1. Introduction
The last few decades have been characterized by a significant increase in the importance of cryogenic applications above 110 K. This has mainly been due to the growing liquified natural gas (LNG) industry [
1], which requires the solutions to either cool down and finally liquefy natural gas [
2,
3,
4,
5,
6,
7,
8,
9], or reliquify LNG boil-off [
10,
11], or upgrade biogas by cryogenic carbon dioxide removal [
12]. Another emerging application and market is whole body cryotherapy [
13], which requires between a few and tens of kilowatts of cooling power, cryoelectronics [
14], cryopreservation [
15], long-term storage [
16] and cryomilling [
17,
18,
19,
20]. An overview of cryogenic applications above 110 K is presented in
Figure 1.
Cooling power within the temperature range of 110 to 150 K on an industrial scale is provided mainly by reverse Brayton cycles [
8,
10,
21,
22], Claude cycles [
23], or Kapitza [
10] and hydrocarbon-based cascade solutions [
8,
21]. These solutions are mainly used as refrigeration cycles of LNG boil-off gas reliquefaction systems. In addition to industrial-scale systems, the increase in demand for cooling power at temperatures above 110 K requires the development of new solutions dedicated to smaller capacities, such as cascade cryorefrigerators [
4,
5,
6,
24,
25], mixed-refrigerant Joule–Thomson cryocoolers [
26,
27,
28,
29,
30], combined cascade solutions [
31,
32,
33] and modified Joule–Thomson cryocoolers [
26,
34]. Some of these solutions can be based on standard mass-produced refrigeration compressors [
27,
28,
29]. Standard refrigeration compressors are cost-effective and reliable solutions, but on the other hand, they are subject to strict limitations in terms of operating pressures and temperatures. Due to these limitations, some of the proposed systems based on standard refrigeration compressors cannot be built at very high discharge pressure [
5,
6,
9], very low suction temperatures [
11], or very high discharge temperatures [
31]. This article aims to assess the potential of three-stage cascaded cryorefrigerators based on standard refrigeration compressors in cryogenic applications above 110 K. The investigation includes an analysis of the available refrigerant configurations, modeling of the system under the operating limitations of the refrigeration compressors and a study of the influences of the system architecture. The study provides vital information on the feasibility and performance limits of three-stage cascaded cryorefrigerators. According to the authors’ knowledge, similar work has not been published yet.
2. Materials and Methods
The analysis carried out aimed to assess the applicability of different refrigerants characterized by
in the three-stage cascaded cryofrigerator model. To be classified as applicable, the refrigerant must enable thermal coupling with heat sources: within specified ranges of suction and discharge pressures, with sufficiently low discharge temperature. According to European regulations on fluorinated greenhouse gases and the regulation [
35] from 1 January 2020, the use of fluorinated greenhouse gases, with a GWP of 2500, is prohibited, with the exception of military use and applications designed to cool products to temperatures below −50 °C. Therefore, in the application considered, the use of refrigerants with global warming potentials (GWPs) greater than 2500 is exceptionally allowed. A similar study was carried out by [
31]. Furthermore, due to the maximum allowable pressure of refrigeration compressors of 30 bar [
36,
37,
38,
39,
40] and the limitation of the suction pressure to at least 0.2 bar [
41,
42], the refrigerant should allow its stage to be coupled with the neighboring one. Several single component refrigerants were taken into account. Some of the initially included refrigerants, such as R161, R218, R22, R32, R41, and R143a, were found not to be applicable due to strict operational limits; it was not possible to thermally couple them to other cascade stages. The condensation or evaporation temperatures do not match the temperatures of the neighboring stages, and a further increase in discharge pressure or decrease in suction pressure was not possible due to the operational limitations of the compressors. The remaining refrigerants are briefly described in
Table 1 and their saturation curves are presented in
Figure 2. The analysis considered non-flammable (A1), flammable (A2, A2l and A3) and zero-ODP refrigerants. The saturation curves were drawn at 0.5 bar. One can see that only flammable R50 allows temperatures below 125 K. On the other hand, R50 is characterized by a critical temperature of 190.6 K, which means that to apply this natural refrigerant as a third stage working fluid, it is required to reach the temperature of 185.6 K by means of only two stages. Moreover, substantial differences in the heat of evaporation between natural refrigerants (HCs and HOs) and synthetic refrigerants (CFCs, HFCs and PFCs) can be seen. This affects the required mass and volumetric flows of the refrigerant.
The analysis was carried out for two different configurations of the three-stage cascaded refrigeration systems, which are presented in
Figure 3 and
Figure 4. The first system considered, presented in
Figure 3, applies only single-stage compression at each stage. The second configuration, presented in
Figure 4, is more complex, having compression in two stages, in the second and third stages. These two configurations were chosen to highlight the performance improvement achieved at the expense of a more complex system architecture. Two-stage compression was not considered in the first stage, as this stage is actually a typical refrigeration cycle which is unlikely to operate with two-stage compression. In addition to the cascade systems schemes analyzed,
Figure 2 and
Figure 3 also contain Ts diagrams for each stage with the given characteristic points of the systems. To model the performance of the whole system, all the thermodynamic states at each stage have to be determined. This was performed using CoolProp [
44], which is an open thermodynamic database packaged with Python and Excel. The thermodynamic state was determined for the known pair out of five considered thermodynamic parameters: temperature, pressure, enthalpy, entropy, and quality. The design procedure of each stage is similar; therefore, it is presented using the example of the second stage with two-stage compression. Initially, the assumption of the stage evaporation temperature
and the stage mass flow rate
is made. The modeling takes into account the assumed pressure losses of the heat exchangers, which are consistent with [
3] and are given in
Table 2. The isentropic efficiency of the compressors is not constant and depends on several operational factors, such as the compressed fluid’s pressure ratio, as shown in
Figure 5. It typically ranges from 60 to 75% [
36,
45,
46]. There is no comprehensive work describing the method for obtaining the actual efficiency of the compressor, and therefore it is very common to assume this value as constant even in very extensive analyses that include different sets of fluids and operating conditions [
26,
47,
48,
49,
50]. Isentropic efficiencies generally range from 60% [
50] to 80% [
26,
48,
51], but an isentropic efficiency of 100% can also be found [
49,
52,
53]. Moreover, manufacturers generally specify the minimum suction gas temperature [
36,
38].
The condensing pressure is determined on the basis of the higher-stage evaporation temperature.
This allows us to determine all the pressures on the high-pressure side:
The pressures on the low-pressure side are governed by the evaporation temperature
:
Pressures between compression stages
and
are determined on the basis of the pressure ratio
:
Temperatures
,
, and
are determined based on modeling assumptions.
Thermodynamic states at the compressor discharges are determined using isentropic compression as a reference:
The thermodynamic state 2.6 is evaluated using the recuperator heat balance:
The specific enthalpy of 2.8 is determined as follows:
The modeling parameters for Equations (1)–(17) are given in
Table 2.
The results are then iterated, according to the procedure presented, in order to meet the requirements of saturated liquid at point 2.7 and to get close to the operating limits. Therefore, the results can be interpreted as limiting the performance of the system. The method of determining the thermodynamic state of the characteristic points of the system is summarized in
Table 3.
The aim of this paper is to point out the operational limits of three-stage cascaded refrigeration systems consisting of typical refrigeration equipment: compressors, heat exchangers, expansion valves, etc. Therefore, the operation of each stage was designed to reach the operational limits of the most crucial components of this kind of system—the compressors. Other elements do not introduce significant operational limitations that should be taken into account. The operation limitations of the refrigeration compressors are based on the manufacturer’s specifications [
36,
37,
38,
39,
40,
42] and the maintenance practices for the refrigeration systems [
41,
42] that are valid for open and semi-hermetic units and all applicable fluids.
The compressor suction pressure cannot be less than 0.2 bar [
41,
42].
Compressor discharge pressure cannot exceed 30 bar [
36,
37,
38,
39,
40].
Gas temperature at the compressor suction cannot be less than 240 K [
37].
Gas temperature at the compressor discharge can not exceed 393 K [
36,
41,
42].
It is recommended that the compressor suction pressure be maintained above 1 bar. Nevertheless, it is allowed to lower it below this value [
41,
42]. This results in the possibility of air penetration into the system or overheating of the compressor motor in the case of semi-hermetic units.
Figure 5 presents the modeling flowchart. The modeling started with the selection of fluids and parameters and variables: pressure drops in system components, heat rejection temperature
, compressor efficiency (see
Table 2), and stage temperature difference (see
Table 4).
Then, the first stage was designed as long as its operation is within assumed operational limits. This was done by adjusting the evaporation temperature and the mass flow. For stages with two-stage compression, an additional parameter is available, which is the pressure ratio of the second compressor . After reaching the limits, the second stage and then the third stage were designed. If, because of the fluid selection, it was not possible to design the stage to reach proper temperatures, the modeling was interrupted. In this way, certain fluids (R161, R218, R22, R32, R41) were eliminated from further analysis at the modeling stage.
The performance of the three-stage cascaded refrigeration system was expressed by means of the COP and Carnot efficiency, which refers the obtained COP compared to the Carnot COP. The Carnot efficiency allows one to eliminate the influence of the cooling power temperature
on COP and to compare cases characterized by different cooling power temperatures. The COP of the system is expressed as the cooling power available in the third stage evaporator divided by the sum of the compressors’ power demand:
Carnot COP is obtained using heat rejection and cooling power temperatures:
Carnot efficiency is a ratio of COP and Carnot COP:
3. Results
One can see that the application of single-stage compression in a three-stage cascaded system does not allow for the use of R50. This is not possible because to apply to R50 the evaporation temperature of around 172 K (saturation temperature at maximum discharge pressure) would have to have been achieved by means of two stages. The lack of the possibility to use R50 has a considerable impact on the cooling power temperatures reached, which for single-stage compression cases are not lower than 144 K. This was due to much higher evaporation temperatures with R14 than R50, which is clearly shown in
Table 1. Moreover, a significant impact of flammable refrigerants can be seen in the enhancements in COP and Carnot efficiency. The sets of flammable fluids applied in simulations 1.2 and 1.3 resulted in 12–30% higher Carnot efficiency than those based only on non-flammable refrigerants (1.1, 1.4–1.6). This occurred due to the considerably greater heat of evaporation of flammable compounds. The application of two-stage compression significantly enhances the reachable cooling power temperatures: the discharge temperature limitation can be overcome (limitation of discharge pressure is still valid). This meant for R50 a cooling power temperature drop all the way down to 127 K. For two-stage compression systems with R14, the cooling power temperature did not drop below 135 K. The results show the general advantage of flammable refrigerants. The application of R290, R170, R1150, R1270 or R50 allows for a significant increase in Carnot efficiency compared to other refrigerants. This results from considerably greater heat of evaporation of flammable compounds, which can be seen in
Table 1.
One of the most substantial operational limits of refrigeration compressors is the gas discharge temperature, which cannot exceed 393 K. This puts a significant limitation on the pressure ratio obtained, which, in turn, affects the stage temperature difference (the difference between the condensation and evaporation temperatures of the stage). The gas discharge temperature can be lowered by lowering the gas suction temperature. In the case of the analyzed system, this can be achieved by increasing the recuperation temperature difference
or by two-stage compression. An increased recuperation temperature difference can keep the gas discharge temperature within the limits, but at the expense of a reduced COP because of worsened recuperation.
Figure 7,
Figure 8 and
Figure 9 present the influences of the difference in recuperation temperature on the applicability and performances of three different refrigerant kits: flammable (R290, R1150, R50), non-flammable (R125, R23, R14) and mixed (R125, R1150, R50). Due to the limitation of the suction gas temperature to at least 240 K, the recuperation temperature difference cannot be greater than 73 K. The results show that the application of flammable and mixed sets of refrigerants (flammable along with non-flammable) requires a recuperation temperature difference of at least 55 K for mixed refrigerants and 61 K for flammable. For a non-flammable refrigerant kit, the recuperation temperature difference can be much lower. Increasing the recuperation temperature difference is crucial for the applicability of the given refrigerant kits and reachable cooling power temperatures. This is done at the expense of systems’ COP, and it causes, despite a cooling power temperature drop, a decrease in Carnot efficiency.
The performance of the complete system depends on the performance of each stage; therefore,
Figure 10,
Figure 11 and
Figure 12 present the performances of the first, second and third stages, respectively. Stage performance is expressed as stage temperature difference (the difference between stage condensation and evaporation temperatures), COP and Carnot efficiency. In
Figure 10, one can see that the first stage has the highest potential for decreasing temperature. The temperature differences range from 88 to 103 K, which means that within the given limitations, the evaporation temperature of 210 K can be reached. Such a great temperature difference results in a reduction in COP ranging from 0.6 to 1.1, which corresponds to 0.3 to 0.42 Carnot efficiency. This also confirms that two-stage compression in cases of the first system stage not being required. It is due to the fact that refrigerants matching the first stage have complex molecules which are characterized by lower heat capacity ratios. This significantly affects the discharge temperature.
Figure 11 presents the performance of the second stage with respect not only to the applied refrigerant but also to the type of compression (single stage or two stage). Application of two-stage compression allows one to enhance the stage temperature difference. The highest temperature differences can be obtained using R13 (non-zero-ODP refrigerant) and flammable refrigerants R170 and R1150. The application of zero-ODP refrigerants from the A1 group limits the temperature difference to less than 35 K.
Figure 12 presents the performance of the third stage of the three-stage cascaded refrigeration system. This stage can be realized only by applying R14 or R50 (only by using two-stage stage compression). The temperature difference was limited to 40 K for single-stage compression and 43 K for two-stage compression. Such a small increase in the temperature difference for two-stage compression resulted from a lower covered temperature range: R50 can be applied only if the condensation temperature of about 172 K is satisfied (due to the compressor pressure limitation). In contrast, R14 requires only a condensation temperature of 220 K.
A factor which also limits the applicability of three-stage cascaded refrigeration systems is the gas suction pressure of the compressors. Lowering the gas suction pressure reduces the evaporation temperature, but on the other hand, the decrease leads to an increase in required volumetric capacity of the compressor, and increases in the pressure ratio and in gas discharge temperatures—or, in the case of semi-hermetic compressors, to technical problems, such as overheating of the electric motor winding. Operation of the system with subatmospheric pressures will also reverse the consequences of leakage: instead of rejecting the refrigerant into the atmosphere, air will be sucked into the system, causing its contamination.
Figure 13 and
Figure 14 show the gas suction pressures for each stage for each of the cases analyzed.
It can be seen that most of the cases analyzed require operation with subatmospheric gas suction pressures. Only case 1.3 operates with all gas suction pressures above 1 bar, but this, according to
Figure 5, results in a cooling power temperature of around 150 K. This significantly limits the applications of such systems: LNG could be reliquefied only under saturation pressures greater than 10 bar. Furthermore, the refrigerant configuration is based on flammable R1270 and R1150, which are not allowed in many cryogenic applications, such as cryotherapy. To mitigate the issue of a low suction pressure, the following approaches can be used:
Limit the cooling power temperature to the saturation temperature corresponding to 1 bar. This approach is applicable only to R14 and would limit the cooling power temperature to 144.9 K.
Minimization of pressure drops. The assumed evaporator and recuperator pressure drops comprise 10% of the gas suction pressure. Therefore, minimizing these losses can increase the gas suction pressure by 20%.
Increasing number of stages. Ultimately, the number of stages would probably need to increase to four. This significantly increases the complexity of the system and questions the legitimacy of the use of such systems.