference time domain method. For the physical mechanism, the electric and magnetic field distribution indicates that ultra-wideband absorption is caused by propagation surface plasmon resonance (SPR), localized SPR and Fabry–Perot (F-P) resonance excited between Ti and Al2O3 disks. The results demonstrate that the absorption bandwidth with the absorption rate beyond 90% reaches 1380 nm (385–1765 nm), and the average absorption reaches an astonishing 98.78%. The absorption bandwidth matches the main radiation bandwidth of the solar energy, which is approximately 295–2500 nm according to the data from the literature, and the total thickness of the structure is only 445 nm. Moreover, the ultra-wideband solar absorber is insensitive to the polarization angle and oblique incidence angle. The proposed ultra-wideband solar absorber has research and application value in solar energy harvesting, photothermal conversion and utilization. Full article
(This article belongs to the Special Issue Micro-Nano Optics and Its Applications)
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21 pages, 3428 KB  
Article
Machinability Assessment of Hybrid Nano Cutting Oil for Minimum Quantity Lubrication (MQL) in Hard Turning of 90CrSi Steel
by Tran Bao Ngoc, Tran Minh Duc, Ngo Minh Tuan, Vu Lai Hoang and Tran The Long
Lubricants 2023, 11(2), 54; https://doi.org/10.3390/lubricants11020054 - 31 Jan 2023
Cited by 28 | Viewed by 3421
Abstract
Friction and very high temperature are still the major challenges in hard machining technology and they greatly affect cutting efficiency. The application of the MQL (minimum quantity lubrication) method, using nanoparticles in order to improve the cooling lubrication performance of the base cutting [...] Read more.
Friction and very high temperature are still the major challenges in hard machining technology and they greatly affect cutting efficiency. The application of the MQL (minimum quantity lubrication) method, using nanoparticles in order to improve the cooling lubrication performance of the base cutting oil, has proven to be a promising solution. Hence, this work aimed to investigate the effectiveness of Al2O3/MoS2 hybrid nanofluid and Al2O3 and MoS2 mono nanofluids in the hard turning of 90CrSi steel (60–62 HRC) under an MQL environment. The Box-Behnken experimental design was used for three input variables, including nanoparticle concentration, air pressure, and air flow rate. Their influences on surface roughness and cutting forces were studied. According to the obtained results, it was shown that the application of hybrid nano cutting oils in MQL contributes to achieving better hard machining performance than the use of mono nanofluids. In particular, a lower cutting temperature is reported and the values of surface roughness Ra, back force Fp, and cutting force Fc were smaller and more stable under Al2O3/MoS2 hybrid nanofluid MQL than those under Al2O3 and MoS2 mono nanofluid MQL due to an improvement in cooling lubrication characteristics. Thus, this work provides a novel approach to study hybrid nanofluids for MQL hard machining. Full article
(This article belongs to the Special Issue Tribological Applications of Nano & Submicro Structured Materials)
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10 pages, 2488 KB  
Article
Genetic Algorithm-Assisted Design of Sandwiched One-Dimensional Photonic Crystals for Efficient Fluorescence Enhancement of 3.18-μm-Thick Layer of the Fluorescent Solution
by Jiantong Song, Guang Feng, Xiao Liu, Haoqiang Hou and Zhihui Chen
Materials 2022, 15(21), 7803; https://doi.org/10.3390/ma15217803 - 4 Nov 2022
Cited by 7 | Viewed by 2211
Abstract
One-dimensional photonic crystal structures have been widely used to enhance fluorescence. However, its fluorescence enhancement is low-fold because of a weak excitation field region. In this paper, we used a genetic algorithm to assist in the design of two photonic crystals based on [...] Read more.
One-dimensional photonic crystal structures have been widely used to enhance fluorescence. However, its fluorescence enhancement is low-fold because of a weak excitation field region. In this paper, we used a genetic algorithm to assist in the design of two photonic crystals based on Al2O3 and TiO2 materials. One of them has a defect consisting of SiO2. The Fabry-Perot cavity (FP cavity) formed by the sandwiched photonic crystal achieves up to 14-fold enhancement of the excitation electric field. We modulate the electric field radiation distribution of the fluorescent material by using photonic forbidden bands. For a 3.18 μm thick layer of the fluorescent solution, the structure achieves up to 60-fold fluorescence enhancement. We also discussed that the reason for the different enhancement abilities in different places is the phase change caused by the optical path difference. This design is expected to have applications in display, imaging, etc. Full article
(This article belongs to the Special Issue Microcavity Optics: Materials, Physics and Devices)
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21 pages, 6130 KB  
Article
Sr-Nd-Pb-Ca Isotopes of Holocene Basalts from Jingpohu, NE China: Implications for the Origin of Their Enriched Mantle Signatures
by Feixiang Wei, Bo Pan and Jiandong Xu
Minerals 2021, 11(8), 790; https://doi.org/10.3390/min11080790 - 21 Jul 2021
Cited by 8 | Viewed by 3250
Abstract
The geochemistry on Holocene lavas from the Jingpohu volcanic field in NE China are compared with other Cenozoic lavas from across the back-arc rift of NE China, in order to constrain their enriched mantle sources. Holocene lavas within Jingpohu volcanic field comprise two [...] Read more.
The geochemistry on Holocene lavas from the Jingpohu volcanic field in NE China are compared with other Cenozoic lavas from across the back-arc rift of NE China, in order to constrain their enriched mantle sources. Holocene lavas within Jingpohu volcanic field comprise two separate “Crater Forest” (CF) and “Frog Pool” (FP) volcanic areas. FP lavas have lower MgO, CaO, and heavy rare earth elements and higher Al2O3, Na2O, K2O, and large-ion lithophile elements than CF lavas. Yet, both CF and FP lavas share similar isotopic signatures, with depleted Sr and Nd isotopes (87Sr/86Sr = 0.703915–0.704556, 143Nd/144Nd = 0.512656–0.512849) and unradiogenic Pb isotopes (208Pb/204Pb = 37.79–38.06, 207Pb/204Pb = 15.45–15.54, 206Pb/204Pb = 17.49–18.15), similar to oceanic island basalts. An important new constraint for the Jingpohu lavas lies in their Ca isotopes of δ44/40Ca from 0.63‰ to 0.77‰, which are lower than that of the bulk silicate earth (0.94 ± 0.05‰). By comparing the isotopic signatures of sodic lavas with that of the potassic lavas across NE China, we propose a three-component mixing model as the source for the sodic lavas. In consistence with geophysical results, we propose that subducting Pacific plate induces asthenospheric mantle upwelling of an upper depleted mantle (DM), including subducted ancient sediments (EM I), which partially melted upon ascent. These primary melts further interacted with the lithospheric mantle (EM II), before differentiating within crustal magma chambers and erupting. Full article
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14 pages, 3948 KB  
Article
Alumina Ceramic Exacerbates the Inflammatory Disease by Activation of Macrophages and T Cells
by Seong-Min Lim, Juyoung Hwang, Hae-Bin Park, Chan Ho Park and Jun-O Jin
Int. J. Mol. Sci. 2020, 21(19), 7114; https://doi.org/10.3390/ijms21197114 - 26 Sep 2020
Cited by 4 | Viewed by 3025
Abstract
(1) Background: Aluminum oxide (Al2O3) ceramic is one of the materials used for artificial joints, and it has been known that their fine particles (FPs) are provided by the wear of the ceramic. Al2O3 FPs have [...] Read more.
(1) Background: Aluminum oxide (Al2O3) ceramic is one of the materials used for artificial joints, and it has been known that their fine particles (FPs) are provided by the wear of the ceramic. Al2O3 FPs have been shown to induce macrophage activation in vitro; however, the inflammatory effect in vivo has not been studied. (2) Methods: We examined the in vivo effect of Al2O3 FPs on the innate and adaptive immune cells in the mice. (3) Results: Al2O3 FPs promoted the activation of spleen macrophages; however, conventional dendritic cells (cDCs), plasmacytoid DCs (pDCs), and natural killer (NK) cells were not activated. In addition, increases in the CD4 and CD8 T cells was induced in the spleens of the mice treated with Al2O3 FPs, which differentiated into interferon-gamma (IFN-γ)-producing helper T1 (Th1) and cytotoxic T1 (Tc1) cells. Finally, the injection of Al2O3 FPs exacerbated dextran sulfate sodium (DSS)-induced inflammation in the colon, mediated by activated and increased number of CD4 and CD8 T cells. (4) Conclusions: These data demonstrate that FPs of Al2O3 ceramic may contribute to the exacerbation of inflammatory diseases in the patients. Full article
(This article belongs to the Special Issue Nanotoxicology and Nanosafety 3.0)
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11 pages, 2563 KB  
Article
Coupling of Surface Plasmon Polariton in Al-Doped ZnO with Fabry-Pérot Resonance for Total Light Absorption
by David George, Murthada Adewole, Safaa Hassan, David Lowell, Jingbiao Cui, Hualiang Zhang, Usha Philipose and Yuankun Lin
Photonics 2017, 4(2), 35; https://doi.org/10.3390/photonics4020035 - 27 Apr 2017
Cited by 7 | Viewed by 6816
Abstract
Al-doped ZnO (AZO) can be used as an electrically tunable plasmonic material in the near infrared range. This paper presents finite-difference time-domain (FDTD) simulations on total light absorption (TLA) resulting from the coupling of a surface plasmon polariton (SPP) with Fabry-Pérot (F-P) resonance [...] Read more.
Al-doped ZnO (AZO) can be used as an electrically tunable plasmonic material in the near infrared range. This paper presents finite-difference time-domain (FDTD) simulations on total light absorption (TLA) resulting from the coupling of a surface plasmon polariton (SPP) with Fabry-Pérot (F-P) resonance in a three-layer structure consisting of an AZO square lattice hole array, a spacer, and a layer of silver. Firstly, we identified that the surface plasmon polariton (SPP) that will couple to the F-P resonance because of an SPP standing wave in the (1,0) direction of the square lattice. Two types of coupling between SPP and F-P resonance are observed in the simulations. In order to achieve TLA, an increase in the refractive index of the spacer material leads to a decrease in the thickness of the spacer. Additionally, it is shown that the replacement of silver by other, more cost-effective metals has no significance influence on the TLA condition. It is observed in the simulations that post-fabrication tunability of the TLA wavelength is possible via the electrical tunability of the AZO. Finally, electric field intensity distributions at specific wavelengths are computed to further prove the coupling of SPP with F-P resonance. This work will contribute to the design principle for future device fabrication for TLA applications. Full article
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