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Volume 13
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10.3390/catal13020297
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Article

Synthesis of Phenol-Tagged Ruthenium Alkylidene Olefin Metathesis Catalysts for Robust Immobilisation Inside Metal–Organic Framework Support

by
Maryana Nadirova
1,
Joel Cejas-Sánchez
1,2,
Rosa María Sebastián
2,
Marcin Wiszniewski
1,
Michał J. Chmielewski
1,*,
Anna Kajetanowicz
1,* and
Karol Grela
1,*
1
Biological and Chemical Research Centre, Faculty of Chemistry, University of Warsaw, Żwirki i Wigury 101, 02-089 Warsaw, Poland
2
Department of Chemistry and Centro de Innovación en Química Avanzada, Universitat Autònoma de Barcelona, Cerdanyola del Vallès, Bellaterra, 08193 Barcelona, Spain
*
Authors to whom correspondence should be addressed.
Catalysts 2023, 13(2), 297; https://doi.org/10.3390/catal13020297
Submission received: 31 December 2022 / Revised: 23 January 2023 / Accepted: 25 January 2023 / Published: 28 January 2023
(This article belongs to the Special Issue Metal-Organic Framework Materials as Catalysts)
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Abstract

Two new unsymmetrical N-heterocyclic carbene ligand (uNHC)-based ruthenium complexes featuring phenolic OH function were obtained and fully characterised. The more active one was then immobilised on the metal–organic framework (MOF) solid support (Al)MIL-101-NH2. The catalytic activity of such a heterogeneous system was tested, showing that, while the heterogeneous catalyst is less active than the corresponding homogeneous catalyst in solution, it can catalyse selected olefin metathesis reactions, serving as the proof-of-concept for the immobilisation of catalytically active complexes in MOFs using a phenolic tag.
Keywords: olefin metathesis; ruthenium; metal–organic framework (MOF); immobilisation olefin metathesis; ruthenium; metal–organic framework (MOF); immobilisation

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MDPI and ACS Style

Nadirova, M.; Cejas-Sánchez, J.; Sebastián, R.M.; Wiszniewski, M.; Chmielewski, M.J.; Kajetanowicz, A.; Grela, K. Synthesis of Phenol-Tagged Ruthenium Alkylidene Olefin Metathesis Catalysts for Robust Immobilisation Inside Metal–Organic Framework Support. Catalysts 2023, 13, 297. https://doi.org/10.3390/catal13020297

AMA Style

Nadirova M, Cejas-Sánchez J, Sebastián RM, Wiszniewski M, Chmielewski MJ, Kajetanowicz A, Grela K. Synthesis of Phenol-Tagged Ruthenium Alkylidene Olefin Metathesis Catalysts for Robust Immobilisation Inside Metal–Organic Framework Support. Catalysts. 2023; 13(2):297. https://doi.org/10.3390/catal13020297

Chicago/Turabian Style

Nadirova, Maryana, Joel Cejas-Sánchez, Rosa María Sebastián, Marcin Wiszniewski, Michał J. Chmielewski, Anna Kajetanowicz, and Karol Grela. 2023. "Synthesis of Phenol-Tagged Ruthenium Alkylidene Olefin Metathesis Catalysts for Robust Immobilisation Inside Metal–Organic Framework Support" Catalysts 13, no. 2: 297. https://doi.org/10.3390/catal13020297

APA Style

Nadirova, M., Cejas-Sánchez, J., Sebastián, R. M., Wiszniewski, M., Chmielewski, M. J., Kajetanowicz, A., & Grela, K. (2023). Synthesis of Phenol-Tagged Ruthenium Alkylidene Olefin Metathesis Catalysts for Robust Immobilisation Inside Metal–Organic Framework Support. Catalysts, 13(2), 297. https://doi.org/10.3390/catal13020297

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