1. Introduction
Despite widespread belief, increasing cement content may not result in higher quality or faster construction schedules. However, concrete with lower cementitious content and more substitution of cementitious materials can decrease environmental impact while still reaching sufficient strength on time to avoid construction delays and last longer [
1,
2,
3,
4,
5].
Overstrength caused by high cementitious content may induce concrete cracking. This occurs because (1) higher concrete temperature can increase the temperature differential between core and surface and induce thermal contraction cracks; (2) the higher the cementitious content, the higher the heat of hydration, which may increase the concrete porosity and engender the delayed ettringite formation (
DEF) depending on the water availability and internal sulfate release; and (3) high cementitious contents can require higher water contents, which may bleed, evaporate and increase concrete permeability, hence the ingress of external agents causing internal expansions in concrete [
2,
3,
4,
5]. Pathologies can occur in a few pours, during the construction phase, or even many years after construction. When deficiencies in concrete are identified before the end of the construction phase, contractors often need to perform repairs. Such repairs usually are time-consuming, delaying construction completion and increasing costs.
Many contract terms have also induced the increase in
f’cr to become the norm in construction by offering bonuses to contractors to expedite construction. For example, the “No Excuse Bonus” terms have encouraged builders to work more quickly, fit fast-track schedules and minimize inconvenience during construction (e.g., traffic delays). This incentive, very common in building contracts, bonds and rewards a contractor for early completion but may affect the quality and durability of the constructed element. For example, using admixtures to accelerate setting time associated with high contents of fast-reacting cement can induce concrete pathologies [
5]. However, both contractors and owners may fail when bonuses reward fast but deficient construction. Contractors can end the contract even by using bonuses to offset extra construction costs. Owners can receive lower-quality assets with potential maintenance costs down the line.
The article is organized as follows. In the section that follows, an overview of cement production and strategies that have been developed to reduce the environmental impact of the cement industry are provided. Additionally, the case of limestone mining in Florida is discussed to provide context and motivation for the study. Following this, the materials and methods are considered. Next, findings from the three concrete mixtures studied are presented. Finally, the strategies to mitigate additional overdesign (AOD) to improve the quality of the structures are presented, after which a brief conclusion ends the paper.
2. Literature Review
Concrete mixtures are typically proportioned following the American Concrete Institute (ACI) standard 211-1 [
6] or similar. The ACI 318 [
4] specifies that concrete should reach a minimum required compressive strength,
f’cr, higher than the specified design compressive strength
f’c. The ACI 214R [
7] defines the
f’cr as the average compressive strength guaranteeing that only one percent of measurements fall below the
f’c. The difference between
f’cr and
f’c is defined as overdesign (
OD).
The
OD calculation is based on the availability of relevant data for similar concrete mixtures. ACI 214R [
7] recommends modification factors for standard deviation (
S) from 1.16 when 15 tests are available to 1.0 when 30 or more compressive strength (
σ) tests are available. When a concrete mix design has a normal distribution of
σ test results, Equation (1) can be used:
where
f’cr is the required compressive strength of concrete,
f’c is the specified compressive strength of concrete,
z is the reliability factor (typically 2.33 in the U.S. for acceptance of the 1% failure rate), and
S is the standard deviation of a concrete series.
When fewer than 15 compressive strength tests are available, the overdesign determination relies upon the
f’c level. In such a case, 7 MPa is added to
f’c when
f’c is less than 21 MPa, 8 MPa is added to
f’c when
f’c is greater or equal to 21 MPa and less than or equal to 35 MPa, and Equation (2) should be used when
f’c is greater than 35 MPa:
where
f’cr is the required compressive strength of concrete and
f’c is the specified compressive strength of concrete.
During construction, concrete specimens are cured in moisture rooms or curing tanks with lime water. Typically, after 7 and 28 days of curing,
σ is tested and compared to
f’c [
5,
8,
9]. Ultimately, concrete is considered adequate if
σ falls above
f’c. Such evaluations are specified in contracts that hold builders and concrete producers liable for concrete failures, and therefore efforts are made to keep σ higher than the minimum. To accomplish this, producers tend to increase the cementitious content in concrete. However, it is widely known that the water-to-cementitious ratio (w/cm) is the primary factor that affects concrete strength [
5], not the amount of cementitious materials. The prevailing, yet flawed, logic behind this is that the higher the
OD, the lower the risk of obtaining strength results below
f’c.
The construction materials industry is a significant user of the world’s natural resources. Current practices and research in this field focus on developing sustainable structural materials and long-lasting infrastructure. This research agenda is timely and influential because, despite the advances in concrete technology and materials engineering in the last decades, concrete has presented severe durability problems in the U.S., requiring large amounts of money to repair and replace concrete structures. This occurs primarily due to failures in the design and execution of structures and the specification of materials in building codes [
5,
10]. For those reasons, this study investigates the actual cementitious materials content in concrete required to meet the
OD. Although standard guidelines require concrete
OD for decades, such a threshold can be abused to avoid results below the
f’c. The present study is a first-of-its-kind (based on field data) and will be helpful for the development of concrete technology. Having consistent findings obtained from different data (field and laboratory-based) contributes to expanding and deepening one’s knowledge of concrete durability and
OD.
2.1. Portland Cement Production
Portland cement (
PC) is the most used construction material on Earth because it is adaptable, reliable, accessible and affordable. Over 159 countries manufacture clinker, the primary ingredient in cement [
11]. Four billion tons of cement are manufactured each year worldwide. In 2020, the United States (U.S.) was the world’s fourth-largest producer of cement (90 million metric tons), behind China (2.2 billion metric tons), India (340 million metric tons) and Vietnam (96 million metric tons). In the U.S., cement is produced at 98 plants in 34 states and two in Puerto Rico. Florida alone has eight large cement plants producing 6 million metric tons of
PC and 8 million metric tons of clinker per year [
12].
The production process for Portland cement is energy—and pollution-intensive. Due to its substantial environmental impact, the cement industry has focused on reducing carbon dioxide (CO
2) emissions, accounting for 5–10% globally [
5,
10,
13,
14,
15]. Therefore, reducing the cementitious materials in concrete can substantially reduce the environmental impact of Portland cement production.
For
PC production, limestone, aluminum, iron and silica are blended into a raw meal that passes throughout the process. Next, the raw meal is pre-heated as it flows down into towers with gasses heated by outlet heat from kilns. Finally, pre-heated meals are burnt in kilns at approximately 1500 °C, which is the required temperature to generate the chemical reactions needed to form the clinker. Pre-heating towers have been incorporated into the system to optimize energy consumption because the raw meal arrives at higher temperatures at kilns, and less burning is needed to reach the required temperatures. Raw materials take about 10 s from top to bottom of pre-heating towers, increasing its temperature from 100 to 870 °C [
16].
Efforts to reduce the environmental footprint of the cement industry include replacing inefficient equipment with more environmentally friendly versions, using alternative fuels, clean energy systems, innovative technologies for CO
2 capture and storage and the production of blended cement. Cement can be replaced with alternative raw materials such as coarse aggregates (e.g., industrial waste products) [
17,
18,
19,
20] and supplementary cementitious materials (SCM) like ground granulated blast furnace slag (GGBFS, Slag cement) and fly ash [
21]. With these substitutions, U.S. producers decreased their use of fossil fuels by over 15% and the total energy required to produce a ton of cement by approximately 40%.
2.2. Portland Limestone Cement (PLC) Production
Portland limestone cement (PLC) is a blended cement that requires reduced limestone burned in kilns, decreasing CO
2 emissions and the total amount of mined limestone. Due to its lower clinker-to-cement ratio, PLC is considered an eco-friendly cement, which has become widely used [
22,
23,
24]. The creation of Portland limestone cement (PLC), dubbed Type IL cement, is also part of the industry effort to reduce greenhouse gas (GHG) emissions. PLC production represents an effort to reduce the environmental impact of cement production; however, cement consumption in concrete remains a problem that can be particularly acute in some regions. For example, South Florida in the U.S. is an intensive producer of cement, limestone aggregates and concrete. The high-quality limestone produced in the region is used in cement and most concrete production because of its suitable hardness. Thus, although PLC can reduce some of the limestone demand, the potential production of concrete with high cement contents can increase pressure on the local deposits and challenge the long-term availability of limestone.
Currently,
PCL is produced at three plants in Florida.
Figure 1 illustrates the locations of the limestone formations and PLC plants used in this study.
Mill certificates from these plants show that the Blaine fineness is 51% higher than the standard fineness of Type I/II cement. Although finer than Type I/II, PLC is expected to produce similar heat during hydration because the Calcium Oxide (CaO) contents are comparable in both cement types.
PC is produced by heating limestone, silica, alumina and iron in kilns at approximately 1500 °C to produce clinker. The clinker passes through ball mills to achieve the target particle size distribution (
PSD) and fineness. Afterward, up to 5% of gypsum is blended to control the setting properties, adding sulfate to the cement’s chemical composition [
5,
10,
16,
18,
25]. The cement used in commercial construction in the U.S. must be produced conforming to either ASTM C150 [
26] or C595 [
27], besides AASHTO M85 [
28] for PC and M240 [
29] for blended cement for road construction.
PLC differs from
PC in its manufacturing process. Although both cement types use similar clinker, PLC can receive up to 15% ground limestone in the finishing mill. Manufacturers claim that this reduces their CO
2 emission rates without increasing cost or reducing performance. The
PSD of PLC is also enhanced and often achieves higher cementitious efficiency [
11,
30,
31].
2.3. Limestone Mining
Limestone is a sedimentary rock composed of over 50% of carbonate minerals, primarily calcium carbonate (CaCO
3). The limestone content in cement is determined by its chemical composition, which varies in purity, consistency and hardness based on location.
PC is one of the most important products made from limestone, comprising at least 70% of CaCO
3 by mass in cement production composition [
11,
32].
Florida produces 92% of the in-state demand for limestone. The hardest limestone for aggregate materials occurs in small areas on the Southeast coast (Lake-Belt), which is the source of 95% of the crushed limestone used in concrete statewide. In addition, the state has an abundance of soft limestone, typically unsuitable for structural concrete.
Figure 2 shows the crushed-stone production in Florida between 2001 and 2015. Limestone mining has increased steadily after the 2008 national economic crisis [
11].
2.4. Structural Resilience
Structural safety is paramount. Işık et al. [
33] reported that low concrete strength is the primary cause of reinforced concrete structure failures under significant loadings, such as earthquakes. The study suggests that increasing the concrete strength could optimize structural resilience.
Danesh et al. [
34] found that the optimization of reinforced concrete structures appears to be challenging due to the variety of potential structural solutions and element dimensions with related reinforcement configurations. In addition, some of the current design codes for seismic design of structures frequently generate overdesigned solutions. Such findings emphasize the need to investigate material overstrength toward optimal concrete properties.
Işık et al. [
35] also published that concrete minimum cover should be prioritized due to the critical role in protecting steel from environmental effects. Inadequate concrete cover thickness can increase the base shear force, weaken reinforcement strength over time, and negatively affect the structural performance to withstand earthquakes and other demanding loads. Antunes [
36] studied the temperatures developed in several massive elements and concluded that the dimensions are the most relevant parameter to control the peak temperatures in elements, followed by the concrete temperature at placement.
It appears that concrete strength, cross-section dimensions influenced by the concrete cover and structural design considerations, volumes of the concrete pour and concrete temperatures can be affected by the cementitious contents in concrete. Therefore, optimizing concrete composition can help design more resilient structures.
5. Results and Discussion
Figure 4 shows the
σ results for the three concrete mixtures studied. Three specimens were prepared for testing at 7 days and three at 28 days for every 40 m
3 of concrete delivered in most job sites, while some only cast specimens for 28 days for contractual reasons. Two specimens were discarded due to damage during transport to the laboratory. A total of 345 specimens were tested for
σ at 7 days and 613 at 28 days. The sets investigated represented 8200 m
3 of placed concrete. The
f’c of the three mixtures was exceeded within 7 days, which is common in today’s construction. Contractors may reduce construction time by removing forms earlier so that the next group of elements can be built and buildings can be completed quickly.
The
σ test results from different batch plants can vary. According to ACI 214R [
7], these variations typically originate from two sets of conditions: (1) Batch-to-batch due to ingredients or proportions of ingredients, mixing, transporting, placing, sampling, consolidating and curing; and (2) Within-batch due to differences in sampling, specimen preparation, curing and testing procedures.
The primary source of
σ variation in this study should be batch-to-batch because of the different ready-mixed concrete plants that produced the concrete. The data were statistically evaluated based on
S, which is the criterion in ACI 214R to classify the quality control of concrete production per concrete strength. For general construction and
f’c less than 35 MPa, the batch-to-batch control is considered excellent when
S is below 2.8 MPa, very good when
S is between 2.8 and 3.4 MPa, good for
S between 3.4 and 4.1 MPa, fair for
S between 4.1 and 4.8 MPa, or poor for
S above 4.8 MPa. For general construction and
f’c greater or equal to 35 MPa, the batch-to-batch control is considered excellent when
S is below 7 MPa, very good when
S is between 7 and 9 MPa, good for
S between 9 and 11 MPa, fair for
S between 11 and 14 MPa, or poor for
S above 14 MPa. At 28 days, two cylinders presented
σ lower than the
f’c of 41 MPa, representing 0.4%. None of the cylinders for 28 and 44 MPa tested below the
f’c.
Table 3 shows that the data analyzed in this study were classified between good and excellent, which indicates that the entire operational chain, including ingredients, mixing, transporting, placing, sampling, consolidating and curing, was developed according to the standard procedures. The complete σ data set can be found in
Appendix A.
The concrete production has yielded relatively low
S because the ingredients are produced under rigorous quality standards. For example, cement production has adopted several technological measures to control raw materials’ physical and chemical properties. Typically, from the limestone quarry until the raw materials are fed into kilns, sensors measure PSD, relative humidity and samples are taken for microscopical determination of the chemical composition. Cement quality is highly controlled during construction, where fresh and hardened properties are verified. If anomalies are detected, the entire production and logistics chain can be broken down to identify the points of failure. For those reasons, it is customary to observe rigorous quality control in concrete construction because all players need to work according to the standards [
5].
The test results presented were used to determine
RCC for each concrete mixture, as shown in
Table 4. The
f’cr values were calculated using Equation (1) based on the
S for each mixture using a value of
z = 2.33. The difference between the
σ reached by each concrete mixture and the
f’cr, the
AOD, was calculated and multiplied by
CCR to obtain the additional cementitious used in the mixtures. The
CCR was calculated by dividing the
CC of the mixtures by the σ achieved. The
RCC is the difference between the
CC and the additional cementitious. The mixture
f’c = 28 MPa used 300 kg/m
3 of cementitious, and its
RCC was 282 kg/m
3. The mixture
f’c = 38 MPa used 395 kg/m
3 of cementitious, and its
RCC was 350 kg/m
3. The mixture
f’c = 44 MPa used 450 kg/m
3 of cementitious, and its
RCC was 372 kg/m
3. The
RCC calculations are aligned with the recently developed research. To illustrate the extent to which cementitious content can be decreased, it was found that it can be reduced by 25% without compromising the compressive strength and consistency. Such reductions can be achieved by optimizing binary and ternary aggregate systems [
16,
17,
18,
19,
25,
41,
42].
Although concrete should meet the
f’cr to mitigate
σ results below the
f’c, it appears that strategies to mitigate
AOD should be pursued to improve the quality of the structures. How much time is saved by increasing the cementitious content in concrete? Based on the strength developments of the three types of concrete, one can observe that all mixtures reached the 28-day required strength between 5.5 and 6.5 days of the pour. However, ACI 318 [
4] recommends that forms should be removed when the removal will not affect the serviceability of the structure. It appears that the strength reached the targets three weeks earlier, indicating that both
AOD and
OD can be reduced so that the
f’cr is achieved later.
That leads to the second strategy: reducing the confidence interval (
CI) from 99 to 95%. Confidence intervals between 95 to 92.5% have been successfully used to design and control the compressive strength of concrete in Spain, Belgium and Brazil, for example [
43,
44,
45,
46,
47,
48,
49,
50]. Per ACI 214.R [
7], the
z would decrease from 2.33 to 1.65 by narrowing the
CI. Such a reduction can diminish the
OD, leading to lower cementitious contents in concrete and slower strength development. It is important to note that the reduction of the
CI is positive statistically because the failure threshold is 5%, that is, the acceptance range is narrower. Hence, high-quality concrete can be produced with lower strength.
The third strategy relates to the misconception that strength development requires long curing times, leading to construction delays. The structure will be subjected to service loads several months or years after construction, but the strength was reached in less than one week. Such a gap between strength achievement and service can be addressed by designing concrete mixtures to reach the f’cr at 28 days or later if agreed in special provisions.
The first step to lowering the cementitious content in concrete should be to optimize the
AOD because it can be accomplished based on the current specifications.
Figure 5 demonstrates the difference in cementitious content needed to produce concrete with a target strength. The curve from the trial batches shows a range of cementitious content (
CC) between 300 and 450 kg/m
3 materials to produce concrete between 28 and 44 MPa. The optimized (
RCC) curve shows the range of cementitious content between 282 and 372 kg/m
3 of cementitious materials to produce concrete between 28 and 44 MPa. Hence, concrete with similar strength could be obtained with a lower cementitious content.
6. Conclusions
Although decades-old standard guidelines require concrete overdesign, these standards can be abused, leading to environmental damage. This investigation was carried for the first time and will be particularly useful to concrete technology. Studies assessing the actual overdesign (OD) magnitudes with field data are rare.
This study aimed to assess the high current contents of combined Portland cement and slag cement in concrete and the compressive strengths obtained versus the strength (σ) required in project plans. The required cementitious materials content (RCC) to meet the OD was determined based on 958 compressive strength tests (σ) representing 8200 m3 of ready-mixed concrete for threshold buildings. The following conclusions can be drawn from the results regarding the tested concrete:
The actual OD in the concrete mixtures was 7 to 21% higher than required.
The cementitious materials content should be reduced between 6 and 17% so that concrete can reach the required compressive strength (f’cr) without cement overconsumption.
The overall reduction of cementitious content in concrete can increase the quality of the built elements and reduce the use of natural resources required to build. However, the implementation still presents challenges in reducing the CI from 99 to 95% and breaking the misconception that cement excess in concrete does not accelerate construction. The main reasons for these recommendations are the estimate of substantial savings in the long term and an increase in concrete durability, and more rational use of natural resources.
The novel and rare assessment presented in this article should be contrasted to recent and relevant publications. For example, recent studies have investigated the effects of lower cementitious paste volume in concrete, mainly in the laboratory, and found that it could be reduced without affecting concrete strength and durability evaluated through rapid chloride penetrability testing (RCPT) and surface resistivity (SR) tests [
51,
52]. The consistency and similarity in findings in this article to such published research indicate that research predominantly developed with field-prepared concrete and specimens can provide accurate outcomes that can be compared to those of laboratory-based experiments, enabling cross verification and triangulation of results.
Concrete and cement demand is expected to increase in the near future. It is in the construction industry’s interest to consider reducing cementitious content in concrete as the trend towards more environmentally friendly building materials continues.