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Article

Thermal Decomposition of [AH][M(HCOO)3] Perovskite-Like Formates

1
QuiMolMat Group, Department of Chemistry, Faculty of Science and Advanced Scientific Research Center (CICA), University of A Coruna, Zapateira, 15071 A Coruña, Spain
2
Molecular Spectroscopy Unit, SAI, University of A Coruña, 15071 A Coruña, Spain
*
Authors to whom correspondence should be addressed.
Academic Editor: Guido Kickelbick
Solids 2021, 2(2), 165-176; https://doi.org/10.3390/solids2020011
Received: 14 February 2021 / Revised: 2 April 2021 / Accepted: 4 April 2021 / Published: 2 May 2021
(This article belongs to the Special Issue Feature Papers of Solids 2021)
A systematic study of the thermal decomposition of hybrid perovskites of formula [AH][M(HCOO)3] under inert atmosphere was performed by means of thermogravimetry and simultaneous infrared spectroscopy of the evolved gases. The influence of: (i) the metal ion of the [M(HCOO)3]- framework and (ii) the guest [AH]+ cation, in the composition of the final residue was evaluated. In this work, it has been demonstrated that these materials can be used as precursors of metal or metal-oxide compounds—obtained free of carbon—, and that the composition of the final residue is determined by the standard reduction potential of the metal cation of the framework. View Full-Text
Keywords: coordination polymers; hybrid perovskites; thermolysis; formates coordination polymers; hybrid perovskites; thermolysis; formates
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MDPI and ACS Style

Gómez-Aguirre, L.C.; Otero-Canabal, J.; Sánchez-Andújar, M.; Señarís-Rodríguez, M.A.; Castro-García, S.; Pato-Doldán, B. Thermal Decomposition of [AH][M(HCOO)3] Perovskite-Like Formates. Solids 2021, 2, 165-176. https://doi.org/10.3390/solids2020011

AMA Style

Gómez-Aguirre LC, Otero-Canabal J, Sánchez-Andújar M, Señarís-Rodríguez MA, Castro-García S, Pato-Doldán B. Thermal Decomposition of [AH][M(HCOO)3] Perovskite-Like Formates. Solids. 2021; 2(2):165-176. https://doi.org/10.3390/solids2020011

Chicago/Turabian Style

Gómez-Aguirre, Lilián C., Jorge Otero-Canabal, Manuel Sánchez-Andújar, María A. Señarís-Rodríguez, Socorro Castro-García, and Breogán Pato-Doldán. 2021. "Thermal Decomposition of [AH][M(HCOO)3] Perovskite-Like Formates" Solids 2, no. 2: 165-176. https://doi.org/10.3390/solids2020011

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