Search Results (7)

Residual Macadamia F.Muell nutshell gasification assisted by CO₂ was studied in this work. Monometallic Co, Na, and K and bimetallic CoNa and CoK catalysts were prepared and tested in the catalytic process. The idea of this research was to try to find any synergism between already known catalytically active components and to investigate possible ways to use mixed materials. All the materials under investigation were examined by SEM-EDX and XRD. The DTA-TG of the initial fresh macadamia nutshell was presented in this work. The synergism between the Co and K components was revealed in the CO₂-assisted gasification process. The found optimal catalyst was 1.5 wt%K-1.5 wt% Co/PMNS. Full article

While the attempts to find new energy sources have intensified, the interest in the use of biomass as a carbon-rich raw material still is increasing. In this work, we studied iron-, cobalt-, and nickel-based materials in the process of CO₂-assisted gasification of sunflower husk. The materials with and without metal additives were examined by XRD, SEM, EDX, and TEM techniques and were tested in their gasification under the action of CO₂. It was found that the Co-based material demonstrates the best activity among the studied ones (the CO₂ conversion was up to 83%). The possible reason for such superiority may be related to the capability of Ni compounds to the formation of the metallic nickel phase and insufficient activity of iron species. Full article

This paper seeks and examines N-symmetric vortical solutions of the two-layer geostrophic model for the special case when the vortices (or eddies) have vanishing summed strength (circulation anomaly). This study is an extension [Sokolovskiy et al. Phys. Fluids 2020, 32, 09660], where the general formulation for arbitrary N was given, but the analysis was only carried out for $N=2$. Here, families of stationary solutions are obtained and their properties, including asymptotic ones, are investigated in detail. From the point of view of geophysical applications, the results may help interpret the propagation of thermal anomalies in the oceans. Full article

The new xMnAs/(1 − x)PMN–PT (x = 0.2, 0.3) multicaloric composites, consisting of the modified PMN–PT-based relaxor-type ferroelectric ceramics and ferromagnetic compound of MnAs were fabricated, and their structure, magnetic, dielectric properties, and caloric effects were studied. Both components of the multicaloric composite have phase transition temperatures around 315 K, and large electrocaloric (~0.27 K at 20 kV/cm) and magnetocaloric (~13 K at 5 T) effects around this temperature were observed. As expected, composite samples exhibit a decrease in magnetocaloric effect (<1.4 K at 4 T) in comparison with an initial MnAs magnetic component (6.7 K at 4 T), but some interesting phenomena associated with magnetoelectric interaction between ferromagnetic and ferroelectric components were observed. Thus, a composite with x = 0.2 exhibits a double maximum in isothermal magnetic entropy changes, while a composite with x = 0.3 demonstrates behavior more similar to MnAs. Based on the results of experiments, the model of the multicaloric effect in an MnAs/PMN–PT composite was developed and different scenario observations of multicaloric response were modeled. In the framework of the proposed model, it was shown that boosting of caloric effect could be achieved by (1) compilation of ferromagnetic and ferroelectric components with large caloric effects in selected mass ratio and phase transition temperature; and (2) choosing of magnetic and electric field coapplying protocol. The 0.3MnAs/0.7PMN–PT composite was concluded to be the optimal multicaloric composite and a phase shift ∆φ = −π/4 between applied manetic fields can provide a synergetic caloric effect at a working point of 316 K. Full article

To meet the increasing needs of fuels, especially non-fossil fuels, the production of “bio-oil” is proposed and many efforts have been undertaken to find effective ways to transform bio-wastes into valuable substances to obtain the fuels and simultaneously reduce carbon wastes, including CO₂. This work is devoted to the gasification of sugar cane bagasse to produce CO in the process assisted by CO₂. The metals were varied (Fe, Co, or Ni), along with their amounts, in order to find the optimal catalyst composition. The materials were investigated by scanning electron microscopy (SEM), energy-dispersive X-ray spectroscopy (EDX), transmission electron microscopy (TEM), X-ray diffraction (XRD), and electron diffraction, and were tested in the process of CO₂-assisted gasification. The catalysts based on Co and Ni demonstrate the best activity among the investigated systems: the conversion of CO₂ reached 88% at ~800 °C (vs. 20% for the pure sugarcane bagasse). These samples contain metallic Co or Ni, while Fe is in oxide form. Full article

The three-layer version of the contour dynamics/surgery method is used to study the interaction mechanisms of a large-scale surface vortex with a smaller vortex/vortices of the middle layer (prototypes of intrathermocline vortices in the ocean) belonging to the middle layer of a three-layer rotating fluid. The lower layer is assumed to be dynamically passive. The piecewise constant vertical density distribution approximates the average long-term profile for the North Atlantic, where intrathermocline eddies are observed most often at depths of 300–1600 m. Numerical experiments were carried out with different initial configurations of vortices, to evaluate several effects. Firstly, the stability of the vortex compound was evaluated. Most often, it remains compact, but when unstable, it can break as vertically coupled vortex dipoles (called hetons). Secondly, we studied the interaction between a vertically tilted cyclone and lenses. Then, the lenses first undergo anticlockwise rotation determined by the surface cyclone. The lenses can induce alignment or coupling with cyclonic vorticity above them. Only very weak lenses are destroyed by the shear stress exerted by the surface cyclone. Thirdly, under the influence of lens dipoles, the surface cyclone can be torn apart. In particular, the shedding of rapidly moving vortex pairs at the surface reflects the presence of lens dipoles below. More slowly moving small eddies can also be torn away from the main surface cyclone. In this case, they do not appear to be coupled with middle layer vortices. They are the result of large shear-induced deformation. Common and differing features of the vortex interaction, modeled in the framework of the theory of point and finite-core vortices, are noted. Full article

The theory of point vortices is used to explain the interaction of a surface vortex with subsurface vortices in the framework of a three-layer quasigeostrophic model. Theory and numerical experiments are used to calculate the interaction between one surface and one subsurface vortex. Then, the configuration with one surface vortex and two subsurface vortices of equal and opposite vorticities (a subsurface vortex dipole) is considered. Numerical experiments show that the self-propelling dipole can either be captured by the surface vortex, move in its vicinity, or finally be completely ejected on an unbounded trajectory. Asymmetric dipoles make loop-like motions and remain in the vicinity of the surface vortex. This model can help interpret the motions of Lagrangian floats at various depths in the ocean. Full article