Drone Delivery of Dehydro-Sulfurization Utilizing Doubly-Charged Negative Ions of Nanoscale Catalysts Inspired by the Biomimicry of Bee Species’ Bio-Catalysis of Pollen Conversion to Organic Honey
Abstract
:1. Introduction
2. Results
3. Discussion
4. Materials and Methods
5. Conclusions
Author Contributions
Funding
Data Availability Statement
Conflicts of Interest
References
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Catalyst (Doubly-Charged) | ΔTS-1 (eV) | Barrier (%) Change (TS-1) | ΔTS-2 (eV) | Barrier (%) Change (TS-2) |
---|---|---|---|---|
CNT (6,6) | 4.44 | 92.6 | 4.36 | 73.2 |
MoS2 | 1.12 | 70.5 | 1.06 | −10.4 |
GR-28 | 0.49 | 32.7 | 4.59 | 74.5 |
C-60 | 0.44 | 25 | 4.30 | 72.8 |
Doubly-charged only | 0.33 | 0 | 1.17 | 0 |
Catalyst (Doubly-Charged) | Initial 1 (eV) | TS-1 (eV) | Final 1 (eV) | Initial 2 (eV) | TS-2 (eV) | Final 2 (eV) |
---|---|---|---|---|---|---|
CNT (6,6) | 0 | 4.44 | 15.34 | 8.89 | 4.36 | 5.68 |
MoS2 | 10.09 | 11.21 | 10.16 | 0 | 1.06 | 0.95 |
GR-28 | 10.62 | 11.10 | 7.05 | 0 | 4.59 | 10.29 |
C-60 | 0 | 0.44 | 2.31 | 11.92 | 4.30 | 9.53 |
Doubly-charged only | 0 | 0.33 | 0.31 | 0.19 | 1.17 | 1.09 |
Catalyst (Neutral) | TS-1 (eV) | TS-2 (eV) |
---|---|---|
CNT (6,6) | 10.21 | - |
MoS2 | 0.05 | - |
GR-28 | 0.35 | - |
C-60 | 0.03 | 2.37 |
Nanoscale | STEP 1 | STEP 2 | ||||
---|---|---|---|---|---|---|
Molecules | Initial-1 | TS-1 | Final-1 | Initial-2 | TS-2 | Final-2 |
Armchair Carbon Nanotube CNT (6,6) | ||||||
Energy Levels | 0 eV | 4.44 eV | 15.34 eV | 8.89 eV | 4.36 eV | 5.68 eV |
MoS2 Molydisulfide | ||||||
Energy Levels | 10.09 eV | 11.21 eV | 10.36 eV | 0 eV | 1.06 eV | 0.95 eV |
Gr-28 28-atom Graphene | ||||||
Energy Levels | 10.62 eV | 11.10 eV | 7.05 eV | 0 eV | 4.59 eV | 10.29 eV |
C-60 Fullerene 60 | ||||||
Energy Levels | 0 eV | 0.44 eV | 2.31 eV | 11.92 eV | 4.30 eV | 9.53 eV |
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Suggs, K.L.; Samarakoon, D.K.; Msezane, A.Z. Drone Delivery of Dehydro-Sulfurization Utilizing Doubly-Charged Negative Ions of Nanoscale Catalysts Inspired by the Biomimicry of Bee Species’ Bio-Catalysis of Pollen Conversion to Organic Honey. Hydrogen 2023, 4, 133-145. https://doi.org/10.3390/hydrogen4010009
Suggs KL, Samarakoon DK, Msezane AZ. Drone Delivery of Dehydro-Sulfurization Utilizing Doubly-Charged Negative Ions of Nanoscale Catalysts Inspired by the Biomimicry of Bee Species’ Bio-Catalysis of Pollen Conversion to Organic Honey. Hydrogen. 2023; 4(1):133-145. https://doi.org/10.3390/hydrogen4010009
Chicago/Turabian StyleSuggs, Kelvin L., Duminda K. Samarakoon, and Alfred Z. Msezane. 2023. "Drone Delivery of Dehydro-Sulfurization Utilizing Doubly-Charged Negative Ions of Nanoscale Catalysts Inspired by the Biomimicry of Bee Species’ Bio-Catalysis of Pollen Conversion to Organic Honey" Hydrogen 4, no. 1: 133-145. https://doi.org/10.3390/hydrogen4010009
APA StyleSuggs, K. L., Samarakoon, D. K., & Msezane, A. Z. (2023). Drone Delivery of Dehydro-Sulfurization Utilizing Doubly-Charged Negative Ions of Nanoscale Catalysts Inspired by the Biomimicry of Bee Species’ Bio-Catalysis of Pollen Conversion to Organic Honey. Hydrogen, 4(1), 133-145. https://doi.org/10.3390/hydrogen4010009