Modelling of Open Circuit Cooling Systems Chemical Emissions to River Water via Blowdown Water and Their Impact on the Quality of Effluents Discharged †
Abstract
1. Introduction
2. Materials and Methods
3. Results and Discussion
| Control Parameter | France [34] (Green Quality Class) | Switzerland [35] | Portugal [36] | Spain [37] | Ukraine [38] |
|---|---|---|---|---|---|
| pH, units | 6.0–9.0 | no change | 5.0–9.0 | 5.5–9.0 | 6.5–8.5 |
| N-NH3, mg/L | 1.0 | 0.2 | 1.0 | - | - |
| NO3−, mg/L | 10.0 | 5.6 | 5.0 | 50.0 | - |
| BOD5, mg/L | 3.0 | 2.0–4.0 | 5.0 | 7.0 | - |
| COD, mg/L | 30 | - | - | 30 | - |
| TOC, mg/L | 7.0 | 1.0–4.0 | - | - | - |
| SO42−, mg/L | - | - | 250 | 250 | - |
| Cl−, mg/L | 100 | 100 | 250 | 200 | - |
| PO43−, mg/L | - | - | 1.0 | 0.4 | - |
| TSS, mg/L | 25 | 20 | - | 25 | no increase > 0.75 |
| Dissolved oxygen, mg/L | ≥9 for 50% of monthly; ≥7 for 100% results | no change | - | - | not less than 4.0 |
4. Conclusions
Author Contributions
Funding
Institutional Review Board Statement
Informed Consent Statement
Data Availability Statement
Conflicts of Interest
References
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| Application | Chemical | Purpose | Comments |
|---|---|---|---|
| Scale control | H2SO4 | Prevents | Increases sulfate ion (SO42−) levels in discharge water; requires neutralization to prevent water quality degradation and ecological impact |
| Polyacrylic acid | Dispersant | Used to control TSS; may contribute to organic and chemical load in effluent water | |
| Corrosion control | Sodium nitrite | Inhibitor | Reduces metal oxidation; may release nitrate ions (NO3−), which can affect aquatic life in high concentrations |
| Sodium phosphate | Inhibitor | Helps prevent corrosion; phosphate ion (PO43−) in discharge can lead to eutrophication | |
| Sodium hydroxide | pH adjustment | Controls pH levels in cooling water; can alter pH of receiving water | |
| Biological control | Chlorine, chlorine dioxide | Biocide | Controls microbial growth; residual chlorine and its byproducts in blowdown can be toxic and disrupt biological processes |
| Bromine compounds | Used to enhance biocidal effects; potentially impacting aquatic life | ||
| Corrosion byproduct management | Cu | Corrosion byproduct | Cu released from pipes can be toxic to fish and accumulate in sediment |
| Zn | Zn can still affect aquatic species and contribute to metal accumulation in water body sediments | ||
| Fe | Non-toxic in low concentrations, but can accumulate | ||
| General indicators | - | - | pH, COD, and TSS are indicators of pollution levels and are monitored in blowdown |
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Kuznietsov, P.; Biedunkova, O.; Pryshchepa, A.; Mandryk, O. Modelling of Open Circuit Cooling Systems Chemical Emissions to River Water via Blowdown Water and Their Impact on the Quality of Effluents Discharged. Eng. Proc. 2025, 117, 22. https://doi.org/10.3390/engproc2025117022
Kuznietsov P, Biedunkova O, Pryshchepa A, Mandryk O. Modelling of Open Circuit Cooling Systems Chemical Emissions to River Water via Blowdown Water and Their Impact on the Quality of Effluents Discharged. Engineering Proceedings. 2025; 117(1):22. https://doi.org/10.3390/engproc2025117022
Chicago/Turabian StyleKuznietsov, Pavlo, Olha Biedunkova, Alla Pryshchepa, and Oleg Mandryk. 2025. "Modelling of Open Circuit Cooling Systems Chemical Emissions to River Water via Blowdown Water and Their Impact on the Quality of Effluents Discharged" Engineering Proceedings 117, no. 1: 22. https://doi.org/10.3390/engproc2025117022
APA StyleKuznietsov, P., Biedunkova, O., Pryshchepa, A., & Mandryk, O. (2025). Modelling of Open Circuit Cooling Systems Chemical Emissions to River Water via Blowdown Water and Their Impact on the Quality of Effluents Discharged. Engineering Proceedings, 117(1), 22. https://doi.org/10.3390/engproc2025117022

