Search Results (36)

The effects of produced wood particles from three wood species—alder, birch, and larch—added in various amounts in the particle mixture consisting of spruce particles and three tested wood species in a particleboard core layer on selected physical and mechanical properties of particleboard were studied. In a laboratory, 16 mm thick three-layer urea–formaldehyde (UF)-bonded particleboards were produced at 5.23 MPa, 240 °C, and with a 10 s/mm pressing factor. Two particleboard surface layers consisted of fine spruce particles. In the particleboard core layer, spruce particles were combined with particles from alder, birch, and larch. The tested particleboards containing alder, birch, and larch were characterized by approximately identical thickness swelling and they met the requirements of the conventional values stated by major particleboard manufacturers of 8–10%. The tested particleboard in all variations met the minimum strength value P2 particleboard in three-point bending, which is conventionally set at 11.0 MPa. The tested particleboard also exceeded the required values of modulus of elasticity in bending and internal bond strength. Analysis of the relationships demonstrated by the density profile confirmed that all three investigated wood species are usable in a mixture of core particles of high-quality particleboard in the recommended amounts (10, 15, 20%). Full article

Particleboard, engineered wood products as part of a large family of wood composite materials, developed in use mainly in the 1950s and 1960s to utilize inferior wood and wood waste when good-quality wood was in short supply; the annual production capacity worldwide is over 100 million m³. It is also necessary to have a lot of wood raw material for its production, although raw material resources are limited on our planet. In addition to the main wood species, it is therefore possible to think about the wider use of alternative, lesser-known European species of alder, larch, and birch in particleboard production. These three wood species represent an eco-friendly and sustainable wood alternative to the conventional wood raw materials used. This review confirms the diversity of the use of these three species in different fields and proves their suitability in relation to particleboard production. Fundamental research is ongoing in certain universities to determine the proportional shares of use of these tree species in particleboard (in a certain weight proportion in their core layers) for the purpose of formulating the correct technology shares and rules for their application in the wood-based panel industry. Full article

Molded plywood is used for furniture components such as seats, backrests, or integral seat shells, and it must be durable and harmless to health. Molded plywood is made with urea-formaldehyde (UF) adhesives; therefore, the issue of the fillers used in them is important. The potential of using ground beech (Fagus sylvatica L.) bark as an eco-friendly additive in UF adhesives for molded plywood manufacturing was investigated in this work. Wheat flour was used as a reference filler. The beech bark (BB) level as a filler was 10%, a value verified under laboratory conditions. Nine-layer flat and molded plywood were produced under industrial conditions from beech veneers bonded with a UF adhesive mixture. The mechanical (bending strength and bonding quality) and physical (swelling and absorbency values after 2 and 24 h) properties of the industrially fabricated molded plywood were evaluated and compared with the European standard requirements (EN 310 and EN 314-2). The mechanical properties of the molded plywood with the addition of BB in the adhesive mixture were acceptable and met these standards’ requirements. The positive effect of BB in the UF adhesive mixture on a reduction in formaldehyde emissions from the molded plywood was also confirmed. BB, considered to be wood-processing industry waste or a by-product, has significant potential to be used as a filler in UF resins for molded plywood production, providing an environmentally friendly, inexpensive solution for the industrial valorization of bark as a bio-based formaldehyde scavenger. Full article

The depletion of natural resources and increasing environmental apprehension regarding the reduction of harmful isocyanates employed in manufacturing polyurethanes (PUs) have generated significant attention from both industrial and academic sectors. This attention is focused on advancing bio-based non-isocyanate polyurethane (NIPU) resins as viable and sustainable substitutes, possessing satisfactory properties. This review presents a comprehensive analysis of the progress made in developing bio-based NIPU polymers for wood adhesive applications. The main aim of this paper is to conduct a comprehensive analysis of the latest advancements in the production of high-performance bio-based NIPU resins derived from lignin and tannin for wood composites. A comprehensive evaluation was conducted on scholarly publications retrieved from the Scopus database, encompassing the period from January 2010 to April 2023. In NIPU adhesive manufacturing, the exploration of substitute materials for isocyanates is imperative, due to their inherent toxicity, high cost, and limited availability. The process of demethylation and carbonation of lignin and tannin has the potential to produce polyphenolic compounds that possess hydroxyl and carbonyl functional groups. Bio-based NIPUs can be synthesized through the reaction involving diamine molecules. Previous studies have provided evidence indicating that NIPUs derived from lignin and tannin exhibit enhanced mechanical properties, decreased curing temperatures and shortened pressing durations, and are devoid of isocyanates. The characterization of NIPU adhesives based on lignin and tannin was conducted using various analytical techniques, including Fourier-transform infrared spectroscopy (FTIR), thermogravimetric analysis (TGA), matrix-assisted laser desorption/ionization with time-of-flight (MALDI-TOF) mass spectrometry, and gel permeation chromatography (GPC). The adhesive performance of tannin-based NIPU resins was shown to be superior to that of lignin-based NIPUs. This paper elucidates the potential of lignin and tannin as alternate sources for polyols in the manufacturing of NIPUs, specifically for their application as wood adhesives. Full article

Phenol-formaldehyde (PF) resin is one of the most well-known adhesives for exterior use. PF adhesive is one of the commercial thermoset polymers that is used extensively due to its many benefits. This study investigated the influence of different types and levels of catalysts, i.e., NaOH and CaCO₃ at 1% and 5% based on the solids content of PF resin on the adhesive properties, adhesion, and cohesion strength of PF resin. The results show that the catalyst type significantly influenced the PF adhesive viscosity and pH. Furthermore, the catalyst level significantly affected the PF adhesive’s solids content, viscosity, and gelation time. The cohesion strength of PF-CaCO₃-1% was more significant than the PF control at 75 °C. According to the DMA analysis, the mixed PF-NaOH-5% provided the highest storage modulus, followed by the PF-CaCO₃-1%, with values that were not statistically different from one another. The adhesion strength of PF-CaCO₃-1% was the highest, whereas the adhesion strength of the PF control was the lowest, as confirmed by the cohesion strength. According to the findings, adding CaCO₃-1% as a catalyst of PF resin would result in better adhesive adhesion and cohesion properties for wood composites in the future. Full article

Composite wood materials, also known as engineered wood products, are fabricated from wood veneer, particles, strands, flakes, or fibers that are bonded together with synthetic or renewable, biobased adhesive systems and designed to meet a wide range of structural and non-structural applications [...] Full article

The ongoing twin transition of the wood-based panel industry towards a green, digital, and more resilient bioeconomy is essential for a successful transformation, with the aim of decarbonising the sector and implementing a circular development model, transforming linear industrial value chains to minimize pollution and waste generation, and providing more sustainable growth and jobs [...] Full article

The plywood industry’s sustainability, performance, and production costs depend on wood adhesives and the hot pressing technique. In this investigation, a cold-setting plywood adhesive based on polyvinyl alcohol (P), tannin (T), and hexamine (H) was produced. The physical and mechanical properties of plywood were examined at different formulations such as tannin concentration (10% and 20%), hexamine content (5%, 10%, and 15%), and cold-pressing time (3, 6, 12, and 24 h). This study showed that high tannin and hexamine content also increased the solids content, but decreased the average viscosity of the adhesive. Markedly, the cohesion strength of PTH-based adhesives increased from 5.57 Pa at 1/s to 1411.6 Pa at 400/s shear rate, regardless of the adhesive formulation. The shear modulus subsequently decreased as a function of the shear rate and increased with a higher tannin and hexamine content. This study revealed that the higher tannin and hexamine content and longer cold-pressing times could produce plywood with the tested adhesive that met the Japanese standard strength requirements. A combination of PTH-based adhesive prepared with formula 2 and 24 h cold-pressing resulted in the highest TSS value of 1.42 MPa, MOR values of 88.7 MPa, MOE values of 14,025.6 MPa, and wood failure of 47.2%. This study showed the possibility of fabricating eco-friendly plywood panels bonded with PTH-based adhesive using the cold-pressing process as an alternative to conventional plywood. Full article

Semantan (Gigantochloa scortechinii) and beting (Gigantochloa levis) bamboo are the two Malaysian bamboo that are suitable to be converted into laminated bamboo boards. One of the main criteria for laminated board is its good bondability, which is determined by shear performance. The shear performance of laminated board is influenced by several factors such as the species used, adhesive types and lamination configurations. Therefore, in this study, laminated bamboo boards were produced using Semantan and Beting bamboo bonded with phenol–resorcinol–formaldehyde (PRF) and polyurethane (PUR) adhesives. Different configurations (lay-up patterns and strip arrangements) were used during the consolidation of the laminated boards. The bamboo strips were arranged in three different arrangements, namely vertical, horizontal and mixed, and then assembled into a three-layered structure with two lay-up patterns, which are perpendicular and parallel. Shear performances, such as shear strength, bamboo failure and delamination of the boards, were evaluated. The results revealed that the adhesive type and lay-up pattern were the most influential factors on the shear performance. PRF-bonded laminated bamboo boards outperformed PUR-bonded laminated bamboo boards in terms of shear strength and bamboo failure but PUR bonding had better bond durability as indicated by its low delamination. Boards laminated parallelly significantly outperformed those bonded perpendicularly. As for strip arrangement, PRF-bonded laminated boards were less influenced by it compared to PUR-bonded laminated boards. The results suggested that PRF is a better adhesive for bamboo lamination due to its higher shear performance and more consistent performance across structural configurations (lay-up patterns and strip arrangements). Full article

Bamboo requires treatment to extend its service life. However, as bamboo strips could serve as a suitable candidate for lamination, the treatment may affect its bendability. The current study investigated the effects of boric acid treatment on the physical, mechanical, adhesion, and morphological properties of bamboo strips. Owing to their availability and popularity in local industries, four Malaysian bamboo species were used in this study, namely Gigantochloa scortechinii, Gigantochloa levis, Dendrocalamus asper, and Bambusa vulgaris. These four species’ bamboo strips were treated with 5% boric acid and their properties were evaluated. The findings revealed that the boric acid treatment had varying degrees of effect on the properties of the bamboo. Despite having lower treatability and stability, both G. scortechinii and G. levis have greatly superior mechanical properties that justify their use in the production of laminated products. The boric acid treatment was found to provide several benefits to bamboo strips intended for lamination, including increased wettability, dimensional stability, and mechanical strength. Full article

The valorization of tree bark through chemical treatment into valuable products, such as bark acid, leads to the formation of process residues with a high solids content. Since they are of natural origin and are able to be suspended in water and acid, research was carried out on the recycling of suberic acid residues (SAR) as a bi-functional component of binder mixtures in the production of plywood. The 5%–20% (5%–30% for curing time) mass content of SAR has been investigated with urea-formaldehyde (UF) resin of about 66% of dry content. The results show that the curing time of the bonding mixture can be reduced to about 38% and 10%, respectively, for hot and cold curing, of the initial curing time for the lowest SAR content. The decreasing curing time of the tested binder mixtures with the increase in SAR content was caused by the increasing amount of acidic filler, since amine resins as UF require acidification hardening, and the curing dynamics are strongly dependent, among others, on the content of the acid medium (curing agent). In the case of hot curing, a SAR content of about 20% allowed us to achieve the curing time of bonding mass with an industrial hardener. Investigations into the mechanical properties of examined panels showed a significant modulus of elasticity (MOE) increase with filler content increase. Similar conclusions can be drawn when analyzing the results of the modulus of rupture (MOR) investigations; however, these were only significant regarding hot-pressed samples. The shear strength of the plywood samples increased with the SAR rise for both cold- and hot-pressed panels. The in-wood damage of samples with SAR filler, hot-pressed, rose up to about 30% for the highest SAR filler content. For cold-pressed samples, no in-wood damage was found. The positive effect of veneer impregnation limiter by resin was identified for SAR acting as a filler. Moreover, a higher density of SAR-containing bonding lines was reached for hot-pressed panels. Therefore, the results confirmed the ability to use the SAR as an upcycled component of the bonding mixture for plywood production. Full article

Bamboo is suitable to be a material for the production of new products that can be used indoors and outdoors. Five-, seven- and nine-ply laminated woven bamboo mat boards from semantan bamboo, Gigantochloa scortechinii, were fabricated in this study. G. scortechinii has been used commercially in a structural application and is easily available in Malaysia. The present work investigated the physico-mechanical properties and flammability of the laminated bamboo mat boards as a function of the number of ply. Phenol-formaldehyde resin was used as a binder. The panels’ density, physical, mechanical properties, formaldehyde emission and flammability were evaluated. As the number of ply increased, the density of the laminated boards decreased. Similarly, the highest modulus of elasticity was found in 5-ply laminated boards. However, the lowest modulus of rupture was also measured in 5-ply laminated boards. Regarding shear strength, 5-ply and 7-ply laminated boards outperformed 9-ply laminated boards. Meanwhile, 7-ply laminated boards exhibited the highest dimensional stability, as evidenced by the lowest water absorption and thickness swelling. In terms of flammability, all composites are classified as V-0 because the burning stops within 10 s and no flaming drips are observed. Full article